CN107523096A - A kind of ceramics etching frosted color artistic decorative pigment - Google Patents
A kind of ceramics etching frosted color artistic decorative pigment Download PDFInfo
- Publication number
- CN107523096A CN107523096A CN201710703581.9A CN201710703581A CN107523096A CN 107523096 A CN107523096 A CN 107523096A CN 201710703581 A CN201710703581 A CN 201710703581A CN 107523096 A CN107523096 A CN 107523096A
- Authority
- CN
- China
- Prior art keywords
- parts
- pigment
- solution
- arabic gum
- slurry
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0009—Pigments for ceramics
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/006—Combinations of treatments provided for in groups C09C3/04 - C09C3/12
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/08—Treatment with low-molecular-weight non-polymer organic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/10—Treatment with macromolecular organic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
Abstract
The invention discloses a kind of ceramics etching frosted color artistic decorative pigment, the formula is made up of azurite, malachite green, cinnabar, realgar, mica, high territory, clam meal, phosphatidyl choline, Arabic gum, deionized water, powdered sodium carbonate, by a certain percentage mixing；Preparation method of the present invention comprises the following steps：It is 1 3um with ball mill grinding above-mentioned raw materials to particle diameter；Screening；Phosphatidyl choline is taken, Arabic gum, both are stirred；The deionized water added into the mixture of phosphatidyl choline and Arabic gum, is well mixed again；It is to be well mixed to add powdered sodium carbonate；Above-mentioned all the components are well mixed, produce ceramic decoration pigment；The pigment that the present invention is prepared is used in ceramics, has good coloring effect and stability, is mixed in decoration using the natural minerals pigment of different melting points by certain proportioning, and obtains the etched decoration effect of various different colours.
Description
Technical field
The present invention relates to ceramic decoration pigment technology field, is specially a kind of ceramics etching frosted color artistic decoration face
Material.
Background technology
Traditional etching effect is to pass through pre-treatment：Ceramic material product is put in laser platform and carries out laser treatment, control
Laser scribing speed and cutting speed processed, so that the colourity of ceramic material product surface after laser treatment, glossiness and thick
Rugosity meets design requirement；Laser-induced thermal etching：The pattern of ceramic material product surface is designed using computer programming, then using sharp
Light laser system scribing speed of laser during ceramic material product surface progress laser engraving, laser engraving is 0-
200mm/s, cutting speed 0-3mm/s, scribing depth are 0-0.6mm/ times, scribing width >=0.1mm, are controlled by computer
Pattern, so that caused by after ceramic material product surface forms the relief pattern of solid.
But current etch effect ceramic on the market only has metallochrome, due to the improvement of people's living standards, to color art
Property requirement more and more higher, to meet the needs of market is to multiple color etch effect, using the mixing of different minerals pigment, production
Raw etch effect.
The content of the invention
The present invention provides a kind of ceramics etching frosted color artistic decorative pigment, and the pigment being prepared is used in ceramics,
With good coloring effect and stability, mixed in decoration using the natural minerals pigment of different melting points by certain proportioning
Close, and obtain the etched decoration effect of various different colours, can effectively solve the problems, such as in above-mentioned background technology.
To achieve the above object, the present invention provides following technical scheme：A kind of ceramics etching frosted color artistic decoration face
Material, the formula is by azurite, malachite green, cinnabar, realgar, mica, high territory, clam meal, phosphatidyl choline, Arabic gum, deionization
Water, powdered sodium carbonate, mixing composition, the formula are made up of the raw material of following percentage by weight by a certain percentage：Azurite 10-15
Part, malachite green 10-15 parts, cinnabar 4-6 parts, realgar 8-10 parts, mica 5-15 parts, high territory 20-30 parts, clam meal 10-20 parts, phosphatide
Phatidylcholine 8-10 parts, Arabic gum 5-7 parts, deionized water 3-5 parts, powdered sodium carbonate 2-4 parts.
