CN107556931A - Eutectic refers to the compound white photovoltaic glued membranes of EVA - Google Patents

Eutectic refers to the compound white photovoltaic glued membranes of EVA Download PDF

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Publication number
CN107556931A
CN107556931A CN201710785199.7A CN201710785199A CN107556931A CN 107556931 A CN107556931 A CN 107556931A CN 201710785199 A CN201710785199 A CN 201710785199A CN 107556931 A CN107556931 A CN 107556931A
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white
eva
eutectic
content
refer
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曾金栋
何胡送
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CHANGZHOU SIWEIKE PHOTOVOLTAIC NEW MATERIAL Co Ltd
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CHANGZHOU SIWEIKE PHOTOVOLTAIC NEW MATERIAL Co Ltd
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Publication of CN107556931A publication Critical patent/CN107556931A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

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Abstract

The present invention relates to photovoltaic glued membrane technical field, especially a kind of eutectic refers to the compound white photovoltaic glued membranes of EVA, including lower floor's white EVA layer and upper strata transparent EVA layer, wherein white EVA layer weight/mass percentage composition is as follows:Eutectic refers to ethylene-vinyl acetate copolymer resin content as 80%~95%, and white filler 5% 20%, antioxidant content is 0.05%~5%, and content of crosslinking agent is 0.25%~2%, and silane coupled agent content is 0.1%~4%;Transparent EVA layer weight/mass percentage composition is as follows:It is 87%~98% that eutectic, which refers to ethylene-vinyl acetate copolymer resin content, and antioxidant content is 0.05%~5%, and content of crosslinking agent is 0.25%~2%, and silane coupled agent content is 0.1%~4%.After said structure, eutectic of the invention refers to the compound white photovoltaic glued membranes of EVA and had wide range of applications, and reflecting rate reaches more than 90%, it is possible to increase the photoelectric transformation efficiency of photovoltaic module, and can eliminate simultaneously bubble and it is hidden split, fold and the white phenomenon of overflowing.

