CN107539012B - Flexible temperature-sensitive color-changing composite material and temperature-sensitive design producing apparatus - Google Patents

Flexible temperature-sensitive color-changing composite material and temperature-sensitive design producing apparatus Download PDF

Info

Publication number
CN107539012B
CN107539012B CN201710749695.7A CN201710749695A CN107539012B CN 107539012 B CN107539012 B CN 107539012B CN 201710749695 A CN201710749695 A CN 201710749695A CN 107539012 B CN107539012 B CN 107539012B
Authority
CN
China
Prior art keywords
temperature
flexible substrate
flexible
composite material
sensitive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201710749695.7A
Other languages
Chinese (zh)
Other versions
CN107539012A (en
Inventor
陈鲁倬
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fujian Normal University
Original Assignee
Fujian Normal University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fujian Normal University filed Critical Fujian Normal University
Priority to CN201710749695.7A priority Critical patent/CN107539012B/en
Publication of CN107539012A publication Critical patent/CN107539012A/en
Application granted granted Critical
Publication of CN107539012B publication Critical patent/CN107539012B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Laminated Bodies (AREA)

Abstract

The invention discloses a kind of flexible temperature-sensitive color-changing composite material and temperature-sensitive design producing apparatus, the heat-sensitive variable colour composite material includes the first flexible substrate, multiple first absorbing grains are dispersed in first flexible substrate, the second flexible substrate being stacked with first flexible substrate, heat-sensitive variable colour component is dispersed in second flexible substrate, discoloration when the heat-sensitive variable colour component is warming up to the first temperature, restore color when being cooled to second temperature, the more convenient people of stretchable and flexible performance that the flexibility temperature-sensitive color-changing composite material has use, and increase the application range of the flexible temperature-sensitive color-changing composite material, it is radiated at by the light that temperature-sensitive design producing apparatus can also will be patterned on the heat-sensitive variable colour composite material, it is set to show corresponding pattern.

