CN107555921A - A kind of anti-cracking environment-protection azulejo watt and preparation method - Google Patents

A kind of anti-cracking environment-protection azulejo watt and preparation method Download PDF

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Publication number
CN107555921A
CN107555921A CN201710716436.4A CN201710716436A CN107555921A CN 107555921 A CN107555921 A CN 107555921A CN 201710716436 A CN201710716436 A CN 201710716436A CN 107555921 A CN107555921 A CN 107555921A
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parts
protection
water
component
azulejo watt
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梁维东
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SHOUXIAN WEIDONG BUILDING MATERIALS TRADING Co Ltd
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SHOUXIAN WEIDONG BUILDING MATERIALS TRADING Co Ltd
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Abstract

The invention discloses a kind of anti-cracking environment-protection azulejo watt, parts by weight of raw materials ratio are as follows:20 parts of quick lime, 15 parts of clay, 2 parts of glass fibre, 20 parts of cement, 8 parts of quartz sand, 15 parts of attapulgite, 1 part of iron oxide, 1 part of stearic acid sodium, 4 parts of auxiliary agent, 2 parts of additive, 40 parts of water.Raw material quick lime, clay, cement, quartz sand, iron oxide and stearic acid sodium are weighed according to proportioning to grind to 100 mesh, it is well mixed, add attapulgite clay and glass fibre, spray graphene modified polyurethane paint and pigment, final to be molded watt, the present invention has advantages below compared with prior art:Cream-like attapulgite clay is added with anti-cracking environment-protection azulejo watt, with preferable viscosity and plasticity, be advantageous to the emulsification between raw material and bonding, increase the cracking resistance intensity of azulejo watt, while the application of graphene modified polyurethane paint and acrylic acid make it that the waterproof effect of azulejo watt is further lifted.

Description

A kind of anti-cracking environment-protection azulejo watt and preparation method
Technical field
The present invention relates to building materials technology field, more particularly to a kind of anti-cracking environment-protection azulejo watt and preparation method.
Background technology
Azulejo watt scientific name color concrete watt, is called color cement tile, cement encaustic tile etc..Described encaustic tile is general on the market Refer both to color cement tile.It is new roof decorations building materials recent years.Encaustic tile is by after the rational proportions such as cement, sand, is led to Mould is crossed, is formed through high pressure compacting, there is the advantages that compressive resistance is strong, high capacity.Concerned countries standard has JC/T746-2007 Standard.
The general klining watt of color concrete watt ratio has impermeability strong, and bearing capacity is strong, the advantages such as water absorption rate is low.Cement encaustic tile Have the advantages that compactness is big, intensity is high, in light weight, tile-type is reasonable, revolutionize traditional use dry concrete and pass through The shortcomings of cement tile is coarse, low intensity, tile-type dullness of rolling-type shaping.It has unique waterproof construction, the intensity of superelevation, U.S. Beautiful outward appearance etc..
Chinese patent《A kind of rolling color tile and its production technology》(document number CN104016634A;The day for announcing in September, 2014 3 days) a kind of rolling color tile and its production technology, a kind of rolling color tile, including cement, coarse sand, fine sand and pigment are disclosed, it is described The mass fraction of each component is cement 28~32, coarse sand 37~44, fine sand 18~22, pigment 9~12, a kind of life of rolling color tile Production. art, including following process:Dispensing, once stirring, secondary agitation, triple mixing, main watt of shaping, acrylic acid spraying, interior Maintenance, showering curing, spraying, drying, inspection.Although the encaustic tile machine preparation technology is controlled to encaustic tile from encaustic tile density Water penetration improved, add the adhesiveness of pigment, but the water resistance of simple acrylic coating need to be improved, And then the overall water resistance of encaustic tile can also be impacted, and the intensity of encaustic tile, effect are only controlled by the fineness of fine sand Unobvious.
Therefore, it is necessary to research and develop a kind of anti-cracking environment-protection azulejo watt, it can not only prevent azulejo watt from ftractureing in use, And with the benefit of environmental protection.
The content of the invention
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of anti-cracking environment-protection azulejo watt and its prepare Method, it can not only prevent azulejo watt from ftractureing in use, and with the benefit of environmental protection.
