CN107629359A - A kind of abrasion resistant fire blocking cable jacket material - Google Patents

A kind of abrasion resistant fire blocking cable jacket material Download PDF

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Publication number
CN107629359A
CN107629359A CN201710952903.3A CN201710952903A CN107629359A CN 107629359 A CN107629359 A CN 107629359A CN 201710952903 A CN201710952903 A CN 201710952903A CN 107629359 A CN107629359 A CN 107629359A
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CN
China
Prior art keywords
parts
rubber
abrasion resistant
butadiene
cable jacket
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Pending
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CN201710952903.3A
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Chinese (zh)
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曾伟平
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Sihui City Eic Information Advisory Services Ltd
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Sihui City Eic Information Advisory Services Ltd
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Priority to CN201710952903.3A priority Critical patent/CN107629359A/en
Publication of CN107629359A publication Critical patent/CN107629359A/en
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Abstract

The present invention provides a kind of abrasion resistant fire blocking cable jacket material, and its raw material includes by weight:75 80 parts of polyvinyl chloride resin, 15 22 parts of trichloroactic acid ethylene copolymer, 13 18 parts of Kynoar, 8 12 parts of neoprene, 13 15 parts of nitrile rubber, 58 parts of butadiene-styrene rubber, 39 parts of butadiene rubber, 10 12 parts of glass fibre, 8 14 parts of carboxymethyl cellulose, 13 parts of carbon black, 13 parts of white carbon, 1.5 2 parts of talcum powder, 0.5 1.8 parts of zinc oxide, 1.5 2 parts of magnesia, 58 parts of nano-calcium carbonate, 58 parts of nano silica fume, 57 parts of nanometer Xuancheng stone, 6 12 parts of insect-and mouse-preventing auxiliary agent, 5 10 parts of sulphur, 5 10 parts of three-level stearic acid, 6 12 parts of pitch, 14 16 parts of composite flame-retardant agent, 15 19 parts of filler, 13 parts of plasticizer;The present invention is with polyvinyl chloride resin; butadiene-styrene rubber, nitrile rubber, ethylene propylene diene rubber; neoprene; the mixture of butadiene rubber is base-material, its excellent fireproof performance, is aided with other each raw materials; including composite flame-retardant agent; age resister, can be remarkably reinforced the ageing resistance and anti-flammability of cable, increase the service life of cable significantly.

