CN107628676A - A kind of super Magneto separate waste water treatment process of electric flocculation - Google Patents

A kind of super Magneto separate waste water treatment process of electric flocculation Download PDF

Info

Publication number
CN107628676A
CN107628676A CN201711092931.9A CN201711092931A CN107628676A CN 107628676 A CN107628676 A CN 107628676A CN 201711092931 A CN201711092931 A CN 201711092931A CN 107628676 A CN107628676 A CN 107628676A
Authority
CN
China
Prior art keywords
magnetic
waste water
electric flocculation
magneto separate
treatment process
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711092931.9A
Other languages
Chinese (zh)
Inventor
王利军
易洋
吕志国
肖波
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chengdu Huanneng German Environmental Protection Equipment Manufacturing Co Ltd
Original Assignee
Chengdu Huanneng German Environmental Protection Equipment Manufacturing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chengdu Huanneng German Environmental Protection Equipment Manufacturing Co Ltd filed Critical Chengdu Huanneng German Environmental Protection Equipment Manufacturing Co Ltd
Priority to CN201711092931.9A priority Critical patent/CN107628676A/en
Publication of CN107628676A publication Critical patent/CN107628676A/en
Pending legal-status Critical Current

Links

Abstract

The invention discloses a kind of super Magneto separate waste water treatment process of electric flocculation, comprise the following steps:(1)Pending waste water is transported to and assigned in magnetic response device, magnetic kind is added, is uniformly mixed;(2)The waste water of step 1 processing is transported in electric flocculation device, and electric flocculation reaction is carried out with pulse current;(3)Waste water after step 2 is handled is transported in magnetic separating device, progress Magneto separate processing, sludge floc sedimentation and waste water separate during Magneto separate, except the waste water of crude removal is discharged by delivery port;(4)The sewage floc that step 3 magnetic separating device separates is transported in magnetic retracting device, reclaims magnetic kind, separated sludge, sludge is transferred in storage basin.The super Magneto separate technique of electric flocculation of the present invention is electrochemically generated coagulant reaction efficiency and is higher than outer adding medicine several times, active ingredient utilization is more abundant without dosing coagulant;The dosage of flocculation aid can be reduced simultaneously, and technique is more environmentally-friendly.

