CN107603401A - A kind of strong interiro wall latex paint of abrasion resistance - Google Patents
A kind of strong interiro wall latex paint of abrasion resistance Download PDFInfo
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- CN107603401A CN107603401A CN201710850481.9A CN201710850481A CN107603401A CN 107603401 A CN107603401 A CN 107603401A CN 201710850481 A CN201710850481 A CN 201710850481A CN 107603401 A CN107603401 A CN 107603401A
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- abrasion resistance
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- latex paint
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Abstract
The invention belongs to technical field of coatings, the strong interiro wall latex paint of especially a kind of abrasion resistance, it is made up of following raw material:Lauryl aldehyde, nerol, phenolic resin, konjac glucomannan, bamboo juice, silicone acrylic emulsion, nanometer illite powder, activation pitchstone powder, propylene glycol methyl ether acetate, alumina silicate, deionized water;Nanometer illite powder and activation pitchstone powder are fully dispersed in emulsion paint system, the interface binding power that can be effectively improved between emulsion particle, play enhancing and repairing effect, gather into network structure, coating strength is further improved, improves its mechanical property, strengthens its abrasion resistance;In addition, each component mating reaction, not only so that film is fine and close, viscoplasticity is good, good to the adhesive force of base material, hardness and wearability are good, so as to improve the wash-resistant property of paint film, and active material therein occurs through aldehyde condensation reaction and electrophilic addition reaction effectively by formaldehyde removing with formaldehyde, and suppress the generation of VOC.
Description
Technical field
The invention belongs to technical field of coatings, the strong interiro wall latex paint of especially a kind of abrasion resistance.
Background technology
With the fast development of society, the material and culture and living standard of people also increasingly improve, and living conditions are increasingly
Good, home improvement is also just more and more luxurious, but as the change of living conditions and the passage of dwell time, indoor emulsion paint are difficult
Exempt from pollution or invasion of the meeting by each side such as dust, spot, it is necessary to which not timing shampoo, this requires interior wall latex
Paint has good wash-resistant property, but commercially available common interiro wall latex paint wash-resistant property is unsatisfactory, so as to wall
Aesthetic property causes very big harmful effect;Therefore, it is urgently to be resolved hurrily at present ask to invent a kind of strong interiro wall latex paint of abrasion resistance
Topic.
The content of the invention
A kind of in view of the above-mentioned problems, the present invention is intended to provide strong interiro wall latex paint of abrasion resistance.
The present invention is achieved through the following technical solutions:
A kind of strong interiro wall latex paint of abrasion resistance, is made up of the raw material of following parts by weight:1.2 ~ 1.4 parts of lauryl aldehyde, nerol
0.5 ~ 0.7 part, 18 ~ 20 parts of phenolic resin, 4 ~ 5 parts of konjac glucomannan, 6 ~ 7 parts of bamboo juice, silicone acrylic emulsion 16 ~ 18 part, nanometer illite powder
4 ~ 5 parts of end, 5 ~ 6 parts of activation pitchstone powder, 12 ~ 14 parts of propylene glycol methyl ether acetate, 2.4 ~ 2.8 parts of alumina silicate, deionized water
24 ~ 28 parts.
As the further scheme of invention:The granularity of described nanometer illite powder is 10 ~ 20nm.
As the further scheme of invention:Described activation pitchstone powder, is prepared according to the following steps:By pitchstone
Powder inserts cryostat under conditions of temperature is -7 ~ -5 DEG C and handles 34 ~ 38min, takes out, it is 370 ~ 390 DEG C to insert temperature
Under the conditions of 26 ~ 30min of steam treatment, add the boric acid solution that weight is 0.2 ~ 0.3 times of pitchstone powder weight amount and mix
Uniformly, the microwave drying under conditions of temperature is 72 ~ 78 DEG C, frequency is 660 ~ 680MPa, must activate pitchstone powder.
As the further scheme of invention:The mass fraction of described boric acid solution is 6% ~ 8%.
As the further scheme of invention:A kind of preparation method of the strong interiro wall latex paint of abrasion resistance, specifically include with
Lower step:
(1)Phenolic resin, konjac glucomannan and silicone acrylic emulsion are heated to 85 ~ 90 DEG C, with the agitator that rotating speed is 330 ~ 350r/min
Stir 17 ~ 19min, add nanometer illite powder, activation pitchstone powder, propylene glycol methyl ether acetate, alumina silicate and go from
Sub- water, adjustment agitator speed are that 180 ~ 200r/min continues 29 ~ 31min of stirring, obtain mixing slurry;
(2)Lauryl aldehyde and nerol are added into mixing slurry, under conditions of temperature is 45 ~ 50 DEG C, pressure is 5.4 ~ 5.8MPa
14 ~ 16min of homogeneous and then adjustment temperature are 55 ~ 60 DEG C, pressure is 8.4 ~ 8.8MPa, 18 ~ 20min of homogeneous, and it is strong to obtain abrasion resistance
Interiro wall latex paint.