Description

A kind of abrasion resistant fire blocking cable jacket material
Technical field
The present invention relates to CABLE MATERIALS, and in particular to a kind of abrasion resistant fire blocking cable jacket material.
Background technology
With developing rapidly for economy, electric wire is widely used in industry-by-industry, field.Cable, lead to It is often by several or the cable of similar rope that several groups of wires (every group at least two) are twisted, between every group of wire mutually absolutely Edge, and be often twisted into around a center, whole outside is surrounded by the cable cover(ing) of high-insulation.Cable has interior energization, outer exhausted The feature of edge.
Into after modern society, because urban land is nervous, traffic pressure is big, the reason such as appearance of the city construction, and big city is universal Using buried cable power transmission mode.Relative to aerial cable, buried cable, which has, takes up an area small, reliable, strong antijamming capability of transmitting electricity The advantages that.
But the wearability of existing cable is poor, by easily being deformed with ground friction in transport and process of deployment With different degrees of damage, meanwhile, buried cable is often bitten by biologies such as worm mouse, and fault occurs.In order to Solves above-mentioned phenomenon, the wearability and the anti-characteristic that bites for improving cable turn into the current technical issues that need to address.
The content of the invention
In view of the shortcomings of the prior art, the invention provides a kind of abrasion resistant fire blocking cable jacket material, the anti-ageing of cable is strengthened The property changed and anti-flammability.
To realize object above, the present invention is achieved by the following technical programs:A kind of abrasion resistant fire blocking cable jacket material, Its raw material includes by weight:Polyvinyl chloride resin 75-80 parts, vinyl chloride-vinyl acetate copolymer 15-22 parts, Kynoar 13- 18 parts, neoprene 8-12 parts, nitrile rubber 13-15 parts, butadiene-styrene rubber 5-8 parts, butadiene rubber 3-9 parts, glass fibre 10-12 Part, carboxymethyl cellulose 8-14 parts, carbon black 1-3 parts, white carbon 1-3 parts, talcum powder 1.5-2 parts, zinc oxide 0.5-1.8 parts, oxygen Change magnesium 1.5-2 parts, nano-calcium carbonate 5-8 parts, nano silica fume 5-8 parts, nanometer Xuancheng stone 5-7 parts, insect-and mouse-preventing auxiliary agent 6-12 parts, Sulphur 5-10 parts, three-level stearic acid 5-10 parts, pitch 6-12 parts, composite flame-retardant agent 14-16 parts, filler 15-19 parts, plasticizer 1-3 parts.
Preferably, the composite flame-retardant agent is that weight part ratio is 1:2:5 silicon nitride, magnesium silicate, modified calcium carbonate.
Preferably, the filler is the one or more in carbon black, lignin and plant ash.
Preferably, the plasticizer is one kind in epoxy aliphatic acid methyl ester and chlorinated paraffin.
Preferably, the insect-and mouse-preventing auxiliary agent is the molten alkyl cuprammonium of ammonia, paracide, allicin, 4,5,9-trithiadodeca-1,6,11-triene 9-oxide and capsicum Element presses 3:2:4:2:1 ratio mixes.
Preferably, the nitrile rubber is BMI modified butadiene acrylonitrile rubbers.
Preferably, the butadiene-styrene rubber is acrylic modified butadiene-styrene rubber.
Preferably, the butadiene rubber is Polystyrene butadiene rubber.
The invention provides a kind of abrasion resistant fire blocking cable jacket material, the present invention is with polyvinyl chloride resin, butadiene-styrene rubber, nitrile rubber, Ethylene propylene diene rubber, neoprene, the mixture of butadiene rubber is base-material, its excellent fireproof performance, is aided with other each raw materials, bag Composite flame-retardant agent is included, age resister, the ageing resistance and anti-flammability of cable can be remarkably reinforced, increase cable significantly uses the longevity Life.
Embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, Obviously, described embodiment is only part of the embodiment of the present invention, rather than whole embodiments.Based in the present invention Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all Belong to the scope of protection of the invention.
In description of the invention, it is also necessary to explanation, unless otherwise clear and definite regulation and limitation, term " setting ", " peace Dress ", " connected ", " connection " should be interpreted broadly, for example, it may be fixedly connected or be detachably connected, or integratedly Connection, can be mechanical connection or electrical connection, can be directly connected to or be connected by intermediary, can To be the connection of two element internals.For the ordinary skill in the art, can understand as the case may be above-mentioned The concrete meaning of term in the present invention.