A kind of preparation method of the preparation method of ceramics etching frosted color artistic decorative pigment, comprises the following steps：
1）Feeding：Above-mentioned mineral pigment is taken, is 1-3um with ball mill grinding to particle diameter；Obtain mixed powder；Screening；It is standby；
2）Uniform stirring：Phosphatidyl choline 8-10 parts are taken, Arabic gum 5-7 parts, both are stirred；
3）Prepare mixture：The deionized water of 3-5 parts is added into the mixture of phosphatidyl choline and Arabic gum, is mixed again
Uniformly, mixture is obtained；It is 2-4 parts that powdered sodium carbonate is added into mixture, is well mixed；
4）Prepare pigment：Above-mentioned mineral pigment after grinding is taken, is added in mixture, above-mentioned all the components is well mixed,
Produce ceramic decoration pigment.
According to above-mentioned technical proposal, the kleit preparation method is：Kaolin mineral aggregate is isolated into clay, debris,
Then add 5-6 times of water and slurry is made, obtain the slurry of kaolin ore slurry first；By the obtained slurry of kaolin ore slurry first and insurance
Powder kaolin ore slurry in mass ratio:Sodium hydrosulfite=1:0.0008-0.0015 is well mixed, and then adds conditioning agent, adjusts its pH value
To 3-5, the slurry of kaolin ore slurry second is obtained；The obtained slurry of kaolin ore slurry second is placed in equipped with Solid-state Ion-exchange tree
In the ion exchange agitator of fat, stir -1 hour 0.5 hour, obtain the slurry of kaolin ore slurry the 3rd；The kaolin that will be obtained
The solid ion-exchange resin contained in the slurry of ore pulp the 3rd is separated, and obtains kaolin ore slurry fine fodder；The kaolinite that will be obtained
Native ore pulp fine fodder is washed, then spray-dried into microballoon, produces Kaolin pigments.
According to above-mentioned technical proposal, the Arabic gum is a kind of Arabic gum of modification, and its preparation method is：It is Arabic
It is prepared by sol solution：Arabic gum is placed on 60-80 DEG C of stirred in water bath until being completely dissolved, takes out and places to room temperature, use hydrogen-oxygen
Change the pH of sodium solution regulation solution, filter, filtrate be transferred in large beaker, the dosage of the sodium hydroxide solution is Arabic
The 3% of sol solution；The preparation of octenyl succinic acid anhydride solution：Octenyl succinic acid anhydride is well mixed with ethanol or isopropanol, made
It is standby to obtain octenyl succinic acid anhydride solution；Esterification：Filtered 38-63 DEG C of gumwater temperature is adjusted, by octene
Base succinic anhydride solution is slowly added into gumwater, reaction time 1-2.5h, is adjusted and reacted with sodium hydroxide solution
The pH of liquid, the dosage of sodium hydroxide are the 3% of octenyl succinic acid anhydride solution and gumwater total amount, pH is maintained at permanent
In fixed alkalescence；React and adjust reaction solution pH with hydrochloric acid solution after terminating, hydrochloric acid solution dosage is above-mentioned addition sodium hydroxide
The 3% of solution afterwards, react 1-2.5h；Dry：Then successively with second alcohol and water alternating washing reaction liquid, the octenyl that will be settled out
Butanedioic acid Arabic gum ester is put dries in an oven, finally crushes the product after drying, sieves, and collects；Or it will directly adjust
Good pH solution is spray-dried, you can obtains a kind of Arabic gum of chemical modification.
According to above-mentioned technical proposal, the deionized water is a kind of deionized water of the carbonating with specific electrical conductivity,
Its preparation method is：Deionized water is provided to contactor；Carbon dioxide is provided to contactor；Utilize at least one sensor
Measure the flow velocity of the deionized water and the temperature of the deionized water, wherein at least one sensor be placed on it is described
The exit of the entrance of contactor or the contactor；It is determined that to be supplied to the amount of the carbon dioxide of the contactor, make
Obtain the contactor connected by the supply with least one sensor and the carbon dioxide and produce specific conductance
The deionized water of the carbonating of rate, wherein the determination is based on measured flow velocity and temperature；Via with the carbon dioxide gas
The one or more flow restrictors and one or more valves that the supply of body and the contactor are in fluid communication are by determined amount
Carbon dioxide is supplied to the contactor；And the deionized water for making to have the carbonating of specific electrical conductivity is from the contactor
Outflow.