The present invention is achieved by the following technical solutions:
A kind of anti-cracking environment-protection azulejo watt, it is characterised in that:It is prepared by the raw material of following parts by weight:Quick lime 20-40 parts, clay 15-25 parts, glass fibre 2-4 parts, cement 20-30 parts, quartz sand 8-10 parts, attapulgite 15-25 parts, oxygen Change iron 1-2 parts, stearic acid sodium 1-2 parts, auxiliary agent 4-6 parts, additive 2-4 parts, water 40-60 parts.
Preferably, described auxiliary agent is prepared by the raw material of following parts by weight:Maleic anhydride 1-2 parts, Arab Glue 1-2 parts, acrylic acid 4-8 parts, Tween-80 2-4 parts, Bian fork acetone 1-3 parts, sodium carbonate 1-3 parts and water 5-10 parts are described The preparation method of auxiliary agent is as follows:Step S1:Arabic gum and Tween-80 are added to the water input reactor, setting temperature is 50- 70 DEG C, rotating speed is that 300-400r/min stirs 30-40min;
Step S2:According to proportioning weigh respectively maleic anhydride, acrylic acid, Bian fork acetone and acrylic acid it is well mixed after Put into reactor, meanwhile, sodium carbonate is ground to 40~60 mesh and slowly put into reactor, setting rotating speed is 800- 100r/min stirs 40-60min, produces.
It is pigment and coating as preferential, described additive, described pigment is red pigment, gray paint and blueness One kind in pigment, described coating are graphene modified polyurethane paint.
Preferably, acrylic acid is added in described pigment to mix, the ratio of described pigment and acrylic acid is 10:1.
A kind of preparation method of anti-cracking environment-protection azulejo watt, it is characterised in that:Comprise the following steps:
Step S1:Quick lime, clay, cement, quartz sand, iron oxide and stearic acid sodium grounds travel are weighed respectively according to proportioning 80~120 mesh are broken to, component A is obtained after being well mixed;
Step S2:Attapulgite clay is added in said components A to be mixed evenly, and water is slowly added in whipping process, is added Water is the 1/4-1/3 of mixture, adds glass fibre and stirs 30~40min, component B is obtained after stirring;
Step S3:Component A and component B is mixed, auxiliary agent is added after well mixed, adds the water of surplus, be sufficiently stirred Component C is obtained after uniformly;
Step S3:Component C is filled into mould, extrusion forming obtains unbaked tile;
Step S4:Graphite spraying alkene modified polyurethane paint on to the unbaked tile of shaping, after spraying terminates, unbaked tile is placed in baking 8~10h of baking in dry chamber, the temperature for setting drying chamber is 50~60 DEG C, terminates rear natural curing 10~15 days.
Step S5:The spray coated paint on the unbaked tile of natural curing, spray 2-3 times, spraying produces shaping azulejo watt after terminating.
A kind of anti-cracking environment-protection azulejo watt of the invention mutually provided has preferably combination property, especially has preferably Cracking resistance and water resistance, specific advantage are as follows:(1) due to a certain proportion of quick lime, clay, cement, quartz sand, iron oxide With the addition of stearic acid sodium so that azulejo watt has preferably performance, while avoid the burning process of traditional tile, reduces Consumption of raw materials and pollution environment, encaustic tile can also be avoided cause because of excessive sintering shrinkage asking for deformation or precise decreasing Topic;(2) quartz sand is hard, wear-resisting, stable chemical performance, can increase the compression strength and cracking resistance intensity of azulejo watt after addition; (3) cream-like attapulgite clay is added with anti-cracking environment-protection azulejo watt, there is preferably viscosity and plasticity, be advantageous to raw material Between emulsification and bonding, increase the cracking resistance intensity of azulejo watt, at the same graphene modified polyurethane paint and acrylic acid should With make it that the waterproof effect of azulejo watt is further lifted.In summary, using technical scheme, production effect Rate is high, and the azulejo watt intensity height produced, and can prevent from ftractureing, and securely and reliably, service life length, material is evenly distributed, pigment Adhesiveness is good.
Embodiment
Embodiments of the invention are elaborated below, the present embodiment is carried out lower premised on technical solution of the present invention Implement, give detailed embodiment and specific operating process, but protection scope of the present invention is not limited to following implementation Example.
