CN107523991A - A kind of processing method of terylene weaving face fabric antistatic coating - Google Patents

A kind of processing method of terylene weaving face fabric antistatic coating Download PDF

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CN107523991A
CN107523991A CN201710855004.1A CN201710855004A CN107523991A CN 107523991 A CN107523991 A CN 107523991A CN 201710855004 A CN201710855004 A CN 201710855004A CN 107523991 A CN107523991 A CN 107523991A
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antistatic
polyester fabric
10min
antistatic treatment
fabric
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施金椽
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Anhui Jin School Textile And Clothing Co Ltd
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Anhui Jin School Textile And Clothing Co Ltd
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
    • D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic System; Titanates; Zirconates; Stannates; Plumbates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/285—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
    • D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/59—Polyamides; Polyimides
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    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters

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  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses a kind of processing method of terylene weaving face fabric antistatic coating, it is related to fabric final finishing technical field, the pretreatment of (1) polyester fabric, the preparation of (2) antistatic treatment liquid, (3) polyester fabric pads, (4) high temperature set.Antistatic coating processing method of the present invention acts on after polyester fabric the antistatic property that can significantly improve polyester fabric, its surface specific resistance is less than 107Ω/m2；And the polyester fabric after collated has preferable antistatic behaviour stabilizability, stronger antistatic property is still kept after washing 50 times；It is simultaneously safe to use, any adverse effect will not be caused to human body after long-term use of, avoids using murder by poisoning problem existing for conventional chemical class antistatic additive.

Description

A kind of processing method of terylene weaving face fabric antistatic coating
Technical field：
The present invention relates to fabric final finishing technical field, and in particular to a kind of processing of terylene weaving face fabric antistatic coating Method.
Background technology：
Terylene, nickname polyester fiber.Polyester fabric, it is that a kind of quite varied chemical fiber garment face is applied in daily life Material, with intensity height, elasticity is good, heat-resist, thermoplasticity is good, wearability is good, light resistance is good, corrosion resistant advantage, therefore suitable The outdoor goods such as coat garment, all kinds of case and bag and tent are done in conjunction.But there is also dyeability is poor, hygroscopicity is poor, easy band for polyester fabric The problem of the defects of electrostatic, especially easy static electrification, brings very big puzzlement to user.
The defects of polyester fabric can be improved by chemical fibre emulation technology, improve its quality.When synthetic fiber modification technology, i.e., Some monomers for being advantageous to improve its performance are added in polyester fiber building-up process, make fiber bulk modified, but this technology is grasped Make that difficulty is big, cost is high, effect is undesirable, less use.Second, the final finishing technology of polyester fabric, i.e., carried out to polyester fabric The special process makes it have the performances such as hydrophilic, antistatic, easy decontamination, and the technology processing cost is low, simple for process and right The finishing effect of polyester fabric is preferable, is the main research and development direction of current improvement polyester fabric quality.
At present, domestic hydrophilic antistatic agent mainly has non-ionic antistatic agent CAS, non-ionic hydrophilic antistatic additive FS, quaternaries cation antistatic additive SN etc., product antistatic property is undesirable, antistatic property is unstable, washability is poor. Same kind of products at abroad mainly has antistatic additive EP, guarantor to wash easypro TM, and the antistatic effect of these antistatic additive is better than domestic antistatic Agent, but it is expensive, and chemical preparation process is complicated, and final finishing power consumption of polymer processing is big.
The content of the invention：
The technical problems to be solved by the invention are to provide a kind of simple for process, antistatic property by force and stability The processing method of terylene weaving face fabric antistatic coating good, washability is strong.
