CN107539012B - Flexible temperature-sensitive color-changing composite material and temperature-sensitive design producing apparatus - Google Patents
Flexible temperature-sensitive color-changing composite material and temperature-sensitive design producing apparatus Download PDFInfo
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- CN107539012B CN107539012B CN201710749695.7A CN201710749695A CN107539012B CN 107539012 B CN107539012 B CN 107539012B CN 201710749695 A CN201710749695 A CN 201710749695A CN 107539012 B CN107539012 B CN 107539012B
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Abstract
The invention discloses a kind of flexible temperature-sensitive color-changing composite material and temperature-sensitive design producing apparatus, the heat-sensitive variable colour composite material includes the first flexible substrate, multiple first absorbing grains are dispersed in first flexible substrate, the second flexible substrate being stacked with first flexible substrate, heat-sensitive variable colour component is dispersed in second flexible substrate, discoloration when the heat-sensitive variable colour component is warming up to the first temperature, restore color when being cooled to second temperature, the more convenient people of stretchable and flexible performance that the flexibility temperature-sensitive color-changing composite material has use, and increase the application range of the flexible temperature-sensitive color-changing composite material, it is radiated at by the light that temperature-sensitive design producing apparatus can also will be patterned on the heat-sensitive variable colour composite material, it is set to show corresponding pattern.
Description
Technical field
The present invention relates to Material Field, especially flexible temperature-sensitive color-changing composite material and temperature-sensitive design producing apparatus.
Background technique
Traditional thermal off-color material has certain rigidity, and quality is brittle, is easy to be answered by the external world during use
Power and damage, this all brings inconvenience to people's use, and limits the use scope of thermosensitive chromotropic material.
Summary of the invention
In view of the deficiencies of the prior art, it is an object of the invention to ask for traditional thermal off-color material quality is brittle
Topic provides a kind of flexible temperature-sensitive color-changing composite material and temperature-sensitive design producing apparatus.
In order to realize technical purpose of the invention, the technical solution adopted by the present invention are as follows:
A kind of flexibility temperature-sensitive color-changing composite material comprising:
First flexible substrate is dispersed with multiple first absorbing grains in first flexible substrate;
Second flexible substrate, second flexible substrate is stacked with the first flexible substrate, in the second flexible substrate
It is dispersed with heat-sensitive variable colour component, the heat-sensitive variable colour component changes colour when being warming up to the first temperature, is being cooled to the second temperature
Restore color when spending.
As one of embodiment of the present invention program, the flexible temperature-sensitive color-changing composite material further include:
Multiple first air bags are scattered in first flexible substrate, the setting of the multiple first air bag interval;
Multiple second absorbing grains are set in each first air bag;
When first flexible substrate extends along direction elongation, the multiple first air bag is close to each other and is deformed into
Flat makes the second absorbing grains mutual extrusion form stratiform to reduce the vertical direction of the plane of first flexible substrate
Glazed area.
Shading liquid is filled in the multiple first air bag in one of the embodiments,.
The flexible temperature-sensitive color-changing composite material further includes multiple second air bags in one of the embodiments, described
Multiple second air bags are spaced apart from each other scattering device in second flexible substrate, and the multiple second air bag is close to the second flexibility
Matrix is configured far from the surface of the first flexible substrate.
The flexible temperature-sensitive color-changing composite material further includes multiple flexible thermally conductive sheets, institute in one of the embodiments,
It states multiple flexible thermally conductive sheets to be arranged at intervals in first flexible substrate and the second flexible substrate, the one of each flexibility thermally conductive sheet
End is connect with first air bag, and the other end of flexible thermally conductive sheet is connect with second air bag.
Heat conduction particle is provided in second air bag connecting with flexible thermally conductive sheet in one of the embodiments,;
The heat conduction particle is connect with the flexible thermally conductive sheet;
Second air bag is provided with close to the side of the second flexible substrate outer surface for exposing the heat conduction particle
First opening.
Surface setting of first flexible substrate far from second flexible substrate is useful in one of the embodiments,
In the second opening of release stress.
The flexible temperature-sensitive color-changing composite material further includes multiple capsules in one of the embodiments, and described is more
A capsule scattering device in second flexible substrate, the part heat-sensitive variable colour component dispersion are coated in multiple capsules.
It is connected between the capsule by heat conductive filament in one of the embodiments,.