Embodiment 1
The preparation of anti-cracking environment-protection azulejo watt, parts by weight of raw materials ratio:20 parts of quick lime, 15 parts of clay, 2 parts of glass fibre, 20 parts of cement, 8 parts of quartz sand, 15 parts of attapulgite, 1 part of iron oxide, 1 part of stearic acid sodium, 4 parts of auxiliary agent, 2 parts of additive, water 40 Part;
The preparation of auxiliary agent, parts by weight of raw materials ratio:1 part of maleic anhydride, 4 parts of acrylic acid, 1 part of acetone of Bian fork, sodium carbonate 1 Part, 1 part of Arabic gum, 2 parts of Tween-80 and 6 parts of water;
The preparation method of described auxiliary agent is as follows:
Step S1:Arabic gum and Tween-80 are added to the water input reactor, it is 60 DEG C to set temperature, and rotating speed is 350r/min stirs 35min;
Step S2:According to proportioning weigh respectively maleic anhydride, acrylic acid, Bian fork acetone and acrylic acid it is well mixed after Put into reactor, meanwhile, sodium carbonate is ground to 50 mesh and slowly put into reactor, sets rotating speed to be stirred for 900r/min 50min is mixed, is produced;
The preparation method of anti-cracking environment-protection azulejo watt, comprises the following steps:
Step S1:Quick lime, clay, cement, quartz sand, iron oxide and stearic acid sodium grounds travel are weighed respectively according to proportioning 100 mesh are broken to, component A is obtained after being well mixed;
Step S2:Attapulgite clay is added in said components A to be mixed evenly, and water is slowly added in whipping process, is added Water is the 1/3 of mixture, adds glass fibre stirring 35min, component B is obtained after stirring;
Step S3:Component A and component B is mixed, auxiliary agent is added after well mixed, adds the water of surplus, be sufficiently stirred Component C is obtained after uniformly;
Step S3:Component C is filled into mould, extrusion forming obtains unbaked tile;
Step S4:Graphite spraying alkene modified polyurethane paint on to the unbaked tile of shaping, after spraying terminates, unbaked tile is placed in baking 8~10h of baking in dry chamber, the temperature for setting drying chamber is 50~60 DEG C, terminates rear natural curing 12 days.
Step S5:The spray coated paint on the unbaked tile of natural curing, spray 2-3 times, spraying produces shaping azulejo watt after terminating.
Embodiment 2
The preparation of anti-cracking environment-protection azulejo watt, parts by weight of raw materials ratio:25 parts of quick lime, 18 parts of clay, 3 parts of glass fibre, 22 parts of cement, 9 parts of quartz sand, 18 parts of attapulgite, 1.5 parts of iron oxide, 1.5 parts of stearic acid sodium, 4 parts of auxiliary agent, 2 parts of additive, 45 parts of water;
The preparation of auxiliary agent, parts by weight of raw materials ratio:1.5 parts of maleic anhydride, 5 parts of acrylic acid, 2 parts of acetone of Bian fork, carbonic acid 7 parts of 2 parts of sodium, 1.5 parts of Arabic gum, 3 parts of Tween-80 and water;
The preparation method of described auxiliary agent is as follows:
Step S1:Arabic gum and Tween-80 are added to the water input reactor, it is 60 DEG C to set temperature, and rotating speed is 350r/min stirs 35min;
Step S2:According to proportioning weigh respectively maleic anhydride, acrylic acid, Bian fork acetone and acrylic acid it is well mixed after Put into reactor, meanwhile, sodium carbonate is ground to 50 mesh and slowly put into reactor, setting rotating speed is 1000r/min 60min is stirred, is produced;
The preparation method of anti-cracking environment-protection azulejo watt, comprises the following steps:
Step S1:Quick lime, clay, cement, quartz sand, iron oxide and stearic acid sodium grounds travel are weighed respectively according to proportioning 100 mesh are broken to, component A is obtained after being well mixed;
Step S2:Attapulgite clay is added in said components A to be mixed evenly, and water is slowly added in whipping process, is added Water is the 1/3 of mixture, adds glass fibre stirring 35min, component B is obtained after stirring;
Step S3:Component A and component B is mixed, auxiliary agent is added after well mixed, adds the water of surplus, be sufficiently stirred Component C is obtained after uniformly;
Step S3:Component C is filled into mould, extrusion forming obtains unbaked tile;
Step S4:Graphite spraying alkene modified polyurethane paint on to the unbaked tile of shaping, after spraying terminates, unbaked tile is placed in baking 8~10h of baking in dry chamber, the temperature for setting drying chamber is 50~60 DEG C, terminates rear natural curing 12 days.