The technical problems to be solved by the invention are realized using following technical scheme：
A kind of processing method of terylene weaving face fabric antistatic coating, comprises the following steps：
(1) pretreatment of polyester fabric：Polyester fabric is immersed in the 5-10wt% sodium bicarbonate aqueous solution, and in 45-50 Heat-insulation soaking 10-15min at DEG C, then washed with clear water and remove sodium bicarbonate, clean after being dried to constant weight in 55-60 DEG C of baking oven；
(2) preparation of antistatic treatment liquid：First clear water is added in Agitation Tank, and under mixing speed 300-400r/min Antistatic treatment agent is added portionwise, is gone to after adding under 700-800r/min and stirs 10-15min, and is heated to reflux state guarantor Temperature stirring 5-10min, produces antistatic treatment liquid；
(3) polyester fabric pads：The antistatic treatment liquid pump prepared is entered in immersion liquid groove, the temperature of antistatic treatment liquid Degree maintains 50-55 DEG C, and roll mode using two leachings two pads to polyester fabric, and each soak time 5-10min, padding machine turns Fast 2-3m/min, pressure 0.25-0.3MPa, pick-up 70-80%；
(4) high temperature set：Polyester fabric after padding is placed in 120-125 DEG C of baking oven high temperature set 3-5min, finally Constant weight is dried in 60-65 DEG C of baking oven.
Antistatic treatment agent, the weight ratio of clear water are 1 in the step (2):15-30.
The one kind of antistatic treatment agent in antistatic agent C AS, antistatic additive SN in the step (2).
Antistatic treatment agent is made up of the raw material of following parts by weight in the step (2)：PLURONICS F87 10-15 parts, Nanometer rubber powder 5-10 parts, ceramic 1-5 parts, PAMA 1-5 parts, polyvinyl alcohol 2170.5-2 parts, cocounut oil acyl Base sodium glutamate 0.5-2 parts, sodium gluconate 0.1-1 parts, HPMA 0.05-0.5 parts；Its preparation method is included such as Lower step：
(1) sodium cocoyl glutamate and HPMA are added into polyvinyl alcohol 217, and is heated to 110- 120 DEG C of insulation mixing 10-15min, add sodium gluconate, are well mixed, produce auxiliary agent；
(2) ceramic and auxiliary agent are added into nanometer rubber powder, and is heated to 115-125 DEG C of insulation mixing 5-10min, then PLURONICS F87 and PAMA are added, continues, in 115-125 DEG C of insulation mixing 10-15min, to produce antistatic Inorganic agent.
The molecular weight of the PAMA is in 800-1000 ten thousand.
The nanometer rubber powder is made up of nano titanium oxide, poly-aspartic-acid and cetanol, and its specific preparation method is： Absolute ethyl alcohol is added dropwise until be completely dissolved into cetanol under stirring, at the same into poly-aspartic-acid deionized water is added dropwise until It is completely dissolved, then the ethanol solution and the 95wt% concentrated sulfuric acids of cetanol is added into poly-aspartic aqueous acid, is sufficiently mixed Microwave treater microwave irradiation reflow treatment 10min is utilized afterwards, continues microwave irradiation reflow treatment 10min after being spaced 5min, The microwave irradiation reflow treatment 10min again after 5min, so makes microwave irradiation reflow treatment total time reach 40- repeatedly 60min, nano titanium oxide and tri (propylene glycol) diacrylate are then added, microwave irradiation reflow treatment after being well mixed 10min, microwave irradiation reflow treatment 10min again is spaced after 10min, gained mixture is sent into spray dryer, dries institute Obtain the ground machine of particle and powder is made, produce a nanometer rubber powder.
The molecular weight of the poly-aspartic-acid is in 3000-4000.
The cetanol, poly-aspartic-acid, the concentrated sulfuric acid, nano titanium oxide, tri (propylene glycol) diacrylate Weight ratio is 5-10:10-15:0.05-0.5:10-20:0.5-3.
Esterification generation macromolecule ester compound occurs first with cetanol and poly-aspartic-acid when prepared by nanometer rubber powder, Make nano titanium oxide uniformly penetrating under the crosslinked action of tri (propylene glycol) diacrylate again into macromolecule ester compound And solidify, obtained nanometer rubber powder has stronger antistatic property relative to nano titanium oxide, and antistatic property is steady It is qualitative good.