Beneficial effects of the present invention:A kind of strong interiro wall latex paint of abrasion resistance provided by the invention, nanometer illite powder
End and activation pitchstone powder are fully dispersed in emulsion paint system, the interface binding power that can be effectively improved between emulsion particle,
Enhancing and repairing effect are played, network structure is gathered into, further improves coating strength, improve its mechanical property, it is resistance to strengthen its
Scrubbing property;In addition, each component mating reaction, not only make it that film is fine and close, viscoplasticity is good, good to the adhesive force of base material, hardness and
Wearability is good, and so as to improve the wash-resistant property of paint film, and active material therein with formaldehyde with occurring through aldehyde condensation reaction
With electrophilic addition reaction effectively by formaldehyde removing, and suppress the generation of VOC, it is safe to use to effectively improve its
Property.
Embodiment
Illustrate the present invention with specific embodiment below, but be not limitation of the present invention.
Embodiment 1
In the embodiment of the present invention, a kind of strong interiro wall latex paint of abrasion resistance, it is made up of the raw material of following parts by weight:Lauryl aldehyde
1.2 parts, 0.5 part of nerol, 18 parts of phenolic resin, 4 parts of konjac glucomannan, 6 parts of bamboo juice, part, nanometer the illite powder 4 of silicone acrylic emulsion 16
Part, 5 parts of activation pitchstone powder, 12 parts of propylene glycol methyl ether acetate, 2.4 parts of alumina silicate, 24 parts of deionized water.
As the further scheme of invention:The granularity of described nanometer illite powder is 10nm.
As the further scheme of invention:Described activation pitchstone powder, is prepared according to the following steps:By pitchstone
Powder inserts cryostat under conditions of temperature is -7 DEG C and handles 34min, takes out, it is steam under conditions of 370 DEG C to insert temperature
Handle 26min, add the boric acid solution that weight is 0.2 times of pitchstone powder weight amount and be mixed evenly, temperature be 72 DEG C,
Frequency is microwave drying under conditions of 660MPa, must activate pitchstone powder.
As the further scheme of invention:The mass fraction of described boric acid solution is 6%.
As the further scheme of invention:A kind of preparation method of the strong interiro wall latex paint of abrasion resistance, specifically include with
Lower step:
(1)Phenolic resin, konjac glucomannan and silicone acrylic emulsion are heated to 85 DEG C, the agitator for being 330r/min with rotating speed stirs
17min, nanometer illite powder, activation pitchstone powder, propylene glycol methyl ether acetate, alumina silicate and deionized water are added, is adjusted
Whole agitator speed is that 180r/min continues to stir 29min, obtains mixing slurry;
(2)Lauryl aldehyde and nerol, the homogeneous under conditions of temperature is 45 DEG C, pressure is 5.4MPa are added into mixing slurry
14min and then adjustment temperature are 55 DEG C, pressure is 8.4MPa homogeneous 18min, obtain the strong interiro wall latex paint of abrasion resistance.
Embodiment 2
In the embodiment of the present invention, a kind of strong interiro wall latex paint of abrasion resistance, it is made up of the raw material of following parts by weight:Lauryl aldehyde
1.3 parts, 0.6 part of nerol, 19 parts of phenolic resin, 4.5 parts of konjac glucomannan, 6.5 parts of bamboo juice, silicone acrylic emulsion 17 part, nanometer illite
4.5 parts of powder, 5.5 parts of activation pitchstone powder, 13 parts of propylene glycol methyl ether acetate, 2.6 parts of alumina silicate, 26 parts of deionized water.
As the further scheme of invention:The granularity of described nanometer illite powder is 15nm.
As the further scheme of invention:Described activation pitchstone powder, is prepared according to the following steps:By pitchstone
Powder inserts cryostat under conditions of temperature is -6 DEG C and handles 36min, takes out, it is steam under conditions of 380 DEG C to insert temperature
28min is handled, the boric acid solution that weight is 0.25 times of amount of pitchstone powder weight is added and is mixed evenly, be 75 in temperature
DEG C, frequency be 670MPa under conditions of microwave drying, pitchstone powder must be activated.
