CN107603154A - Traction motor casting resin and preparation method thereof - Google Patents

Traction motor casting resin and preparation method thereof Download PDF

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Publication number
CN107603154A
CN107603154A CN201710909178.1A CN201710909178A CN107603154A CN 107603154 A CN107603154 A CN 107603154A CN 201710909178 A CN201710909178 A CN 201710909178A CN 107603154 A CN107603154 A CN 107603154A
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China
Prior art keywords
parts
casting resin
preparation
curing agent
resin
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CN201710909178.1A
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Chinese (zh)
Inventor
高桂林
周鑫
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Anhui Zhongbo New Materials Co ltd
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Anhui Zhongbo New Materials Co ltd
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Priority to CN201710909178.1A priority Critical patent/CN107603154A/en
Publication of CN107603154A publication Critical patent/CN107603154A/en
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  • Compositions Of Macromolecular Compounds (AREA)
  • Epoxy Resins (AREA)

Abstract

The invention discloses traction motor casting resin and a preparation method thereof, and relates to the technical field of casting resin. The traction motor casting resin is prepared from a resin composition and a curing agent composition, wherein the resin composition comprises the following raw materials in parts by weight: 70-95 parts of E51 bisphenol A epoxy resin; 2-28 parts of polyether polyol; 2-25 parts of a sea-island structure toughening agent; 1-3 parts of a nanoparticle composition; the curing agent composition comprises methyl tetrahydrophthalic anhydride, modified maleic anhydride and a mixed accelerator; the preparation method comprises the steps of resin composition preparation, curing agent composition preparation and casting resin preparation. The casting resin for the traction motor has excellent weather resistance, temperature resistance, tensile strength, yield strength and insulating property, and has good surface gloss, wear resistance and water resistance.