Description

Eutectic refers to the compound white photovoltaic glued membranes of EVA
Technical field
The present invention relates to photovoltaic glued membrane technical field, especially a kind of eutectic refers to the compound white photovoltaic glued membranes of EVA.
Background technology
Nearly ten years, because technological progress and cost are cheap, the development of China's photovoltaic industry is very swift and violent, from 2008 with Come, yield and the output value exceed the photovoltaics such as Germany, Japan power and occupy the first in the world.But solar cell photoelectric converts at present Effect is difficult to improve, and between maintaining 18%~19% always, how to improve the photoelectric transformation efficiency of photovoltaic cell turns into the world The important references of photovoltaic industry focus of attention and national governments' New Energy Industry layout.Present photoelectric transformation efficiency is from theory Also there is a big difference for the generating efficiency 26.8%~30% of calculating, and the source of these losses is many, including battery The blank at interval and cell piece and module edge between piece.
Solar photovoltaic assembly basic structure is formed by 5 layers from top to bottom:Upper strata high-transparency Guang volt Bo Li ﹑ upper stratas EVA glue Mo ﹑ electricity Chi Pian ﹑ lower floor's EVA Jiao Mo ﹑ photovoltaic backs or lower floor's photovoltaic glass.Due to this structure, sunshine is incident from glass, warp Upper strata EVA adhesive film is crossed, cell piece is reached and realizes opto-electronic conversion, interval and cell piece and component side of the sunshine between cell piece There is greater loss in the blank space of edge, if bottom is photovoltaic glass, then sunshine can be projected directly, if photovoltaic back Plate, because backboard reflectivity is not high, about 70-80%, the sunshine for thus having 20-30% is lost.Therefore, high reflecting rate White EVA adhesive film preparation and application just turn into solar energy industry circle research focus.But go deep into research, gas Pao ﹑ folds and the problem of white of overflowing, gradually display.Because photovoltaic module needs high temperature lamination ability curing molding, and it was laminated In order to solve the generation of bubble, it is necessary to vacuumize in journey, under the double action of air pressure and internal stress, white EVA adhesive film occurs Fold, and easily overflow in vain on cell piece and busbar, the attractive in appearance of photovoltaic module is so not only have impact on, and reduce work( Rate.So solve the problems, such as Qi Pao ﹑ folds and overflow white just to turn into the task of top priority.
The content of the invention
The technical problem to be solved in the invention, which is to provide, a kind of heats that mobility is low and corrugationless and white risk of overflowing are answered Mould assembly EVA photovoltaic glued membranes.
In order to solve the above technical problems, the eutectic of the present invention refers to the compound white photovoltaic glued membranes of EVA, including lower floor white EVA Layer and upper strata transparent EVA layer, wherein white EVA layer weight/mass percentage composition is as follows:Eutectic refers to ethylene-vinyl acetate copolymer resin Content is 80%~95%, white filler 5%-20%, and antioxidant content is 0.05%~5%, content of crosslinking agent 0.25% ~2%, silane coupled agent content is 0.1%~4%;Transparent EVA layer weight/mass percentage composition is as follows:Eutectic refers to ethyl vinyl acetate second Alkene copolymer resin content is 87%~98%, and antioxidant content is 0.05%~5%, and content of crosslinking agent is 0.25%~2%, Silane coupled agent content is 0.1%~4%.
Further, the molar content that the eutectic refers to vinyl acetate in ethylene-vinyl acetate copolymer resin is 20% ~50%, the melt flow rate (MFR) that the eutectic refers to ethylene-vinyl acetate copolymer resin is 1.0g/10min~10g/ 10min。
Further, the antioxidant includes primary antioxidant and auxiliary anti-oxidant, wherein, the main antioxygen base is β-(3,5- Di-tert-butyl-hydroxy phenyl) propionic acid octadecanol ester;The auxiliary anti-oxidant is three (4- nonyl phenols) phosphite esters and/or Asia Tricresyl phosphate (2,4- di-tert-butyl-phenyls) ester.
Further, the auxiliary anti-oxidant is three (4- nonyl phenols) phosphite esters and (2, the 4- di-t-butyls of phosphorous acid three Phenyl) ester compound.
Further, the crosslinking agent includes crosslinking and curing agent and assistant crosslinking agent, wherein, the crosslinking and curing agent includes Machine peroxide and/or azo-compound, the organic peroxide are included for dicumyl peroxide, di-tert-butyl peroxide Thing, di-isopropylbenzene hydroperoxide, the di-t-butyl hexane peroxide of 2,5- dimethyl -2,5,4,4- bis- (t-amyl peroxy) valeric acid are just Butyl ester, the one or more in the peroxidating 2- ethylhexyl carbonates tert-butyl ester, 3,3- bis- (t-butyl peroxy) ethyl butyrate;Institute State assistant crosslinking agent include Triallyl isocyanurate, TAC, trimethylol-propane trimethacrylate, One or more mixing in diethyleneglycol dimethacrylate.