A kind of temperature-sensitive design producing apparatus comprising optical transmitting set, template, the refrigerating plant being set in sequence, the light hair
Emitter and template cooperation to the illumination that will be patterned on the surface of the flexible temperature-sensitive color-changing composite material, it is described cold
Freeze device to make the flexible temperature-sensitive color-changing composite material restore color.
Using above-mentioned technical solution, the flexible thermosensitive chromotropic material of the present invention program has the first flexibility being layered on top of each other
Matrix and the second flexible substrate will be inhaled wherein being dispersed with the first absorbing grains in the first flexible substrate by the first absorbing grains
The thermal energy of receipts passes to the heat-sensitive variable colour component in the second flexible substrate, enables heat-sensitive variable colour component change colour, wherein first is soft
Property matrix and the second flexible substrate be with certain flexibility and tensility energy so that flexible heat-sensitive variable colour material of the invention
Material has flexibility and stretchable characteristic, and can be more conveniently for people to use, and increases flexible temperature-sensitive
The scope of application of off-color material.
Detailed description of the invention
The present invention is further elaborated with reference to the accompanying drawings and detailed description:
Fig. 1 is the structural schematic diagram of the flexible temperature-sensitive color-changing composite material of the embodiment of the present invention 1;
Fig. 2 is the structural schematic diagram of the first air bag in embodiment 1;
Fig. 3 is the structural schematic diagram of the flexible temperature-sensitive color-changing composite material of the embodiment of the present invention 2;
Fig. 4 is the structural schematic diagram after flexible temperature-sensitive color-changing composite material is stretched in the embodiment of the present invention 2;
Fig. 5 is the structure simplified diagram of the second air bag in the embodiment of the present invention 3;
Fig. 6 is the structure simplified diagram of the flexible temperature-sensitive color-changing composite material of the embodiment of the present invention 3;
Fig. 7 is the structure simplified diagram of the flexible temperature-sensitive color-changing composite material of the embodiment of the present invention 4;
Fig. 8 is the structure simplified diagram of temperature-sensitive design producing apparatus of the present invention;
Wherein, each Major Symbol is expressed as follows in Fig. 1 to 8:
Flexible temperature-sensitive color-changing composite material 10, the first flexible substrate 100, the first absorbing grains 110, the first air bag 120,
Two absorbing grains 121, shading liquid 122, the second flexible substrate 200, flexible thermally conductive sheet 210, branch's thermally conductive sheet 211, the second gas
Capsule 220, first opening 221, second opening 222, heat conduction particle 223, heat-sensitive variable colour component 230, capsule 240, heat conductive filament 250,
Temperature-sensitive design producing apparatus 20, optical transmitting set 310, template 320, fixed frame 330, refrigerating plant 340.
Specific embodiment
In order to which goal of the invention of the invention, technical solution and technical effect is more clearly understood, below in conjunction with attached drawing pair
Specific embodiments of the present invention are described.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention,
It is not intended to limit the present invention.
Embodiment 1
As shown in Figure 1, one of embodiment as flexible temperature-sensitive color-changing composite material of the invention, the present embodiment institute
Stating flexible temperature-sensitive color-changing composite material 10 includes the first flexible substrate 100, and multiple the are dispersed in first flexible substrate 100
One absorbing grains 110, stacking is provided with the second flexible substrate 200, the described second flexible base on first flexible substrate 100
Heat-sensitive variable colour component 230 is dispersed in body 200, the discoloration when being warming up to the first temperature of heat-sensitive variable colour component 230 is being dropped
Restore color when temperature to second temperature.
Wherein, first flexible substrate 100 and the second flexible substrate 200 have certain tensile property, Ke Yili
Solution be that constitute the material of first flexible substrate 100 and the second flexible substrate 200 be that silicone elastomer, fluorine silicone rubber are elastic
It one of body, polyurethane, epoxy resin, poly-methyl methacrylate vinegar and any several is combined.