According to above-mentioned technical proposal, the step 1）The idiographic flow of middle screening is：Feeding, mixing powder raw material input high frequency
Sieve, dither separation mixed powder；The raw material tentatively sieved by high-frequency screen is conveyed into high-pressure pump；Raw material is sent into by high-pressure pump
Magnetic separator, and magnetic separation is carried out, fine powder is filtered out from raw material, and the feeding belt of next step is sent into, fine powder is sent into and wrapped by feeding belt
Installation carries out bag and turns to complete screening.
According to above-mentioned technical proposal, the step 4）The middle temperature for preparing pigment is 20 DEG C -30 DEG C.
Compared with prior art, beneficial effects of the present invention：The pigment that the present invention is prepared is used in ceramics, has good
Good coloring effect and stability, mixed, and obtained by certain proportioning using the natural minerals pigment of different melting points in decoration
To the etched decoration effect of various different colours.
Brief description of the drawings
Accompanying drawing is used for providing a further understanding of the present invention, and a part for constitution instruction, the reality with the present invention
Apply example to be used to explain the present invention together, be not construed as limiting the invention.
In the accompanying drawings：
Fig. 1 is the preparation flow figure of the present invention.
Embodiment
The preferred embodiments of the present invention are illustrated below in conjunction with accompanying drawing, it will be appreciated that described herein preferred real
Apply example to be merely to illustrate and explain the present invention, be not intended to limit the present invention.
Embodiment 1：As shown in figure 1, the present invention provides a kind of ceramics etching frosted color artistic decorative pigment, the formula
By azurite, malachite green, cinnabar, realgar, mica, high territory, clam meal, phosphatidyl choline, Arabic gum, deionized water, carbonic acid sodium powder
End, mixing composition, the formula are made up of the raw material of following percentage by weight by a certain percentage：10 parts of azurite, 10 parts of malachite green, Zhu
4 parts of sand, 8 parts of realgar, 5 parts of mica, 20 parts of high territory, 10 parts of clam meal, 8 parts of phosphatidyl choline, 5 parts of Arabic gum, deionized water 3
Part, 2 parts of powdered sodium carbonate.
A kind of preparation method of ceramics etching frosted color artistic decorative pigment, comprises the following steps：
1）Feeding：Above-mentioned mineral pigment is taken, is 1-3um with ball mill grinding to particle diameter；Obtain mixed powder；Screening；It is standby；
2）Uniform stirring：8 parts of phosphatidyl choline is taken, 5 parts of Arabic gum, both are stirred；
3）Prepare mixture：3 parts of deionized water is added into the mixture of phosphatidyl choline and Arabic gum, mixing is equal again
It is even, obtain mixture；It is 2 parts that powdered sodium carbonate is added into mixture, is well mixed；
4）Prepare pigment：Above-mentioned mineral pigment after grinding is taken, is added in mixture, above-mentioned all the components is well mixed,
Produce ceramic decoration pigment.
According to above-mentioned technical proposal, the kleit preparation method is：Kaolin mineral aggregate is isolated into clay, debris,
Then add 5-6 times of water and slurry is made, obtain the slurry of kaolin ore slurry first；By the obtained slurry of kaolin ore slurry first and insurance
Powder kaolin ore slurry in mass ratio:Sodium hydrosulfite=1:0.0008-0.0015 is well mixed, and then adds conditioning agent, adjusts its pH value
To 3-5, the slurry of kaolin ore slurry second is obtained；The obtained slurry of kaolin ore slurry second is placed in equipped with Solid-state Ion-exchange tree
In the ion exchange agitator of fat, stir -1 hour 0.5 hour, obtain the slurry of kaolin ore slurry the 3rd；The kaolin that will be obtained
The solid ion-exchange resin contained in the slurry of ore pulp the 3rd is separated, and obtains kaolin ore slurry fine fodder；The kaolinite that will be obtained
Native ore pulp fine fodder is washed, then spray-dried into microballoon, produces Kaolin pigments.