Further, the silane coupler is VTES, vinyltrimethoxy silane, vinyl In three tert-butyl peroxide silane, vinyltriacetoxy silane, vinyl three ('beta '-methoxy ethyoxyl) silane at least It is a kind of.
Further, the white filler, is titanium dioxide, white carbon, the white inorganic particle of barium sulfate.
Further, the white filler surface is handled by Coated with Organic Matter, is processed into the EVA of 30-70% concentration Used after white master batch.
Further, the gross thickness that the eutectic refers to the compound white photovoltaic glued membranes of EVA is 350-750 μm.
After said structure, eutectic of the invention refers to the compound white photovoltaic glued membranes of EVA and had wide range of applications, and reflecting rate reaches To more than 90%, it is possible to increase the photoelectric transformation efficiency of photovoltaic module, and can eliminate simultaneously bubble and it is hidden split, fold and overflow White phenomenon.In addition, have the characteristics that:
1st, EVA adhesive film hot melt viscosity can be greatly improved by referring to EVA micelles from eutectic, reduced it and heated mobility, reduce Its fold and white risk of overflowing in vacuum is laminated.
2nd, EVA compound cutans are produced from the method for double-layer coextrusion, upper strata is transparent EVA glued membrane, and lower floor is white EVA glue Film.Due to being covered above tunica albuginea by layer of transparent film, further reduce its fold in vacuum is laminated and overflow white Risk, while the thickness of tunica albuginea is also reduced, the dosage of titanium dioxide is reduced on the basis of reflecting rate is ensured, reduces manufacture Cost.
Brief description of the drawings
The present invention is further detailed explanation with reference to the accompanying drawings and detailed description.
Fig. 1 is the structural representation that eutectic of the present invention refers to the compound white photovoltaic glued membranes of EVA.
In figure:1 is lower floor's white EVA layer, and 2 be upper strata transparent EVA layer, and 3 be white filler
Embodiment
As shown in figure 1, the eutectic of the present invention refers to the compound white photovoltaic glued membranes of EVA, including lower floor's white EVA layer 1 and upper strata Transparent EVA layer 2, white filler 3 is included in lower floor's white EVA layer 1.
The material used is:
Major ingredient:Ethylene-vinyl acetate copolymer (EVA).VA contents are 33%.
Titanium dioxide:Surface is handled by Coated with Organic Matter, is used after being processed into the EVA white master batch of 30-70% concentration.
Antioxidant:Main antioxygen base is β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid octadecanol ester;Auxiliary anti-oxidant is The compound of three (4- nonyl phenols) phosphite esters and phosphorous acid three (2,4- di-tert-butyl-phenyls) ester.
Crosslinking agent:Crosslinking and curing agent is the peroxidating 2- ethylhexyl carbonates tert-butyl ester and 3,3- bis- (t-butyl peroxy) butyric acid The compound of ethyl ester;Assistant crosslinking agent is Triallyl isocyanurate, TAC and trimethylolpropane tris first The compound of base acrylate.
Silane coupler:Vinyl three ('beta '-methoxy ethyoxyl) silane.
The technological process of production of this patent is:Batch mixing-double-deck extrusion-curtain coating-thickness measuring-embossing-sizing-trimming-winding-bag Dress.
Formula such as table 1
Transparent film formulation is according to EVA:Antioxidant:Crosslinking agent:Silane coupler=100:0.5:2.0:0.5, tunica albuginea formula According to EVA+ titanium dioxides:Antioxidant:Crosslinking agent:Silane coupler=100:0.5:2.0:0.5, tunica albuginea formula titanium dioxide addition ratio Example calculates according to (the total adding proportion * gross thickness/tunica albuginea thickness of composite membrane), and tunica albuginea is formulated EVA adding proportions according to (100- tunica albugineas Titanium dioxide adding proportion) calculate, above-mentioned material is sufficiently mixed uniformly in the ratio of table 1, is added separately to two extruder material Bucket, carries out melting coextrusion, 80~90 DEG C of the temperature humidity in each region of extruder, die head, is extruded through co-extrusion die head, by way of curtain coating Roller cools down, then is shaped after thickness measuring, embossing procedure, finally trimming, winding again, packaging and storage.Then transmissivity, resistance to is carried out Burn-in test and cell piece power test.
Table 1-different embodiments formula and performance
Although the foregoing describing the embodiment of the present invention, those skilled in the art should be appreciated that this Be merely illustrative of, various changes or modifications can be made to present embodiment, without departing from the present invention principle and essence, Protection scope of the present invention is only limited by the claims that follow.