Step S5:The spray coated paint on the unbaked tile of natural curing, spray 2-3 times, spraying produces shaping azulejo watt after terminating.
Embodiment 3
The preparation of anti-cracking environment-protection azulejo watt, parts by weight of raw materials ratio:30 parts of quick lime, 20 parts of clay, 2 parts of glass fibre, 25 parts of cement, 8 parts of quartz sand, 20 parts of attapulgite, 1 part of iron oxide, 1 part of stearic acid sodium, 4 parts of auxiliary agent, 4 parts of additive, water 50 Part;
The preparation of auxiliary agent, parts by weight of raw materials ratio:1 part of maleic anhydride, 6 parts of acrylic acid, 3 parts of acetone of Bian fork, sodium carbonate 3 Part, 2 parts of Arabic gum, 4 parts of Tween-80 and 8 parts of water;
The preparation method of described auxiliary agent is as follows:
Step S1:Arabic gum and Tween-80 are added to the water input reactor, it is 60 DEG C to set temperature, and rotating speed is 300r/min stirs 40min;
Step S2:According to proportioning weigh respectively maleic anhydride, acrylic acid, Bian fork acetone and acrylic acid it is well mixed after Put into reactor, meanwhile, sodium carbonate is ground to 60 mesh and slowly put into reactor, sets rotating speed to be stirred for 900r/min 50min is mixed, is produced;
The preparation method of anti-cracking environment-protection azulejo watt, comprises the following steps:
Step S1:Quick lime, clay, cement, quartz sand, iron oxide and stearic acid sodium grounds travel are weighed respectively according to proportioning 100 mesh are broken to, component A is obtained after being well mixed;
Step S2:Attapulgite clay is added in said components A to be mixed evenly, and water is slowly added in whipping process, is added Water is the 1/3 of mixture, adds glass fibre stirring 35min, component B is obtained after stirring;
Step S3:Component A and component B is mixed, auxiliary agent is added after well mixed, adds the water of surplus, be sufficiently stirred Component C is obtained after uniformly;
Step S3:Component C is filled into mould, extrusion forming obtains unbaked tile;
Step S4:Graphite spraying alkene modified polyurethane paint on to the unbaked tile of shaping, after spraying terminates, unbaked tile is placed in baking 8~10h of baking in dry chamber, the temperature for setting drying chamber is 50~60 DEG C, terminates rear natural curing 12 days.
Step S5:The spray coated paint on the unbaked tile of natural curing, spray 2-3 times, spraying produces shaping azulejo watt after terminating.
Embodiment 4
The preparation of anti-cracking environment-protection azulejo watt, parts by weight of raw materials ratio:35 parts of quick lime, 23 parts of clay, 4 parts of glass fibre, 28 parts of cement, 10 parts of quartz sand, 23 parts of attapulgite, 2 parts of iron oxide, 2 parts of stearic acid sodium, 6 parts of auxiliary agent, 26 parts of additive, water 55 parts;
The preparation of auxiliary agent, parts by weight of raw materials ratio:2 parts of maleic anhydride, 7 parts of acrylic acid, 1 part of acetone of Bian fork, sodium carbonate 1 Part, 1.5 parts of Arabic gum, 2 parts of Tween-80 and 9 parts of water;
The preparation method of described auxiliary agent is as follows:
Step S1:Arabic gum and Tween-80 are added to the water input reactor, it is 60 DEG C to set temperature, and rotating speed is 400r/min stirs 35min;
Step S2:According to proportioning weigh respectively maleic anhydride, acrylic acid, Bian fork acetone and acrylic acid it is well mixed after Put into reactor, meanwhile, sodium carbonate is ground to 50 mesh and slowly put into reactor, sets rotating speed to be stirred for 900r/min 60min is mixed, is produced;
The preparation method of anti-cracking environment-protection azulejo watt, comprises the following steps:
Step S1:Quick lime, clay, cement, quartz sand, iron oxide and stearic acid sodium grounds travel are weighed respectively according to proportioning 800 mesh are broken to, component A is obtained after being well mixed;
Step S2:Attapulgite clay is added in said components A to be mixed evenly, and water is slowly added in whipping process, is added Water is the 1/4 of mixture, adds glass fibre stirring 35min, component B is obtained after stirring;
Step S3:Component A and component B is mixed, auxiliary agent is added after well mixed, adds the water of surplus, be sufficiently stirred Component C is obtained after uniformly;
Step S3:Component C is filled into mould, extrusion forming obtains unbaked tile;
Step S4:Graphite spraying alkene modified polyurethane paint on to the unbaked tile of shaping, after spraying terminates, unbaked tile is placed in baking 8~10h of baking in dry chamber, the temperature for setting drying chamber is 50~60 DEG C, terminates rear natural curing 12 days.