Description

A kind of traction electric machine casting resin and preparation method thereof
Technical field:
The present invention relates to casting resin technical field, and in particular to a kind of traction electric machine casting resin and preparation method thereof.
Background technology:
Traction electric machine reliability of operation and life-span, determined by its insulating properties, operation warp Test and relevant information counts surface, the failure of traction electric machine, it is because caused by breaking down insulation to have more than half.Electricity simultaneously Some main economic and technical indices of machine such as power output of voltage class, Unit Weight etc., insulation system with it, used Insulating materials and insulating treatment process also have very big relation.Therefore, insulating materials occupies very heavy in traction electric machine The status wanted.
The conventional insulating materials of Engine on National Locomotive traction electric machine has High Strength Polyimide film, high-strength composite mica paper And the solvent-free immersion paint of high temperature classification, inorganic fibers etc., but quality also needs to stabilize and increase.Epoxy resin conduct It is excellent insulate, be weather-proof, etch-proof insulating materials base material, can further study synthesis traction electric machine casting resin.
The content of the invention:
The defects of technical problems to be solved by the invention are to overcome prior art, there is provided a kind of mechanical performance, insulation Excellent traction electric machine casting resin of performance, weatherability and preparation method thereof.
The technical problems to be solved by the invention are realized using following technical scheme:
A kind of traction electric machine casting resin, the casting resin are prepared by resin combination and curing agent composition, The resin combination includes the raw material of following parts by weight:
The curing agent composition includes the raw material of following parts by weight:
80~98 parts of methyl tetrahydro phthalic anhydride;
2~20 parts of modified maleic acid anhydride;
0.1~1.8 part of mixed accelerators;
Wherein, Nanoparticulate compositions by nanometer silicon dioxide particle, nano aluminium oxide, nano aluminum nitride according to mass ratio 3:1:1 mixing;Mixed accelerators includes the composition of following parts by weight:10~20 parts of benzyl dimethylamine, 0~8 part of DMP-30, miaow 0~20 part of azoles.
Preferably, the resin combination includes the raw material of following parts by weight:
The curing agent composition includes the raw material of following parts by weight:
95 parts of methyl tetrahydro phthalic anhydride;
10 parts of modified maleic acid anhydride;
0.7 part of mixed accelerators;
Wherein, Nanoparticulate compositions by nanometer silicon dioxide particle, nano aluminium oxide, nano aluminum nitride according to mass ratio 3:1:1 mixing;Mixed accelerators includes the composition of following parts by weight:15 parts of benzyl dimethylamine, 6 parts of DMP-30,12 parts of imidazoles.
The preparation method of above-mentioned traction electric machine casting resin, comprises the following steps:
(1) prepared by resin combination:E51 bisphenol A epoxide resins are added in reactor, are preheated to 60~70 DEG C, successively PPG, island structure toughener, Nanoparticulate compositions are added, stirring at low speed mixing, 70~80 DEG C is warming up to, continues After stirring 30~50min, vacuum defoamation is carried out, after 20~40min of deaeration, obtains resin combination;
(2) preparation of curing agent composition:Methyl tetrahydro phthalic anhydride is added in reactor, stirring is warming up to 30~40 DEG C, modified maleic acid anhydride, mixed accelerators are added, after 300~500r/min rotating speed insulated and stirreds, 20~30min, is obtained Curing agent composition;
(3) preparation of casting resin:Resin combination prepared by step (1) is combined with curing agent prepared by step (2) Thing is with mass ratio 1:1 ratio is mixed evenly to obtain compound, and compound is poured into a mould to obtain the traction electric machine casting resin.
Preferably, the step (1) is warming up to 75 DEG C, continues after stirring 42min, carries out vacuum defoamation, speed of agitator is 100~200r/min.
Preferably, step (3) compound is poured into mould under vacuum conditions, form removal after solidification.
The beneficial effects of the invention are as follows:1. the traction electric machine casting resin of the present invention, materials safety is nontoxic, reasonable mixture ratio, Good, the wear-resisting and waterproof with excellent weatherability, temperature tolerance, tensile strength, yield strength, insulating properties, and surface gloss.
Using E51 bisphenol A epoxide resins as main component, 2. island structure toughener can change the resin combination of the present invention The toughness of kind resin, reduces cure shrinkage and thermal stress, strengthens heat resistance and mechanical performance.