Description

Flexible temperature-sensitive color-changing composite material and temperature-sensitive design producing apparatus
Technical field
The present invention relates to Material Field, especially flexible temperature-sensitive color-changing composite material and temperature-sensitive design producing apparatus.
Background technique
Traditional thermal off-color material has certain rigidity, and quality is brittle, is easy to be answered by the external world during use Power and damage, this all brings inconvenience to people's use, and limits the use scope of thermosensitive chromotropic material.
Summary of the invention
In view of the deficiencies of the prior art, it is an object of the invention to ask for traditional thermal off-color material quality is brittle Topic provides a kind of flexible temperature-sensitive color-changing composite material and temperature-sensitive design producing apparatus.
In order to realize technical purpose of the invention, the technical solution adopted by the present invention are as follows:
A kind of flexibility temperature-sensitive color-changing composite material comprising:
First flexible substrate is dispersed with multiple first absorbing grains in first flexible substrate;
Second flexible substrate, second flexible substrate is stacked with the first flexible substrate, in the second flexible substrate It is dispersed with heat-sensitive variable colour component, the heat-sensitive variable colour component changes colour when being warming up to the first temperature, is being cooled to the second temperature Restore color when spending.
As one of embodiment of the present invention program, the flexible temperature-sensitive color-changing composite material further include:
Multiple first air bags are scattered in first flexible substrate, the setting of the multiple first air bag interval;
Multiple second absorbing grains are set in each first air bag;
When first flexible substrate extends along direction elongation, the multiple first air bag is close to each other and is deformed into Flat makes the second absorbing grains mutual extrusion form stratiform to reduce the vertical direction of the plane of first flexible substrate Glazed area.
Shading liquid is filled in the multiple first air bag in one of the embodiments,.
The flexible temperature-sensitive color-changing composite material further includes multiple second air bags in one of the embodiments, described Multiple second air bags are spaced apart from each other scattering device in second flexible substrate, and the multiple second air bag is close to the second flexibility Matrix is configured far from the surface of the first flexible substrate.
The flexible temperature-sensitive color-changing composite material further includes multiple flexible thermally conductive sheets, institute in one of the embodiments, It states multiple flexible thermally conductive sheets to be arranged at intervals in first flexible substrate and the second flexible substrate, the one of each flexibility thermally conductive sheet End is connect with first air bag, and the other end of flexible thermally conductive sheet is connect with second air bag.
Heat conduction particle is provided in second air bag connecting with flexible thermally conductive sheet in one of the embodiments,;
The heat conduction particle is connect with the flexible thermally conductive sheet;
Second air bag is provided with close to the side of the second flexible substrate outer surface for exposing the heat conduction particle First opening.
Surface setting of first flexible substrate far from second flexible substrate is useful in one of the embodiments, In the second opening of release stress.
The flexible temperature-sensitive color-changing composite material further includes multiple capsules in one of the embodiments, and described is more A capsule scattering device in second flexible substrate, the part heat-sensitive variable colour component dispersion are coated in multiple capsules.
It is connected between the capsule by heat conductive filament in one of the embodiments,.
A kind of temperature-sensitive design producing apparatus comprising optical transmitting set, template, the refrigerating plant being set in sequence, the light hair Emitter and template cooperation to the illumination that will be patterned on the surface of the flexible temperature-sensitive color-changing composite material, it is described cold Freeze device to make the flexible temperature-sensitive color-changing composite material restore color.
Using above-mentioned technical solution, the flexible thermosensitive chromotropic material of the present invention program has the first flexibility being layered on top of each other Matrix and the second flexible substrate will be inhaled wherein being dispersed with the first absorbing grains in the first flexible substrate by the first absorbing grains The thermal energy of receipts passes to the heat-sensitive variable colour component in the second flexible substrate, enables heat-sensitive variable colour component change colour, wherein first is soft Property matrix and the second flexible substrate be with certain flexibility and tensility energy so that flexible heat-sensitive variable colour material of the invention Material has flexibility and stretchable characteristic, and can be more conveniently for people to use, and increases flexible temperature-sensitive The scope of application of off-color material.