Step S5:The spray coated paint on the unbaked tile of natural curing, spray 2-3 times, spraying produces shaping azulejo watt after terminating.
Embodiment 5
The preparation of anti-cracking environment-protection azulejo watt, parts by weight of raw materials ratio:40 parts of quick lime, 25 parts of clay, 3 parts of glass fibre, 30 parts of cement, 9 parts of quartz sand, 25 parts of attapulgite, 1.5 parts of iron oxide, 1.5 parts of stearic acid sodium, 5 parts of auxiliary agent, 3 parts of additive, 60 parts of water;
The preparation of auxiliary agent, parts by weight of raw materials ratio:1.5 parts of maleic anhydride, 8 parts of acrylic acid, 2 parts of acetone of Bian fork, carbonic acid 10 parts of 1 part of sodium, 1 part of Arabic gum, 3 parts of Tween-80 and water;
The preparation method of described auxiliary agent is as follows:
Step S1:Arabic gum and Tween-80 are added to the water input reactor, it is 50 DEG C to set temperature, and rotating speed is 350r/min stirs 40min;
Step S2:According to proportioning weigh respectively maleic anhydride, acrylic acid, Bian fork acetone and acrylic acid it is well mixed after Put into reactor, meanwhile, sodium carbonate is ground to 70 mesh and slowly put into reactor, sets rotating speed to be stirred for 900r/min 50min is mixed, is produced;
The preparation method of anti-cracking environment-protection azulejo watt, comprises the following steps:
Step S1:Quick lime, clay, cement, quartz sand, iron oxide and stearic acid sodium grounds travel are weighed respectively according to proportioning 100 mesh are broken to, component A is obtained after being well mixed;
Step S2:Attapulgite clay is added in said components A to be mixed evenly, and water is slowly added in whipping process, is added Water is the 1/3 of mixture, adds glass fibre stirring 35min, component B is obtained after stirring;
Step S3:Component A and component B is mixed, auxiliary agent is added after well mixed, adds the water of surplus, be sufficiently stirred Component C is obtained after uniformly;
Step S3:Component C is filled into mould, extrusion forming obtains unbaked tile;
Step S4:Graphite spraying alkene modified polyurethane paint on to the unbaked tile of shaping, after spraying terminates, unbaked tile is placed in baking 8~10h of baking in dry chamber, the temperature for setting drying chamber is 50~60 DEG C, terminates rear natural curing 12 days.
Step S5:The spray coated paint on the unbaked tile of natural curing, spray 2-3 times, spraying produces shaping azulejo watt after terminating.
In summary, using technical scheme, production efficiency is high, and the azulejo watt intensity height produced, and can prevent Only ftracture, securely and reliably, service life length, material is evenly distributed, and pigment adhesiveness is good.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention All any modification, equivalent and improvement made within refreshing and principle etc., should be included in the scope of the protection.

Claims (5)

  1. A kind of 1. anti-cracking environment-protection azulejo watt, it is characterised in that:It is prepared by the raw material of following parts by weight:Quick lime 20- 40 parts, clay 15-25 parts, glass fibre 2-4 parts, cement 20-30 parts, quartz sand 8-10 parts, attapulgite 15-25 parts, oxidation Iron 1-2 parts, stearic acid sodium 1-2 parts, auxiliary agent 4-6 parts, additive 2-4 parts, water 40-60 parts.
