CN107619625A - A kind of environmentally friendly showering finish paint of high comprehensive performance and preparation method thereof - Google Patents

A kind of environmentally friendly showering finish paint of high comprehensive performance and preparation method thereof Download PDF

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Publication number
CN107619625A
CN107619625A CN201710627583.4A CN201710627583A CN107619625A CN 107619625 A CN107619625 A CN 107619625A CN 201710627583 A CN201710627583 A CN 201710627583A CN 107619625 A CN107619625 A CN 107619625A
Authority
CN
China
Prior art keywords
finish paint
environmentally friendly
comprehensive performance
high comprehensive
showering finish
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201710627583.4A
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Chinese (zh)
Inventor
陈春梅
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Individual
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Individual
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Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201710627583.4A priority Critical patent/CN107619625A/en
Priority to PCT/CN2017/101471 priority patent/WO2019019299A1/en
Publication of CN107619625A publication Critical patent/CN107619625A/en
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/08—Polyesters modified with higher fatty oils or their acids, or with resins or resin acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D101/00—Coating compositions based on cellulose, modified cellulose, or cellulose derivatives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D101/00—Coating compositions based on cellulose, modified cellulose, or cellulose derivatives
    • C09D101/08—Cellulose derivatives
    • C09D101/16—Esters of inorganic acids
    • C09D101/18—Cellulose nitrate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
    • C09D161/02—Condensation polymers of aldehydes or ketones only
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
    • C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20—Diluents or solvents

Abstract

The present invention relates to a kind of coating.A kind of environmentally friendly showering finish paint of high comprehensive performance, is made up of, the varnish is made up of the component of following mass percent varnish and diluent：Hydroxyl alkyd resinses 10 ~ 20%, aldehyde ketone resin 20 ~ 25%, amino resins 3 5%, 1/4 second nitrocotton 25 ~ 35%, auxiliary agent 5.5% ~ 15%, solvent 25 ~ 35%.For the present invention by screening suitable resin system and dicyandiamide solution, prepared showering finish paint has excellent dryness, glossiness, richness, adhesive force.

Description

A kind of environmentally friendly showering finish paint of high comprehensive performance and preparation method thereof
Technical field
The present invention relates to a kind of coating.
Background technology
Loss is big when showering finish paint generally existing in the market is constructed, the easy lifting of paint film, the shortcomings of easily turning white.
The content of the invention
Based on this, the technical problems to be solved by the invention are to provide a kind of good environmentally friendly showering finish paint of combination property, Its preparation method is also provided.
A kind of environmentally friendly showering finish paint of high comprehensive performance, is made up of, the varnish is by following quality varnish and diluent The component composition of percentage：Hydroxyl alkyd resinses 10 ~ 20%, aldehyde ketone resin 20 ~ 25%, amino resins 3-5%, 1/4 second nitrocotton 25 ~ 35%, auxiliary agent 5.5% ~ 15%, solvent 25 ~ 35%.Resin in the formula is to the dryness of paint film, gloss, richness, solid Part content is significantly improved, and product is also had clear improvement to the adhesive force of ground, can also improve hardness of paint film.
Further, the solvent 100% is counted by mass percentage, by butyl glycol ether 2-10%, acetone 5-10%, methyl Pentanone alcohol 10-20%, isopropanol 20-30%, isobutanol 25-35%, ethyl acetate 15-30% compositions.Above-mentioned solvent formula is special For the dicyandiamide solution different from conventional spray paint technique of showering finish paint research and development, solves the problems, such as conventional spray paint finish paint because of solvent The problem of caused paint film easily turns white, lifting, bad levelling, also solve the easy stream pendant caused by showering is constructed, paint film The problem of thickness bad control.
Further, the solvent 100% is counted by mass percentage, by ethylene glycol monomethyl ether 5%, acetone 5%, methylpentanone Alcohol 10%, isopropanol 30%, isobutanol 35%, ethyl acetate 15% form.
Further, the auxiliary agent is plasticizer 2 ~ 5%, levelling agent 0.5 ~ 1.5%, adhesion promoter 3-5%.
Further, the diluent is based on percent by volume 100%, by ethyl acetate 20-30%, methyl iso-butyl ketone (MIBK) 5- 10%, methylpentanolone 10-20%, isopropanol 20-30%, isobutanol 20-30% are formed.
The preparation method of above-mentioned environmental protection coating material is：First solvent is mixed, is slowly added into while stirring with dispersion machine 1/4 second Nitrocotton, side adds hydroxyl alkyd resinses and aldehyde ketone resin while stirring after nitrocotton dissolving completely in 1/4 second, treats hydroxyl alkyd After resin and aldehyde ketone resin dissolve well, auxiliary agent is sequentially added while stirring, is stirred.
The present invention has the advantages that：
For the present invention by screening suitable resin system and dicyandiamide solution, prepared showering finish paint has excellent dryness, light Damp degree, richness, adhesive force.
Embodiment
With reference to embodiment, the present invention will be described in detail.
Above example uses following preparation technology：First solvent is mixed, is slowly added into while stirring with dispersion machine 1/4 second Nitrocotton, side adds hydroxyl alkyd resinses and aldehyde ketone resin while stirring after nitrocotton dissolving completely in 1/4 second, treats hydroxyl alkyd After resin and aldehyde ketone resin dissolve well, auxiliary agent is sequentially added while stirring, is stirred.
Varnish prepared by above three embodiment, with diluent with 1:3 volume ratio mixing, obtains being directly used in construction Finished product finish paint.The formula of diluent, based on percent by volume 100%, by ethyl acetate 20%, methyl iso-butyl ketone (MIBK) 10%, methyl Pentanone alcohol 10%, isopropanol 30%, isobutanol 30% form.
As shown in upper table, the advantages such as finish paint of the invention has good surface effect, hardness, adhesive force, dryness good.

Claims (6)

1. a kind of environmentally friendly showering finish paint of high comprehensive performance, is made up of varnish and diluent, it is characterised in that：The varnish by The component composition of following mass percent：Hydroxyl alkyd resinses 10 ~ 20%, aldehyde ketone resin 20 ~ 25%, amino resins 3-5%, 1/4 Second nitrocotton 25 ~ 35%, auxiliary agent 5.5% ~ 15%, solvent 25 ~ 35%.
2. the environmentally friendly showering finish paint of high comprehensive performance according to claim 1, it is characterised in that：The solvent presses quality Percentage 100% is counted, by butyl glycol ether 2-10%, acetone 5-10%, methylpentanolone 10-20%, isopropanol 20-30%, isobutanol 25-35%, ethyl acetate 15-30% are formed.
3. the environmentally friendly showering finish paint of high comprehensive performance according to claim 2, it is characterised in that：The solvent presses quality Percentage 100% is counted, by ethylene glycol monomethyl ether 5%, acetone 5%, methylpentanolone 10%, isopropanol 30%, isobutanol 35%, ethyl acetate 15% composition.
4. the environmentally friendly showering finish paint of high comprehensive performance according to claim 1, it is characterised in that：The auxiliary agent is plasticising Agent 2 ~ 5%, levelling agent 0.5 ~ 1.5%, adhesion promoter 3-5%.
5. the environmentally friendly showering finish paint of high comprehensive performance according to claim 1, it is characterised in that：The diluent presses body Product percentage 100% is counted, by ethyl acetate 20-30%, methyl iso-butyl ketone (MIBK) 5-10%, methylpentanolone 10-20%, isopropanol 20- 30%, isobutanol 20-30% are formed.
A kind of 6. preparation method of the environmentally friendly showering finish paint described in claim 1 ~ 4 any one, it is characterised in that the varnish Preparation technology be：First solvent is mixed, is slowly added into 1/4 second nitrocotton while stirring with dispersion machine, treats that 1/4 second nitrocotton is molten Solution completely after while stirring side add hydroxyl alkyd resinses and aldehyde ketone resin, treat hydroxyl alkyd resinses and aldehyde ketone resin dissolve it is good with Afterwards, auxiliary agent is sequentially added while stirring, is stirred.
CN201710627583.4A 2017-07-28 2017-07-28 A kind of environmentally friendly showering finish paint of high comprehensive performance and preparation method thereof Withdrawn CN107619625A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201710627583.4A CN107619625A (en) 2017-07-28 2017-07-28 A kind of environmentally friendly showering finish paint of high comprehensive performance and preparation method thereof
PCT/CN2017/101471 WO2019019299A1 (en) 2017-07-28 2017-09-13 Environment-friendly curtain-coating paint with excellent comprehensive performance and preparation method therefor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710627583.4A CN107619625A (en) 2017-07-28 2017-07-28 A kind of environmentally friendly showering finish paint of high comprehensive performance and preparation method thereof

Publications (1)

Publication Number Publication Date
CN107619625A true CN107619625A (en) 2018-01-23

Family

ID=61088735

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710627583.4A Withdrawn CN107619625A (en) 2017-07-28 2017-07-28 A kind of environmentally friendly showering finish paint of high comprehensive performance and preparation method thereof

Country Status (2)

Country Link
CN (1) CN107619625A (en)
WO (1) WO2019019299A1 (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1390899A (en) * 2002-07-26 2003-01-15 东莞东成发化工有限公司 Vacuum electroplating surface paint for plastics and its preparing process
CN102020916A (en) * 2010-12-14 2011-04-20 惠州市长润发涂料有限公司 Nitrocellulose varnish and preparation method thereof
CN102408551A (en) * 2011-10-19 2012-04-11 江苏三木集团有限公司 Preparation method of alkyd resin
CN104927488A (en) * 2015-05-25 2015-09-23 恒昌涂料（惠阳）有限公司 Shower coating finish paint for plastic vacuum electroplated product, and preparation method and construction method of shower coating finish paint
CN106398400A (en) * 2016-09-22 2017-02-15 广东珠江化工涂料有限公司 Environment-friendly nitrocellulose varnish and preparation method thereof

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5352542A (en) * 1976-10-01 1978-05-13 Kansai Paint Co Ltd Cold curing high solid coatng composition
CN102061122A (en) * 2010-12-16 2011-05-18 铁岭永新涂料有限公司 Low-temperature baking automobile finish and preparation method thereof
CN103031051A (en) * 2012-12-27 2013-04-10 合众（佛山）化工有限公司 Preparation method of scratch-resistant bicomponent polyurethane carpentry matt varnish
CN103333599B (en) * 2013-07-24 2015-08-19 紫荆花制漆（成都）有限公司 A kind of dull finishing coat and preparation method thereof, using method

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1390899A (en) * 2002-07-26 2003-01-15 东莞东成发化工有限公司 Vacuum electroplating surface paint for plastics and its preparing process
CN102020916A (en) * 2010-12-14 2011-04-20 惠州市长润发涂料有限公司 Nitrocellulose varnish and preparation method thereof
CN102408551A (en) * 2011-10-19 2012-04-11 江苏三木集团有限公司 Preparation method of alkyd resin
CN104927488A (en) * 2015-05-25 2015-09-23 恒昌涂料（惠阳）有限公司 Shower coating finish paint for plastic vacuum electroplated product, and preparation method and construction method of shower coating finish paint
CN106398400A (en) * 2016-09-22 2017-02-15 广东珠江化工涂料有限公司 Environment-friendly nitrocellulose varnish and preparation method thereof

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Publication number Publication date
WO2019019299A1 (en) 2019-01-31

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Application publication date: 20180123

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