CN108545882A - A kind of electric flocculation, magnetic flocculation and the integrated sewage-treatment plant of Magneto separate and method - Google Patents

A kind of electric flocculation, magnetic flocculation and the integrated sewage-treatment plant of Magneto separate and method Download PDF

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Publication number
CN108545882A
CN108545882A CN201810676398.9A CN201810676398A CN108545882A CN 108545882 A CN108545882 A CN 108545882A CN 201810676398 A CN201810676398 A CN 201810676398A CN 108545882 A CN108545882 A CN 108545882A
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magnetic
flocculation
reactive tank
magneto separate
aerator
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CN108545882B (en
Inventor
王郑
王子杰
许锴
薛红琴
刘亚利
林少华
林子增
陈蕾
荆肇乾
曹世玮
王祝来
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Nanjing Forestry University
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Nanjing Forestry University
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/463Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrocoagulation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/48Treatment of water, waste water, or sewage with magnetic or electric fields
    • C02F1/484Treatment of water, waste water, or sewage with magnetic or electric fields using electromagnets
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/722Oxidation by peroxides
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/74Treatment of water, waste water, or sewage by oxidation with air
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/20Heavy metals or heavy metal compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/02Specific form of oxidant
    • C02F2305/026Fenton's reagent

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The present invention relates to a kind of electric flocculation, magnetic flocculation and the integrated sewage-treatment plants of Magneto separate and method, the sewage-treatment plant to include:Inlet tank, reactive tank, water tank, aerator, store up mud box and power module, the inside of the reactive tank includes soluble electrode and electromagnetic induction device, when being carried out using the device, flco can be made fully to flocculate, electric flocculation, magnetic flocculation, the processing of Magneto separate integrated high-efficiency, device in the present invention is energy saving, it saves land, processing capacity is strong, sinking speed is fast, substantially increase the processing capacity and sinking speed of electric flocculation, and solves the problems, such as the magnetic powder recycling of magnetic flocculation, it can be directly used for processing electroplating wastewater, desulfurization wastewater, the higher industrial wastewater of the content of beary metal such as mine wastewater.

Description

A kind of electric flocculation, magnetic flocculation and the integrated sewage-treatment plant of Magneto separate and method
Technical field
The present invention relates to the sewage treatment fields in environmental project, in particular to a kind of electric flocculation, magnetic flocculation and magnetic The sewage-treatment plant and method of isolation integral.
Background technology
Heavy metal wastewater thereby is to an environmental pollution most serious and to endanger one of maximum industrial wastewater to the mankind, usually from In the industrial processes such as mining and metallurgy, machine-building, chemical industry, electronics, instrument.It is higher containing a large amount of dissolubilities in heavy metal wastewater thereby The heavy metal elements such as lead, chromium, nickel, mercury, copper, be discharged into water body if dealt with improperly, ecological environment can not only be damaged, The health of the mankind can be also influenced by biological chain enrichment.Heavy metal in waste water cannot generally be decomposed destruction, Its existence position can only be shifted and change its Material Form, traditional treatment method has chemical precipitation method, ion-exchange, biology Method, membrane separation process etc., but since operating cost is high, treatment effect is undesirable, easily causes secondary pollution problems, it is difficult to meet The processing requirement of Practical Project.
Electric flocculation, can be using metals such as aluminium, iron as anode, in direct current as novel heavy metal waste water treatment process Under the action of generate Al, Fe plasma, through it is a series of hydrolysis, polymerization and ferrous iron oxidation process, develop into various hydroxyls Complex compound, multinuclear hydroxo complex so that hydroxide, make the colloidal state impurity in waste water, suspended impurity coagulative precipitation and detach. Have the characteristics that take up little area compared to traditional handicraft, small investment, high treating effect, high degree of automation.Magnetic flocculation is a kind of logical It crosses and adds magnetic powder in common flocculation process and make the technology of flco high speed settling, the place of original flocculation process can be increased substantially Manage effect and sinking speed.But the problem that magnetic powder recycling is difficult so that magnetic flocculation can not be widely used in Practical Project.
It can be seen that electric flocculation and magnetic flocculation are separated in sewage disposal process at present, in different devices respectively Electric flocculation and magnetic flocculation are carried out, during magnetic powder recycles, the flco that impurity and magnetic powder are formed typically is transferred to other In device, is then detached or recycled, it is complicated during the impurity flocculation separation in sewage, and cannot effectively recycle Magnetic powder.