Detailed description of the invention
The present invention is further elaborated with reference to the accompanying drawings and detailed description:
Fig. 1 is the structural schematic diagram of the flexible temperature-sensitive color-changing composite material of the embodiment of the present invention 1;
Fig. 2 is the structural schematic diagram of the first air bag in embodiment 1;
Fig. 3 is the structural schematic diagram of the flexible temperature-sensitive color-changing composite material of the embodiment of the present invention 2;
Fig. 4 is the structural schematic diagram after flexible temperature-sensitive color-changing composite material is stretched in the embodiment of the present invention 2;
Fig. 5 is the structure simplified diagram of the second air bag in the embodiment of the present invention 3;
Fig. 6 is the structure simplified diagram of the flexible temperature-sensitive color-changing composite material of the embodiment of the present invention 3;
Fig. 7 is the structure simplified diagram of the flexible temperature-sensitive color-changing composite material of the embodiment of the present invention 4;
Fig. 8 is the structure simplified diagram of temperature-sensitive design producing apparatus of the present invention;
Wherein, each Major Symbol is expressed as follows in Fig. 1 to 8:
Flexible temperature-sensitive color-changing composite material 10, the first flexible substrate 100, the first absorbing grains 110, the first air bag 120, Two absorbing grains 121, shading liquid 122, the second flexible substrate 200, flexible thermally conductive sheet 210, branch's thermally conductive sheet 211, the second gas Capsule 220, first opening 221, second opening 222, heat conduction particle 223, heat-sensitive variable colour component 230, capsule 240, heat conductive filament 250, Temperature-sensitive design producing apparatus 20, optical transmitting set 310, template 320, fixed frame 330, refrigerating plant 340.
Specific embodiment
In order to which goal of the invention of the invention, technical solution and technical effect is more clearly understood, below in conjunction with attached drawing pair Specific embodiments of the present invention are described.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, It is not intended to limit the present invention.
Embodiment 1
As shown in Figure 1, one of embodiment as flexible temperature-sensitive color-changing composite material of the invention, the present embodiment institute Stating flexible temperature-sensitive color-changing composite material 10 includes the first flexible substrate 100, and multiple the are dispersed in first flexible substrate 100 One absorbing grains 110, stacking is provided with the second flexible substrate 200, the described second flexible base on first flexible substrate 100 Heat-sensitive variable colour component 230 is dispersed in body 200, the discoloration when being warming up to the first temperature of heat-sensitive variable colour component 230 is being dropped Restore color when temperature to second temperature.
Wherein, first flexible substrate 100 and the second flexible substrate 200 have certain tensile property, Ke Yili Solution be that constitute the material of first flexible substrate 100 and the second flexible substrate 200 be that silicone elastomer, fluorine silicone rubber are elastic It one of body, polyurethane, epoxy resin, poly-methyl methacrylate vinegar and any several is combined.
In addition, first absorbing grains 110 are for absorbing luminous energy, and convert light energy into thermal energy to pass to second soft Property matrix 200 in heat-sensitive variable colour component 230, the first absorbing grains 110 can receive for graphene, graphene oxide, carbon black, carbon The combination of one of mitron, gold nano grain, silver nano-grain, tungsten oxide nanoparticles or its any two or multiple components The particle of formation;The heat-sensitive variable colour component 230 can by containing supplied for electronic compound, by electron compound and organic solvent The composition of composition is constituted;It is colored state under 230 room temperature of heat-sensitive variable colour component, is heated to the first temperature or is higher than institute Colour killing reaction occurs when stating the first temperature, 230 color of heat-sensitive variable colour component disappears and stops heating after colour killing reaction occurs Color is no longer restored afterwards, will be placed in the second temperature by the heat-sensitive variable colour component 230 of colour killing or lower than second temperature The color of the heat-sensitive variable colour component 230 is restored again when spending, and the second temperature is lower than first temperature, and the heat The discoloration of quick chromic component and recovery process may be repeated, wherein first temperature be 55 DEG C ~ 60 DEG C, described second Temperature is -8 DEG C ~ -10 DEG C.