Description

A kind of super Magneto separate waste water treatment process of electric flocculation
Technical field
The present invention relates to a kind of waste water flocculating purification techniques, the more particularly to super Magneto separate waste water treatment process of electric flocculation, category In environmental technology field.
Background technology
Wastewater processing technology includes filtration method, flocculence, centrifugal separation at present, and wherein flocculence is with its disposal ability By force, the features such as energy consumption is low, and clean-up effect is stable is widely applied.Conventional chemical flocculation be added into waste water it is various Flocculant, after flocculant is dissolved in waste water generation containing the hydroxide ion largely with strong suction-operated, hydroxyl from It is miscellaneous that son and colloidal state impurity, suspended impurity generation flocculation reaction generation flocculate, while flocculate can adsorb nonreactive suspension Matter, most the colloidal state impurity in waste water and suspended impurity coprecipitation remove at last.
Super Magneto separate is a kind of fast treating process to be grown up based on flocculence, is mainly guided using super magnetic material Flocculate precipitate quick separating from waste water removes.Super Magneto separate generally refers to Magnaglo or ferromagnetism dusty material is used as and drawn Lead a kind of magnetic separation technique that core of the flocculation without separation is implemented.Super Magneto separate technique is to take up an area the characteristics of small, processing speed is fast Be widely used in various sewage disposal devices, can suspension, colloid in quick separating water, while to dissolubility COD, total phosphorus etc. Acted on good removal.
The prime cost of current super magnetic separating device system operation is waste water lifting expense and dosing coagulant, flocculant Expense.Conventional coagulant includes aluminium polychloride, bodied ferric sulfate etc., and it is polyacrylamide to commonly use flocculant, can be divided into the moon Ion, cation, nonionic etc..Because wastewater treatment total amount is a lot, so coagulant and flocculant usage are generally bigger, This causes in wastewater treatment process dosing coagulant and flocculant into the major part of purification of waste water cost.
Effluent water quality varies, and colloid, the suspension equal size for needing flocculation to remove in waste water are different, add medicine The dosage of agent is also required to corresponding adjust.But often it is difficult to the adjustment needs for taking into account different situations during wastewater purification, Coagulant and the slight excess of dosing method of flocculant can be used in most cases, to ensure that final purification effect reaches preferable It is horizontal.This to add medicament application efficiency not high, causes part medicament to waste loss.
According to analysis, the expense for adding medicament at present has accounted for the 40-70% of the total processing cost of wastewater treatment, if can reduce Medicament expense can significantly lift the economy of super magnetic separation technique, lift its competitiveness.
The content of the invention
It is an object of the invention to overcome in the wastewater treatment process in the presence of prior art, magnetic separation technique adds medicine The control of agent dosage is inaccurate, adds the high deficiency of reagent cost, there is provided a kind of super Magneto separate waste water treatment process of electric flocculation.This hair For the dosage for the medicament that flocculates in the bright super Magneto separate waste water treatment process of optimization, the implementation of flocculation reaction is controlled by electric flocculation, While ensuring flocculating effect, overcome the shortcomings of that flocculation adding of agent dosage is difficult to accurate perception control.
In order to realize foregoing invention purpose, the invention provides following technical scheme:
A kind of super Magneto separate waste water treatment process of electric flocculation, comprises the following steps:
(1)Pending waste water is transported to and assigned in magnetic response device, magnetic kind is added, is uniformly mixed.
(2)The waste water of step 1 processing is transported in electric flocculation device, and electric flocculation reaction, electric flocculation are carried out with pulse current Reaction time 10-120min.The electrode used in electric flocculation course of reaction, which can decompose, produces aluminium ion and/or iron ion Electrode.
(3)Waste water after step 2 is handled is transported in magnetic separating device, carries out Magneto separate processing, Magneto separate mistake Sludge floc sedimentation and waste water separate in journey, except the waste water of crude removal is discharged by delivery port.The sludge floc sedimentation contains sludge wadding Condensate and magnetic kind.
(4)The sewage floc that step 3 magnetic separating device separates is transported in magnetic retracting device, reclaims magnetic kind, separation is dirty Mud, sludge are transferred in storage basin.
The super Magneto separate waste water treatment process of electric flocculation of the present invention is in no longer dosing coagulant of super Magneto separate leading portion coagulation stage (Such as aluminium polychloride, bodied ferric sulfate, poly-ferric chloride), and use and electric wadding is carried out to sewage by high-frequency pulse current It is solidifying, the floc sedimentation of formation.The metal such as aluminium, iron is anode in electric flocculation course of reaction, is dissoluted in the presence of electric current, produce aluminium from Son, iron ion, in a series of oxidizing process through hydrolysis, polymerization and ferrous iron, develop into various hydroxo complexes, multinuclear hydroxyl Complex compound makes colloidal state impurity in waste water, suspended impurity cohesion so that hydroxide, and condensation product and magnetic kind be combined with each other precipitation. High-frequency pulse current electrode decomposing produces aluminium ion, iron ion, and using magnetic kind as " core " flocculation reaction, generation occur for reaction generation Floc sedimentation.The growing amount of floc sedimentation is controlled according to high-frequency pulse current parameter, and floc sedimentation growing amount is controllable, accurate reaction, is subtracted Few wasting of resources, it is cost-effective.Floc sedimentation has magnetic because including magnetic kind, can be separated from the water out rapidly by ultra-magnetic separator Come, sewage is purified by above-mentioned flow.The characteristics of magnetic, also referred to as magnetic floc sedimentation, are had according to sludge floc sedimentation.
Simultaneously as flocculation ion equally has the characteristic in pulse spacing caused by pulse current electrode decomposing, and it is adjoint Repulsion before ionization produces mutually drives so that magnetic kind can more disperse between each other.Flocculation ion caused by electrolysis Relative spacing flocculation reaction, the flocculate of final purification show as the flocculate largely disperseed, can more sufficiently cleaned up waste water In colloidal state, suspended state impurity.Meanwhile swimming can occur in the electric field for charged contaminants particle or floc sedimentation, its Partial charge quilt Electrode neutralizes and promotes it to take off steady coagulation.Waste water colloidal state by the purification of electric flocculation of the present invention super Magneto separate waste water treatment process and Suspended contamination content is extremely low, and the quality after purification of waste water is extremely outstanding.
In addition, when waste water carries out electrolytic flocculation processing, not only there is coagulative precipitation effect to colloidal state impurity and suspended impurity, also Including the purified treatment by anodizing and cathodic reduction effect, multiple pollutant in water removal can be removed.
Further, in step 1, pending waste water is first filtered to remove debris, subsequently into tax magnetic response by collecting Device.By filtering can rapidly remove in waste water can directly simple and mechanical separation bulk debris, avoid bulk for electricity wadding The harmful effect of solidifying reaction, reduce the cost consumption of electric flocculation.
Further, in step 1, the magnetic kind is magnetic, 0.1-100 μm of magnetic particle size range.Small magnetic can be more preferable And flocculation dirt combine, strengthen the effect of follow-up Magneto separate/super Magneto separate.
Preferably, magnetic kind dosage is 10-200mg/L, the speed that adds of magnetic kind is set according to pending wastewater flow, really Floc sedimentation total amount caused by the dosage and rear process electric flocculation of guarantor's magnetic kind is adapted, and facilitates dirt Magneto separate, while ensures that magnetic kind is returned Receive efficiency high.It is highly preferred that magnetic kind dosage 50-150mg/L.
Preferably, add after magnetic kind, waste water is stirred.Through being sufficiently stirred magnetic kind in advance it is dispersed come, It can preferably be combined with floc sedimentation caused by electric flocculation, especially as the core of floc sedimentation floc sedimentation preferably be reunited one Rise.
Further, in step 2, in magnetic separating device, magnetic separating device includes disk, and disk can rotate, and turns in disk When dynamic, containing the floc sedimentation that is magnetic(Sludge floc sedimentation)Sewage flow through magnetic disk surface, wherein magnetic floc sedimentation(Sludge floc sedimentation)By magnetic Disk is adsorbed and collected to magnetic retracting device, and water quality is purified.
Preferably, in step 2, magnetic separating device is super magnetic separating device.Super magnetic separation technique is regarded as a kind of reinforcing Mixed flocculation sediment technology." core " that magnetic kind is formed as flco/floc sedimentation, then in the presence of coagulant, suspends in water The effects such as thing, colloid etc. are compressed by electric double layer, chemistry is built bridge form coagulation flco based on " core ", then pass through flocculation Agent is named the effect of flocculation aid so that floc sedimentation becomes much larger, be more closely knit, and for pulse current swimming effect, floccule body equally may be used With more closely knit, and floc sedimentation has magnetic because of parcel magnetic kind, can be attracted to a magnet and be salvaged from water and.
Further, in step 3, magnetic kind retracting device is by floc sedimentation(Sludge floc sedimentation)In magnetic kind recovery, then magnetic kind is returned Return in magnetic kind configuration throwing device, be configured to after finite concentration and add again into pending waste water.Magnetic kind is equipped with to return Knock off skill so that magnetic kind is separated again in floc sedimentation is reused, it is ensured that magnetic kind is fully used, and avoids adding magnetic kind The waste of medicament.
Further, the spacing of electrode is that the distance between 1-10cm, electrode should not be too remote, to ensure to be electrolysed caused flocculation Ion dirt interaction to be precipitated, fully reaction can realize catharsis quickly and in waste water.Preferred electrode spacing For 2-9cm.Such as can be 3cm, 4 cm, 5 cm, 6 cm, 7 cm etc..
Further, in step 2, electrode uses aluminium sheet or iron plate.Plate electrode has bigger surface area, in pulse current Flocculation ion caused by the lower decomposition of effect is more scattered, can more preferably complete the flocculation treatment reaction for impurity component.
Further, in step 2, the current density of pulse current is 1-10A/cm3, higher current density is to ensure to be electrolysed Flocculation reaction, adsorption precipitation impurity can sufficiently occur for caused ion.
Preferably, the dutycycle of pulse current is 0.1-0.9, and appropriate dutycycle ensures that ion caused by electrolysis is fully made With spaced separation so that magnetic kind is more obvious as the effect of floc sedimentation core, lifts the effect and magnetic of follow-up Magneto separate The kind rate of recovery.Meanwhile pulse current advantageously reduces electrolysis energy consumption, cost for wastewater treatment is saved.
Further, if the electrical conductivity of waste water is relatively low, a certain amount of salt is added.The conductance of waste water is improved by adding salt Rate so that waste water has higher efficiency in electric flocculation course of reaction.Such as can be sodium sulphate, sodium chloride, potassium sulfate etc. Salt.
Preferably, the dosage of salt is added as the μ s/cm of conductivity of waste water >=5003
Further, step 2, after the completion of the reaction of electric flocculation device electric flocculation, the precipitation that PAM promotes floc sedimentation is added.
Compared with prior art, beneficial effects of the present invention:
1st, the super Magneto separate technique of electric flocculation of the present invention is electrochemically generated coagulant reaction efficiency higher than additional without dosing coagulant Medicament several times, active ingredient utilization are more abundant;The dosage of flocculation aid can be reduced simultaneously, and technique is more environmentally-friendly.
2nd, the super Magneto separate technique post precipitation of electric flocculation of the present invention is realized using Magneto separate or super Magneto separate, whole system Floor space significantly reduces, and good separating effect.
3rd, macromolecule organic in waste water is synchronously realized in the super Magneto separate technique electrochemical reaction process of electric flocculation of the present invention Oxidation Decomposition, improve biodegradability, while notable to sewage decoloring and other effects.
4th, high volence metal ion in water can be reduced and sunk in the super Magneto separate technique electrochemical process of electric flocculation of the present invention Form sediment and separate, be particularly suitable for handling heavy metal-containing waste water.
Brief description of the drawings:
Fig. 1 is electric flocculation Magneto separate sewage treatment technology process figure of the present invention.
Embodiment
With reference to test example and embodiment, the present invention is described in further detail.But this should not be understood Following embodiment is only limitted to for the scope of the above-mentioned theme of the present invention, it is all that this is belonged to based on the technology that present invention is realized The scope of invention.
<Embodiment 1>
Process object is is dyeing waste water in this process example, pH ≈ 6.8, COD ≈ 400mg/L, suspension about 300mg/ L, about 260 times of colourity, the μ s/cm of electrical conductivity about 12003
Waste water first adds magnetic about 100mg/L, enters electric flocculation device, electric flocculation device negative and positive after abundant high-speed stirred Pole electrode is iron, and wherein electrode sets parallel plate electrode 5cm or so, current strength about 3.5mA/cm3;Power supply is pulse, Power supply dutycycle is 0.4, and frequency 1KHz, the electric flocculation reaction time is 30min, and the water after processing adds PAM(Polyacrylamide Amine)Then about 4mg/L stirs, ultra-magnetic separator is entered after floc sedimentation is formed, and main part is in ultra-magnetic separator The basic no suspended substance state of clarification is presented in parallel disk composition, spacing about 3-5cm, waste water after super Magneto separate.
Through analysis, water outlet COD is 89mg/L, and pH value about 7.2, suspension 19mg/L, colourity is 20 times.
<Comparative example 1>
Waste water is handled with embodiment 1, waste water adds PAC after first adding magnetic about 100mg/L, abundant high-speed stirred 2min(It is poly- Close aluminium chloride)About 80mg/L, after being sufficiently stirred about 5min, PAM about 4mg/L are added, 2min is reacted after reducing mixing speed, is wadding a quilt with cotton Group enters ultra-magnetic separator after being formed, main part forms for parallel disk in ultra-magnetic separator, spacing about 3- The basic no suspended substance state of clarification is presented in 5cm, waste water after super Magneto separate.
Through analysis, water outlet COD is 173mg/L, and pH value about 7.0, suspension 22mg/L, colourity is 50 times.
<Comparative example 2>
Waste water is handled with embodiment 1, waste water adds PFS after first adding magnetic about 100mg/L, abundant high-speed stirred 2min(It is poly- Close ferric sulfate)About 80mg/L, after being sufficiently stirred about 5min, PAM about 4mg/L are added, 2min is reacted after reducing mixing speed, is wadding a quilt with cotton Group enters ultra-magnetic separator after being formed, main part forms for parallel disk in ultra-magnetic separator, spacing about 3- The basic no suspended substance state of clarification is presented in 5cm, waste water after super Magneto separate.
Through analysis, water outlet COD is 167mg/L, and pH value about 7.0, suspension 24mg/L, colourity is 60 times.
Analyze in visible embodiment 1 and the comparative example 1 and 2 of additional coagulant, wherein COD are better than to the treatment effect of waste water Become apparent with the removal effect of colourity.
<Comparative example 3>
Pole plate spacing is set
Purified treatment is carried out to same dyeing waste water using the technique similar to embodiment 1, parallel pole is adjusted in processing procedure Plate spacing 7cm, 10cm, 15cm or so, remaining parameter and embodiment 1 are consistent.
Through analysis, parallel plate electrode spacing 7cm scheme:By same 30min electric flocculations, final outflow water COD about 91mg/L, PH value about 7.1, suspension 24mg/L, colourity are 21 times.
Through analysis, parallel plate electrode spacing 10cm scheme:By same 30min electric flocculations, final outflow water COD is 97mg/ L, pH value about 7.2, suspension 36mg/L, colourity are 23 times.
Through analysis, parallel plate electrode spacing 15cm scheme:By same 30min electric flocculations, final outflow water COD is 205mg/ L, pH value about 7.1, suspension 167mg/L, colourity are 56 times.
It can be seen that the spacing setting for parallel plate electrode during electric flocculation has a significant impact for purification of waste water quality, If pole plate spacing sets the flocculating effect of too big waste water bad, all unfavorable finally for COD, suspension and colourity, therefore not Excessive pole plate spacing can be set, should preferably controlling plate spacing 1-10cm.
<Embodiment 2>
The present embodiment process object is desulfurization wastewater, and pH ≈ 6.4, COD ≈ 360mg/L, suspension about 210mg/L, colourity is about 310 times, the μ s/cm of electrical conductivity about 13503
Waste water first adds magnetic about 110mg/L, enters electric flocculation device, electric flocculation device negative and positive after abundant high-speed stirred Pole electrode is aluminium sheet, and wherein battery lead plate spacing about 4cm is set, current strength about 5mA/cm3;Power supply is pulse, power supply Dutycycle is 0.3, frequency 1KHz, and the electric flocculation reaction time is 45min, and the water after processing adds PAM about 6mg/L and then stirred Uniformly, ultra-magnetic separator is entered after floc sedimentation is formed, main part forms for parallel disk in ultra-magnetic separator, spacing The basic no suspended substance state of clarification is presented in about 3-5cm, waste water after super Magneto separate.
Through analysis, water outlet COD is 57mg/L, and pH value about 7.1, suspension 12mg/L, colourity is 25 times.
<Embodiment 3>
The present embodiment process object is dyeing waste water, and pH ≈ 6.7, COD ≈ 360mg/L, suspension about 400mg/L, colourity is about 240 times, the μ s/cm of electrical conductivity about 11003
Waste water first adds magnetic about 95mg/L, enters electric flocculation device, electric flocculation device negative and positive after abundant high-speed stirred Pole electrode is iron plate, spacing 3-4cm, current strength about 8mA/cm3;Power supply is pulse, and power supply dutycycle is 0.5, frequency Rate is 1KHz, and the electric flocculation reaction time is 20min, and the water after processing adds PAM about 5mg/L and then stirred, in floc sedimentation shape Enter ultra-magnetic separator into later, main part forms for parallel disk in ultra-magnetic separator, spacing 4-5cm, waste water warp The basic no suspended substance state of clarification is presented after crossing super Magneto separate.
Through analysis, water outlet COD is 76mg/L, and pH value about 7.3, suspension 21mg/L, colourity is 22 times.
<Comparative example 4>
Using the technique similar to embodiment 3 to same dyeing waste water purified treatment, the pulse power is simply changed to constant current, its Remaining parameter and embodiment 3 are consistent.
Through analysis, water outlet COD is 86mg/L, and pH value about 7.5, suspension 36mg/L, colourity is 25 times.Constant Electric Current is wadded a quilt with cotton It is solidifying to handle the energy consumption for having increased considerably electric flocculation, but without the effect of lifting waste water purification.Probably due to non-pulse electric current is electric In solution preocess it is caused flocculation ion do not disperseed sufficiently, ion caused by electrolysis itself mutually flocculates, lack for The flocculation of waste water impurity composition, and then cause clean-up effect not rise anti-drop.Preferably, therefore use dutycycle 0.1-0.9 Pulse current carry out electric flocculation.It is highly preferred that the pulse current using dutycycle 0.3-0.7.
<Embodiment 4>
The present embodiment process object is sanitary sewage, and pH ≈ 6.7, COD ≈ 520mg/L, suspension about 600mg/L, colourity is about 120 times, the μ s/cm of electrical conductivity about 8703
Waste water first adds magnetic about 100mg/L, enters electric flocculation device, electric flocculation device negative and positive after abundant high-speed stirred Pole electrode is iron, and wherein electrode sets parallel plate electrode 3cm or so, current strength about 10mA/cm3;Power supply is pulse, electricity Source dutycycle is 0.2, and frequency 1KHz, the electric flocculation reaction time is 10min, and the water after processing adds PAM about 4mg/L and then stirred To mix uniformly, ultra-magnetic separator is entered after floc sedimentation is formed, main part forms for parallel disk in ultra-magnetic separator, Away from about 3-5cm, the basic no suspended substance state of clarification is presented in waste water after super Magneto separate.
Through analysis, water outlet COD is 46mg/L, and pH value about 7.2, suspension 8mg/L, colourity is 15 times.
<Comparative example 5>
Purified treatment is carried out to same sanitary wastewater using the technique similar to embodiment 4, it is close to adjust electric current in processing procedure Spend 3A/cm3、5A/cm3、7A/cm3、13A/cm3Left and right, remaining parameter and embodiment 4 are consistent.
Through analysis, 3A/cm3Electric flocculation processing, final outflow water COD is 47mg/L, pH value about 7.2, suspension 8mg/ L, colourity are 15 times.
Through analysis, 5A/cm3Electric flocculation processing, final outflow water COD is 46mg/L, pH value about 7.2, suspension 9mg/ L, colourity are 14 times.
Through analysis, 7A/cm3Electric flocculation processing, final outflow water COD is 47mg/L, pH value about 7.2, suspension 7mg/ L, colourity are 14 times.
Through analysis, 13A/cm3Electric flocculation processing, final outflow water COD is 50mg/L, pH value about 7.2, and suspension is 29mg/L, colourity are 19 times.
Research finds that the current density of electric flocculation is little for the influential effect of electric flocculation, but when the electric current of electric flocculation is close After degree is more than 10A, clean-up effect does not rise further not only, occurs reduction slightly on the contrary, while electric flocculation Energy consumption increases considerably, so the current density of electric flocculation is no more than 10A/cm3

Claims (10)

1. a kind of super Magneto separate waste water treatment process of electric flocculation, comprises the following steps:
(1)Pending waste water is transported to and assigned in magnetic response device, magnetic kind is added, is uniformly mixed;
(2)The waste water of step 1 processing is transported in electric flocculation device, and electric flocculation reaction, electric flocculation reaction are carried out with pulse current Time 10-120mim;The electrode used in electric flocculation course of reaction is can to decompose the electricity for producing aluminium ion and/or iron ion Pole;
(3)Waste water after step 2 is handled is transported in magnetic separating device, progress Magneto separate processing, during Magneto separate Sludge floc sedimentation and waste water separate, except the waste water of crude removal is discharged by delivery port;The sludge floc sedimentation contains sludge flocculation thing With magnetic kind;
(4)The sewage floc that step 3 magnetic separating device separates is transported in magnetic retracting device, reclaims magnetic kind, separated sludge is dirty Mud is transferred in storage basin.
2. the super Magneto separate waste water treatment process of electric flocculation as claimed in claim 1, it is characterised in that in step 1, pending is useless Water is filtered to remove debris, enters after regulation and assign magnetic response device by collecting.
3. the super Magneto separate waste water treatment process of electric flocculation as claimed in claim 1, it is characterised in that in step 1, the magnetic kind is Magnetic, 0.1-100 μm of magnetic particle size range.
4. the super Magneto separate waste water treatment process of electric flocculation as claimed in claim 1, it is characterised in that the dosage of magnetic kind is 10- 200mg/L。
5. the super Magneto separate waste water treatment process of electric flocculation as claimed in claim 1, it is characterised in that in step 2, magnetic separating device In, magnetic separating device includes disk, and disk can rotate, and when disc rotation, the sewage containing the floc sedimentation that is magnetic flows through magnetic Panel surface, wherein magnetic floc sedimentation are adsorbed and collected to magnetic retracting device by disk, and water quality is purified.
6. the super Magneto separate waste water treatment process of electric flocculation as claimed in claim 1, it is characterised in that in step 2, magnetic separating device It is super magnetic separating device.
7. the super Magneto separate waste water treatment process of electric flocculation as claimed in claim 1, it is characterised in that in step 3, magnetic kind recovery dress Put and reclaim the magnetic kind in floc sedimentation, then magnetic kind is returned in magnetic kind configuration throwing device, is configured to after finite concentration again Add into pending waste water.
8. the super Magneto separate waste water treatment process of electric flocculation as claimed in claim 1, it is characterised in that the spacing of electrode is 1- 10cm。
9. the super Magneto separate waste water treatment process of electric flocculation as claimed in claim 1, it is characterised in that in step 2, electrode uses aluminium Plate or iron plate.
10. the super Magneto separate waste water treatment process of electric flocculation as claimed in claim 1, it is characterised in that in step 2, pulse current Current density be 1-10A/cm3
CN201711092931.9A 2017-11-08 2017-11-08 A kind of super Magneto separate waste water treatment process of electric flocculation Pending CN107628676A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711092931.9A CN107628676A (en) 2017-11-08 2017-11-08 A kind of super Magneto separate waste water treatment process of electric flocculation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711092931.9A CN107628676A (en) 2017-11-08 2017-11-08 A kind of super Magneto separate waste water treatment process of electric flocculation

Publications (1)

Publication Number Publication Date
CN107628676A true CN107628676A (en) 2018-01-26

Family

ID=61107364

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711092931.9A Pending CN107628676A (en) 2017-11-08 2017-11-08 A kind of super Magneto separate waste water treatment process of electric flocculation

Country Status (1)

Country Link
CN (1) CN107628676A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108545882A (en) * 2018-06-26 2018-09-18 南京林业大学 A kind of electric flocculation, magnetic flocculation and the integrated sewage-treatment plant of Magneto separate and method
CN110540327A (en) * 2019-08-27 2019-12-06 首创爱华(天津)市政环境工程有限公司 Advanced treatment process for activated sand micro-flocculation sewage
CN112607929A (en) * 2020-11-25 2021-04-06 湖南鑫远环境科技股份有限公司 Method and device for reinforced recovery of nitrogen and phosphorus from struvite
CN112607928A (en) * 2020-11-25 2021-04-06 湖南鑫远环境科技股份有限公司 Method for separating and recovering struvite crystal precipitate

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU806618A1 (en) * 1976-11-23 1981-02-23 Харьковский Институт Инженеровкоммунального Строительства Method of preparation of alumo-containing coagulant solution for clarifying naturaal and waste water
CN102531242A (en) * 2012-02-16 2012-07-04 江苏科润环境工程有限公司 Electric flocculating method for treating sewage
CN103819045B (en) * 2014-01-26 2015-09-02 浙江省环境保护科学设计研究院 A kind of magnetic loads the waste water recycling method of coagulation clarification and membrane sepn combination
CN105967428A (en) * 2016-06-17 2016-09-28 中海油天津化工研究设计院有限公司 Electromagnetic coupling inclined plate electric flocculation reactor
CN106976938A (en) * 2017-04-24 2017-07-25 大连理工大学 A kind of method of wadding magnetism separation technical finesse production of propylene oxide waste water

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU806618A1 (en) * 1976-11-23 1981-02-23 Харьковский Институт Инженеровкоммунального Строительства Method of preparation of alumo-containing coagulant solution for clarifying naturaal and waste water
CN102531242A (en) * 2012-02-16 2012-07-04 江苏科润环境工程有限公司 Electric flocculating method for treating sewage
CN103819045B (en) * 2014-01-26 2015-09-02 浙江省环境保护科学设计研究院 A kind of magnetic loads the waste water recycling method of coagulation clarification and membrane sepn combination
CN105967428A (en) * 2016-06-17 2016-09-28 中海油天津化工研究设计院有限公司 Electromagnetic coupling inclined plate electric flocculation reactor
CN106976938A (en) * 2017-04-24 2017-07-25 大连理工大学 A kind of method of wadding magnetism separation technical finesse production of propylene oxide waste water

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
中国环境保护产业协会: "《国家重点环境保护实用技术及示范工程汇编 2014版》", 31 January 2015, 中国环境出版社.北京 *
张振家等: "《工厂废水处理站工艺原理与维护管理》", 28 February 2003 *
闫大鹏等: "《非传统水资源利用技术及应用》", 30 November 2013 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108545882A (en) * 2018-06-26 2018-09-18 南京林业大学 A kind of electric flocculation, magnetic flocculation and the integrated sewage-treatment plant of Magneto separate and method
CN110540327A (en) * 2019-08-27 2019-12-06 首创爱华(天津)市政环境工程有限公司 Advanced treatment process for activated sand micro-flocculation sewage
CN112607929A (en) * 2020-11-25 2021-04-06 湖南鑫远环境科技股份有限公司 Method and device for reinforced recovery of nitrogen and phosphorus from struvite
CN112607928A (en) * 2020-11-25 2021-04-06 湖南鑫远环境科技股份有限公司 Method for separating and recovering struvite crystal precipitate

Similar Documents

Publication Publication Date Title
CN107628676A (en) A kind of super Magneto separate waste water treatment process of electric flocculation
CN101088938B (en) Process of treating heavy metal containing sewage
Jotin et al. Electro coagulation for removal of chemical oxygen demand in sanitary landfill leachate
CN107337301B (en) A kind of method of the electric Fenton processing waste water of additional hydrogen peroxide
CN103523969B (en) Special apparatus for removing heavy metal ions in wastewater, and method thereof
CN105174633A (en) Comprehensive standard increase method for increasing standard of discharged water of municipal wastewater treatment plant from first grade B to first grade A
CN102730888B (en) High hardness and high turbidity industry wastewater treatment method
CN106800356A (en) A kind of advanced treatment of wastewater regeneration device based on biochemical and electrolysis tech
CN107055937A (en) A kind of advanced treatment of wastewater regeneration method based on biochemical and electrolysis tech
CN206486383U (en) Effectively reduce the processing system of chemical nickle-plating wastewater pollutant
CN107857401A (en) A kind of percolate nanofiltration concentrate treatment combined device
CN107540135A (en) A kind of safe and efficient percolate nanofiltration concentrate processing group technology
CN102153220A (en) Method for treating and recycling polishing waste water of plated part in electroplating industry
CN106242129A (en) A kind of municipal sewage plant discharge water is put forward mark method by one-level B to one-level A
CN108545882B (en) Electric flocculation, magnetic flocculation and magnetic separation integrated sewage treatment device and method
KR101238879B1 (en) Treatment Method for Cokes Waste Water Using Electrolysis and HGMS
CN105060411A (en) Internal electrolysis-electric flocculation method for processing phosphor-containing wastewater
CN107162121A (en) The method of electric flocculation-magnetic loading flocculation coupling processing heavy metal wastewater thereby
CN106630399A (en) Method for treating oily sewage by electrocatalytic oxidation MBR combined technology
CN105236662A (en) Comprehensive standard improving apparatus for municipal sewage treatment plant discharge water from glade 1B to grade A
CN103951139A (en) Oilfield wastewater treatment process
JP2007021427A (en) Wastewater treatment apparatus
CN107176729A (en) A kind of AEC electric flocculations waste water treatment process
CN106430744A (en) Device for improving standards of discharged water of municipal sewage treatment plant to first-level A from first-level B
CN108408846B (en) Electrochemical advanced treatment method for wastewater

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20180126

RJ01 Rejection of invention patent application after publication