According to above-mentioned technical proposal, the Arabic gum is a kind of Arabic gum of modification, and its preparation method is：It is Arabic
It is prepared by sol solution：Arabic gum is placed on 60-80 DEG C of stirred in water bath until being completely dissolved, takes out and places to room temperature, use hydrogen-oxygen
Change the pH of sodium solution regulation solution, filter, filtrate be transferred in large beaker, the dosage of the sodium hydroxide solution is Arabic
The 3% of sol solution；The preparation of octenyl succinic acid anhydride solution：Octenyl succinic acid anhydride is well mixed with ethanol or isopropanol, made
It is standby to obtain octenyl succinic acid anhydride solution；Esterification：Filtered 38-63 DEG C of gumwater temperature is adjusted, by octene
Base succinic anhydride solution is slowly added into gumwater, reaction time 1-2.5h, is adjusted and reacted with sodium hydroxide solution
The pH of liquid, the dosage of sodium hydroxide are the 3% of octenyl succinic acid anhydride solution and gumwater total amount, pH is maintained at permanent
In fixed alkalescence；React and adjust reaction solution pH with hydrochloric acid solution after terminating, hydrochloric acid solution dosage is above-mentioned addition sodium hydroxide
The 3% of solution afterwards, react 1-2.5h；Dry：Then successively with second alcohol and water alternating washing reaction liquid, the octenyl that will be settled out
Butanedioic acid Arabic gum ester is put dries in an oven, finally crushes the product after drying, sieves, and collects；Or it will directly adjust
Good pH solution is spray-dried, you can obtains a kind of Arabic gum of chemical modification.
According to above-mentioned technical proposal, the deionized water is a kind of deionized water of the carbonating with specific electrical conductivity,
Its preparation method is：Deionized water is provided to contactor；Carbon dioxide is provided to contactor；Utilize at least one sensor
Measure the flow velocity of the deionized water and the temperature of the deionized water, wherein at least one sensor be placed on it is described
The exit of the entrance of contactor or the contactor；It is determined that to be supplied to the amount of the carbon dioxide of the contactor, make
Obtain the contactor connected by the supply with least one sensor and the carbon dioxide and produce specific conductance
The deionized water of the carbonating of rate, wherein the determination is based on measured flow velocity and temperature；Via with the carbon dioxide gas
The one or more flow restrictors and one or more valves that the supply of body and the contactor are in fluid communication are by determined amount
Carbon dioxide is supplied to the contactor；And the deionized water for making to have the carbonating of specific electrical conductivity is from the contactor
Outflow.
According to above-mentioned technical proposal, the step 1）The idiographic flow of middle screening is：Feeding, mixing powder raw material input high frequency
Sieve, dither separation mixed powder；The raw material tentatively sieved by high-frequency screen is conveyed into high-pressure pump；Raw material is sent into by high-pressure pump
Magnetic separator, and magnetic separation is carried out, fine powder is filtered out from raw material, and the feeding belt of next step is sent into, fine powder is sent into and wrapped by feeding belt
Installation carries out bag and turns to complete screening.
According to above-mentioned technical proposal, the step 4）The middle temperature for preparing pigment is 20 DEG C -30 DEG C.
Embodiment 2：As shown in figure 1, the present invention provides a kind of ceramics etching frosted color artistic decorative pigment, the formula
By azurite, malachite green, cinnabar, realgar, mica, high territory, clam meal, phosphatidyl choline, Arabic gum, deionized water, carbonic acid sodium powder
End, mixing composition, the formula are made up of the raw material of following percentage by weight by a certain percentage：15 parts of azurite, 15 parts of malachite green, Zhu
6 parts of sand, 10 parts of realgar, 15 parts of mica, 30 parts of high territory, 20 parts of clam meal, 10 parts of phosphatidyl choline, 7 parts of Arabic gum, deionization
5 parts of water, 4 parts of powdered sodium carbonate.