In flexible temperature-sensitive color-changing composite material 10 described in the present embodiment, first absorbing grains 110 are by the heat of absorption The heat-sensitive variable colour component 230, which can be passed to, makes the heat-sensitive variable colour component 230 change colour, first flexible substrate 100 and institute Stating the second flexible substrate 200 has certain flexible and stretchable performance, therefore the flexible temperature-sensitive color-changing composite material 10 With stretchable and flexible characteristic, the stretchable and flexible performance that the flexibility temperature-sensitive color-changing composite material 10 has is more It is convenient for people to use, and increases the use scope of the flexible temperature-sensitive color-changing composite material 10.
As shown in Fig. 2, the flexible temperature-sensitive color-changing composite material 10 further includes being scattered in first flexible substrate 100 In multiple first air bags 120, the setting of the multiple first air bag 120 interval is provided with multiple the in each first air bag 120 Two absorbing grains 121.Second absorbing grains 121 can be graphene, graphene oxide, carbon black, carbon nanotube, gold nano The particle that the combination of one of grain, silver nano-grain, tungsten oxide nanoparticles or its any two or multiple components is formed.Institute When stating extending direction elongation of first flexible substrate 100 along first flexible substrate 100, the multiple first air bag, 120 phase Mutually it is close, be deformed into flat make 121 mutual extrusion of the second absorbing grains formed stratiform to reduce first flexible substrate 100 The glazed area of the vertical direction of plane.It is to be understood that when the flexible temperature-sensitive color-changing composite material 10 is stretched, it is described The area of flexible temperature-sensitive color-changing composite material 10 will increase, but thickness can be corresponding thinning.When the flexible heat-sensitive variable colour is compound Its translucency can become strong when 10 thickness of material is thinning.In visual effect, the flexible temperature-sensitive color-changing composite material 10 is whole Color can be thin out, this can all influence the perception of people.The flexibility is utilized on the surface of the flexible temperature-sensitive color-changing composite material 10 When the temperature-sensitive property of heat-sensitive variable colour composite material 10 draws a design, it usually needs draw the flexible temperature-sensitive color-changing composite material 10 It stretches and paves, flexible temperature-sensitive color-changing composite material 10 will be thinning during stretching, during stretching first air bag 120 can correspondingly deform, and space can become smaller after first air bag 120 deforms, and the multiple second absorbing grains 121 can phase It mutually squeezes, the distance between the multiple second absorbing grains 121 will become smaller, therefore can reduce and become in the flexible temperature-sensitive The area of light transmission in the vertical direction of 10 plane of color composite material.It will visually reduce due to the flexible heat-sensitive variable colour Composite material 10 be stretched it is thinning after caused by color change influence.In addition, in the flexible temperature-sensitive color-changing composite material 10 After being stretched, after the space in each first air bag 120 is compressed, the multiple second absorbing grains 121 are mutually squeezed Pressure has bigger density, therefore can have stronger absorbing ability.
Wherein, it is filled with shading liquid 122 in the multiple first air bag 120, shading liquid 122 is for being filled in second Gap between absorbing grains 121, thus the shading performance of the first air bag 120 can be made more preferable.Preferably, the shading liquid 122 color can be same or similar with 121 color of the second absorbing grains.It is described as one of embodiment Shading liquid 122 can be dark colour ink, and first air bag 120 can be made of flexible silica gel material, soft first The first air bag 120 can be added during property 100 curing molding of matrix, the first air bag 120 solidifies in the first flexible substrate 100 During can be integrally formed with the first flexible substrate 100.
Embodiment 2
As shown in figure 3 or 4, the present embodiment is roughly the same with 1 structure of embodiment, the difference is that described second is soft Property matrix in have multiple the second air bags 220 for being spaced apart from each other scattering device, the multiple second air bag 220 close to second flexibility Matrix 200 is configured far from the surface of the first flexible substrate 100, and multiple second air bags 220 are in the second flexible substrate 200 Surface setting far from first flexible substrate 100 can form the structure of stratiform, so that the stratiform of multiple second air bags 220 Arrangement has the effect of heat-insulated.When the heat transfer that first flexible substrate 100 absorbs gives second flexible substrate 200 Afterwards, second air bag 220 can slow down heat and outwardly conduct, therefore second flexible substrate 200 can be with rapid aggregation Heat accelerates the discoloration of the heat-sensitive variable colour component 230.
