CN107556958A - A kind of mould proof beauty glue - Google Patents
A kind of mould proof beauty glue Download PDFInfo
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- CN107556958A CN107556958A CN201710908269.3A CN201710908269A CN107556958A CN 107556958 A CN107556958 A CN 107556958A CN 201710908269 A CN201710908269 A CN 201710908269A CN 107556958 A CN107556958 A CN 107556958A
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- Prior art keywords
- beauty
- glue
- mass percent
- coupling agent
- ultraviolet absorber
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Abstract
The present invention provides a kind of mould proof beauty glue, and the component of the beauty glue includes trimethoxy silane end capped polyether.The beauty glue is solvent-free, without plasticizer, without isocyanates, without diacetylmonoxime, without VOC, low smell, have a variety of pearl effects ornamental and fungicidal properties.
Description
Technical field
The invention belongs to adhesive area, is related to a kind of mould proof beauty glue.
Background technology
Beauty glue is also known as stained glass glue, is the material for receiving side decoration and sealing.Mainly it is divided to two major classes：Silicone adhesive
With polyurethane adhesive (PU).Silicone adhesive is divided into Aci-Jel and neutral gum again, and neutral gum has structure glue and fluid sealant and weather-resistant glue.It is beautiful
It is generally rich in color to hold glue, there is preferable decoration function, may be used as adhesive again, but current beauty glue is usually present
The defects of slow drying speed, smell be big, easily mouldy, low in glossiness, neutral gum contain diacetylmonoxime, and Polyurethane glue contains isocyanates etc. no
Environmentally friendly material；Silicone adhesive contains silicone oil etc. and easily separates out material；And after using a period of time, it is often mouldy to cause blackening or change
Color, influence attractive in appearance.Therefore, it is necessary to which a kind of beauty glue of new formula meets the market demand of people.
The A of CN 106190011 disclose a kind of glass cement, the glass cement by following parts by weight group
Point：Organic hydroxylic silicone 30-40 parts, organic methyl silicone 10-20 parts, calcium carbonate 5-15 parts, antiseptic 0.1-0.5 parts, rubber
3-9 parts, lauryl sodium sulfate 5-10 parts, sodium monofluorophosphate 2-6 parts, hydrogen peroxide 3-7 parts, ethylene glycol 2-6 parts, olive oil 2.5-
6.5 parts, phenolic resin 10-15 parts, waterglass 30-50 parts, spices 3-8 parts configuration form.The glass cement of the present invention, has
The features such as drying time is short, rate of drying is fast, bonding force is strong, environmentally friendly；Make the application of glass cement become more extensively, production
Technique is simple, is adapted to batch production, can be applicable.But the glass cement contains silicone compound, there is stronger smell, and it is anti-
Mouldiness is poor.
The A of CN 105368377 disclose a kind of glass cement, including organic hydroxylic silicone, organic methyl silicone, methyl silicon
Alkane, aerosil, calcium carbonate, olive oil, dibutyl tin laurate, acetic acid, amino silane, antiseptic and deionization
Water, it is reasonable that it is formulated, and easy to use, nontoxic pollution-free, green, rate of drying is fast, and viscosity is strong, and tensile strength is big, is not easy
Come unglued, the application of glass cement can be made to become more extensively, to facilitate industrial production and life, and its raw material is easy to get, and makes
Cost is low.But the glass cement also contains silicone compound, there is stronger smell, and mildew resistance is poor.
The content of the invention
For technical problem present in prior art, the present invention provides a kind of mould proof beauty glue, and the beauty glue is without molten
Agent, without plasticizer, without isocyanates, without diacetylmonoxime, without VOC, low smell, have a variety of pearl effects it is ornamental and anti-
Mouldiness energy.
The present invention provides a kind of mould proof beauty glue, and the component of the beauty glue includes trimethoxy silane end capped polyether.
As currently preferred technical scheme, include according to the component of beauty glue described in mass percent meter：
Wherein, the mass fraction of trimethoxy silane end capped polyether can be 65%, 70%, 75%, 80%, 85% or
90% etc., the mass fraction of pigment can be 1%, 2%, 3%, 4%, 5%, 6%, 7%, 8%, 9% or 10% etc., catalyst
Mass fraction can be 1%, 1.1%, 1.2%, 1.3%, 1.4%, 1.5%, 1.6%, 1.7%, 1.8%, 1.9% or
2% etc., the mass fraction of auxiliary agent can be 5%, 6%, 7%, 8%, 9%, 10%, 11%, 12%, 13%, 14% or 15%
Deng it is not limited to cited numerical value, other unrequited numerical value are equally applicable in above-mentioned each number range.
As currently preferred technical scheme, include according to the component of beauty glue described in mass percent meter：
As currently preferred technical scheme, include according to the component of beauty glue described in mass percent meter：
As currently preferred technical scheme, the pigment includes pearl essence and/or glitter powder.
As currently preferred technical scheme, the catalyst is organotin catalysts.
Preferably, the organotin catalysts include dibutyltin diacetate, stannous octoate or dibutyl tin laurate
In any one or at least two combination, it is described combination typical case but non-limiting examples have：Dibutyltin diacetate and octanoic acid
The combination of stannous, the combination of stannous octoate and dibutyl tin laurate, dibutyl tin laurate and dibutyltin diacetate
Combination or dibutyltin diacetate, stannous octoate and dibutyl tin laurate combination etc..
As currently preferred technical scheme, the auxiliary agent includes rheological agent, coupling agent, light stabilizer or UV absorption
Any one in agent or at least two combination, the combination is typical but non-limiting examples have：The group of rheological agent and coupling agent
Close, coupling agent and the combination of light stabilizer, the combination of rheological agent and ultraviolet absorber or rheological agent, coupling agent, light stabilizer and
Combination of ultraviolet absorber etc..
As currently preferred technical scheme, the rheological agent is polyamide wax.
Preferably, the mass percent of the polyamide wax be 1~3%, such as 1%, 1.2%, 1.5%, 1.8%, 2%,
2.2%th, 2.5%, 2.8% or 3% etc., it is not limited to cited numerical value, other interior unrequited numbers of the number range
It is worth equally applicable.
As currently preferred technical scheme, the coupling agent is silane coupler.
Preferably, the silane coupler includes vinyl silicane coupling agent and/or amino silicane coupling agent.
Preferably, the mass percent of the silane coupler be 2~6%, such as 2%, 2.5%, 3%, 3.5%, 4%,
4.5%th, 5%, 5.5% or 6% etc., it is not limited to cited numerical value, other interior unrequited numerical value of the number range
It is equally applicable.
As currently preferred technical scheme, the light stabilizer is hindered amine type light stabilizer.
Preferably, the mass percent of the light stabilizer be 1~3%, such as 1%, 1.2%, 1.5%, 1.8%, 2%,
2.2%th, 2.5%, 2.8% or 3% etc., it is not limited to cited numerical value, other interior unrequited numbers of the number range
It is worth equally applicable.
Preferably, the ultraviolet absorber is benzotriazole ultraviolet absorber.
Preferably, the mass fraction of the ultraviolet absorber be 1~3%, such as 1%, 1.2%, 1.5%, 1.8%, 2%,
2.2%th, 2.5%, 2.8% or 3% etc., it is not limited to cited numerical value, other interior unrequited numbers of the number range
It is worth equally applicable.
Compared with prior art, the present invention at least has the advantages that：
(1) present invention provides a kind of mould proof beauty glue, and the beauty glue has excellent mechanical property, and elongation at break can
Up to more than 160%；
(2) present invention provides a kind of mould proof beauty glue, and the beauty glue has excellent humidity resistance, under high humidity environment
After placing 48h, mechanical properties decrease is less than 10%；
(3) present invention provides a kind of mould proof beauty glue, the beauty glue is solvent-free, without plasticizer, without isocyanates, no
Containing diacetylmonoxime, without VOC, low smell, have a variety of pearl effects ornamental and fungicidal properties.
Embodiment
For ease of understanding the present invention, it is as follows that the present invention enumerates embodiment.Those skilled in the art are it will be clearly understood that the implementation
Example is only to aid in understanding the present invention, is not construed as the concrete restriction to the present invention.
Embodiment 1
A kind of mould proof beauty glue, includes according to the component of beauty glue described in mass percent meter：
Embodiment 2
A kind of mould proof beauty glue, includes according to the component of beauty glue described in mass percent meter：
Embodiment 3
A kind of mould proof beauty glue, includes according to the component of beauty glue described in mass percent meter：
Embodiment 4
A kind of mould proof beauty glue, includes according to the component of beauty glue described in mass percent meter：
Embodiment 5
A kind of mould proof beauty glue, includes according to the component of beauty glue described in mass percent meter：
Comparative example 1
A kind of mould proof beauty glue, includes according to the component of beauty glue described in mass percent meter：
Comparative example 2
A kind of mould proof beauty glue, includes according to the component of beauty glue described in mass percent meter：
Comparative example 3
A kind of mould proof beauty glue, includes according to the component of beauty glue described in mass percent meter：
Comparative example 4
A kind of mould proof beauty glue, includes according to the component of beauty glue described in mass percent meter：
The elongation at break and humidity resistance of the embodiment 1-5 and comparative example 1-4 mould proof beauty glue provided are surveyed
Examination, as a result as shown in table 1.
Humidity resistance test is that tested beauty glue is placed in into 48h under 95% humidity environment, and its elongation at break is entered
Row test, compared with testing obtained elongation at break with normal condition, performance, which is reduced, to be less than 10% and meets humidity resistance
It is required that.
Table 1
The elongation at break that the mould proof beauty glue of embodiment 1-5 offers is can be seen that according to the test result of table 1 is reachable
162~171%, after handling 48h under high humidity environment, elongation at break change is respectively less than 10%, has good humidity resistance.
And comparative example 1 substitutes trimethoxy silane end capped polyether using PPG, elongation at break is only 102%, and moist bar
Elongation at break declines nearly 50% after part processing, and humidity resistance is poor；Comparative example 2 is using dimethoxysilane end capped polyether substitution three
Methoxy silane end capped polyether, elongation at break and humidity resistance is caused to decline；Front three is greatly reduced in comparative example 3
The mass fraction of TMOS end capped polyether, elongation at break and humidity resistance is also caused to decline；Comparative example 3 is by meteorological titanium dioxide
Silicon is changed to nano-calcium carbonate, causes elongation at break to reduce.
Applicant states that the present invention illustrates the detailed process equipment of the present invention and technological process by above-described embodiment,
But the invention is not limited in above-mentioned detailed process equipment and technological process, that is, it is above-mentioned detailed not mean that the present invention has to rely on
Process equipment and technological process could be implemented.Person of ordinary skill in the field it will be clearly understood that any improvement in the present invention,
The addition of equivalence replacement and auxiliary element to each raw material of product of the present invention, selection of concrete mode etc., all fall within the present invention's
Within the scope of protection domain and disclosure.
Claims (10)
1. a kind of mould proof beauty glue, it is characterised in that the component of the beauty glue includes trimethoxy silane end capped polyether.
2. beauty glue according to claim 1, it is characterised in that according to the component bag of beauty glue described in mass percent meter
Include：
3. beauty glue according to claim 1 or 2, it is characterised in that according to the group of beauty glue described in mass percent meter
Dividing includes：
4. according to the beauty glue described in claim any one of 1-3, it is characterised in that according to beauty glue described in mass percent meter
Component include：
5. according to the beauty glue described in claim any one of 1-4, it is characterised in that the pigment includes pearl essence and/or gold
Green onion powder.
6. according to the beauty glue described in claim any one of 1-5, it is characterised in that catalyst described in the catalyst is organic
Tin catalyst；
Preferably, the organotin catalysts include appointing in dibutyltin diacetate, stannous octoate or dibutyl tin laurate
Anticipate a kind of or at least two combinations.
7. according to the beauty glue described in claim any one of 1-6, it is characterised in that the auxiliary agent include rheological agent, coupling agent,
Any one in light stabilizer or ultraviolet absorber or at least two combination.
8. beauty glue according to claim 6, it is characterised in that the rheological agent is polyamide wax；
Preferably, the mass percent of the polyamide wax is 1~3%.
9. the beauty glue according to claim 6 or 7, it is characterised in that the coupling agent is silane coupler；
Preferably, the silane coupler includes vinyl silicane coupling agent and/or amino silicane coupling agent；
Preferably, the mass percent of the silane coupler is 2~6%.
10. the beauty glue according to any one of claim 7~9, it is characterised in that the light stabilizer is the amine type light that is obstructed
Stabilizer；
Preferably, the mass percent of the light stabilizer is 1~3%；
Preferably, the ultraviolet absorber is benzotriazole ultraviolet absorber；
Preferably, the mass fraction of the ultraviolet absorber is 1~3%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710908269.3A CN107556958A (en) | 2017-09-29 | 2017-09-29 | A kind of mould proof beauty glue |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710908269.3A CN107556958A (en) | 2017-09-29 | 2017-09-29 | A kind of mould proof beauty glue |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107556958A true CN107556958A (en) | 2018-01-09 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710908269.3A Pending CN107556958A (en) | 2017-09-29 | 2017-09-29 | A kind of mould proof beauty glue |
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| Country | Link |
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| CN (1) | CN107556958A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110951437A (en) * | 2019-12-20 | 2020-04-03 | 上海东大化学有限公司 | Antibacterial silane modified sealant and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103320079A (en) * | 2013-07-11 | 2013-09-25 | 上海回天化工新材料有限公司 | Preparation method of flame retardant single-component silane modified polyether sealant |
| CN103555255A (en) * | 2013-09-29 | 2014-02-05 | 江苏中矿大正表面工程技术有限公司 | Elastic waterproof sealant, preparation method thereof, and roof waterproof structure formed by eastic waterproof sealant |
| CN103642376A (en) * | 2013-09-29 | 2014-03-19 | 江苏中矿大正表面工程技术有限公司 | Waterproof paint |
| CN104893646A (en) * | 2015-05-29 | 2015-09-09 | 饶玉明 | Preparation method of high-strength water-resistant mildewproof glass cement |
| CN104910850A (en) * | 2015-05-29 | 2015-09-16 | 饶玉明 | High-strength water-resistant and mildew-proof glass cement |
| CN106833321A (en) * | 2016-12-29 | 2017-06-13 | 浙江中天氟硅材料有限公司 | A kind of transparent mould proof silane modified polyether seal glue and preparation method thereof |
-
2017
- 2017-09-29 CN CN201710908269.3A patent/CN107556958A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103320079A (en) * | 2013-07-11 | 2013-09-25 | 上海回天化工新材料有限公司 | Preparation method of flame retardant single-component silane modified polyether sealant |
| CN103555255A (en) * | 2013-09-29 | 2014-02-05 | 江苏中矿大正表面工程技术有限公司 | Elastic waterproof sealant, preparation method thereof, and roof waterproof structure formed by eastic waterproof sealant |
| CN103642376A (en) * | 2013-09-29 | 2014-03-19 | 江苏中矿大正表面工程技术有限公司 | Waterproof paint |
| CN104893646A (en) * | 2015-05-29 | 2015-09-09 | 饶玉明 | Preparation method of high-strength water-resistant mildewproof glass cement |
| CN104910850A (en) * | 2015-05-29 | 2015-09-16 | 饶玉明 | High-strength water-resistant and mildew-proof glass cement |
| CN106833321A (en) * | 2016-12-29 | 2017-06-13 | 浙江中天氟硅材料有限公司 | A kind of transparent mould proof silane modified polyether seal glue and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110951437A (en) * | 2019-12-20 | 2020-04-03 | 上海东大化学有限公司 | Antibacterial silane modified sealant and preparation method thereof |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180109 |
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