In addition, first absorbing grains 110 are for absorbing luminous energy, and convert light energy into thermal energy to pass to second soft
Property matrix 200 in heat-sensitive variable colour component 230, the first absorbing grains 110 can receive for graphene, graphene oxide, carbon black, carbon
The combination of one of mitron, gold nano grain, silver nano-grain, tungsten oxide nanoparticles or its any two or multiple components
The particle of formation;The heat-sensitive variable colour component 230 can by containing supplied for electronic compound, by electron compound and organic solvent
The composition of composition is constituted;It is colored state under 230 room temperature of heat-sensitive variable colour component, is heated to the first temperature or is higher than institute
Colour killing reaction occurs when stating the first temperature, 230 color of heat-sensitive variable colour component disappears and stops heating after colour killing reaction occurs
Color is no longer restored afterwards, will be placed in the second temperature by the heat-sensitive variable colour component 230 of colour killing or lower than second temperature
The color of the heat-sensitive variable colour component 230 is restored again when spending, and the second temperature is lower than first temperature, and the heat
The discoloration of quick chromic component and recovery process may be repeated, wherein first temperature be 55 DEG C ~ 60 DEG C, described second
Temperature is -8 DEG C ~ -10 DEG C.
In flexible temperature-sensitive color-changing composite material 10 described in the present embodiment, first absorbing grains 110 are by the heat of absorption
The heat-sensitive variable colour component 230, which can be passed to, makes the heat-sensitive variable colour component 230 change colour, first flexible substrate 100 and institute
Stating the second flexible substrate 200 has certain flexible and stretchable performance, therefore the flexible temperature-sensitive color-changing composite material 10
With stretchable and flexible characteristic, the stretchable and flexible performance that the flexibility temperature-sensitive color-changing composite material 10 has is more
It is convenient for people to use, and increases the use scope of the flexible temperature-sensitive color-changing composite material 10.
As shown in Fig. 2, the flexible temperature-sensitive color-changing composite material 10 further includes being scattered in first flexible substrate 100
In multiple first air bags 120, the setting of the multiple first air bag 120 interval is provided with multiple the in each first air bag 120
Two absorbing grains 121.Second absorbing grains 121 can be graphene, graphene oxide, carbon black, carbon nanotube, gold nano
The particle that the combination of one of grain, silver nano-grain, tungsten oxide nanoparticles or its any two or multiple components is formed.Institute
When stating extending direction elongation of first flexible substrate 100 along first flexible substrate 100, the multiple first air bag, 120 phase
Mutually it is close, be deformed into flat make 121 mutual extrusion of the second absorbing grains formed stratiform to reduce first flexible substrate 100
The glazed area of the vertical direction of plane.It is to be understood that when the flexible temperature-sensitive color-changing composite material 10 is stretched, it is described
The area of flexible temperature-sensitive color-changing composite material 10 will increase, but thickness can be corresponding thinning.When the flexible heat-sensitive variable colour is compound
Its translucency can become strong when 10 thickness of material is thinning.In visual effect, the flexible temperature-sensitive color-changing composite material 10 is whole
Color can be thin out, this can all influence the perception of people.The flexibility is utilized on the surface of the flexible temperature-sensitive color-changing composite material 10
When the temperature-sensitive property of heat-sensitive variable colour composite material 10 draws a design, it usually needs draw the flexible temperature-sensitive color-changing composite material 10
It stretches and paves, flexible temperature-sensitive color-changing composite material 10 will be thinning during stretching, during stretching first air bag
120 can correspondingly deform, and space can become smaller after first air bag 120 deforms, and the multiple second absorbing grains 121 can phase
It mutually squeezes, the distance between the multiple second absorbing grains 121 will become smaller, therefore can reduce and become in the flexible temperature-sensitive
The area of light transmission in the vertical direction of 10 plane of color composite material.It will visually reduce due to the flexible heat-sensitive variable colour
Composite material 10 be stretched it is thinning after caused by color change influence.In addition, in the flexible temperature-sensitive color-changing composite material 10
After being stretched, after the space in each first air bag 120 is compressed, the multiple second absorbing grains 121 are mutually squeezed
Pressure has bigger density, therefore can have stronger absorbing ability.
Wherein, it is filled with shading liquid 122 in the multiple first air bag 120, shading liquid 122 is for being filled in second
Gap between absorbing grains 121, thus the shading performance of the first air bag 120 can be made more preferable.Preferably, the shading liquid
122 color can be same or similar with 121 color of the second absorbing grains.It is described as one of embodiment
Shading liquid 122 can be dark colour ink, and first air bag 120 can be made of flexible silica gel material, soft first
The first air bag 120 can be added during property 100 curing molding of matrix, the first air bag 120 solidifies in the first flexible substrate 100
During can be integrally formed with the first flexible substrate 100.