In addition, flexible temperature-sensitive color-changing composite material 10 further includes multiple flexible thermally conductive sheets 210, multiple flexibility thermally conductive sheets 210 It is arranged at intervals in first flexible substrate 100 and the second flexible substrate 200, one end and one of each flexibility thermally conductive sheet 210 A first air bag 120 connects, and the other end of flexible thermally conductive sheet 210 is connect with second air bag 220, the flexible thermally conductive sheet 210 for giving the heat transfer of first air bag 120 to the second air bag 220, and the second air bag 220 can be quickly swollen after heat absorption It is swollen, so as to increase thermal resistance, reduce the loss of 200 heat of the second flexible substrate, also, the flexible thermally conductive sheet 210 can be with With certain heat dissipation area.Heat can be quickly conducted to second flexible substrate by the flexible thermally conductive sheet 210 So that heat-sensitive variable colour component 230 changes colour, the flexibility thermally conductive sheet 210 can be passed heat-sensitive variable colour component 230 in 200 by heat Adhesive tape is led to be made.Wherein, the flexible thermally conductive sheet 210 can be added during the second flexible substrate 200 is cured, and with institute State the integrated molding of the second flexible substrate 200.An embodiment wherein can be set point on the flexibility thermally conductive sheet 210 Branch thermally conductive sheet 211, branch's thermally conductive sheet 211 can be in 200 internal stretches of the second flexible substrate, to increase thermally conductive road Diameter and heat-conducting area are to accelerate heat conduction rate.
Embodiment 3
As shown in Fig. 5 or 6, the present embodiment is roughly the same with embodiment 2, the difference is that the flexibility thermally conductive sheet Heat conduction particle 223 is provided in second air bag 220 of 210 connections, the heat conduction particle 223 connects with the flexible thermally conductive sheet 210 It connects, second air bag 220 is provided with close to the side of 200 outer surface of the second flexible substrate for exposing described thermally conductive First opening 221 of grain 223, second air bag 220 can be made of the rubber material with favorable elasticity, it will be understood that Under room temperature, second air bag 220 can be wrapped tightly in the outer surface of the heat conduction particle 223.The heat conduction particle 223 can be by Metal material is made, and can also be made of the good material of the heating conductions such as diamond.Heat can be thermally conductive by the flexibility Piece 210 passes to the heat conduction particle 223 from first flexible substrate 100, and the heat conduction particle 223 can heat described Gas in two air bags 220 is to make the expansion of the second air bag 220 become larger to increase thermal resistance.Second flexible substrate 200 It can have good elasticity, when the expansion of the second air bag 220 becomes larger, the convergent force of second flexible substrate 200 can The aperture of first opening 221 is reduced, therefore first opening 221 influences the swelling volume of second air bag 220 Very little.Also, due to persistently thermally conductive, in second air bag 220 increase of air pressure and as first opening 221 caused by described in The reduction of air pressure is able to maintain that balance in second air bag 220, and the volume of second air bag 220 is enabled to be maintained at expansion State.Also, it when the flexible temperature-sensitive color-changing composite material 10 restores color, needs the flexible heat-sensitive variable colour composite wood Material 10 is placed on low temperature environment, second air bag 220 at low temperature can contraction distortion be wrapped in the table of the heat conduction particle 223 Face, second air bag 220 while retraction volume.The heat conduction particle 223 can expose from first opening 221, thus Convenient for the heat exchange of the heat conduction particle 223.It can be understood as the rate of heat dispation of the heat conduction particle 223 at low temperatures more Fastly, therefore the speed of 10 cooling of flexible temperature-sensitive color-changing composite material can be accelerated, thus the flexible temperature-sensitive can be accelerated The speed that color-changing composite material 10 changes colour.
As one of embodiment, surface of first flexible substrate 100 far from second flexible substrate 200 It is provided with the second opening 222 for discharging stress.After the flexibility temperature-sensitive color-changing composite material 10 is stretched, first gas Capsule 120 is understood along the Direction distortion being stretched, therefore in the stress of first air bag 120 and the draw direction vertical direction Can accordingly it become larger, second opening 222 can slow down first air bag 120 and answer with the draw direction vertical direction Power, increases the space of 120 Free Transform of the first air bag, thus can increase the flexible temperature-sensitive color-changing composite material 10 Service life avoids excessive stress from damaging the flexible temperature-sensitive color-changing composite material 10.
