CN107603016A - A kind of high-temperature flame-retardant plastic film and preparation method thereof - Google Patents

A kind of high-temperature flame-retardant plastic film and preparation method thereof Download PDF

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Publication number
CN107603016A
CN107603016A CN201710904530.2A CN201710904530A CN107603016A CN 107603016 A CN107603016 A CN 107603016A CN 201710904530 A CN201710904530 A CN 201710904530A CN 107603016 A CN107603016 A CN 107603016A
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parts
plastic film
raw material
temperature flame
retardant
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CN201710904530.2A
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Chinese (zh)
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潘卫兵
方凌云
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Tongcheng Zhonghui Plastic Industry Co Ltd
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Tongcheng Zhonghui Plastic Industry Co Ltd
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Priority to CN201710904530.2A priority Critical patent/CN107603016A/en
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Abstract

The invention discloses a kind of high-temperature flame-retardant plastic film and preparation method thereof, the high-temperature flame-retardant plastic film is made up of the raw material of following parts by weight:25 35 parts of butyl propionate, 50 65 parts of acrylic resin, 20 35 parts of ethyl-para-hydroxybenzoate, 10 20 parts of polyketone resin, 5 10 parts of cumyl peroxide, 12 18 parts of Phenoxyethanol, 26 parts of fire retardant, 36 parts of phosphorous acid lipid stabilizer, 25 parts of magnesium stearate, 39 parts of Tissuemat E, 3 12 parts of lagoriolite, 37 parts of diatomite, 5 parts of silica 1,27 parts of oleamide, 10 25 parts of polyoxyethylene carboxylate, 28 parts of calcium monohydrogen phosphate, 22 33 parts of PLA.High-temperature flame-retardant plastic film in the present invention has good heat-resisting quantity, anti-flammability, can better meet requirement.