Embodiment 1:
A kind of abrasion resistant fire blocking cable jacket material, its raw material include by weight:75 parts of polyvinyl chloride resin, vinyl chloride-acetate 5 parts of copolymer 1,13 parts of Kynoar, 8 parts of neoprene, 13 parts of nitrile rubber, 5 parts of butadiene-styrene rubber, 3 parts of butadiene rubber, glass 10 parts of glass fiber, 8 parts of carboxymethyl cellulose, 1 part of carbon black, 1 part of white carbon, 1.5 parts of talcum powder, 0.5 part of zinc oxide, magnesia 1.5 parts, 8 parts of nano-calcium carbonate, 5 parts of nano silica fume, 5 parts of nanometer Xuancheng stone, 12 parts of insect-and mouse-preventing auxiliary agent, 5 parts of sulphur, three-level is hard 5 parts of resin acid, 12 parts of pitch, 16 parts of composite flame-retardant agent, 15 parts of filler, 1 part of plasticizer.
Preferably, the composite flame-retardant agent is that weight part ratio is 1:2:5 silicon nitride, magnesium silicate, modified calcium carbonate.
Preferably, the filler is the one or more in carbon black, lignin and plant ash.
Preferably, the plasticizer is one kind in epoxy aliphatic acid methyl ester and chlorinated paraffin.
Preferably, the insect-and mouse-preventing auxiliary agent is the molten alkyl cuprammonium of ammonia, paracide, allicin, 4,5,9-trithiadodeca-1,6,11-triene 9-oxide and capsicum Element presses 3:2:4:2:1 ratio mixes.
Preferably, the nitrile rubber is BMI modified butadiene acrylonitrile rubbers.
Preferably, the butadiene-styrene rubber is acrylic modified butadiene-styrene rubber.
Preferably, the butadiene rubber is Polystyrene butadiene rubber.
Embodiment 2:
A kind of abrasion resistant fire blocking cable jacket material, its raw material include by weight:80 parts of polyvinyl chloride resin, vinyl chloride-acetate 22 parts of copolymer, 13 parts of Kynoar, 8 parts of neoprene, 15 parts of nitrile rubber, 8 parts of butadiene-styrene rubber, 9 parts of butadiene rubber, glass 12 parts of glass fiber, 14 parts of carboxymethyl cellulose, 3 parts of carbon black, 3 parts of white carbon, 2 parts of talcum powder, 1.8 parts of zinc oxide, magnesia 2 Part, 8 parts of nano-calcium carbonate, 8 parts of nano silica fume, 7 parts of nanometer Xuancheng stone, 12 parts of insect-and mouse-preventing auxiliary agent, 10 parts of sulphur, three-level tristearin 10 parts of acid, 12 parts of pitch, 16 parts of composite flame-retardant agent, 19 parts of filler, 3 parts of plasticizer.
Preferably, the composite flame-retardant agent is that weight part ratio is 1:2:5 silicon nitride, magnesium silicate, modified calcium carbonate.
Preferably, the filler is the one or more in carbon black, lignin and plant ash.
Preferably, the plasticizer is one kind in epoxy aliphatic acid methyl ester and chlorinated paraffin.
Preferably, the insect-and mouse-preventing auxiliary agent is the molten alkyl cuprammonium of ammonia, paracide, allicin, 4,5,9-trithiadodeca-1,6,11-triene 9-oxide and capsicum Element presses 3:2:4:2:1 ratio mixes.
Preferably, the nitrile rubber is BMI modified butadiene acrylonitrile rubbers.
Preferably, the butadiene-styrene rubber is acrylic modified butadiene-styrene rubber.
Preferably, the butadiene rubber is Polystyrene butadiene rubber.
Experiment
Apparatus for Pressure at high-temp condition:
Test temperature:80 DEG C ± 2 DEG C,
The load lower duration:The outside diameter of cable≤12.5mm, 4h;
The outside diameter of cable > 12.5mm, 6h;
Cable jacket material made from embodiment 1,2 is tested, and contrasted with market common cable protective cover material row.Experiment As a result it is as follows:
The invention provides a kind of abrasion resistant fire blocking cable jacket material, the present invention is with polyvinyl chloride resin, butadiene-styrene rubber, nitrile rubber, Ethylene propylene diene rubber, neoprene, the mixture of butadiene rubber is base-material, its excellent fireproof performance, is aided with other each raw materials, bag Composite flame-retardant agent is included, age resister, the ageing resistance and anti-flammability of cable can be remarkably reinforced, increase cable significantly uses the longevity Life.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations;Although with reference to the foregoing embodiments The present invention is described in detail, it will be understood by those within the art that:It still can be to foregoing each implementation Technical scheme described in example is modified, or carries out equivalent substitution to which part technical characteristic;And these modification or Replace, the essence of appropriate technical solution is departed from the spirit and scope of various embodiments of the present invention technical scheme.