Embodiment 4
As shown in fig. 7, the present embodiment is roughly the same with embodiment 1, the difference is that the heat-sensitive variable colour component 230 Dispersion is coated in multiple capsules 240, the multiple capsule 240 scattering device, glue in second flexible substrate 200 Capsule 240 wraps up the heat-sensitive variable colour component 230 and the density of the heat-sensitive variable colour component 230 is increased, thus macroscopically sees institute It states flexible 10 metachromatism of temperature-sensitive color-changing composite material to become apparent, the capsule 240 can be by transparent silastic material system At.
As one of connection embodiment between capsule 240, connected between the capsule 240 by heat conductive filament 250 It connects.When the flexible temperature-sensitive color-changing composite material 10 is whole to be needed to change colour, the heat conductive filament 250 can make the capsule Heat between 240 is rapidly reached balance, therefore the degree meeting of the heat-sensitive variable colour component 230 discoloration in the capsule 240 It reaches unanimity, the non-uniform of color can be caused to avoid even due to flexible temperature-sensitive 10 uneven heatings of color-changing composite material Phenomenon.
As shown in figure 8, it illustrates a kind of temperature-sensitive design producing apparatus 20, the temperature-sensitive design producing apparatus 20 include according to The optical transmitting set 310 of sequence setting, template 320, refrigerating plant 340, the optical transmitting set 310 and the cooperation of template 320 will be will scheme The illumination of case is on the surface of the flexible temperature-sensitive color-changing composite material 10, and the refrigerating plant 340 is to make the flexibility Heat-sensitive variable colour composite material 10 restores color, the template 320 be set to the optical transmitting set 310 and the fixed frame 330 it Between, the fixed frame 330 is for the flexible temperature-sensitive color-changing composite material 10, and the refrigerating plant 340 is to make It states flexible temperature-sensitive color-changing composite material 10 and restores color, the light that the optical transmitting set 310 issues has certain energy, wherein The optical transmitting set 310 can be laser emitter, infrared transmitter etc..
Flexible temperature-sensitive color-changing composite material 10 temperature after different positions absorbs energy increases discoloration, passes through the template The section of 320 light can be different pattern, and the light of the different pattern is radiated at the flexible temperature-sensitive color-changing composite material After on 10 surface, 10 surface of flexibility temperature-sensitive color-changing composite material can form pattern corresponding with the template 320, The fixed frame 330 is used to after flexible temperature-sensitive color-changing composite material 10 is stretched flattening fix, and fixed frame 330 is to the flexible thermal The stretching distance of quick color-changing composite material 10 is adjustable.Refrigerating plant 340 can be correspondingly arranged with fixed frame 330, when described It, can be by the fixed frame 330 by the flexible thermal when pattern on flexible 10 surface of temperature-sensitive color-changing composite material needs to disappear Quick color-changing composite material 10 is sent into the refrigerating plant 340, makes flexible temperature-sensitive color-changing composite material by the cooling of refrigerating plant 340 10 surface recovery colors, and pattern, Reusability can be changed again.
It should be noted that it can directly on the other element when element is referred to as " being fixed on " another element Or there may also be elements placed in the middle.When an element is considered as " connection " another element, it, which can be, is directly connected to To another element or it may be simultaneously present centering elements.On the contrary, when element is referred to as " directly existing " another element "upper", There is no intermediary elements.Term as used herein "vertical", "horizontal", "left" and "right" and similar statement are For illustrative purposes.
The embodiments described above only express several embodiments of the present invention, and the description thereof is more specific and detailed, but simultaneously Limitations on the scope of the patent of the present invention therefore cannot be interpreted as.It should be pointed out that for those of ordinary skill in the art For, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to guarantor of the invention Protect range.Therefore, the scope of protection of the patent of the invention shall be subject to the appended claims.