Description

A kind of high-temperature flame-retardant plastic film and preparation method thereof
Technical field
The invention belongs to thin film materials art, more particularly to a kind of high-temperature flame-retardant plastic film and preparation method thereof.
Background technology
Plastic sheeting can be used for packaging, coating layer, and in recent years, plastics package and plastic packet product are commercially shared Share it is increasing, particularly composite plastic flexible package, have been widely used for the fields such as food, medicine, chemical industry, wherein It is again maximum with packaging for foodstuff proportion, such as beverage packaging, quick-frozen food packaging, cooking food packaging, fast food packaging All brought great convenience Deng, these products to people's life.However, existing plastic sheeting generally existing resistance to elevated temperatures And fire resistance is poor, while toughness is also required to further improve, thus makes its application field and application by great Limitation.
The content of the invention
It is an object of the invention to provide a kind of high-temperature flame-retardant plastic film and preparation method thereof, the plastic sheeting has excellent Good heat-resisting quantity and anti-flammability.
To achieve the above object, the present invention provides following technical scheme:
A kind of high-temperature flame-retardant plastic film is made up of the raw material of following parts by weight:Butyl propionate 25-35 parts, polypropylene Resin 50-65 parts, ethyl-para-hydroxybenzoate 20-35 parts, polyketone resin 10-20 parts, cumyl peroxide 5-10 parts, benzene oxygen Ethanol 12-18 parts, fire retardant 2-6 parts, phosphorous acid lipid stabilizer 3-6 parts, magnesium stearate 2-5 parts, Tissuemat E 3-9 parts, silicon Sour aluminium sodium 3-12 parts, diatomite 3-7 parts, -5 parts of silica 1, oleamide 2-7 parts, polyoxyethylene carboxylate 10-25 parts, Calcium monohydrogen phosphate 2-8 parts, PLA 22-33 parts.
Preferably, described high-temperature flame-retardant plastic film is made up of the raw material of following parts by weight:27 parts of butyl propionate, 60 parts of acrylic resin, 25 parts of ethyl-para-hydroxybenzoate, 14 parts of polyketone resin, 8 parts of cumyl peroxide, Phenoxyethanol 16 Part, 3 parts of fire retardant, 4 parts of phosphorous acid lipid stabilizer, 3 parts of magnesium stearate, 5 parts of Tissuemat E, 10 parts of lagoriolite, diatomite 5 Part, 3 parts of silica, 5 parts of oleamide, 16 parts of polyoxyethylene carboxylate, 6 parts of calcium monohydrogen phosphate, 30 parts of PLA.
Preferably, described high-temperature flame-retardant plastic film is prepared from the following raw materials in parts by weight:30 parts of butyl propionate, 52 parts of acrylic resin, 28 parts of ethyl-para-hydroxybenzoate, 13 parts of polyketone resin, 7 parts of cumyl peroxide, Phenoxyethanol 12 Part, 2 parts of fire retardant, 5 parts of phosphorous acid lipid stabilizer, 3 parts of magnesium stearate, 8 parts of Tissuemat E, 6 parts of lagoriolite, diatomite 3 Part, 2 parts of silica, 6 parts of oleamide, 17 parts of polyoxyethylene carboxylate, 3 parts of calcium monohydrogen phosphate, 24 parts of PLA.
Preferably, described high-temperature flame-retardant plastic film is prepared from the following raw materials in parts by weight:35 parts of butyl propionate, 55 parts of acrylic resin, 33 parts of ethyl-para-hydroxybenzoate, 18 parts of polyketone resin, 8 parts of cumyl peroxide, Phenoxyethanol 14 Part, 3 parts of fire retardant, 6 parts of phosphorous acid lipid stabilizer, 3 parts of magnesium stearate, 7 parts of Tissuemat E, 9 parts of lagoriolite, diatomite 4 Part, 3 parts of silica, 3 parts of oleamide, 25 parts of polyoxyethylene carboxylate, 5 parts of calcium monohydrogen phosphate, 22 parts of PLA.
The preparation method of described high-temperature flame-retardant plastic film, comprises the following steps:
(1) each raw material components are weighed according to ratio of weight and number;
(2) each raw material components being ready in step (1) are added in kneading machine and stirred, mixing speed is 270-285 revs/min, mixing time is 16-22 minutes, and temperature control is 80-85 DEG C, obtains raw mixture;
(3) by step (2) raw mixture add extruder in, extrusion forming, cooling, obtain plastic sheeting into Product.
Compared with prior art, the beneficial effects of the invention are as follows:
Plastic sheeting in the present invention is mainly added with butyl propionate, ethyl-para-hydroxybenzoate, polyketone resin, fire-retardant The raw materials such as agent, phosphorous acid lipid stabilizer, lagoriolite, silica, the plastics are made by rational proportion between each raw material components Film has the advantages that heat-resisting quantity, fire resistance are good, greatly improves its using effect.
Embodiment
Technical scheme is described in detail with reference to embodiment, but protection domain is not limited thereto.
Embodiment one:
A kind of high-temperature flame-retardant plastic film is made up of the raw material of following parts by weight:26 parts of butyl propionate, polypropylene tree 57 parts of fat, 33 parts of ethyl-para-hydroxybenzoate, 17 parts of polyketone resin, 7 parts of cumyl peroxide, 14 parts of Phenoxyethanol are fire-retardant 3 parts of agent, 6 parts of phosphorous acid lipid stabilizer, 5 parts of magnesium stearate, 4 parts of Tissuemat E, 8 parts of lagoriolite, 4 parts of diatomite, dioxy 3 parts of SiClx, 6 parts of oleamide, 15 parts of polyoxyethylene carboxylate, 6 parts of calcium monohydrogen phosphate, 30 parts of PLA.
The preparation method of described high-temperature flame-retardant plastic film, comprises the following steps:
(1) each raw material components are weighed according to ratio of weight and number;
(2) each raw material components being ready in step (1) are added in kneading machine and stirred, mixing speed is 270-285 revs/min, mixing time is 16-22 minutes, and temperature control is 80-85 DEG C, obtains raw mixture;
(3) by step (2) raw mixture add extruder in, extrusion forming, cooling, obtain plastic sheeting into Product.
Embodiment two:
A kind of high-temperature flame-retardant plastic film is made up of the raw material of following parts by weight:27 parts of butyl propionate, polypropylene tree 60 parts of fat, 25 parts of ethyl-para-hydroxybenzoate, 14 parts of polyketone resin, 8 parts of cumyl peroxide, 16 parts of Phenoxyethanol are fire-retardant 3 parts of agent, 4 parts of phosphorous acid lipid stabilizer, 3 parts of magnesium stearate, 5 parts of Tissuemat E, 10 parts of lagoriolite, 5 parts of diatomite, dioxy 3 parts of SiClx, 5 parts of oleamide, 16 parts of polyoxyethylene carboxylate, 6 parts of calcium monohydrogen phosphate, 30 parts of PLA.
The preparation method of described high-temperature flame-retardant plastic film, comprises the following steps:
(1) each raw material components are weighed according to ratio of weight and number;
(2) each raw material components being ready in step (1) are added in kneading machine and stirred, mixing speed is 270-285 revs/min, mixing time is 16-22 minutes, and temperature control is 80-85 DEG C, obtains raw mixture;
(3) by step (2) raw mixture add extruder in, extrusion forming, cooling, obtain plastic sheeting into Product.
Embodiment three:
A kind of high-temperature flame-retardant plastic film is made up of the raw material of following parts by weight:30 parts of butyl propionate, polypropylene tree 52 parts of fat, 28 parts of ethyl-para-hydroxybenzoate, 13 parts of polyketone resin, 7 parts of cumyl peroxide, 12 parts of Phenoxyethanol are fire-retardant 2 parts of agent, 5 parts of phosphorous acid lipid stabilizer, 3 parts of magnesium stearate, 8 parts of Tissuemat E, 6 parts of lagoriolite, 3 parts of diatomite, dioxy 2 parts of SiClx, 6 parts of oleamide, 17 parts of polyoxyethylene carboxylate, 3 parts of calcium monohydrogen phosphate, 24 parts of PLA.
The preparation method of described high-temperature flame-retardant plastic film, comprises the following steps:
(1) each raw material components are weighed according to ratio of weight and number;
(2) each raw material components being ready in step (1) are added in kneading machine and stirred, mixing speed is 270-285 revs/min, mixing time is 16-22 minutes, and temperature control is 80-85 DEG C, obtains raw mixture;
(3) by step (2) raw mixture add extruder in, extrusion forming, cooling, obtain plastic sheeting into Product.
Example IV:
A kind of high-temperature flame-retardant plastic film is made up of the raw material of following parts by weight:35 parts of butyl propionate, polypropylene tree 55 parts of fat, 33 parts of ethyl-para-hydroxybenzoate, 18 parts of polyketone resin, 8 parts of cumyl peroxide, 14 parts of Phenoxyethanol are fire-retardant 3 parts of agent, 6 parts of phosphorous acid lipid stabilizer, 3 parts of magnesium stearate, 7 parts of Tissuemat E, 9 parts of lagoriolite, 4 parts of diatomite, dioxy 3 parts of SiClx, 3 parts of oleamide, 25 parts of polyoxyethylene carboxylate, 5 parts of calcium monohydrogen phosphate, 22 parts of PLA.
The preparation method of described high-temperature flame-retardant plastic film, comprises the following steps:
(1) each raw material components are weighed according to ratio of weight and number;
(2) each raw material components being ready in step (1) are added in kneading machine and stirred, mixing speed is 270-285 revs/min, mixing time is 16-22 minutes, and temperature control is 80-85 DEG C, obtains raw mixture;
(3) by step (2) raw mixture add extruder in, extrusion forming, cooling, obtain plastic sheeting into Product.
Embodiment five:
A kind of high-temperature flame-retardant plastic film is made up of the raw material of following parts by weight:25 parts of butyl propionate, polypropylene tree 50 parts of fat, 20 parts of ethyl-para-hydroxybenzoate, 10 parts of polyketone resin, 5 parts of cumyl peroxide, 12 parts of Phenoxyethanol are fire-retardant 2 parts of agent, 3 parts of phosphorous acid lipid stabilizer, 2 parts of magnesium stearate, 3 parts of Tissuemat E, 3 parts of lagoriolite, 3 parts of diatomite, dioxy 1 part of SiClx, 2 parts of oleamide, 10 parts of polyoxyethylene carboxylate, 2 parts of calcium monohydrogen phosphate, 22 parts of PLA.
The preparation method of described high-temperature flame-retardant plastic film, comprises the following steps:
(1) each raw material components are weighed according to ratio of weight and number;
(2) each raw material components being ready in step (1) are added in kneading machine and stirred, mixing speed is 270-285 revs/min, mixing time is 16-22 minutes, and temperature control is 80-85 DEG C, obtains raw mixture;
(3) by step (2) raw mixture add extruder in, extrusion forming, cooling, obtain plastic sheeting into Product.
Embodiment six:
A kind of high-temperature flame-retardant plastic film is made up of the raw material of following parts by weight:35 parts of butyl propionate, polypropylene tree 65 parts of fat, 35 parts of ethyl-para-hydroxybenzoate, 20 parts of polyketone resin, 10 parts of cumyl peroxide, 18 parts of Phenoxyethanol are fire-retardant 6 parts of agent, 6 parts of phosphorous acid lipid stabilizer, 5 parts of magnesium stearate, 9 parts of Tissuemat E, 12 parts of lagoriolite, 7 parts of diatomite, dioxy 5 parts of SiClx, 7 parts of oleamide, 25 parts of polyoxyethylene carboxylate, 8 parts of calcium monohydrogen phosphate, 33 parts of PLA.
The preparation method of described high-temperature flame-retardant plastic film, comprises the following steps:
(1) each raw material components are weighed according to ratio of weight and number;
(2) each raw material components being ready in step (1) are added in kneading machine and stirred, mixing speed is 270-285 revs/min, mixing time is 16-22 minutes, and temperature control is 80-85 DEG C, obtains raw mixture;
(3) by step (2) raw mixture add extruder in, extrusion forming, cooling, obtain plastic sheeting into Product.
Finally illustrate, the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted, although with reference to compared with The present invention is described in detail good embodiment, it will be understood by those within the art that, can be to the skill of the present invention Art scheme is modified or equivalent substitution, and without departing from the objective and scope of the technical program, it all should cover in the present invention Right among.

Claims (5)

1. a kind of high-temperature flame-retardant plastic film, it is characterised in that be made up of the raw material of following parts by weight:Butyl propionate 25- 35 parts, acrylic resin 50-65 parts, ethyl-para-hydroxybenzoate 20-35 parts, polyketone resin 10-20 parts, cumyl peroxide 5-10 parts, Phenoxyethanol 12-18 parts, fire retardant 2-6 parts, phosphorous acid lipid stabilizer 3-6 parts, magnesium stearate 2-5 parts, polyethylene Wax 3-9 parts, lagoriolite 3-12 parts, diatomite 3-7 parts, -5 parts of silica 1, oleamide 2-7 parts, aliphatic acid polyethenoxy Ester 10-25 parts, calcium monohydrogen phosphate 2-8 parts, PLA 22-33 parts.
2. high-temperature flame-retardant plastic film according to claim 1, it is characterised in that by the raw material group of following parts by weight Into:27 parts of butyl propionate, 60 parts of acrylic resin, 25 parts of ethyl-para-hydroxybenzoate, 14 parts of polyketone resin, peroxidating diisopropyl 8 parts of benzene, 16 parts of Phenoxyethanol, 3 parts of fire retardant, 4 parts of phosphorous acid lipid stabilizer, 3 parts of magnesium stearate, 5 parts of Tissuemat E, silicic acid 10 parts of aluminium sodium, 5 parts of diatomite, 3 parts of silica, 5 parts of oleamide, 16 parts of polyoxyethylene carboxylate, 6 parts of calcium monohydrogen phosphate, 30 parts of PLA.
3. high-temperature flame-retardant plastic film according to claim 1, it is characterised in that by the raw material system of following parts by weight Into:30 parts of butyl propionate, 52 parts of acrylic resin, 28 parts of ethyl-para-hydroxybenzoate, 13 parts of polyketone resin, peroxidating diisopropyl 7 parts of benzene, 12 parts of Phenoxyethanol, 2 parts of fire retardant, 5 parts of phosphorous acid lipid stabilizer, 3 parts of magnesium stearate, 8 parts of Tissuemat E, silicic acid 6 parts of aluminium sodium, 3 parts of diatomite, 2 parts of silica, 6 parts of oleamide, 17 parts of polyoxyethylene carboxylate, 3 parts of calcium monohydrogen phosphate, gather 24 parts of lactic acid.
4. high-temperature flame-retardant plastic film according to claim 1, it is characterised in that by the raw material system of following parts by weight Into:35 parts of butyl propionate, 55 parts of acrylic resin, 33 parts of ethyl-para-hydroxybenzoate, 18 parts of polyketone resin, peroxidating diisopropyl 8 parts of benzene, 14 parts of Phenoxyethanol, 3 parts of fire retardant, 6 parts of phosphorous acid lipid stabilizer, 3 parts of magnesium stearate, 7 parts of Tissuemat E, silicic acid 9 parts of aluminium sodium, 4 parts of diatomite, 3 parts of silica, 3 parts of oleamide, 25 parts of polyoxyethylene carboxylate, 5 parts of calcium monohydrogen phosphate, gather 22 parts of lactic acid.
5. the preparation method of the high-temperature flame-retardant plastic film according to any one of claim 1-4, it is characterised in that bag Include following steps:
(1) each raw material components are weighed according to ratio of weight and number;
(2) each raw material components being ready in step (1) are added in kneading machine and stirred, mixing speed 270- 285 revs/min, mixing time is 16-22 minutes, and temperature control is 80-85 DEG C, obtains raw mixture;
(3) raw mixture in step (2) is added in extruder, extrusion forming, cooling, obtains plastic sheeting finished product.
CN201710904530.2A 2017-09-29 2017-09-29 A kind of high-temperature flame-retardant plastic film and preparation method thereof Pending CN107603016A (en)

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Application Number Priority Date Filing Date Title
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101469096A (en) * 2007-12-25 2009-07-01 上海普利特复合材料股份有限公司 Flame-retardant polypropylene film material
CN106188971A (en) * 2016-08-11 2016-12-07 安徽松泰包装材料有限公司 A kind of plastic sheeting and preparation method thereof
CN106188863A (en) * 2016-08-08 2016-12-07 安徽松泰包装材料有限公司 A kind of high tenacity flame retardant plastics thin film and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101469096A (en) * 2007-12-25 2009-07-01 上海普利特复合材料股份有限公司 Flame-retardant polypropylene film material
CN106188863A (en) * 2016-08-08 2016-12-07 安徽松泰包装材料有限公司 A kind of high tenacity flame retardant plastics thin film and preparation method thereof
CN106188971A (en) * 2016-08-11 2016-12-07 安徽松泰包装材料有限公司 A kind of plastic sheeting and preparation method thereof

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