Claims (8)

1. a kind of abrasion resistant fire blocking cable jacket material, it is characterised in that its raw material includes by weight:Polyvinyl chloride resin 75-80 parts, chlorine Ethene-vinyl acetate copolymer 15-22 parts, Kynoar 13-18 parts, neoprene 8-12 parts, nitrile rubber 13-15 parts, Butadiene-styrene rubber 5-8 parts, butadiene rubber 3-9 parts, glass fibre 10-12 parts, carboxymethyl cellulose 8-14 parts, carbon black 1-3 parts, hard charcoal Black 1-3 parts, talcum powder 1.5-2 parts, zinc oxide 0.5-1.8 parts, magnesia 1.5-2 parts, nano-calcium carbonate 5-8 parts, nano silica fume 5-8 parts, nanometer Xuancheng stone 5-7 parts, insect-and mouse-preventing auxiliary agent 6-12 parts, sulphur 5-10 parts, three-level stearic acid 5-10 parts, pitch 6-12 Part, composite flame-retardant agent 14-16 parts, filler 15-19 parts, plasticizer 1-3 parts.
2. abrasion resistant fire blocking cable jacket material according to claim 1, it is characterised in that:The composite flame-retardant agent is parts by weight Than for 1:2:5 silicon nitride, magnesium silicate, modified calcium carbonate.
3. abrasion resistant fire blocking cable jacket material according to claim 1, it is characterised in that:The filler is carbon black, wooden One or more in element and plant ash.
4. abrasion resistant fire blocking cable jacket material according to claim 1, it is characterised in that:The plasticizer is epoxyfatty acid One kind in methyl esters and chlorinated paraffin.
5. abrasion resistant fire blocking cable jacket material according to claim 1 or 2, it is characterised in that:The insect-and mouse-preventing auxiliary agent is The molten alkyl cuprammonium of ammonia, paracide, allicin, 4,5,9-trithiadodeca-1,6,11-triene 9-oxide and capsaicine press 3:2:4:2:1 ratio mixes.
6. abrasion resistant fire blocking cable jacket material according to claim 1 or 2, it is characterised in that:The nitrile rubber changes for BMI Property nitrile rubber.
7. abrasion resistant fire blocking cable jacket material according to claim 1 or 2, it is characterised in that:The butadiene-styrene rubber is methyl Acrylic acid modified butadiene-styrene rubber.
8. abrasion resistant fire blocking cable jacket material according to claim 1 or 2, it is characterised in that:The butadiene rubber is polyphenyl Ethylene modified butadiene rubber.
CN201710952903.3A 2017-10-13 2017-10-13 A kind of abrasion resistant fire blocking cable jacket material Pending CN107629359A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108410083A (en) * 2018-02-07 2018-08-17 安徽剑峰通讯科技有限公司 A kind of inside cable sheath material
CN108707299A (en) * 2018-04-24 2018-10-26 苏州耐思特塑胶有限公司 A kind of hard coaxial cable flame retardant jacket materials and preparation method thereof
CN109054221A (en) * 2018-06-21 2018-12-21 安徽省亿嘉弘电器有限公司 A kind of automobile cable sheath material formula and preparation method thereof
CN109251437A (en) * 2018-06-21 2019-01-22 江苏诺贝尔塑业有限公司 A kind of mouse bite preventing pvc pipe and preparation method thereof
CN110283454A (en) * 2019-05-29 2019-09-27 周宁东 A kind of Low-smoke flame retardant cable material and preparation method thereof
CN110483857A (en) * 2019-08-30 2019-11-22 安徽电缆股份有限公司 Wear-resisting ageing-resistant power cable sheath material of one kind and preparation method thereof
CN111732784A (en) * 2020-07-20 2020-10-02 苏州美昱高分子材料有限公司 Ultralow-temperature-resistant torsion-resistant halogen-free elastomer cable material for thermoplastic wind energy cable
CN112226003A (en) * 2020-10-10 2021-01-15 安徽华宇电缆集团有限公司 Rat-proof cable sheath material for ships and warships and preparation method and application thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103834078A (en) * 2012-11-20 2014-06-04 浙江正导电缆有限公司 Flame retardant cable sheath material
CN103304940B (en) * 2013-05-14 2016-01-06 安徽旺达铜业发展有限公司 A kind of flame-proof cable sheath material
CN107033492A (en) * 2017-04-27 2017-08-11 东莞市骏豪电线科技有限公司 A kind of CABLE MATERIALS of high-strength abrasion-proof and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103834078A (en) * 2012-11-20 2014-06-04 浙江正导电缆有限公司 Flame retardant cable sheath material
CN103304940B (en) * 2013-05-14 2016-01-06 安徽旺达铜业发展有限公司 A kind of flame-proof cable sheath material
CN107033492A (en) * 2017-04-27 2017-08-11 东莞市骏豪电线科技有限公司 A kind of CABLE MATERIALS of high-strength abrasion-proof and preparation method thereof

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108410083A (en) * 2018-02-07 2018-08-17 安徽剑峰通讯科技有限公司 A kind of inside cable sheath material
CN108707299A (en) * 2018-04-24 2018-10-26 苏州耐思特塑胶有限公司 A kind of hard coaxial cable flame retardant jacket materials and preparation method thereof
CN109054221A (en) * 2018-06-21 2018-12-21 安徽省亿嘉弘电器有限公司 A kind of automobile cable sheath material formula and preparation method thereof
CN109251437A (en) * 2018-06-21 2019-01-22 江苏诺贝尔塑业有限公司 A kind of mouse bite preventing pvc pipe and preparation method thereof
CN110283454A (en) * 2019-05-29 2019-09-27 周宁东 A kind of Low-smoke flame retardant cable material and preparation method thereof
CN110483857A (en) * 2019-08-30 2019-11-22 安徽电缆股份有限公司 Wear-resisting ageing-resistant power cable sheath material of one kind and preparation method thereof
CN111732784A (en) * 2020-07-20 2020-10-02 苏州美昱高分子材料有限公司 Ultralow-temperature-resistant torsion-resistant halogen-free elastomer cable material for thermoplastic wind energy cable
CN111732784B (en) * 2020-07-20 2022-03-11 苏州美昱高分子材料有限公司 Ultralow-temperature-resistant torsion-resistant halogen-free elastomer cable material for thermoplastic wind energy cable
CN112226003A (en) * 2020-10-10 2021-01-15 安徽华宇电缆集团有限公司 Rat-proof cable sheath material for ships and warships and preparation method and application thereof

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