Claims (9)

1. a kind of flexibility temperature-sensitive color-changing composite material, characterized in that it comprises:
First flexible substrate (100) is dispersed with multiple first absorbing grains (110) in first flexible substrate (100);
Second flexible substrate (200), second flexible substrate (200) are stacked with the first flexible substrate (100), and second It is dispersed in flexible substrate (200) heat-sensitive variable colour component (230), the heat-sensitive variable colour component (230) is warming up to the first temperature Shi Fasheng discoloration, restores color when being cooled to second temperature;
Multiple first air bags (120) are scattered in first flexible substrate (100), the multiple first air bag (120) interval Setting;
Multiple second absorbing grains (121) are set in each first air bag (120);
When first flexible substrate (100) extends along direction elongation, the multiple first air bag (120) is close to each other simultaneously Being deformed into flat makes the second absorbing grains (121) mutual extrusion form stratiform to reduce first flexible substrate (100) Plane vertical direction glazed area.
2. flexibility temperature-sensitive color-changing composite material as described in claim 1, which is characterized in that the multiple first air bag (120) It is interior to be filled with shading liquid (122).
3. flexibility temperature-sensitive color-changing composite material as described in claim 1, which is characterized in that it further includes multiple second air bags (220), the multiple second air bag (220) is spaced apart from each other scattering device in second flexible substrate (200), the multiple Second air bag (220) is configured close to the second flexible substrate (200) far from the surface of the first flexible substrate (100).
4. flexibility temperature-sensitive color-changing composite material as claimed in claim 3, which is characterized in that it further includes multiple flexible thermally conductive sheets (210), the multiple flexible thermally conductive sheet (210) is arranged at intervals at first flexible substrate (100) and the second flexible substrate (200) in, it is each flexibility thermally conductive sheet (210) one end connect with first air bag (120), flexible thermally conductive sheet (210) it is another One end is connect with second air bag (220).
5. flexibility temperature-sensitive color-changing composite material as claimed in claim 4, which is characterized in that connect with flexible thermally conductive sheet (210) The second air bag (220) in be provided with heat conduction particle (223);
The heat conduction particle (223) is connect with the flexible thermally conductive sheet (210);
Second air bag (220) is provided with described thermally conductive for exposing close to the side of the second flexible substrate (200) outer surface First opening (221) of particle (223).
6. flexibility temperature-sensitive color-changing composite material as described in claim 1, which is characterized in that first flexible substrate (100) Surface far from second flexible substrate (200) is provided with the second opening (222) for discharging stress.
7. flexibility temperature-sensitive color-changing composite material as described in claim 1, which is characterized in that it further includes multiple capsules (240), Multiple capsules (240) are in the interior scattering device of second flexible substrate (200), the part heat-sensitive variable colour component (230) dispersion is coated in multiple capsules (240).
8. flexibility temperature-sensitive color-changing composite material as claimed in claim 7, which is characterized in that pass through between the capsule (240) Heat conductive filament (250) connection.
9. a kind of temperature-sensitive design producing apparatus, which is characterized in that it includes the optical transmitting set (310) being set in sequence, template (320), refrigerating plant (340), the optical transmitting set (310) and the template (320) cooperation exist to the illumination that will be patterned into Such as the surface of the described in any item flexible temperature-sensitive color-changing composite materials (10) of claim 1-8, the refrigerating plant (340) to The flexible temperature-sensitive color-changing composite material (10) is set to restore color.
CN201710749695.7A 2017-08-28 2017-08-28 Flexible temperature-sensitive color-changing composite material and temperature-sensitive design producing apparatus Active CN107539012B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710749695.7A CN107539012B (en) 2017-08-28 2017-08-28 Flexible temperature-sensitive color-changing composite material and temperature-sensitive design producing apparatus