  2. A kind of 2. anti-cracking environment-protection azulejo watt according to claim 1, it is characterised in that:Described auxiliary agent is by following weight The raw material of part is prepared:Maleic anhydride 1-2 parts, Arabic gum 1-2 parts, acrylic acid 4-8 parts, Tween-80 2-4 parts, Bian It is as follows to pitch acetone 1-3 parts, sodium carbonate 1-3 parts and water 5-10 parts, the preparation method of described auxiliary agent:Step S1:By Arabic gum It is added to the water input reactor with Tween-80, it is 50-70 DEG C to set temperature, and rotating speed is that 300-400r/min stirs 30-40min;
    Step S2:Weigh after maleic anhydride, acrylic acid, Bian fork acetone and acrylic acid are well mixed and put into respectively according to proportioning In reactor, meanwhile, sodium carbonate is ground to 40~60 mesh and slowly put into reactor, setting rotating speed is 800-100r/ Min stirs 40-60min, produces.
  3. A kind of 3. anti-cracking environment-protection azulejo watt according to claim 1, it is characterised in that:Described additive be pigment and Coating, described pigment are one kind in red pigment, gray paint and blue pigment, and described coating is that graphene modification is poly- Urethane coating.
  4. A kind of 4. anti-cracking environment-protection azulejo watt according to claim 3, it is characterised in that:Propylene is added in described pigment Acid mixes, and the ratio of described pigment and acrylic acid is 10:1.
  5. A kind of 5. preparation method of anti-cracking environment-protection azulejo watt according to claim 1, it is characterised in that:Including following step Suddenly:
    Step S1:According to proportioning weigh respectively quick lime, clay, cement, quartz sand, iron oxide and stearic acid sodium grind to 80~120 mesh, component A is obtained after being well mixed;
    Step S2:Attapulgite clay is added in said components A to be mixed evenly, and water, amount of water are slowly added in whipping process For the 1/4-1/3 of mixture, add glass fibre and stir 30~40min, component B is obtained after stirring;
    Step S3:Component A and component B is mixed, auxiliary agent is added after well mixed, adds the water of surplus, stir Component C is obtained afterwards;
    Step S3:Component C is filled into mould, extrusion forming obtains unbaked tile;
    Step S4:Graphite spraying alkene modified polyurethane paint on to the unbaked tile of shaping, after spraying terminates, unbaked tile is placed in drying chamber 8~10h of interior baking, the temperature for setting drying chamber is 50~60 DEG C, terminates rear natural curing 10~15 days.
    Step S5:The spray coated paint on the unbaked tile of natural curing, spray 2-3 times, spraying produces shaping azulejo watt after terminating.
CN201710716436.4A 2017-08-21 2017-08-21 A kind of anti-cracking environment-protection azulejo watt and preparation method Pending CN107555921A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105948677A (en) * 2016-06-27 2016-09-21 肥西县碧涛建材有限公司 Anti-cracking encaustic tile and production technique thereof
CN106186996A (en) * 2016-06-30 2016-12-07 合肥慧林建材有限公司 A kind of cracking resistance azulejo watt and production technology thereof
CN106938905A (en) * 2017-04-06 2017-07-11 合肥欧克斯新型建材有限公司 A kind of high-strength environment-friendly azulejo watt and preparation method
CN106966657A (en) * 2017-04-06 2017-07-21 合肥欧克斯新型建材有限公司 A kind of high performance azulejo watt and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105948677A (en) * 2016-06-27 2016-09-21 肥西县碧涛建材有限公司 Anti-cracking encaustic tile and production technique thereof
CN106186996A (en) * 2016-06-30 2016-12-07 合肥慧林建材有限公司 A kind of cracking resistance azulejo watt and production technology thereof
CN106938905A (en) * 2017-04-06 2017-07-11 合肥欧克斯新型建材有限公司 A kind of high-strength environment-friendly azulejo watt and preparation method
CN106966657A (en) * 2017-04-06 2017-07-21 合肥欧克斯新型建材有限公司 A kind of high performance azulejo watt and preparation method thereof

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Application publication date: 20180109