A kind of preparation method of ceramics etching frosted color artistic decorative pigment, comprises the following steps：
1）Feeding：Above-mentioned mineral pigment is taken, is 1-3um with ball mill grinding to particle diameter；Obtain mixed powder；Screening；It is standby；
2）Uniform stirring：10 parts of phosphatidyl choline is taken, 7 parts of Arabic gum, both are stirred；
3）Prepare mixture：5 parts of deionized water is added into the mixture of phosphatidyl choline and Arabic gum, mixing is equal again
It is even, obtain mixture；It is 4 parts that powdered sodium carbonate is added into mixture, is well mixed；
4）Prepare pigment：Above-mentioned mineral pigment after grinding is taken, is added in mixture, above-mentioned all the components is well mixed,
Produce ceramic decoration pigment.
According to above-mentioned technical proposal, the kleit preparation method is：Kaolin mineral aggregate is isolated into clay, debris,
Then add 5-6 times of water and slurry is made, obtain the slurry of kaolin ore slurry first；By the obtained slurry of kaolin ore slurry first and insurance
Powder kaolin ore slurry in mass ratio:Sodium hydrosulfite=1:0.0008-0.0015 is well mixed, and then adds conditioning agent, adjusts its pH value
To 3-5, the slurry of kaolin ore slurry second is obtained；The obtained slurry of kaolin ore slurry second is placed in equipped with Solid-state Ion-exchange tree
In the ion exchange agitator of fat, stir -1 hour 0.5 hour, obtain the slurry of kaolin ore slurry the 3rd；The kaolin that will be obtained
The solid ion-exchange resin contained in the slurry of ore pulp the 3rd is separated, and obtains kaolin ore slurry fine fodder；The kaolinite that will be obtained
Native ore pulp fine fodder is washed, then spray-dried into microballoon, produces Kaolin pigments.
According to above-mentioned technical proposal, the Arabic gum is a kind of Arabic gum of modification, and its preparation method is：It is Arabic
It is prepared by sol solution：Arabic gum is placed on 60-80 DEG C of stirred in water bath until being completely dissolved, takes out and places to room temperature, use hydrogen-oxygen
Change the pH of sodium solution regulation solution, filter, filtrate be transferred in large beaker, the dosage of the sodium hydroxide solution is Arabic
The 3% of sol solution；The preparation of octenyl succinic acid anhydride solution：Octenyl succinic acid anhydride is well mixed with ethanol or isopropanol, made
It is standby to obtain octenyl succinic acid anhydride solution；Esterification：Filtered 38-63 DEG C of gumwater temperature is adjusted, by octene
Base succinic anhydride solution is slowly added into gumwater, reaction time 1-2.5h, is adjusted and reacted with sodium hydroxide solution
The pH of liquid, the dosage of sodium hydroxide are the 3% of octenyl succinic acid anhydride solution and gumwater total amount, pH is maintained at permanent
In fixed alkalescence；React and adjust reaction solution pH with hydrochloric acid solution after terminating, hydrochloric acid solution dosage is above-mentioned addition sodium hydroxide
The 3% of solution afterwards, react 1-2.5h；Dry：Then successively with second alcohol and water alternating washing reaction liquid, the octenyl that will be settled out
Butanedioic acid Arabic gum ester is put dries in an oven, finally crushes the product after drying, sieves, and collects；Or it will directly adjust
Good pH solution is spray-dried, you can obtains a kind of Arabic gum of chemical modification.
According to above-mentioned technical proposal, the deionized water is a kind of deionized water of the carbonating with specific electrical conductivity,
Its preparation method is：Deionized water is provided to contactor；Carbon dioxide is provided to contactor；Utilize at least one sensor
Measure the flow velocity of the deionized water and the temperature of the deionized water, wherein at least one sensor be placed on it is described
The exit of the entrance of contactor or the contactor；It is determined that to be supplied to the amount of the carbon dioxide of the contactor, make
Obtain the contactor connected by the supply with least one sensor and the carbon dioxide and produce specific conductance
The deionized water of the carbonating of rate, wherein the determination is based on measured flow velocity and temperature；Via with the carbon dioxide gas
The one or more flow restrictors and one or more valves that the supply of body and the contactor are in fluid communication are by determined amount
Carbon dioxide is supplied to the contactor；And the deionized water for making to have the carbonating of specific electrical conductivity is from the contactor
Outflow.