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710749695.7A CN107539012B (en) 2017-08-28 2017-08-28 Flexible temperature-sensitive color-changing composite material and temperature-sensitive design producing apparatus

Publications (2)

Publication Number Publication Date
CN107539012A CN107539012A (en) 2018-01-05
CN107539012B true CN107539012B (en) 2019-10-25

Family

ID=60958294

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710749695.7A Active CN107539012B (en) 2017-08-28 2017-08-28 Flexible temperature-sensitive color-changing composite material and temperature-sensitive design producing apparatus

Country Status (1)

Country Link
CN (1) CN107539012B (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111908953B (en) * 2020-09-03 2024-04-26 苏州和昌电子材料有限公司 Thermosensitive phase change protective film, preparation method thereof and laminated ceramic capacitor
CN112397245B (en) * 2020-09-29 2022-07-26 广东电网有限责任公司 Cable filler thermochromism color development device capable of developing color faster
CN112289662A (en) * 2020-11-17 2021-01-29 安徽伊法拉电力科技有限公司 Novel reversible thermosensitive ABB fuse early warning insulating sheath material and preparation method thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101819335A (en) * 2009-02-27 2010-09-01 清华大学 Thermochromatic element and thermochromatic display device
CN102827597A (en) * 2012-06-21 2012-12-19 天津工业大学 Thermosensitive discoloring energy-storage material and preparation method thereof
CN103728742A (en) * 2012-10-15 2014-04-16 北京富纳特创新科技有限公司 Thermochromism display element and thermochromism display device
CN103913918A (en) * 2013-01-07 2014-07-09 严旭明 Controllable flexible color change display material and production method thereof
CN104476924A (en) * 2006-12-26 2015-04-01 株式会社理光 Image processing method and image processor
CN104865767A (en) * 2015-06-05 2015-08-26 福建师范大学 Electrochromic composite material and electrochromic device and preparation method thereof
CN106323881A (en) * 2016-08-04 2017-01-11 苏州大学 Heating device and method for testing color characteristic value of thermoreversible color-changing fabric

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7749593B2 (en) * 2006-07-07 2010-07-06 Certainteed Corporation Solar heat responsive exterior surface covering

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104476924A (en) * 2006-12-26 2015-04-01 株式会社理光 Image processing method and image processor
CN101819335A (en) * 2009-02-27 2010-09-01 清华大学 Thermochromatic element and thermochromatic display device
CN102827597A (en) * 2012-06-21 2012-12-19 天津工业大学 Thermosensitive discoloring energy-storage material and preparation method thereof
CN103728742A (en) * 2012-10-15 2014-04-16 北京富纳特创新科技有限公司 Thermochromism display element and thermochromism display device
CN103913918A (en) * 2013-01-07 2014-07-09 严旭明 Controllable flexible color change display material and production method thereof
CN104865767A (en) * 2015-06-05 2015-08-26 福建师范大学 Electrochromic composite material and electrochromic device and preparation method thereof
CN106323881A (en) * 2016-08-04 2017-01-11 苏州大学 Heating device and method for testing color characteristic value of thermoreversible color-changing fabric

Also Published As

Publication number Publication date
CN107539012A (en) 2018-01-05

Similar Documents

Publication Publication Date Title
CN107539012B (en) Flexible temperature-sensitive color-changing composite material and temperature-sensitive design producing apparatus
CN203715549U (en) Aircraft part as compound product
CN107031144A (en) A kind of high efficiency and heat radiation metal foil and preparation method and application
CN108859379A (en) A kind of solar components packaging system
CN111777338A (en) Single-glass film, double-glass film hollow glass, manufacturing method, production equipment and application
Wang et al. Freezing-resistant poly (N-isopropylacrylamide)-based hydrogel for thermochromic smart window with solar and thermal radiation regulation
Jung et al. Strain-insensitive outdoor wearable electronics by thermally robust nanofibrous radiative cooler
CN208801601U (en) Even heat type plastic uptake process equipment
JP2019107817A (en) Method and device of forming curved laminate substrate
CN206406537U (en) A kind of one side is without viscous heat-conducting silica gel sheet
US20210213718A1 (en) Stretchable thermal radiation modulation system via mechanically tunable surface emissivity
EP1640426A3 (en) Heat-resistant label
CN107498423B (en) Cooling device for reflecting mirror ion beam polishing
JP2000160721A (en) Production of silica aerogel panel
CN208812691U (en) A kind of solar components packaging system
JP2018088010A5 (en)
CN209355581U (en) A kind of self-expansion type Novel heating sheet and the battery clamp comprising it
CN205782084U (en) Lamp bar, backlight module and display device
CN204578942U (en) Radiating subassembly
CN104121512A (en) LED flexible line lamp
CN2653346Y (en) Thin film type carbon fiber light transmission heater
CN105676337A (en) Polaroid and liquid crystal display device
CN110193989A (en) Lithium battery heat-resistant fireproof self-heating Soft Roll material fabrication process
CN206999805U (en) Can Electrocontrolled color change diaphragm
CN207443147U (en) A kind of even heat type electric hot plate

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant