CN107629838A - A kind of environment-friendly lubricating oil - Google Patents

A kind of environment-friendly lubricating oil Download PDF

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Publication number
CN107629838A
CN107629838A CN201610576562.XA CN201610576562A CN107629838A CN 107629838 A CN107629838 A CN 107629838A CN 201610576562 A CN201610576562 A CN 201610576562A CN 107629838 A CN107629838 A CN 107629838A
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CN
China
Prior art keywords
oil
dialkyl
dithiophosphate
environment
lubricating oil
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610576562.XA
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Chinese (zh)
Inventor
王平淀
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tianjin Zhongde Lawter Fuchs Petroleum Products Co Ltd
Original Assignee
Tianjin Zhongde Lawter Fuchs Petroleum Products Co Ltd
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Application filed by Tianjin Zhongde Lawter Fuchs Petroleum Products Co Ltd filed Critical Tianjin Zhongde Lawter Fuchs Petroleum Products Co Ltd
Priority to CN201610576562.XA priority Critical patent/CN107629838A/en
Publication of CN107629838A publication Critical patent/CN107629838A/en
Pending legal-status Critical Current

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Abstract

The invention belongs to chemical technology field, and in particular to a kind of environment-protective lubricant oil, base oil selection vegetable oil, it is characterised in that including following components by weight ratio:SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER 2.5 3.8%, molybdenum dialkyl-dithiophosphate 0.1 0.8%, polyisobutene succinimide 3.5 4.5%, zinc dialkyl dithiophosphate 1.6 1.9%, dialkyl diphenylamine 0.1 1.2%, low molecule amount polymethacrylates 0.1 0.36%, silicone emulsion 0.05 0.15%, ethylene propylene copolymer 1 13%, base oil 75 86%.Oil based on the vegetable oil of present invention selection environmental protection, additive level is few, while has the characteristics of good inoxidizability, wear resistence, detergency and good dispersion, has higher economic value and social value, is easy to widely promote and use.

Description

A kind of environment-friendly lubricating oil
Technical field
The invention belongs to chemical technology field, and in particular to a kind of environment-protective lubricant oil.
Background technology
Lubricating oil is used in all kinds automobile, plays lubrication, cooling, antirust, cleaning, sealing and buffering etc. in plant equipment The liquid or semisolid lubricants of effect, protection machinery and workpiece.Typically it is made up of base oil and additive two parts.Basis Oil is the main component of lubricating oil, decides the fundamental property of lubricating oil, and additive can then make up and improve base oil performance side The deficiency in face, some new performances are assigned, be the important component of lubricating oil.Research has good antiwear and antifriction effect, together When ensure its feature of environmental protection, ensure that lubricating oil and its loss product do not damage to ecological environment, or be ring to a certain extent Border is allowed, and is the emphasis of current lubricating oil industry research, and the significant problem point faced.
The content of the invention
It is an object of the invention to provide a kind of environment-friendly lubricating oil, base oil selection vegetable oil, ensures antiwear and antifriction effect While, there is good environment-friendly property.
The technical proposal of the invention is realized in this way:A kind of environment-friendly lubricating oil, base oil selection vegetable oil, its feature It is, including following components by weight ratio:SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER 2.5-3.8%, molybdenum dialkyl-dithiophosphate 0.1-0.8%, polyisobutene succinimide 3.5-4.5%, zinc dialkyl dithiophosphate 1.6-1.9%, dialkyl group hexichol Amine 0.1-1.2%, low molecule amount polymethacrylates 0.1-0.36%, silicone emulsion 0.05-0.15%, ethylene propylene copolymer Thing 1-13%, base oil 75-86%.
The SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER:Serve in engine oil in acid and, it is anti-oxidant and wear-resistant.With good Detergent-dispersant performance and water-resistance, acid neutralization capacity is stronger, and high temperature detergency is good, and water-resistance is good.For modulating medium and high classes internal combustion Machine oil, be particularly suitable for use in pressurized diesel engine oil.Reduce the carbon deposit of top land.Tests prove that high base number in the technical program Sulfenyl phenolate calcium content should be controlled between 2.5-3.8%.
The molybdenum dialkyl-dithiophosphate:It is a kind of new and effective antifriction and antiwear agentses, its typical chemical formula is [(RO):Ps—s]:M0:SO, R represents carbon number as 3~8 straight chained alkyl or branched alkyl in formula;R be alternatively aryl or Aralkyl, the carbon number of aryl is 6~26, and alkyl substituent carbon atom quantity is 4~9.In its molecular structure, each molybdenum Atom is mutually bonded with a dialkyl dithiophosphoric acid base.Molybdenum dialkyl-dithiophosphate be mainly used as I. C. engine oil, hydraulic oil, Air compressor oil, turbine machine oil, hypoid gear oil, the additive of rail oil and various intermetallic composite coating lubricating oil, mainly Function is antifriction, wear-resistant and anti-oxidant etc. multiple functions, and is effectively saved the energy.Tests prove that two in the technical program Alkyl dithiophosphoric acid molybdenum content should be controlled between 0.1-0.8%.
The polyisobutene succinimide:It is for raw material, using hot adduction work with high-activity polyisobutene (=1000) Ashless dispersant prepared by skill.With good detergent-dispersant performance, the generation of carbon deposit and paint film on engine piston can be suppressed, produced Product are not chloride.Experiment proves that polyisobutene succinimide content should be controlled between 3.5-4.5% in the technical program.
Zinc dialkyl dithiophosphate:Also known as accelerator ZDTP, molecular formula are C28H60O4P2S4Zn, and molecular weight is 716.3901 it is a kind of chemical intermediate.Be it is a kind of with antioxygen, anti-rotten and wear-resistant effect multipurpose additive, can press down Paint film, greasy filth, the annular groove of engine motor oil processed stick the generation of thing, suppress oil product viscosity and increase, prevent cylinder, annular groove, cam With the abrasion of valve rod, moreover it is possible to prevent bearing corrosion.Experiment proves that zinc dialkyl dithiophosphate content should be controlled in the technical program System is between 1.6-1.9%.
The silicone emulsion:Have defoaming fast as anti-foaming agent, suds suppressing properties are good, do not influence the basic nature of bubbling system Matter, diffusivity, good penetrability, chemical stabilization.Experiment proves that silicone emulsion content should be controlled in 0.05- in the technical program Between 0.15%.
The ethylene propylene copolymer:As thickening agent, usually it is dispersed in fluid lubricant and is formed with colloidal state Space net structure, or be only dispersed in the form of dispersed phase in base oil, play a part of adsorbing and limit base oil flowing. Thickening agent directly affects the performances such as the mechanical stability of lubricating grease, heat-resisting quantity, colloid stability, water-resistance.Experiment proof, this Ethylene propylene copolymer content should be controlled between 1-13% in technical scheme.
Oil based on the vegetable oil of lubricating oil selection environmental protection provided by the invention, additive level is few, while has good The characteristics of inoxidizability well, wear resistence, detergency and good dispersion, there is higher economic value and social value, be easy to It is extensive to promote and use.
Embodiment
Further to illustrate the present invention, below in conjunction with preferred embodiment, the present invention is described in further details.
Embodiment 1
Environment-friendly lubricating oil, including following components by weight ratio:SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER 2.1%, dialkyl group Molybdenum dithiophosphate 0.3%, polyisobutene succinimide 4.0%, zinc dialkyl dithiophosphate 1.8%, dialkyl group hexichol Amine 0.3%, low molecule amount polymethacrylates 0.2%, silicone emulsion 0.1%, ethylene propylene copolymer 3%, base oil 88.2%.
Environment-friendly lubricating oil, including following components by weight ratio:SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER 3.8%, dialkyl group Molybdenum dithiophosphate 0.8%, polyisobutene succinimide 4.5%, zinc dialkyl dithiophosphate 1.9%, dialkyl group hexichol Amine 1.2%, low molecule amount polymethacrylates 0.36%, silicone emulsion 0.15%, ethylene propylene copolymer 13%, base oil 87.3%.

Claims (1)

1. a kind of environment-friendly lubricating oil, base oil selection vegetable oil, it is characterised in that including following components by weight ratio: SULFURIZED CALCIUM ALKYL PHENATE WITH HIGH BASE NUMBER 2.5-3.8%, molybdenum dialkyl-dithiophosphate 0.1-0.8%, polyisobutene succinimide 3.5-4.5%, zinc dialkyl dithiophosphate 1.6-1.9%, dialkyl diphenylamine 0.1-1.2%, the poly- methyl-prop of low molecule amount Olefin(e) acid ester 0.1-0.36%, silicone emulsion 0.05-0.15%, ethylene propylene copolymer 1-13%, base oil 75-86%.
CN201610576562.XA 2016-07-19 2016-07-19 A kind of environment-friendly lubricating oil Pending CN107629838A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610576562.XA CN107629838A (en) 2016-07-19 2016-07-19 A kind of environment-friendly lubricating oil

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610576562.XA CN107629838A (en) 2016-07-19 2016-07-19 A kind of environment-friendly lubricating oil

Publications (1)

Publication Number Publication Date
CN107629838A true CN107629838A (en) 2018-01-26

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610576562.XA Pending CN107629838A (en) 2016-07-19 2016-07-19 A kind of environment-friendly lubricating oil

Country Status (1)

Country Link
CN (1) CN107629838A (en)

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Application publication date: 20180126

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