According to above-mentioned technical proposal, the step 1）The idiographic flow of middle screening is：Feeding, mixing powder raw material input high frequency
Sieve, dither separation mixed powder；The raw material tentatively sieved by high-frequency screen is conveyed into high-pressure pump；Raw material is sent into by high-pressure pump
Magnetic separator, and magnetic separation is carried out, fine powder is filtered out from raw material, and the feeding belt of next step is sent into, fine powder is sent into and wrapped by feeding belt
Installation carries out bag and turns to complete screening.
According to above-mentioned technical proposal, the step 4）The middle temperature for preparing pigment is 20 DEG C -30 DEG C.
Based on above-mentioned, it is an advantage of the current invention that the pigment being prepared is used in ceramics, there is good coloring effect
And stability, mixed in decoration using the natural minerals pigment of different melting points by certain proportioning, and obtain various different face
The etched decoration effect of color.
Finally it should be noted that：The preferred embodiment of the present invention is the foregoing is only, is not intended to limit the invention, to the greatest extent
The present invention is described in detail with reference to the foregoing embodiments for pipe, and for those skilled in the art, it still can be with
Technical scheme described in foregoing embodiments is modified, or equivalent substitution is carried out to which part technical characteristic.It is all
Within the spirit and principles in the present invention, any modification, equivalent substitution and improvements made etc., it should be included in the guarantor of the present invention
Within the scope of shield.
Claims (7)
- A kind of 1. ceramics etching frosted color artistic decorative pigment, it is characterised in that：The formula is by azurite, malachite green, cinnabar, hero Huang, mica, high territory, clam meal, phosphatidyl choline, Arabic gum, deionized water, powdered sodium carbonate, by a certain percentage mixing group Into the formula is made up of the raw material of following percentage by weight：Azurite 10-15 parts, malachite green 10-15 parts, cinnabar 4-6 parts, realgar 8-10 parts, mica 5-15 parts, high territory 20-30 parts, clam meal 10-20 parts, phosphatidyl choline 8-10 parts, Arabic gum 5-7 parts, go Ionized water 3-5 parts, powdered sodium carbonate 2-4 parts.
- A kind of 2. preparation method of ceramics etching frosted color artistic decorative pigment, it is characterised in that：Comprise the following steps：1）Feeding：Above-mentioned mineral pigment is taken, is 1-3um with ball mill grinding to particle diameter；Obtain mixed powder；Screening；It is standby；2）Uniform stirring：Phosphatidyl choline 8-10 parts are taken, Arabic gum 5-7 parts, both are stirred；3）Prepare mixture：The deionized water of 3-5 parts is added into the mixture of phosphatidyl choline and Arabic gum, is mixed again Uniformly, mixture is obtained；It is 2-4 parts that powdered sodium carbonate is added into mixture, is well mixed；4）Prepare pigment：Above-mentioned mineral pigment after grinding is taken, is added in mixture, above-mentioned all the components is well mixed, Produce ceramic decoration pigment.
- A kind of 3. ceramics etching frosted color artistic decorative pigment according to claim 1, it is characterised in that：The kaolinite Soil preparation method be：Kaolin mineral aggregate is isolated into clay, debris, 5-6 times of water is then added and slurry is made, obtain kaolin ore Starch the first slurry；By the obtained slurry of kaolin ore slurry first and sodium hydrosulfite kaolin ore slurry in mass ratio:Sodium hydrosulfite=1: 0.0008-0.0015 is well mixed, and then adds conditioning agent, is adjusted its pH value to 3-5, is obtained the slurry of kaolin ore slurry second； The obtained slurry of kaolin ore slurry second is placed in the ion exchange agitator equipped with solid ion-exchange resin, stirring 0.5 - 1 hour hour, obtain the slurry of kaolin ore slurry the 3rd；The solid ion that will contain in the obtained slurry of kaolin ore slurry the 3rd Exchange resin comes out, and obtains kaolin ore slurry fine fodder；Obtained kaolin ore slurry fine fodder is washed, then through spraying Microballoon is dried to, produces Kaolin pigments.