Claims (9)

1. a kind of eutectic refers to the compound white photovoltaic glued membranes of EVA, it is characterised in that:Including lower floor's white EVA layer and upper strata transparent EVA Layer, wherein white EVA layer weight/mass percentage composition is as follows:Eutectic refer to ethylene-vinyl acetate copolymer resin content for 80%~ 95%, white filler 5%-20%, antioxidant content are 0.05%~5%, and content of crosslinking agent is 0.25%~2%, and silane is even It is 0.1%~4% to join agent content;Transparent EVA layer weight/mass percentage composition is as follows:Eutectic refers to ethylene-vinyl acetate copolymer resin Content is 87%~98%, and antioxidant content is 0.05%~5%, and content of crosslinking agent is 0.25%~2%, and silane coupler contains Measure as 0.1%~4%.
2. refer to the compound white photovoltaic glued membranes of EVA according to the eutectic described in claim 1, it is characterised in that:The eutectic refer to ethene- The molar content of vinyl acetate is 20%~50% in vinyl acetate copolymer resin, and the eutectic refers to ethene-vinyl acetate and is total to The melt flow rate (MFR) of copolymer resin is 1.0g/10min~10g/10min.
3. refer to the compound white photovoltaic glued membranes of EVA according to the eutectic described in claim 1, it is characterised in that:The antioxidant includes Primary antioxidant and auxiliary anti-oxidant, wherein, the main antioxygen base is β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid octadecanol Ester;The auxiliary anti-oxidant is three (4- nonyl phenols) phosphite esters and/or phosphorous acid three (2,4- di-tert-butyl-phenyls) ester.
4. refer to the compound white photovoltaic glued membranes of EVA according to the eutectic described in claim 3, it is characterised in that:The auxiliary anti-oxidant is The compound of three (4- nonyl phenols) phosphite esters and phosphorous acid three (2,4- di-tert-butyl-phenyls) ester.
5. refer to the compound white photovoltaic glued membranes of EVA according to the eutectic described in claim 1, it is characterised in that:The crosslinking agent includes Crosslinking and curing agent and assistant crosslinking agent, wherein, the crosslinking and curing agent includes organic peroxide and/or azo-compound, described Organic peroxide include for dicumyl peroxide, di-tert-butyl peroxide, di-isopropylbenzene hydroperoxide, 2,5- dimethyl- 2,5 di-t-butyl hexane peroxides, 4,4- bis- (t-amyl peroxy) valeric acid n-butyl, the tertiary fourth of peroxidating 2- ethylhexyl carbonates One or more in ester, 3,3- bis- (t-butyl peroxy) ethyl butyrate;The assistant crosslinking agent includes triallyl isocyanuric acid One kind in ester, TAC, trimethylol-propane trimethacrylate, diethyleneglycol dimethacrylate Or a variety of mixing.
6. refer to white EVA photovoltaics glued membrane according to the eutectic described in claim 1, it is characterised in that:The silane coupler is second Alkenyl triethoxysilane, vinyltrimethoxy silane, the tert-butyl peroxide silane of vinyl three, vinyl triacetoxy At least one of silane, vinyl three ('beta '-methoxy ethyoxyl) silane.
7. refer to white EVA photovoltaics glued membrane according to the eutectic described in claim 1, it is characterised in that:The white filler, it is titanium white Powder, white carbon, the white inorganic particle of barium sulfate.
8. refer to white EVA photovoltaics glued membrane according to the eutectic described in claim 7, it is characterised in that:The white filler surface warp Coated with Organic Matter processing is crossed, is used after being processed into the EVA white master batch of 30-70% concentration.
9. refer to white EVA photovoltaics glued membrane according to the eutectic described in claim 1, it is characterised in that:It is compound white that the eutectic refers to EVA The gross thickness of coloured light volt glued membrane is 350-750 μm.
CN201710785199.7A 2017-09-04 2017-09-04 Eutectic refers to the compound white photovoltaic glued membranes of EVA Pending CN107556931A (en)

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Cited By (7)

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CN110079221A (en) * 2019-03-12 2019-08-02 常州斯威克光伏新材料有限公司 A kind of highly reliable high-gain white EVA photovoltaic glue film of two-layer compound and preparation method thereof
WO2019154300A1 (en) * 2018-02-06 2019-08-15 苏州赛伍应用技术股份有限公司 Encapsulation adhesive film for solar cell, preparation method therefor and use thereof
CN111635706A (en) * 2020-06-12 2020-09-08 常州斯威克光伏新材料有限公司 PID (potential induced degradation) resistant packaging adhesive film for double-sided PREC (pre-positive electrode contact) battery and preparation method thereof
CN113956822A (en) * 2021-11-05 2022-01-21 明冠新材料股份有限公司 High-reflectivity EVA adhesive film without adhesive overflow and preparation method thereof
CN114231210A (en) * 2021-12-31 2022-03-25 常州百佳年代薄膜科技股份有限公司 High-gain grid adhesive film for photovoltaic module, composite EVA resin and production process thereof
CN114940871A (en) * 2021-06-30 2022-08-26 福斯特(嘉兴)新材料有限公司 Three-layer packaging material and photovoltaic module
CN115746739A (en) * 2023-01-09 2023-03-07 常州斯威克光伏新材料有限公司 White foaming adhesive film and preparation method thereof

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CN110079221A (en) * 2019-03-12 2019-08-02 常州斯威克光伏新材料有限公司 A kind of highly reliable high-gain white EVA photovoltaic glue film of two-layer compound and preparation method thereof
CN111635706A (en) * 2020-06-12 2020-09-08 常州斯威克光伏新材料有限公司 PID (potential induced degradation) resistant packaging adhesive film for double-sided PREC (pre-positive electrode contact) battery and preparation method thereof
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CN113956822A (en) * 2021-11-05 2022-01-21 明冠新材料股份有限公司 High-reflectivity EVA adhesive film without adhesive overflow and preparation method thereof
CN114231210A (en) * 2021-12-31 2022-03-25 常州百佳年代薄膜科技股份有限公司 High-gain grid adhesive film for photovoltaic module, composite EVA resin and production process thereof
CN115746739A (en) * 2023-01-09 2023-03-07 常州斯威克光伏新材料有限公司 White foaming adhesive film and preparation method thereof
CN115746739B (en) * 2023-01-09 2023-04-07 常州斯威克光伏新材料有限公司 White foaming adhesive film and preparation method thereof

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Application publication date: 20180109