The beneficial effects of the invention are as follows：
(1) first polyester fabric is pre-processed with the 5-10wt% sodium bicarbonate aqueous solution, avoided using highly basic processing terylene Existing for fabric the problem of heavy damage fibre structure；And sodium bicarbonate aqueous solution environmental pollution is small, through repeatedly pretreatment Liquid waste processing difficulty afterwards is small；In addition the sodium bicarbonate aqueous solution can also play what is cleaned and sterilize while polyester fabric is pre-processed Effect；
(2) using PLURONICS F87 as major ingredient, assist and antistatic treatment is made to make nanometer rubber powder and a variety of auxiliary agents by oneself Agent, the antistatic treatment agent are applied to the final finishing of polyester fabric, terylene face can be significantly improved after being acted on polyester fabric The antistatic property of material, its surface specific resistance is set to be less than 107Ω/m2；And the polyester fabric after collated has preferably anti-quiet Electric performance stablity, stronger antistatic property is still kept after washing 50 times；It is simultaneously safe to use, will not after long-term use of Any adverse effect is caused to human body, avoids using murder by poisoning problem existing for conventional chemical class antistatic additive.
Embodiment：
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below Specific embodiment is closed, the present invention is expanded on further.
Embodiment 1
(1) pretreatment of polyester fabric：Polyester fabric is immersed in the 5wt% sodium bicarbonate aqueous solution, and at 45-50 DEG C Heat-insulation soaking 15min, then washed with clear water and remove sodium bicarbonate, clean after being dried to constant weight in 55-60 DEG C of baking oven；
(2) preparation of antistatic treatment liquid：First clear water is added in Agitation Tank, and under mixing speed 300-400r/min Antistatic agent C AS is added portionwise, is gone to after adding under 700-800r/min and stirs 10min, and is heated to reflux state insulation and stirs 10min is mixed, produces antistatic treatment liquid；Wherein, clear water 25kg is used per 1kg antistatic treatment agents；
(3) polyester fabric pads：The antistatic treatment liquid pump prepared is entered in immersion liquid groove, the temperature of antistatic treatment liquid Degree maintains 50-55 DEG C, and roll mode using two leachings two pads to polyester fabric, each soak time 10min, padding machine rotating speed 2-3m/min, pressure 0.25-0.3MPa, pick-up 70-80%；
(4) high temperature set：Polyester fabric after padding is placed in 120-125 DEG C of baking oven high temperature set 5min, most after Constant weight is dried in 60-65 DEG C of baking oven.
Embodiment 2
(1) pretreatment of polyester fabric：Polyester fabric is immersed in the 5wt% sodium bicarbonate aqueous solution, and at 45-50 DEG C Heat-insulation soaking 15min, then washed with clear water and remove sodium bicarbonate, clean after being dried to constant weight in 55-60 DEG C of baking oven；
(2) preparation of antistatic treatment liquid：First clear water is added in Agitation Tank, and under mixing speed 300-400r/min Antistatic additive SN is added portionwise, is gone to after adding under 700-800r/min and stirs 10min, and is heated to reflux state insulated and stirred 10min, produce antistatic treatment liquid；Wherein, clear water 25kg is used per 1kg antistatic treatment agents；
(3) polyester fabric pads：The antistatic treatment liquid pump prepared is entered in immersion liquid groove, the temperature of antistatic treatment liquid Degree maintains 50-55 DEG C, and roll mode using two leachings two pads to polyester fabric, each soak time 10min, padding machine rotating speed 2-3m/min, pressure 0.25-0.3MPa, pick-up 70-80%；
(4) high temperature set：Polyester fabric after padding is placed in 120-125 DEG C of baking oven high temperature set 5min, most after Constant weight is dried in 60-65 DEG C of baking oven.