As the further scheme of invention:The mass fraction of described boric acid solution is 7%.
As the further scheme of invention:A kind of preparation method of the strong interiro wall latex paint of abrasion resistance, specifically include with
Lower step:
(1)Phenolic resin, konjac glucomannan and silicone acrylic emulsion are heated to 88 DEG C, the agitator for being 340r/min with rotating speed stirs
18min, nanometer illite powder, activation pitchstone powder, propylene glycol methyl ether acetate, alumina silicate and deionized water are added, is adjusted
Whole agitator speed is that 190r/min continues to stir 30min, obtains mixing slurry;
(2)Lauryl aldehyde and nerol, the homogeneous under conditions of temperature is 48 DEG C, pressure is 5.6MPa are added into mixing slurry
15min and then adjustment temperature are 58 DEG C, pressure is 8.6MPa homogeneous 19min, obtain the strong interiro wall latex paint of abrasion resistance.
Embodiment 3
In the embodiment of the present invention, a kind of strong interiro wall latex paint of abrasion resistance, it is made up of the raw material of following parts by weight:Lauryl aldehyde
1.4 parts, 0.7 part of nerol, 20 parts of phenolic resin, 5 parts of konjac glucomannan, 7 parts of bamboo juice, part, nanometer the illite powder 5 of silicone acrylic emulsion 18
Part, 6 parts of activation pitchstone powder, 14 parts of propylene glycol methyl ether acetate, 2.8 parts of alumina silicate, 24 ~ 28 parts of deionized water.
As the further scheme of invention:The granularity of described nanometer illite powder is 20nm.
As the further scheme of invention:Described activation pitchstone powder, is prepared according to the following steps:By pitchstone
Powder inserts cryostat under conditions of temperature is -5 DEG C and handles 38min, takes out, it is steam under conditions of 390 DEG C to insert temperature
Handle 30min, add the boric acid solution that weight is 0.3 times of pitchstone powder weight amount and be mixed evenly, temperature be 78 DEG C,
Frequency is microwave drying under conditions of 680MPa, must activate pitchstone powder.
As the further scheme of invention:The mass fraction of described boric acid solution is 8%.
As the further scheme of invention:A kind of preparation method of the strong interiro wall latex paint of abrasion resistance, specifically include with
Lower step:
(1)Phenolic resin, konjac glucomannan and silicone acrylic emulsion are heated to 90 DEG C, the agitator for being 350r/min with rotating speed stirs
19min, nanometer illite powder, activation pitchstone powder, propylene glycol methyl ether acetate, alumina silicate and deionized water are added, is adjusted
Whole agitator speed is that 200r/min continues to stir 31min, obtains mixing slurry;
(2)Lauryl aldehyde and nerol, the homogeneous under conditions of temperature is 50 DEG C, pressure is 5.8MPa are added into mixing slurry
16min and then adjustment temperature are 60 DEG C, pressure is 8.8MPa homogeneous 20min, obtain the strong interiro wall latex paint of abrasion resistance.
Comparative example
Commercially available common interiro wall latex paint
The commercially available common interiro wall latex paint of the strong interiro wall latex paint of abrasion resistance of the present invention and comparative example is subjected to contrast test, reference
GB18582-2008 and GB/T9756-2009 standards are tested, main performance index such as table 1:
The comparing result of the embodiment of table 1 and comparative example
Abrasion resistance(It is secondary) | Contrast ratio | VOC(g/L) | Free formaldehyde(mg/kg) | |
Embodiment 1 | 9420 | 0.981 | 5.74 | Do not detect |
Embodiment 2 | 9450 | 0.986 | 5.61 | Do not detect |
Embodiment 3 | 9400 | 0.984 | 5.45 | Do not detect |
Comparative example | 5100 | 0.932 | 43.66 | 52.75 |
As it can be seen from table 1 the strong interiro wall latex paint of abrasion resistance of the present invention can not only have the abrasion resistance of high intensity, and
And usage safety performance is significantly improved.
Claims (5)
1. the strong interiro wall latex paint of a kind of abrasion resistance, it is characterised in that be made up of the raw material of following parts by weight:Lauryl aldehyde 1.2 ~
1.4 parts, 0.5 ~ 0.7 part of nerol, 18 ~ 20 parts of phenolic resin, 4 ~ 5 parts of konjac glucomannan, 6 ~ 7 parts of bamboo juice, 16 ~ 18 parts of silicone acrylic emulsion,
4 ~ 5 parts of nanometer illite powder, 5 ~ 6 parts of activation pitchstone powder, 12 ~ 14 parts of propylene glycol methyl ether acetate, alumina silicate 2.4 ~ 2.8
Part, 24 ~ 28 parts of deionized water.