Embodiment 2
As shown in figure 3 or 4, the present embodiment is roughly the same with 1 structure of embodiment, the difference is that described second is soft
Property matrix in have multiple the second air bags 220 for being spaced apart from each other scattering device, the multiple second air bag 220 close to second flexibility
Matrix 200 is configured far from the surface of the first flexible substrate 100, and multiple second air bags 220 are in the second flexible substrate 200
Surface setting far from first flexible substrate 100 can form the structure of stratiform, so that the stratiform of multiple second air bags 220
Arrangement has the effect of heat-insulated.When the heat transfer that first flexible substrate 100 absorbs gives second flexible substrate 200
Afterwards, second air bag 220 can slow down heat and outwardly conduct, therefore second flexible substrate 200 can be with rapid aggregation
Heat accelerates the discoloration of the heat-sensitive variable colour component 230.
In addition, flexible temperature-sensitive color-changing composite material 10 further includes multiple flexible thermally conductive sheets 210, multiple flexibility thermally conductive sheets 210
It is arranged at intervals in first flexible substrate 100 and the second flexible substrate 200, one end and one of each flexibility thermally conductive sheet 210
A first air bag 120 connects, and the other end of flexible thermally conductive sheet 210 is connect with second air bag 220, the flexible thermally conductive sheet
210 for giving the heat transfer of first air bag 120 to the second air bag 220, and the second air bag 220 can be quickly swollen after heat absorption
It is swollen, so as to increase thermal resistance, reduce the loss of 200 heat of the second flexible substrate, also, the flexible thermally conductive sheet 210 can be with
With certain heat dissipation area.Heat can be quickly conducted to second flexible substrate by the flexible thermally conductive sheet 210
So that heat-sensitive variable colour component 230 changes colour, the flexibility thermally conductive sheet 210 can be passed heat-sensitive variable colour component 230 in 200 by heat
Adhesive tape is led to be made.Wherein, the flexible thermally conductive sheet 210 can be added during the second flexible substrate 200 is cured, and with institute
State the integrated molding of the second flexible substrate 200.An embodiment wherein can be set point on the flexibility thermally conductive sheet 210
Branch thermally conductive sheet 211, branch's thermally conductive sheet 211 can be in 200 internal stretches of the second flexible substrate, to increase thermally conductive road
Diameter and heat-conducting area are to accelerate heat conduction rate.
Embodiment 3
As shown in Fig. 5 or 6, the present embodiment is roughly the same with embodiment 2, the difference is that the flexibility thermally conductive sheet
Heat conduction particle 223 is provided in second air bag 220 of 210 connections, the heat conduction particle 223 connects with the flexible thermally conductive sheet 210
It connects, second air bag 220 is provided with close to the side of 200 outer surface of the second flexible substrate for exposing described thermally conductive
First opening 221 of grain 223, second air bag 220 can be made of the rubber material with favorable elasticity, it will be understood that
Under room temperature, second air bag 220 can be wrapped tightly in the outer surface of the heat conduction particle 223.The heat conduction particle 223 can be by
Metal material is made, and can also be made of the good material of the heating conductions such as diamond.Heat can be thermally conductive by the flexibility
Piece 210 passes to the heat conduction particle 223 from first flexible substrate 100, and the heat conduction particle 223 can heat described
Gas in two air bags 220 is to make the expansion of the second air bag 220 become larger to increase thermal resistance.Second flexible substrate 200
It can have good elasticity, when the expansion of the second air bag 220 becomes larger, the convergent force of second flexible substrate 200 can
The aperture of first opening 221 is reduced, therefore first opening 221 influences the swelling volume of second air bag 220
Very little.Also, due to persistently thermally conductive, in second air bag 220 increase of air pressure and as first opening 221 caused by described in
The reduction of air pressure is able to maintain that balance in second air bag 220, and the volume of second air bag 220 is enabled to be maintained at expansion
State.Also, it when the flexible temperature-sensitive color-changing composite material 10 restores color, needs the flexible heat-sensitive variable colour composite wood
Material 10 is placed on low temperature environment, second air bag 220 at low temperature can contraction distortion be wrapped in the table of the heat conduction particle 223
Face, second air bag 220 while retraction volume.The heat conduction particle 223 can expose from first opening 221, thus
Convenient for the heat exchange of the heat conduction particle 223.It can be understood as the rate of heat dispation of the heat conduction particle 223 at low temperatures more
Fastly, therefore the speed of 10 cooling of flexible temperature-sensitive color-changing composite material can be accelerated, thus the flexible temperature-sensitive can be accelerated
The speed that color-changing composite material 10 changes colour.
As one of embodiment, surface of first flexible substrate 100 far from second flexible substrate 200
It is provided with the second opening 222 for discharging stress.After the flexibility temperature-sensitive color-changing composite material 10 is stretched, first gas
Capsule 120 is understood along the Direction distortion being stretched, therefore in the stress of first air bag 120 and the draw direction vertical direction
Can accordingly it become larger, second opening 222 can slow down first air bag 120 and answer with the draw direction vertical direction
Power, increases the space of 120 Free Transform of the first air bag, thus can increase the flexible temperature-sensitive color-changing composite material 10
Service life avoids excessive stress from damaging the flexible temperature-sensitive color-changing composite material 10.
Embodiment 4
As shown in fig. 7, the present embodiment is roughly the same with embodiment 1, the difference is that the heat-sensitive variable colour component 230
Dispersion is coated in multiple capsules 240, the multiple capsule 240 scattering device, glue in second flexible substrate 200
Capsule 240 wraps up the heat-sensitive variable colour component 230 and the density of the heat-sensitive variable colour component 230 is increased, thus macroscopically sees institute
It states flexible 10 metachromatism of temperature-sensitive color-changing composite material to become apparent, the capsule 240 can be by transparent silastic material system
At.
As one of connection embodiment between capsule 240, connected between the capsule 240 by heat conductive filament 250
It connects.When the flexible temperature-sensitive color-changing composite material 10 is whole to be needed to change colour, the heat conductive filament 250 can make the capsule
Heat between 240 is rapidly reached balance, therefore the degree meeting of the heat-sensitive variable colour component 230 discoloration in the capsule 240
It reaches unanimity, the non-uniform of color can be caused to avoid even due to flexible temperature-sensitive 10 uneven heatings of color-changing composite material
Phenomenon.
As shown in figure 8, it illustrates a kind of temperature-sensitive design producing apparatus 20, the temperature-sensitive design producing apparatus 20 include according to
The optical transmitting set 310 of sequence setting, template 320, refrigerating plant 340, the optical transmitting set 310 and the cooperation of template 320 will be will scheme
The illumination of case is on the surface of the flexible temperature-sensitive color-changing composite material 10, and the refrigerating plant 340 is to make the flexibility
Heat-sensitive variable colour composite material 10 restores color, the template 320 be set to the optical transmitting set 310 and the fixed frame 330 it
Between, the fixed frame 330 is for the flexible temperature-sensitive color-changing composite material 10, and the refrigerating plant 340 is to make
It states flexible temperature-sensitive color-changing composite material 10 and restores color, the light that the optical transmitting set 310 issues has certain energy, wherein
The optical transmitting set 310 can be laser emitter, infrared transmitter etc..
Flexible temperature-sensitive color-changing composite material 10 temperature after different positions absorbs energy increases discoloration, passes through the template
The section of 320 light can be different pattern, and the light of the different pattern is radiated at the flexible temperature-sensitive color-changing composite material
After on 10 surface, 10 surface of flexibility temperature-sensitive color-changing composite material can form pattern corresponding with the template 320,
The fixed frame 330 is used to after flexible temperature-sensitive color-changing composite material 10 is stretched flattening fix, and fixed frame 330 is to the flexible thermal
The stretching distance of quick color-changing composite material 10 is adjustable.Refrigerating plant 340 can be correspondingly arranged with fixed frame 330, when described
It, can be by the fixed frame 330 by the flexible thermal when pattern on flexible 10 surface of temperature-sensitive color-changing composite material needs to disappear
Quick color-changing composite material 10 is sent into the refrigerating plant 340, makes flexible temperature-sensitive color-changing composite material by the cooling of refrigerating plant 340
10 surface recovery colors, and pattern, Reusability can be changed again.
It should be noted that it can directly on the other element when element is referred to as " being fixed on " another element
Or there may also be elements placed in the middle.When an element is considered as " connection " another element, it, which can be, is directly connected to
To another element or it may be simultaneously present centering elements.On the contrary, when element is referred to as " directly existing " another element "upper",
There is no intermediary elements.Term as used herein "vertical", "horizontal", "left" and "right" and similar statement are
For illustrative purposes.
The embodiments described above only express several embodiments of the present invention, and the description thereof is more specific and detailed, but simultaneously
Limitations on the scope of the patent of the present invention therefore cannot be interpreted as.It should be pointed out that for those of ordinary skill in the art
For, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to guarantor of the invention
Protect range.Therefore, the scope of protection of the patent of the invention shall be subject to the appended claims.
Claims (9)
1. a kind of flexibility temperature-sensitive color-changing composite material, characterized in that it comprises:
First flexible substrate (100) is dispersed with multiple first absorbing grains (110) in first flexible substrate (100);
Second flexible substrate (200), second flexible substrate (200) are stacked with the first flexible substrate (100), and second
It is dispersed in flexible substrate (200) heat-sensitive variable colour component (230), the heat-sensitive variable colour component (230) is warming up to the first temperature
Shi Fasheng discoloration, restores color when being cooled to second temperature;
Multiple first air bags (120) are scattered in first flexible substrate (100), the multiple first air bag (120) interval
Setting;
Multiple second absorbing grains (121) are set in each first air bag (120);
When first flexible substrate (100) extends along direction elongation, the multiple first air bag (120) is close to each other simultaneously
Being deformed into flat makes the second absorbing grains (121) mutual extrusion form stratiform to reduce first flexible substrate (100)
Plane vertical direction glazed area.
2. flexibility temperature-sensitive color-changing composite material as described in claim 1, which is characterized in that the multiple first air bag (120)
It is interior to be filled with shading liquid (122).
3. flexibility temperature-sensitive color-changing composite material as described in claim 1, which is characterized in that it further includes multiple second air bags
(220), the multiple second air bag (220) is spaced apart from each other scattering device in second flexible substrate (200), the multiple
Second air bag (220) is configured close to the second flexible substrate (200) far from the surface of the first flexible substrate (100).
4. flexibility temperature-sensitive color-changing composite material as claimed in claim 3, which is characterized in that it further includes multiple flexible thermally conductive sheets
(210), the multiple flexible thermally conductive sheet (210) is arranged at intervals at first flexible substrate (100) and the second flexible substrate
(200) in, it is each flexibility thermally conductive sheet (210) one end connect with first air bag (120), flexible thermally conductive sheet (210) it is another
One end is connect with second air bag (220).
5. flexibility temperature-sensitive color-changing composite material as claimed in claim 4, which is characterized in that connect with flexible thermally conductive sheet (210)
The second air bag (220) in be provided with heat conduction particle (223);
The heat conduction particle (223) is connect with the flexible thermally conductive sheet (210);
Second air bag (220) is provided with described thermally conductive for exposing close to the side of the second flexible substrate (200) outer surface
First opening (221) of particle (223).
6. flexibility temperature-sensitive color-changing composite material as described in claim 1, which is characterized in that first flexible substrate (100)
Surface far from second flexible substrate (200) is provided with the second opening (222) for discharging stress.
7. flexibility temperature-sensitive color-changing composite material as described in claim 1, which is characterized in that it further includes multiple capsules (240),
Multiple capsules (240) are in the interior scattering device of second flexible substrate (200), the part heat-sensitive variable colour component
(230) dispersion is coated in multiple capsules (240).
8. flexibility temperature-sensitive color-changing composite material as claimed in claim 7, which is characterized in that pass through between the capsule (240)
Heat conductive filament (250) connection.
9. a kind of temperature-sensitive design producing apparatus, which is characterized in that it includes the optical transmitting set (310) being set in sequence, template
(320), refrigerating plant (340), the optical transmitting set (310) and the template (320) cooperation exist to the illumination that will be patterned into
Such as the surface of the described in any item flexible temperature-sensitive color-changing composite materials (10) of claim 1-8, the refrigerating plant (340) to
The flexible temperature-sensitive color-changing composite material (10) is set to restore color.
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CN111908953B (en) * | 2020-09-03 | 2024-04-26 | 苏州和昌电子材料有限公司 | Thermosensitive phase change protective film, preparation method thereof and laminated ceramic capacitor |
CN112397245B (en) * | 2020-09-29 | 2022-07-26 | 广东电网有限责任公司 | Cable filler thermochromism color development device capable of developing color faster |
CN112289662A (en) * | 2020-11-17 | 2021-01-29 | 安徽伊法拉电力科技有限公司 | Novel reversible thermosensitive ABB fuse early warning insulating sheath material and preparation method thereof |
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