Invention content
The purpose of the present invention is overcome the deficiencies of the prior art and provide a kind of electric flocculation, magnetic flocculation and Magneto separate integration The sewage-treatment plant of sewage disposal reactive tank including above-mentioned reactive tank and a kind of using at above-mentioned sewage-treatment plant Manage sewage method, the present invention in electric flocculation, magnetic flocculation and the integrated sewage-treatment plant processing capacity of Magneto separate it is strong, behaviour It is easy to make operation, the magnetic powder rate of recovery is high, and operating cost is low.
The purpose of the present invention is to provide a kind of electric flocculation, magnetic flocculation and the integrated sewage disposal reactive tank of Magneto separate, It includes being set to inside the reactive tank:
Soluble electrode, corrosion is to realize electric flocculation under the function of current;
Electromagnetic induction device, by adsorbing and discharging magnetic powder to realize magnetic flocculation and Magneto separate.
Preferably, inlet and outlet, and the water inlet are respectively arranged in the two side walls outside the reactive tank Position be higher than the water outlet position.
Preferably, electrode card slot, electrode backing are equipped in the reactive tank, and the electrode card slot is located at the reactive tank On internal two opposite faces, the solubility electrode is positioned in the electrode card slot, and is supported by the electrode backing.
It is furthermore preferred that the solubility electrode is two pieces or more, it is made of iron, aluminium, and the connection side of soluble electrode Formula is that monopole or multipole connect.
Include at above-mentioned electric flocculation, magnetic flocculation and the integrated sewage of Magneto separate the present invention also aims to provide a kind of The sewage-treatment plant of reactive tank, including inlet tank, water tank, aerator, storage mud box, power module and reactive tank are managed, Wherein, the inlet tank, the reactive tank and the water tank are sequentially connected, the power module respectively with the reactive tank and Electromagnetic induction device connection, the aerator are located at the bottom of the reactive tank, the bottom of the reactive tank with it is described Store up mud box connection.
Preferably, the power module includes automatic control system, and the automatic control system can be controlled freely respectively The operation of reactive tank and electromagnetic induction device.
Preferably, bottom cell wall tilts in the reactive tank, and intermediate equipped with mud discharging mouth, the lower section of the mud discharging mouth and institute State storage mud box connection.
Preferably, the aerator is located at the medium position of the four inclination cell walls in bottom in reactive tank, the electromagnetism sense Answer device between the aerator and the mud discharging mouth.
The present invention also aims to provide a kind of electric flocculation, magnetic flocculation and the integrated sewage water treatment method of Magneto separate, Include the following steps:
Sewage is imported in reactive tank, reactive tank unlatching is controlled respectively by power module and electromagnetic induction device is closed, Soluble electrode corrosion in reactive tank generates flocculant, while the magnetic powder in electromagnetic induction device is discharged into sewage,
Opening aerator makes flocculant, magnetic powder and sewage come into full contact with,
After the completion of mixed processing, aerator is closed, flco is made fully to combine,
Electromagnetic induction device is opened, by the flco and magnetic contamination merged with magnetic powder in the absorption effluent of magnetic field,
It is again turned on aerator, adjusts the size of aeration quantity, the intensity of aeration is made to be less than the intensity of magnetic field absorption magnetic powder, Appropriate sweep is carried out to electromagnetic induction device to wash, and sludge is discharged under the premise of magnetic powder retains.
Preferably, the flco is made of flocculant, pollutant and magnetic powder, the flco and magnetic contamination in gravity and It is settled under magnetic collective effect.
Sewage water treatment method in the present invention is a kind of electric flocculation, magnetic flocculation and the integrated sewage disposal side of Magneto separate Method, reactive tank unlatching is controlled by power module respectively and electromagnetic induction device is closed, the soluble electrode corrosion in reactive tank Flocculant is generated, while the magnetic powder in electromagnetic induction device is discharged into sewage, then opening aerator makes flocculant, magnetic powder It is come into full contact with sewage, aerator is closed after the completion of mixed processing, flco fully combines and forms a large amount of alumen ustum in gravity Lower rapid precipitation opens electromagnetic induction device by the flco and magnetic contamination that are merged with magnetic powder in the absorption effluent of magnetic field, then Secondary opening aerator carries out appropriate sweep to electromagnetic induction device using aerator and washes, adjusts the size of aeration quantity, make aeration Intensity be less than the intensity of magnetic field absorption magnetic powder, appropriateness is carried out to electromagnetic induction device and sweeps and washes, is arranged under the premise of magnetic powder retains Go out sludge.
The present invention has the advantages that:
(1) present invention realizes electric flocculation, magnetic flocculation and Magneto separate integration, investment in the different phase of same device and makes Valence is low, and operation operation is easy, can save occupation of land, substantially increase flocculating effect and sinking speed,
(2) Stability and adaptability of the present invention is strong, can bear water quality and the water variation of bigger, can be directly used for handling The higher industrial wastewater of the content of beary metal such as electroplating wastewater, desulfurization wastewater, mine wastewater has wide development space and market Foreground.
Description of the drawings
In order to illustrate the technical solution of the embodiments of the present invention more clearly, below will be to needed in the embodiment attached Figure is briefly described, it should be understood that the following drawings illustrates only certain embodiments of the present invention, therefore is not construed as pair The restriction of range for those of ordinary skill in the art without creative efforts, can also be according to this A little attached drawings obtain other relevant attached drawings.
Fig. 1 is the plan view of electric flocculation of the present invention, magnetic flocculation and the integrated sewage-treatment plant of Magneto separate.
Fig. 2,3 for electric flocculation of the present invention, magnetic flocculation and the integrated sewage-treatment plant of Magneto separate sectional view.
Fig. 4 is the process chart of electric flocculation of the present invention, magnetic flocculation and the integrated sewage-treatment plant of Magneto separate.
Reference sign:1- water inlets;2- water outlets;3- electrode card slots;4- electrode backings;5- solubility electrodes;6- Aerator;7- electromagnetic induction devices;8- mud discharging mouths;9- inlet tanks;10- reactive tanks;11- filtered water tanks;12- power modules;13- Store mud box;14- feed water flows;15- goes out flow;16- electric power connection lines;17- spoil disposal streams;18- intake pumps;19- water outlet pumps;
Specific implementation mode
In order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below in conjunction with the embodiment of the present invention In attached drawing, technical scheme in the embodiment of the invention is clearly and completely described, it is clear that described embodiment is A part of the embodiment of the present invention, instead of all the embodiments.The present invention being usually described and illustrated herein in the accompanying drawings is implemented The component of example can be arranged and be designed with a variety of different configurations.Therefore, below to the reality of the present invention provided in the accompanying drawings The detailed description for applying example is not intended to limit the range of claimed invention, but is merely representative of the selected implementation of the present invention Example.Based on the embodiments of the present invention, those of ordinary skill in the art are obtained without creative efforts Every other embodiment, shall fall within the protection scope of the present invention.
It should be noted that:Similar label and letter indicate similar terms in following attached drawing, therefore, once a certain Xiang Yi It is defined, then it further need not be defined and explained in subsequent attached drawing in a attached drawing.
In the description of the present invention, it should be noted that term "center", "upper", "lower", "left", "right", "vertical", The orientation or positional relationship of the instructions such as "horizontal", "inner", "outside" is to be based on the orientation or positional relationship shown in the drawings, or be somebody's turn to do Invention product using when the orientation or positional relationship usually put, be merely for convenience of description of the present invention and simplification of the description, without It is instruction or implies that signified device or element must have a particular orientation, with specific azimuth configuration and operation, therefore not It can be interpreted as limitation of the present invention.In addition, term " first ", " second ", " third " etc. are only used for distinguishing description, and cannot manage Solution is instruction or implies relative importance.
In the description of the present invention, it is also necessary to which explanation is unless specifically defined or limited otherwise, term " setting ", " installation ", " connected ", " connection " shall be understood in a broad sense, for example, it may be fixedly connected, may be a detachable connection or one Connect to body;It can be mechanical connection, can also be electrical connection;It can be directly connected, it can also be indirect by intermediary It is connected, can is the connection inside two elements.For the ordinary skill in the art, on being understood with concrete condition State the concrete meaning of term in the present invention.
In the present invention unless specifically defined or limited otherwise, fisrt feature the "upper" of second feature or "lower" It may include that the first and second features are in direct contact, can also not be to be in direct contact but pass through it including the first and second features Between other characterisation contact.Moreover, fisrt feature second feature " on ", " top " and " above " include first special Sign is right over second feature and oblique upper, or is merely representative of fisrt feature level height and is higher than second feature.Fisrt feature exists Second feature " under ", " lower section " and " following " include fisrt feature immediately below second feature and obliquely downward, or be merely representative of Fisrt feature level height is less than second feature.
In the present invention, in the case of not contradiction or conflict, all embodiments, embodiment and feature of the invention It can be combined with each other.In the present invention, conventional unit, component etc., both can be commercially available, can also be according to of the invention public The content self-control opened.In the present invention, in order to protrude the emphasis of the present invention, to some conventional operations and unit, component The omission of progress, or be only briefly described.
The object of the present invention is to provide a kind of electric flocculation, magnetic flocculation and the integrated sewage-treatment plant of Magneto separate and sides Method may be implemented electric flocculation, magnetic flocculation, Magneto separate the integrated high-efficiency processing of heavy metal wastewater thereby, electricity carried out using above-mentioned apparatus When flocculation, magnetic flocculation and the integrated sewage disposal of Magneto separate, the impurity in sewage can be made abundant by electric flocculation, magnetic flocculation Flocculation forms flco, flco under gravity and magnetic collective effect rapid subsidence, detach and be discharged, magnetic powder is in electromagnetic induction Recycling under the action of device has not only efficiently separated the impurity in sewage, but also magnetic powder is enable effectively to recycle again It utilizes.
Electric flocculation, magnetic flocculation and the integrated sewage-treatment plant of Magneto separate and method of the present invention, it is energy saving, save land, locate Reason ability is strong, sinking speed is fast, substantially increases the processing capacity and sinking speed of electric flocculation, and solves the magnetic powder of magnetic flocculation Recycling problem can be directly used for the higher industrial wastewaters of content of beary metal such as processing electroplating wastewater, desulfurization wastewater, mine wastewater, With wide development space and market prospects.
Embodiment 1:
As shown in Figure 1, the present embodiment provides a kind of electric flocculation, magnetic flocculation and the integrated sewage disposal reactive tanks of Magneto separate 10, including water inlet 1, water outlet 2, aerator 6, electromagnetic induction device 7 and mud discharging mouth 8.Two side walls outside reactive tank 10 On be respectively arranged with water inlet 1 and water outlet 2, aerator 6 and electromagnetic induction is respectively set in the bottom sidewall in reactive tank 10 The bottom centre of device 7, reactive tank 10 is provided with mud discharging mouth 8.
In use, sewage enters reactive tank 10 by water inlet 1, control reactive tank 10 carries out electric flocculation, electromagnetic induction device 7 Magnetic flocculation is carried out, aerator 6 keeps mixing of sewage during flocculated more uniform, is carried out at the same time in reactive tank 10 Supernatant after the flocculation treatment of electricity-magnetic flocculation is discharged by water outlet 2, and flco is discharged by mud discharging mouth 8.
Embodiment 2:
As shown in Fig. 2, the present embodiment provides a kind of electric flocculation, magnetic flocculation and the integrated sewage disposal reactive tanks of Magneto separate 10, including water inlet 1, water outlet 2, electrode card slot 3, electrode backing 4, soluble electrode 5, aerator 6, electromagnetic induction device 7 and mud discharging mouth 8.Wherein, water inlet 1 and water outlet 2 are located in the two side walls outside reactive tank 10, and water inlet 1 Position is higher than the position of water outlet 2, and electrode card slot 3 is located on 10 two opposite faces in inside of reactive tank, and soluble electrode 5 is positioned over It in electrode card slot 3, and is supported by electrode backing 4, aerator 6 and electromagnetic induction is respectively set in the bottom sidewall in reactive tank 10 The bottom centre of device 7, reactive tank 10 is provided with mud discharging mouth 8.
In use, the electric flocculation process in reactive tank 10 is as follows:Soluble electrode 5 is dissoluted under the action of direct current, Through it is a series of hydrolysis, polymerization and ferrous iron oxidation process, develop into various hydroxo complexes, multinuclear hydroxo complex so that Hydroxide, make the colloidal state impurity in waste water, suspended impurity coagulative precipitation and detach, while charge contaminant particle in electric field Middle swimming, Partial charge are neutralized by electrode and it are promoted to take off steady coagulation.
Magnetic flocculation process in reactive tank 10 is as follows:Electromagnetic induction device can adsorb magnetic powder by discharging magnetic field, lead to Closing magnetic field is crossed to discharge magnetic powder, magnetic field intensity can be changed in electromagnetic induction device.Impurity in sewage changes under the action of magnetic powder The stability for becoming pollutant or jelly surface, make its it is de- it is steady promote cohesion, then the effects that being caught by adsorption bridging and net, makes wadding Body constantly agglomerates increase, and magnetic powder can then play the role of the core that flocculates.
Electric flocculation and magnetic flocculation, aluminium ion, the iron ion generated during electric flocculation, reaction are carried out at the same time in reactive tank 10 It generates with the flocculation reaction that magnetic powder is " core ", generates flco, flco has magnetism because including magnetic powder, simultaneously as solvable Property electrode corrosion generate mutual repulsion driving with ionization so that magnetic powder can more disperse between each other, finally The flocculate of purification shows as the flocculate largely disperseed, colloidal state that can be in more sufficiently cleaned up waste water, suspended state impurity.
Embodiment 3:
As shown in figure 3, the present embodiment provides a kind of electric flocculation, magnetic flocculation and the integrated sewage disposal reactive tanks of Magneto separate 10, including:Water inlet 1, water outlet 2, electrode card slot 3, electrode backing 4, soluble electrode 5, aerator 6, electromagnetic induction dress Set 7 and mud discharging mouth 8, wherein water inlet 1 and water outlet 2 are located at the both sides of reactive tank 10, and the position of water inlet 1 is higher than The position of water outlet 2, electrode card slot 3 are located on 10 two opposite faces in inside of reactive tank, and soluble electrode 5 is positioned over electrode card slot It in 3, and is supported by electrode backing 4, is equipped with aerator 6, reactive tank in reactive tank 10 at the medium position of bottom angled cell wall It is equipped with mud discharging mouth 8 among 10 bottoms, electromagnetic induction device 7 is equipped between aerator 6 and mud discharging mouth 8.
As the preferred embodiment of the present invention, reactive tank 10 is internally provided with water inlet 1, water outlet 2, electrode card slot 3, electricity Pole backing 4, water inlet 1 and water outlet 2 are located at the both sides of reactive tank 10, and the position of water inlet 1 is higher than the position of water outlet 2 It sets, electrode card slot 3 is located on 10 two opposite faces in inside of reactive tank, and soluble electrode 5 is positioned in electrode card slot 3, and by institute The support of electrode backing 4 is stated, soluble electrode 5 is two pieces or more, is made of iron, aluminium, and the connection type of soluble electrode is Monopole or multipole connection.
Sewage enters from water inlet 1 inside reactive tank 10, and soluble electrode 5 is dissoluted under the action of direct current, is being passed through A series of oxidation process of hydrolysis, polymerization and ferrous iron develops into various hydroxo complexes, multinuclear hydroxo complex so that hydrogen-oxygen Compound, make the colloidal state impurity in waste water, suspended impurity coagulative precipitation and detach, while charge contaminant particle swim in the electric field Dynamic, Partial charge is neutralized by electrode and it is promoted to take off steady coagulation.
As the preferred embodiment of the present invention, it is additionally provided with intake pump 18 between inlet tank 9 of the invention and reactive tank 10, Water outlet pump 19 is additionally provided between reactive tank 10 and filtered water tank 11.
Sewage enters reactive tank 10, electric flocculation, magnetic flocculation and Magneto separate one under the action of intake pump 18 in inlet tank 9 The clear water formed after the sewage disposal of change enters under the action of water outlet pump 19 in filtered water tank 11.
As the preferred embodiment of the present invention, 10 bottom cell wall of reactive tank tilts, and intermediate equipped with mud discharging mouth 8, spoil disposal The lower section of mouth 8 is connect with storage mud box 13.
The bottom cell wall of reactive tank 10 tilts so that the flco and magnetic contamination that electric flocculation, magnetic flocculation generate are in gravity Under the action of, it is easier to it is slipped to the bottom of reactive tank 10, the storage mud box 13 of lower section is entered by mud discharging mouth 8.
As the preferred embodiment of the present invention, power module 12 includes automatic control system, and automatic control system can Difference freely controls the operation of the electromagnetic induction device 7 inside reactive tank 10 and reactive tank 10.
When automatic control system can automatically control the switch of reactive tank 10, electric current, voltage, frequency, empty accounting, work Between, cycle-index, automatic control system can automatically control the switch of electromagnetic induction device, electric current, voltage, magnetic field intensity, work Make time, cycle-index.
As the preferred embodiment of the present invention, aerator 6 is located at the middle part of 10 bottom of reactive tank, four inclination cell walls The number of position, aerator 6 is four.
Aerator 6 is located at the medium position of the four inclination cell walls in bottom of reactive tank 10, by adjusting aerator 6 Rotate aeration head position and aeration intensity, make the sewage in reactive tank 10 during electric flocculation and magnetic flocculation can It is sufficiently mixed, is conducive to the impurity in sewage and is flocculated and be detached from, completed in sewage mixed processing and then secondary opening is aerated Device 6 adjusts the size of aeration quantity, so that the intensity of aeration is less than the intensity of magnetic field absorption magnetic powder, is carried out to electromagnetic induction device Appropriateness, which is swept, washes, and sludge is discharged under the premise of magnetic powder retains.
As the preferred embodiment of the present invention, electromagnetic induction device 7 is between aerator 6 and mud discharging mouth 8.
Electromagnetic induction device 7 can adsorb magnetic powder by discharging magnetic field, discharge magnetic powder, electromagnetism sense by closing magnetic field Answer device that magnetic field intensity can be changed, and magnetic field intensity sweeps the intensity for washing mud discharging mouth 8 more than aerator 6.
Embodiment 4
As shown in figure 4, the present embodiment provides a kind of electric flocculation, magnetic flocculation and the integrated sewage-treatment plant of Magneto separate, Including inlet tank 9, intake pump 18, reactive tank 10, water outlet pump 19, filtered water tank 11, power module 12, storage mud box 13, wherein water inlet Case 9, intake pump 18, reactive tank 10, water outlet pump 19, filtered water tank 11 are sequentially connected, power module 12 respectively with reactive tank 10 and anti- The electromagnetic induction device 7 inside slot 10 is answered to connect, the bottom of reactive tank 10 is connect with storage mud box 13.
Electric flocculation, magnetic flocculation and the integrated waste water processes of Magneto separate in the present invention is as follows:Dirt in inlet tank 9 For water under the action of intake pump 18, the feed water flow 14 of formation enters reactive tank 10, power module 12 by electric power connection line 16 with Reactive tank 10 connects and controls reactive tank 10 and handles sewage, and control reactive tank 10 is opened and electromagnetic induction device 7 is closed, Soluble electrode corrosion in reactive tank 10 generates flocculant, while the magnetic powder in electromagnetic induction device 7 is discharged into sewage, so Opening aerator 6 afterwards makes flocculant, magnetic powder and sewage come into full contact with, and aerator 6 is closed after the completion of mixed processing, flco fills Point combine and to form a large amount of alumen ustum and precipitate rapidly under the effect of gravity, open electromagnetic induction device 7 by the absorption effluent of magnetic field with The flco and magnetic contamination of magnetic powder fusion, are again turned on aerator 6, are carried out to electromagnetic induction device 7 using aerator 6 Appropriateness, which is swept, washes, and adjusts the size of aeration quantity, so that the intensity of aeration is less than the intensity of magnetic field absorption magnetic powder, to electromagnetic induction device 7 It carries out appropriate sweep to wash, for wherein clear water under the action of water outlet pump 19, the clear water stream 15 of formation enters filtered water tank 11, what sludge was formed Spoil disposal stream 17 enters storage mud box 13 by mud discharging mouth.
Embodiment 5:
A kind of electric flocculation, magnetic flocculation and the integrated sewage water treatment method of Magneto separate, include the following steps:
Sewage is imported in reactive tank, reactive tank unlatching is controlled respectively by power module and electromagnetic induction device is closed, Soluble electrode corrosion in reactive tank generates flocculant, while the magnetic powder in electromagnetic induction device is discharged into sewage,
Opening aerator makes flocculant, magnetic powder and sewage come into full contact with,
After the completion of mixed processing, aerator is closed, flco is made fully to combine,
Electromagnetic induction device is opened, by the flco and magnetic contamination merged with magnetic powder in the absorption effluent of magnetic field,
It is again turned on aerator, adjusts the size of aeration quantity, the intensity of aeration is made to be less than the intensity of magnetic field absorption magnetic powder, Appropriate sweep is carried out to electromagnetic induction device to wash, and sludge is discharged under the premise of magnetic powder retains.
Electric flocculation, magnetic flocculation and the integrated sewage treatment process of Magneto separate in the present invention is in Magneto separate leading portion coagulation rank Duan Buzai dosing coagulants (such as aluminium polychloride, bodied ferric sulfate, poly-ferric chloride), and pass through the corrosion of soluble electrode Electric flocculation is carried out to sewage, forms flco.The metals such as aluminium, iron are anode, quilt under the action of electric current in electric flocculation reaction process Corrosion generates aluminium ion, iron ion, in a series of oxidation process through hydrolysis, polymerization and ferrous iron, develops into various hydroxyl networks Object, multinuclear hydroxo complex are closed down to hydroxide, meanwhile, during magnetic flocculation, electromagnetic induction device discharges magnetic powder, electricity-magnetic In flocculation process, colloidal state impurity in waste water, suspended impurity cohesion, condensation product and magnetic powder be combined with each other precipitation.Soluble electrode Corrosion generates aluminium ion, iron ion, and it is that flocculation reaction occurs for " core " that reaction, which is generated with magnetic powder, generates flco.The generation of flco Amount is controlled according to current parameters, and flco production quantity is controllable, accurate to react, and reduces the wasting of resources, cost-effective.Flco There is magnetism because including magnetic powder, can be separated from the water out rapidly under the magnetic fields of electromagnetic induction device, sewage It is purified by above-mentioned flow.Have the characteristics that magnetism, also referred to as magnetic flco according to sludge flco.
Simultaneously as the corrosion of soluble electrode generates mutual repulsion driving with ionization so that magnetic powder is mutual Between can more disperse, the flocculate of final purification shows as the flocculate largely disperseed, can more sufficiently cleaned up waste water In colloidal state, suspended state impurity.Meanwhile swimming, Partial charge quilt can occur in the electric field for charged contaminants particle or flco Electrode neutralizes and it is promoted to take off steady coagulation.It is net by electric flocculation magnetic flocculation of the present invention and the integrated sewage treatment process of Magneto separate The waste water colloidal state and suspended contamination content of change are extremely low, and the quality after purification of waste water is extremely outstanding.
In addition, when sewage carries out electrolytic flocculation processing, not only there is coagulative precipitation effect to colloidal state impurity and suspended impurity, also Include the purified treatment acted on by anodizing and cathodic reduction, multiple pollutant in water removal can be removed.
It can be seen that the present invention first turns in electric flocculation, magnetic flocculation and the integrated sewage disposal process of Magneto separate Reactive tank carries out corrosion for soluble electrode and generates flocculant, closes electromagnetic induction device and discharges magnetic powder, makes sewage and flocculation Agent and magnetic powder contact, sewage are carried out at the same time electric flocculation, the flocculation treatment of magnetic flocculation in reactive tank, then open electromagnetic induction again Device carries out separating treatment by the flco and magnetic contamination merged with magnetic powder in the absorption effluent of magnetic field.As it can be seen that in the present invention It is not only carried out at the same time electric flocculation, the flocculation treatment of magnetic flocculation in reactive tank, reduces flocculated complexity respectively, hence it is evident that improve Flocculated effect, and magnetic flocculation and Magneto separate are realized to control absorption and the release of magnetic powder by electromagnetic induction device, It is not only conveniently operated easily controllable, but also the impurity in sewage can be efficiently separated, magnetic powder and magnetic powder separation is added without additional Processing equipment, magnetic powder can be recycled, and magnetic flocculation and the speed and efficiency of Magneto separate are substantially increased.
In this as it can be seen that the present invention realizes electric flocculation, magnetic flocculation and Magneto separate integration in the different phase of same device, Investment cost is low, and operation operation is easy, can save occupation of land, substantially increase flocculating effect and sinking speed;The present invention can be direct For the transformation of original electric flocculation equipment in Practical Project, installation is convenient, and pond and magnetic powder separation are added without increasing magnetic powder Pond can achieve the purpose that propose mark transformation;Magnetic powder is added in the present invention when start to process sewage, sewage is in magnetic powder, wadding Flco is formed under the action of solidifying agent, electromagnetic induction device is then opened and adsorbs the flco combined with magnetic powder, solve magnetic flocculation Magnetic powder recycles problem, increases the rate of recovery of magnetic powder, simplifies the process that magnetic powder is added and detached, improve the speed of wastewater treatment Rate;Stability and adaptability of the present invention is strong, can bear water quality and the water variation of bigger, it is useless to can be directly used for processing plating The higher industrial wastewater of the content of beary metal such as water, desulfurization wastewater, mine wastewater has wide development space and market prospects.
It these are only the preferred embodiment of the present invention, be not intended to restrict the invention, for those skilled in the art For member, the invention may be variously modified and varied.Any modification made by all within the spirits and principles of the present invention, Equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.

Claims (10)

1. a kind of electric flocculation, magnetic flocculation and the integrated sewage disposal reactive tank of Magneto separate, which is characterized in that it includes being set to Inside the reactive tank:
Soluble electrode, corrosion is to realize electric flocculation under the function of current;
Electromagnetic induction device, by adsorbing and discharging magnetic powder to realize magnetic flocculation and Magneto separate.
2. electric flocculation according to claim 1, magnetic flocculation and the integrated sewage disposal reactive tank of Magneto separate, feature exist In being respectively arranged with inlet and outlet in the two side walls outside the reactive tank, and the position of the water inlet is higher than institute State the position of water outlet.
3. electric flocculation according to claim 1, magnetic flocculation and the integrated sewage disposal reactive tank of Magneto separate, feature exist In the reactive tank is interior to be equipped with electrode card slot, electrode backing, and the electrode card slot is located at reactive tank inside two relatively On face, the solubility electrode is positioned in the electrode card slot, and is supported by the electrode backing.
4. electric flocculation according to claim 3, magnetic flocculation and the integrated sewage disposal reactive tank of Magneto separate, feature exist In the solubility electrode is two pieces or more, is made of iron, aluminium, and the connection type of soluble electrode is monopole or multipole Connection.
5. a kind of electric flocculation, magnetic flocculation and the integrated sewage-treatment plant of Magneto separate, which is characterized in that including inlet tank, go out Water tank, aerator, storage mud box, power module and the reactive tank as described in any one of claim 1-4, wherein institute Inlet tank, the reactive tank and the water tank is stated to be sequentially connected, the power module respectively with the reactive tank and the electricity Magnetic-inductive device connects, and the aerator is located at the bottom of the reactive tank, the bottom of the reactive tank and the storage mud box Connection.
6. electric flocculation according to claim 5, magnetic flocculation and the integrated sewage-treatment plant of Magneto separate, feature exist In the power module includes automatic control system, and the automatic control system freely can control reactive tank and electromagnetism respectively The operation of sensing device.
7. electric flocculation according to claim 5, magnetic flocculation and the integrated sewage-treatment plant of Magneto separate, feature exist In bottom cell wall tilts in the reactive tank, and intermediate equipped with mud discharging mouth, and the lower section of the mud discharging mouth connects with the storage mud box It connects.
8. electric flocculation according to claim 7, magnetic flocculation and the integrated sewage-treatment plant of Magneto separate, feature exist In the aerator is located at the medium position of the four inclination cell walls in bottom in the reactive tank, the electromagnetic induction device position Between the aerator and the mud discharging mouth.
9. a kind of electric flocculation, magnetic flocculation and the integrated sewage water treatment method of Magneto separate, which is characterized in that include the following steps:
Sewage is imported in reactive tank, reactive tank is controlled respectively by power module and opens and electromagnetic induction device closing, reaction Soluble electrode corrosion in slot generates flocculant, while the magnetic powder in electromagnetic induction device is discharged into sewage,
Opening aerator makes flocculant, magnetic powder and sewage come into full contact with,
After the completion of mixed processing, aerator is closed, flco is made fully to combine,
Electromagnetic induction device is opened, by the flco and magnetic contamination merged with magnetic powder in the absorption effluent of magnetic field,
It is again turned on aerator, adjusts the size of aeration quantity, so that the intensity of aeration is less than the intensity of magnetic field absorption magnetic powder, to electricity Magnetic-inductive device carries out appropriate sweep and washes, and sludge is discharged under the premise of magnetic powder retains.
10. electric flocculation according to claim 9, magnetic flocculation and the integrated sewage water treatment method of Magneto separate, feature exist In the flco is made of flocculant, pollutant and magnetic powder, and the flco and magnetic contamination are in gravity and magnetic collective effect Lower sedimentation.
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