3. the curing agent composition of the present invention is formed using methyl tetrahydro phthalic anhydride, modified maleic acid anhydride, accelerator compounding, Gu Change speed is fast, and temperature tolerance is good, can ensure that the various aspects of performance of resin is stable.
Embodiment:
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below Specific embodiment is closed, the present invention is expanded on further.
Embodiment 1
A kind of traction electric machine casting resin, is prepared by resin combination and curing agent composition, the resin combination Thing includes the raw material of following parts by weight:
The curing agent composition includes the raw material of following parts by weight:
95 parts of methyl tetrahydro phthalic anhydride;
10 parts of modified maleic acid anhydride;
0.7 part of mixed accelerators;
Wherein, Nanoparticulate compositions by nanometer silicon dioxide particle, nano aluminium oxide, nano aluminum nitride according to mass ratio 3:1:1 mixing;Mixed accelerators includes the composition of following parts by weight:15 parts of benzyl dimethylamine, 6 parts of DMP-30,12 parts of imidazoles.
The preparation method of the traction electric machine casting resin, comprises the following steps:
(1) prepared by resin combination:E51 bisphenol A epoxide resins are added in reactor, 62 DEG C is preheated to, sequentially adds PPG, island structure toughener, Nanoparticulate compositions, stirring at low speed mixing, are warming up to 75 DEG C, continue to stir After 42min, vacuum defoamation is carried out, after speed of agitator 200r/min, deaeration 30min, obtains resin combination;
(2) preparation of curing agent composition:Methyl tetrahydro phthalic anhydride is added in reactor, stirring is warming up to 35 DEG C, then Modified maleic acid anhydride, mixed accelerators are added, after 400r/min rotating speed insulated and stirreds 26min, obtains curing agent composition;
(3) preparation of casting resin:Resin combination prepared by step (1) is combined with curing agent prepared by step (2) Thing is with mass ratio 1:1 ratio is mixed evenly to obtain compound, and compound is poured into mould under vacuum conditions, solidification Form removal obtains the traction electric machine casting resin afterwards.
Just face is smooth for the casting resin of the present embodiment, without obvious impurity, bubble, fold, apparent density 1.36kg/cm3, Tensile strength is 35MPa, yield strength 5.4MPa, hardness 90D, 96 DEG C of heat distortion temperature.
Embodiment 2
A kind of traction electric machine casting resin, is prepared by resin combination and curing agent composition, the resin combination Thing includes the raw material of following parts by weight:
The curing agent composition includes the raw material of following parts by weight:
89 parts of methyl tetrahydro phthalic anhydride;
14 parts of modified maleic acid anhydride;
1.2 parts of mixed accelerators;
Wherein, Nanoparticulate compositions by nanometer silicon dioxide particle, nano aluminium oxide, nano aluminum nitride according to mass ratio 3:1:1 mixing;Mixed accelerators includes the composition of following parts by weight:15 parts of benzyl dimethylamine, 5 parts of DMP-30,6 parts of imidazoles.
The preparation method of the traction electric machine casting resin, comprises the following steps:
(1) prepared by resin combination:E51 bisphenol A epoxide resins are added in reactor, 68 DEG C is preheated to, sequentially adds PPG, island structure toughener, Nanoparticulate compositions, stirring at low speed mixing, are warming up to 75 DEG C, continue to stir After 42min, vacuum defoamation is carried out, after deaeration 25min, obtains resin combination;
(2) preparation of curing agent composition:Methyl tetrahydro phthalic anhydride is added in reactor, stirring is warming up to 40 DEG C, then Modified maleic acid anhydride, mixed accelerators are added, after 300r/min rotating speed insulated and stirreds 30min, obtains curing agent composition;
(3) preparation of casting resin:Resin combination prepared by step (1) is combined with curing agent prepared by step (2) Thing is with mass ratio 1:1 ratio is mixed evenly to obtain compound, and compound is poured into mould under vacuum conditions, solidification Form removal obtains the traction electric machine casting resin afterwards.
Just face is smooth for the casting resin of the present embodiment, without obvious impurity, bubble, fold, apparent density 1.41kg/cm3, Tensile strength is 29MPa, yield strength 5.2MPa, hardness 88D, 92 DEG C of heat distortion temperature.
Embodiment 3
A kind of traction electric machine casting resin, is prepared by resin combination and curing agent composition, the resin combination Thing includes the raw material of following parts by weight:
The curing agent composition includes the raw material of following parts by weight:
90 parts of methyl tetrahydro phthalic anhydride;
12 parts of modified maleic acid anhydride;
1.5 parts of mixed accelerators;
Wherein, Nanoparticulate compositions by nanometer silicon dioxide particle, nano aluminium oxide, nano aluminum nitride according to mass ratio 3:1:1 mixing;Mixed accelerators includes the composition of following parts by weight:20 parts of benzyl dimethylamine, 8 parts of DMP-30,14 parts of imidazoles.
The preparation method of the traction electric machine casting resin, comprises the following steps:
(1) prepared by resin combination:E51 bisphenol A epoxide resins are added in reactor, 70 DEG C is preheated to, sequentially adds PPG, island structure toughener, Nanoparticulate compositions, stirring at low speed mixing, are warming up to 80 DEG C, continue to stir After 50min, vacuum defoamation is carried out, after deaeration 40min, obtains resin combination;
(2) preparation of curing agent composition:Methyl tetrahydro phthalic anhydride is added in reactor, stirring is warming up to 40 DEG C, then Modified maleic acid anhydride, mixed accelerators are added, after 500r/min rotating speed insulated and stirreds 20min, obtains curing agent composition;
(3) preparation of casting resin:Resin combination prepared by step (1) is combined with curing agent prepared by step (2) Thing is with mass ratio 1:1 ratio is mixed evenly to obtain compound, and compound is poured into mould under vacuum conditions, solidification Form removal obtains the traction electric machine casting resin afterwards.
Just face is smooth for the casting resin of the present embodiment, without obvious impurity, bubble, fold, apparent density 1.41kg/cm3, Tensile strength is 27MPa, yield strength 4.9MPa, hardness 86D, 90 DEG C of heat distortion temperature.
Embodiment 4
A kind of traction electric machine casting resin, is prepared by resin combination and curing agent composition, the resin combination Thing includes the raw material of following parts by weight:
The curing agent composition includes the raw material of following parts by weight:
95 parts of methyl tetrahydro phthalic anhydride;
17 parts of modified maleic acid anhydride;
1.6 parts of mixed accelerators;
Wherein, Nanoparticulate compositions by nanometer silicon dioxide particle, nano aluminium oxide, nano aluminum nitride according to mass ratio 3:1:1 mixing;Mixed accelerators includes the composition of following parts by weight:20 parts of benzyl dimethylamine, 8 parts of DMP-30,20 parts of imidazoles.
The preparation method of the traction electric machine casting resin, comprises the following steps:
(1) prepared by resin combination:E51 bisphenol A epoxide resins are added in reactor, 70 DEG C is preheated to, sequentially adds PPG, island structure toughener, Nanoparticulate compositions, stirring at low speed mixing, are warming up to 80 DEG C, continue to stir After 50min, vacuum defoamation is carried out, after deaeration 40min, obtains resin combination;
(2) preparation of curing agent composition:Methyl tetrahydro phthalic anhydride is added in reactor, stirring is warming up to 40 DEG C, then Modified maleic acid anhydride, mixed accelerators are added, after 500r/min rotating speed insulated and stirreds 30min, obtains curing agent composition;
(3) preparation of casting resin:Resin combination prepared by step (1) is combined with curing agent prepared by step (2) Thing is with mass ratio 1:1 ratio is mixed evenly to obtain compound, and compound is poured into mould under vacuum conditions, solidification Form removal obtains the traction electric machine casting resin afterwards.
Just face is smooth for the casting resin of the present embodiment, without obvious impurity, bubble, fold, apparent density 1.38kg/cm3, Tensile strength is 33MPa, yield strength 4.9MPa, hardness 85D, 91 DEG C of heat distortion temperature.
Comparative example 1
A kind of traction electric machine casting resin, is prepared by resin combination and curing agent composition, the resin combination Thing includes the raw material of following parts by weight:
86 parts of E51 bisphenol A epoxide resins;
15 parts of PPG;
16 parts of island structure toughener;
The curing agent composition includes the raw material of following parts by weight:
95 parts of methyl tetrahydro phthalic anhydride;
10 parts of modified maleic acid anhydride;
0.7 part of mixed accelerators;
Wherein, mixed accelerators includes the composition of following parts by weight:15 parts of benzyl dimethylamine, 6 parts of DMP-30, imidazoles 12 Part.
Preparation method is the same as embodiment 1.The casting resin tensile strength is 15MPa, yield strength 1.8MPa, and hardness is 56D, 67 DEG C of heat distortion temperature.
Comparative example 2
A kind of traction electric machine casting resin, is prepared by resin combination and curing agent composition, the resin combination Thing includes the raw material of following parts by weight:
The curing agent composition includes the raw material of following parts by weight:
95 parts of methyl tetrahydro phthalic anhydride;
10 parts of modified maleic acid anhydride;
Wherein, Nanoparticulate compositions by nanometer silicon dioxide particle, nano aluminium oxide, nano aluminum nitride according to mass ratio 3:1:1 mixing.
Preparation method is the same as embodiment 1.The casting resin tensile strength is 22MPa, yield strength 1.8MPa, and hardness is 57D, 66 DEG C of heat distortion temperature.
The traction electric machine casting resin of the present invention, materials safety is nontoxic, reasonable mixture ratio, has excellent weatherability, heatproof Property, tensile strength, yield strength, insulating properties, and surface gloss is good, wear-resisting and waterproof.
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (5)

  1. A kind of 1. traction electric machine casting resin, it is characterised in that:The casting resin is by resin combination and curing agent composition It is prepared, the resin combination includes the raw material of following parts by weight:
    The curing agent composition includes the raw material of following parts by weight:
    80~98 parts of methyl tetrahydro phthalic anhydride;
    2~20 parts of modified maleic acid anhydride;
    0.1~1.8 part of mixed accelerators;
    Wherein, Nanoparticulate compositions by nanometer silicon dioxide particle, nano aluminium oxide, nano aluminum nitride according to mass ratio 3:1: 1 mixing;Mixed accelerators includes the composition of following parts by weight:10~20 parts of benzyl dimethylamine, 0~8 part of DMP-30, imidazoles 0~ 20 parts.
  2. 2. traction electric machine casting resin according to claim 1, it is characterised in that:The resin combination includes following heavy Measure the raw material of part:
    The curing agent composition includes the raw material of following parts by weight:
    95 parts of methyl tetrahydro phthalic anhydride;
    10 parts of modified maleic acid anhydride;
    0.7 part of mixed accelerators;
    Wherein, Nanoparticulate compositions by nanometer silicon dioxide particle, nano aluminium oxide, nano aluminum nitride according to mass ratio 3:1: 1 mixing;Mixed accelerators includes the composition of following parts by weight:15 parts of benzyl dimethylamine, 6 parts of DMP-30,12 parts of imidazoles.
  3. 3. the preparation method of traction electric machine casting resin according to claim 1 or 2, it is characterised in that:Including following step Suddenly:
    (1) prepared by resin combination:E51 bisphenol A epoxide resins are added in reactor, 60~70 DEG C is preheated to, sequentially adds PPG, island structure toughener, Nanoparticulate compositions, stirring at low speed mixing, are warming up to 70~80 DEG C, continue to stir After 30~50min, vacuum defoamation is carried out, after 20~40min of deaeration, obtains resin combination;
    (2) preparation of curing agent composition:Methyl tetrahydro phthalic anhydride is added in reactor, stirring is warming up to 30~40 DEG C, then Modified maleic acid anhydride, mixed accelerators are added, after 300~500r/min rotating speed insulated and stirreds, 20~30min, obtains curing agent Composition;
    (3) preparation of casting resin:Curing agent composition prepared by resin combination and step (2) prepared by step (1) with Mass ratio 1:1 ratio is mixed evenly to obtain compound, and compound is poured into a mould to obtain the traction electric machine casting resin.
  4. 4. the preparation method of traction electric machine casting resin according to claim 3, it is characterised in that:The step (1) rises Temperature continues after stirring 42min to 75 DEG C, carries out vacuum defoamation, speed of agitator is 100~200r/min.
  5. 5. the preparation method of traction electric machine casting resin according to claim 3, it is characterised in that:The step (3) is mixed Close material to be poured into mould under vacuum conditions, form removal after solidification.
CN201710909178.1A 2017-09-29 2017-09-29 Traction motor casting resin and preparation method thereof Withdrawn CN107603154A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710909178.1A CN107603154A (en) 2017-09-29 2017-09-29 Traction motor casting resin and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201710909178.1A CN107603154A (en) 2017-09-29 2017-09-29 Traction motor casting resin and preparation method thereof

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1583928A (en) * 2004-05-27 2005-02-23 哈尔滨工程大学 Epoxy resin pouring sealant
CN101864145A (en) * 2010-06-08 2010-10-20 桂林五环电器制造有限公司 High heat conductive insulating impregnated resin used for air reactor and preparation method thereof
CN106318299A (en) * 2015-06-15 2017-01-11 株洲时代新材料科技股份有限公司 High temperature resistant epoxy pouring sealant, preparation method and application thereof as packaging material in IGBT module

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1583928A (en) * 2004-05-27 2005-02-23 哈尔滨工程大学 Epoxy resin pouring sealant
CN101864145A (en) * 2010-06-08 2010-10-20 桂林五环电器制造有限公司 High heat conductive insulating impregnated resin used for air reactor and preparation method thereof
CN106318299A (en) * 2015-06-15 2017-01-11 株洲时代新材料科技股份有限公司 High temperature resistant epoxy pouring sealant, preparation method and application thereof as packaging material in IGBT module

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Application publication date: 20180119