Embodiment 3
(1) pretreatment of polyester fabric：Polyester fabric is immersed in the 5wt% sodium bicarbonate aqueous solution, and at 45-50 DEG C Heat-insulation soaking 15min, then washed with clear water and remove sodium bicarbonate, clean after being dried to constant weight in 55-60 DEG C of baking oven；
(2) preparation of antistatic treatment liquid：First clear water is added in Agitation Tank, and under mixing speed 300-400r/min Antistatic treatment agent is added portionwise, is gone to after adding under 700-800r/min and stirs 10min, and is heated to reflux state insulation and stirs 10min is mixed, produces antistatic treatment liquid；Wherein, clear water 25kg is used per 1kg antistatic treatment agents；
(3) polyester fabric pads：The antistatic treatment liquid pump prepared is entered in immersion liquid groove, the temperature of antistatic treatment liquid Degree maintains 50-55 DEG C, and roll mode using two leachings two pads to polyester fabric, each soak time 10min, padding machine rotating speed 2-3m/min, pressure 0.25-0.3MPa, pick-up 70-80%；
(4) high temperature set：Polyester fabric after padding is placed in 120-125 DEG C of baking oven high temperature set 5min, most after Constant weight is dried in 60-65 DEG C of baking oven.
The preparation of antistatic treatment agent：
(1) 0.5g sodium cocoyl glutamates and 0.05g HPMAs are added into 2g polyvinyl alcohol 217, and 110-120 DEG C of insulation mixing 10min is heated to, 0.3g sodium gluconates is added, is well mixed, produces auxiliary agent；
(2) 3g ceramics and auxiliary agent are added into 10g nanometer rubber powders, and is heated to 115-125 DEG C of insulation mixing 5min, 15g PLURONICS F87s and 3g PAMAs are added, continues, in 115-125 DEG C of insulation mixing 15min, to produce anti- Electrostatic Treatment agent.
Wherein, the molecular weight of PAMA is in 800-1000 ten thousand.
The preparation of nanometer rubber powder：Absolute ethyl alcohol is added dropwise until be completely dissolved into 10g cetanols under stirring, while to 15g Deionized water is added dropwise until being completely dissolved in poly-aspartic-acid, then the second of cetanol is added into poly-aspartic aqueous acid Alcoholic solution and the 0.05g 95wt% concentrated sulfuric acids, microwave treater microwave irradiation reflow treatment 10min is utilized after being sufficiently mixed, be spaced Continue microwave irradiation reflow treatment 10min after 5min, be spaced after 5min microwave irradiation reflow treatment 10min again, so repeatedly Microwave irradiation reflow treatment total time is reached 40min, then add 20g nano titanium oxides and 1g tripropylene glycol dipropyls Olefin(e) acid ester, microwave irradiation reflow treatment 10min after being well mixed, microwave irradiation reflow treatment 10min again is spaced after 10min, Gained mixture is sent into spray dryer, dries the gained ground machine of particle and powder is made, produce a nanometer rubber powder.Wherein, gather The molecular weight of asparatate is in 3000-4000.
Embodiment 4
(1) pretreatment of polyester fabric：Polyester fabric is immersed in the 5wt% sodium bicarbonate aqueous solution, and at 45-50 DEG C Heat-insulation soaking 15min, then washed with clear water and remove sodium bicarbonate, clean after being dried to constant weight in 55-60 DEG C of baking oven；
(2) preparation of antistatic treatment liquid：First clear water is added in Agitation Tank, and under mixing speed 300-400r/min Antistatic treatment agent is added portionwise, is gone to after adding under 700-800r/min and stirs 10min, and is heated to reflux state insulation and stirs 10min is mixed, produces antistatic treatment liquid；Wherein, clear water 25kg is used per 1kg antistatic treatment agents；
(3) polyester fabric pads：The antistatic treatment liquid pump prepared is entered in immersion liquid groove, the temperature of antistatic treatment liquid Degree maintains 50-55 DEG C, and roll mode using two leachings two pads to polyester fabric, each soak time 10min, padding machine rotating speed 2-3m/min, pressure 0.25-0.3MPa, pick-up 70-80%；
(4) high temperature set：Polyester fabric after padding is placed in 120-125 DEG C of baking oven high temperature set 5min, most after Constant weight is dried in 60-65 DEG C of baking oven.
The preparation of antistatic treatment agent：
(1) 1g sodium cocoyl glutamates and 0.1g HPMAs are added into 2g polyvinyl alcohol 217, and is heated To 110-120 DEG C of insulation mixing 15min, 0.5g sodium gluconates are added, is well mixed, produces auxiliary agent；
(2) 5g ceramics and auxiliary agent are added into 10g nanometer rubber powders, and is heated to 115-125 DEG C of insulation mixing 5min, 15g PLURONICS F87s and 5g PAMAs are added, continues, in 115-125 DEG C of insulation mixing 10min, to produce anti- Electrostatic Treatment agent.
Wherein, the molecular weight of PAMA is in 800-1000 ten thousand.
The preparation of nanometer rubber powder：Absolute ethyl alcohol is added dropwise until being completely dissolved into 5g cetanols under stirring, while gathers to 10g Deionized water is added dropwise until being completely dissolved in asparatate, then the ethanol of cetanol is added into poly-aspartic aqueous acid Solution and the 0.05g 95wt% concentrated sulfuric acids, microwave treater microwave irradiation reflow treatment 10min is utilized after being sufficiently mixed, be spaced Continue microwave irradiation reflow treatment 10min after 5min, be spaced after 5min microwave irradiation reflow treatment 10min again, so repeatedly Microwave irradiation reflow treatment total time is reached 40min, then add 15g nano titanium oxides and 0.5g tripropylene glycols two Acrylate, microwave irradiation reflow treatment 10min after being well mixed, microwave irradiation reflow treatment again is spaced after 10min 10min, gained mixture are sent into spray dryer, dry the gained ground machine of particle and powder is made, produce a nanometer rubber powder.Its In, the molecular weight of poly-aspartic-acid is in 3000-4000.
Reference examples 1
(1) pretreatment of polyester fabric：Polyester fabric is immersed in the 5wt% sodium bicarbonate aqueous solution, and at 45-50 DEG C Heat-insulation soaking 15min, then washed with clear water and remove sodium bicarbonate, clean after being dried to constant weight in 55-60 DEG C of baking oven；
(2) preparation of antistatic treatment liquid：First clear water is added in Agitation Tank, and under mixing speed 300-400r/min Antistatic treatment agent is added portionwise, is gone to after adding under 700-800r/min and stirs 10min, and is heated to reflux state insulation and stirs 10min is mixed, produces antistatic treatment liquid；Wherein, clear water 25kg is used per 1kg antistatic treatment agents；
(3) polyester fabric pads：The antistatic treatment liquid pump prepared is entered in immersion liquid groove, the temperature of antistatic treatment liquid Degree maintains 50-55 DEG C, and roll mode using two leachings two pads to polyester fabric, each soak time 10min, padding machine rotating speed 2-3m/min, pressure 0.25-0.3MPa, pick-up 70-80%；
(4) high temperature set：Polyester fabric after padding is placed in 120-125 DEG C of baking oven high temperature set 5min, most after Constant weight is dried in 60-65 DEG C of baking oven.
The preparation of antistatic treatment agent：
(1) 1g sodium cocoyl glutamates and 0.1g HPMAs are added into 2g polyvinyl alcohol 217, and is heated To 110-120 DEG C of insulation mixing 15min, 0.5g sodium gluconates are added, is well mixed, produces auxiliary agent；
(2) 5g ceramics and auxiliary agent are added into 10g nanometer rubber powders, and is heated to 115-125 DEG C of insulation mixing 5min, 15g PLURONICS F87s and 5g PAMAs are added, continues, in 115-125 DEG C of insulation mixing 10min, to produce anti- Electrostatic Treatment agent.
Wherein, the molecular weight of PAMA is in 800-1000 ten thousand.
The preparation of nanometer rubber powder：Absolute ethyl alcohol is added dropwise until being completely dissolved into 5g cetanols under stirring, while gathers to 10g Deionized water is added dropwise until being completely dissolved in asparatate, then the ethanol of cetanol is added into poly-aspartic aqueous acid Solution and the 0.05g 95wt% concentrated sulfuric acids, microwave treater microwave irradiation reflow treatment 10min is utilized after being sufficiently mixed, be spaced Continue microwave irradiation reflow treatment 10min after 5min, be spaced after 5min microwave irradiation reflow treatment 10min again, so repeatedly Microwave irradiation reflow treatment total time is reached 40min, then add 15g nano titanium oxides, microwave irradiation after being well mixed Reflow treatment 10min, is spaced after 10min microwave irradiation reflow treatment 10min again, and gained mixture is sent into spray dryer In, dry the gained ground machine of particle and powder is made, produce a nanometer rubber powder.Wherein, the molecular weight of poly-aspartic-acid is in 3000- 4000。
Reference examples 2
(1) pretreatment of polyester fabric：Polyester fabric is immersed in the 5wt% sodium bicarbonate aqueous solution, and at 45-50 DEG C Heat-insulation soaking 15min, then washed with clear water and remove sodium bicarbonate, clean after being dried to constant weight in 55-60 DEG C of baking oven；
(2) preparation of antistatic treatment liquid：First clear water is added in Agitation Tank, and under mixing speed 300-400r/min Antistatic treatment agent is added portionwise, is gone to after adding under 700-800r/min and stirs 10min, and is heated to reflux state insulation and stirs 10min is mixed, produces antistatic treatment liquid；Wherein, clear water 25kg is used per 1kg antistatic treatment agents；
(3) polyester fabric pads：The antistatic treatment liquid pump prepared is entered in immersion liquid groove, the temperature of antistatic treatment liquid Degree maintains 50-55 DEG C, and roll mode using two leachings two pads to polyester fabric, each soak time 10min, padding machine rotating speed 2-3m/min, pressure 0.25-0.3MPa, pick-up 70-80%；
(4) high temperature set：Polyester fabric after padding is placed in 120-125 DEG C of baking oven high temperature set 5min, most after Constant weight is dried in 60-65 DEG C of baking oven.
The preparation of antistatic treatment agent：
5g ceramics are added into 10g nanometer rubber powders, and are heated to 115-125 DEG C of insulation mixing 5min, add 15g PLURONICS F87 and 5g PAMAs, continue, in 115-125 DEG C of insulation mixing 10min, to produce antistatic treatment Agent.
Wherein, the molecular weight of PAMA is in 800-1000 ten thousand.
The preparation of nanometer rubber powder：Absolute ethyl alcohol is added dropwise until being completely dissolved into 5g cetanols under stirring, while gathers to 10g Deionized water is added dropwise until being completely dissolved in asparatate, then the ethanol of cetanol is added into poly-aspartic aqueous acid Solution and the 0.05g 95wt% concentrated sulfuric acids, microwave treater microwave irradiation reflow treatment 10min is utilized after being sufficiently mixed, be spaced Continue microwave irradiation reflow treatment 10min after 5min, be spaced after 5min microwave irradiation reflow treatment 10min again, so repeatedly Microwave irradiation reflow treatment total time is reached 40min, then add 15g nano titanium oxides and 0.5g tripropylene glycols two Acrylate, microwave irradiation reflow treatment 10min after being well mixed, microwave irradiation reflow treatment again is spaced after 10min 10min, gained mixture are sent into spray dryer, dry the gained ground machine of particle and powder is made, produce a nanometer rubber powder.Its In, the molecular weight of poly-aspartic-acid is in 3000-4000.
Embodiment 5
Processing method described in embodiment 1-4, reference examples 1-2 is utilized respectively to carry out the equivalent polyester fabric with batch same specification Antistatic coating is processed, and determines the antistatic property of collated rear polyester fabric, as a result as shown in table 1, and is set without anti- The blank control example 3 of Electrostatic Treatment.
The antistatic property of polyester fabric of the table 1 after antistatic treatment agent is handled
Group Initial surface ratio resistance Ω/m2 Wash 50 subsurface ratio resistance Ω/m2
Embodiment 1 5.6×107 9.7×107
Embodiment 2 7.3×107 1.5×108
Embodiment 3 9.8×106 2.1×107
Embodiment 4 9.6×106 1.7×107
Reference examples 1 5.1×106 8.5×106
Reference examples 2 1.8×107 3.4×107
Reference examples 3 5.4×1012 7.7×1012
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (3)

  1. A kind of 1. processing method of terylene weaving face fabric antistatic coating, it is characterised in that：Comprise the following steps：
    (1) pretreatment of polyester fabric：Polyester fabric is immersed in the 5-10wt% sodium bicarbonate aqueous solution, and at 45-50 DEG C Heat-insulation soaking 10-15min, then washed with clear water and remove sodium bicarbonate, clean after being dried to constant weight in 55-60 DEG C of baking oven；
    (2) preparation of antistatic treatment liquid：First clear water is added in Agitation Tank, and under mixing speed 300-400r/min in batches Antistatic treatment agent is added, is gone to after adding under 700-800r/min and stirs 10-15min, and is heated to reflux state insulation and stirs 5-10min is mixed, produces antistatic treatment liquid；
    (3) polyester fabric pads：The antistatic treatment liquid pump prepared is entered in immersion liquid groove, the temperature dimension of antistatic treatment liquid Hold at 50-55 DEG C, roll mode using two leachings two pads to polyester fabric, each soak time 5-10min, padding machine rotating speed 2- 3m/min, pressure 0.25-0.3MPa, pick-up 70-80%；
    (4) high temperature set：Polyester fabric after padding is placed in 120-125 DEG C of baking oven high temperature set 3-5min, most after 60- Constant weight is dried in 65 DEG C of baking ovens.
  2. 2. the processing method of terylene weaving face fabric antistatic coating according to claim 1, it is characterised in that：The step (2) antistatic treatment agent, the weight ratio of clear water are 1 in:15-30.
  3. 3. the processing method of terylene weaving face fabric antistatic coating according to claim 1, it is characterised in that：The step (2) one kind of antistatic treatment agent in antistatic agent C AS, antistatic additive SN in.
CN201710855004.1A 2017-09-20 2017-09-20 A kind of processing method of terylene weaving face fabric antistatic coating Withdrawn CN107523991A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108753099A (en) * 2018-04-30 2018-11-06 安徽恒益纺织科技有限公司 A kind of anti-ultraviolet paint for textile fabric

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102561041A (en) * 2011-12-19 2012-07-11 天津工业大学 Method for improving comfort of polyester fabric by finishing with polyaspartic acid
CN104195775A (en) * 2014-09-05 2014-12-10 吴怡 Antistatic finishing method for polyester fiber shell fabric
CN104593889A (en) * 2014-12-23 2015-05-06 青岛无为保温材料有限公司 Antistatic fabric
CN105970629A (en) * 2016-06-21 2016-09-28 江苏曜彰体育用品有限公司 After-finishing process for textile fabric with antistatic function
CN106480706A (en) * 2015-08-31 2017-03-08 南通市跃达针织服饰有限公司 A kind of postfinishing process of the weaving face fabric with anti-static function

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102561041A (en) * 2011-12-19 2012-07-11 天津工业大学 Method for improving comfort of polyester fabric by finishing with polyaspartic acid
CN104195775A (en) * 2014-09-05 2014-12-10 吴怡 Antistatic finishing method for polyester fiber shell fabric
CN104593889A (en) * 2014-12-23 2015-05-06 青岛无为保温材料有限公司 Antistatic fabric
CN106480706A (en) * 2015-08-31 2017-03-08 南通市跃达针织服饰有限公司 A kind of postfinishing process of the weaving face fabric with anti-static function
CN105970629A (en) * 2016-06-21 2016-09-28 江苏曜彰体育用品有限公司 After-finishing process for textile fabric with antistatic function

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
关志宇等编著: "《药物制剂辅料与包装材料》", 31 January 2017 *
刘建华等编著: "《材料成型工艺基础 第3版》", 28 February 2016 *
王少刚等编著: "《工程材料与成形技术基础 第2版》", 30 June 2016 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108753099A (en) * 2018-04-30 2018-11-06 安徽恒益纺织科技有限公司 A kind of anti-ultraviolet paint for textile fabric

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