2. the strong interiro wall latex paint of abrasion resistance according to claim 1, it is characterised in that described nanometer illite powder
The granularity at end is 10 ~ 20nm.
3. the strong interiro wall latex paint of abrasion resistance according to claim 1, it is characterised in that described activation rosin rock dust
End, prepared according to the following steps:By pitchstone powder insert temperature for cryostat processing 34 under conditions of -7 ~ -5 DEG C ~
38min, take out, it is 26 ~ 30min of steam treatment under conditions of 370 ~ 390 DEG C to insert temperature, and addition weight is pitchstone powder weight
The boric acid solution of 0.2 ~ 0.3 times of amount of amount is mixed evenly, under conditions of temperature is 72 ~ 78 DEG C, frequency is 660 ~ 680MPa
Microwave drying, pitchstone powder must be activated.
4. the strong interiro wall latex paint of abrasion resistance according to claim 1, it is characterised in that the matter of described boric acid solution
It is 6% ~ 8% to measure fraction.
5. the preparation method of the strong interiro wall latex paint of abrasion resistance according to any one of claim 1 ~ 4, it is characterised in that
Specifically include following steps:
(1)Phenolic resin, konjac glucomannan and silicone acrylic emulsion are heated to 85 ~ 90 DEG C, with the agitator that rotating speed is 330 ~ 350r/min
Stir 17 ~ 19min, add nanometer illite powder, activation pitchstone powder, propylene glycol methyl ether acetate, alumina silicate and go from
Sub- water, adjustment agitator speed are that 180 ~ 200r/min continues 29 ~ 31min of stirring, obtain mixing slurry;
(2)Lauryl aldehyde and nerol are added into mixing slurry, under conditions of temperature is 45 ~ 50 DEG C, pressure is 5.4 ~ 5.8MPa
14 ~ 16min of homogeneous and then adjustment temperature are 55 ~ 60 DEG C, pressure is 8.4 ~ 8.8MPa, 18 ~ 20min of homogeneous, and it is strong to obtain abrasion resistance
Interiro wall latex paint.
Priority Applications (1)
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CN201710850481.9A CN107603401A (en) | 2017-09-20 | 2017-09-20 | A kind of strong interiro wall latex paint of abrasion resistance |
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CN201710850481.9A CN107603401A (en) | 2017-09-20 | 2017-09-20 | A kind of strong interiro wall latex paint of abrasion resistance |
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Citations (6)
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CN101215127A (en) * | 2008-01-08 | 2008-07-09 | 太原理工大学 | Rigid and flexible water-proof sealing material for underground engineering and application thereof |
CN103561713A (en) * | 2011-05-26 | 2014-02-05 | 宝洁公司 | Compositions comprising an efficient perfume bloom |
CN105176276A (en) * | 2015-08-31 | 2015-12-23 | 天长市银狐漆业有限公司 | Scrubbing-resistant and antifouling interior wall emulsion paint |
CN105395458A (en) * | 2015-12-15 | 2016-03-16 | 上海相宜本草化妆品股份有限公司 | Herbal composition and application thereof |
CN106189446A (en) * | 2016-08-17 | 2016-12-07 | 柳州市亿廷贸易有限责任公司 | Washability coating |
CN106497260A (en) * | 2016-10-26 | 2017-03-15 | 东南大学 | A kind of washability heat insulation exterior coating material and preparation method thereof |
-
2017
- 2017-09-20 CN CN201710850481.9A patent/CN107603401A/en not_active Withdrawn
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101215127A (en) * | 2008-01-08 | 2008-07-09 | 太原理工大学 | Rigid and flexible water-proof sealing material for underground engineering and application thereof |
CN103561713A (en) * | 2011-05-26 | 2014-02-05 | 宝洁公司 | Compositions comprising an efficient perfume bloom |
CN105176276A (en) * | 2015-08-31 | 2015-12-23 | 天长市银狐漆业有限公司 | Scrubbing-resistant and antifouling interior wall emulsion paint |
CN105395458A (en) * | 2015-12-15 | 2016-03-16 | 上海相宜本草化妆品股份有限公司 | Herbal composition and application thereof |
CN106189446A (en) * | 2016-08-17 | 2016-12-07 | 柳州市亿廷贸易有限责任公司 | Washability coating |
CN106497260A (en) * | 2016-10-26 | 2017-03-15 | 东南大学 | A kind of washability heat insulation exterior coating material and preparation method thereof |
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