- A kind of 4. ceramics etching frosted color artistic decorative pigment according to claim 1, it is characterised in that：It is described I Primary glue is a kind of Arabic gum of modification, and its preparation method is：It is prepared by gumwater：Arabic gum is placed on 60-80 DEG C For stirred in water bath until being completely dissolved, the pH for adjusting solution with sodium hydroxide solution to room temperature is placed in taking-up, is filtered, by filtrate It is transferred in large beaker, the dosage of the sodium hydroxide solution is the 3% of gumwater；Octenyl succinic acid anhydride solution Prepare：Octenyl succinic acid anhydride is well mixed with ethanol or isopropanol, octenyl succinic acid anhydride solution is prepared；Esterification is anti- Should：Filtered 38-63 DEG C of gumwater temperature is adjusted, octenyl succinic acid anhydride solution is slowly added into Arabic gum In solution, reaction time 1-2.5h, the pH of reaction solution is adjusted with sodium hydroxide solution, the dosage of sodium hydroxide is octenyl succinic The 3% of anhydride solution and gumwater total amount, pH is set to be maintained in constant alkalescence；Reaction uses hydrochloric acid solution after terminating Reaction solution pH is adjusted, hydrochloric acid solution dosage is 3% of solution after above-mentioned addition sodium hydroxide, reacts 1-2.5h；Dry：Then according to Secondary second alcohol and water alternating washing reaction liquid, the ocentyl succinic Arabic gum ester being settled out is put and dried in an oven, most The product after drying is crushed afterwards, sieved, is collected；Or directly the solution for mixing up pH is spray-dried, you can obtain one The Arabic gum of kind chemical modification.
- A kind of 5. ceramics etching frosted color artistic decorative pigment according to claim 1, it is characterised in that：It is described go from Sub- water is a kind of deionized water of the carbonating with specific electrical conductivity, and its preparation method is：Deionized water is provided to contactor； Carbon dioxide is provided to contactor；The flow velocity of the deionized water and the deionization are measured using at least one sensor The temperature of water, wherein at least one sensor is placed on the entrance of the contactor or the exit of the contactor； It is determined that to be supplied to the amount of the carbon dioxide of the contactor so that by with least one sensor and the dioxy Change the deionized water of the carbonating of the specific electrical conductivity of contactor generation of the supply connection of carbon gas, wherein the determination base In measured flow velocity and temperature；Be in fluid communication via the supply with the carbon dioxide and the contactor one or The carbon dioxide of determined amount is supplied to the contactor by multiple flow restrictors and one or more valves；And make that there is spy The deionized water for determining the carbonating of electrical conductivity flows out from the contactor.
- 6. a kind of preparation method of ceramics etching frosted color artistic decorative pigment according to claim 2, its feature exist In：The step 1）The idiographic flow of middle screening is：Feeding, mixing powder raw material input high-frequency screen, dither separation mixed powder； The raw material tentatively sieved by high-frequency screen is conveyed into high-pressure pump；Raw material is sent into magnetic separator by high-pressure pump, and carries out magnetic separation, from original Fine powder is filtered out in material, and is sent into the feeding belt of next step, fine powder feeding packing machine is carried out bag and turns to complete screening by feeding belt.
- 7. a kind of preparation method of ceramics etching frosted color artistic decorative pigment according to claim 2, its feature exist In：The step 4）The middle temperature for preparing pigment is 20 DEG C -30 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710703581.9A CN107523096A (en) | 2017-08-16 | 2017-08-16 | A kind of ceramics etching frosted color artistic decorative pigment |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710703581.9A CN107523096A (en) | 2017-08-16 | 2017-08-16 | A kind of ceramics etching frosted color artistic decorative pigment |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107523096A true CN107523096A (en) | 2017-12-29 |
Family
ID=60681299
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710703581.9A Pending CN107523096A (en) | 2017-08-16 | 2017-08-16 | A kind of ceramics etching frosted color artistic decorative pigment |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107523096A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112194911A (en) * | 2019-07-08 | 2021-01-08 | 谌国星 | Novel color aluminum tube pigment on ceramic glaze and preparation method thereof |
-
2017
- 2017-08-16 CN CN201710703581.9A patent/CN107523096A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112194911A (en) * | 2019-07-08 | 2021-01-08 | 谌国星 | Novel color aluminum tube pigment on ceramic glaze and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101096112B (en) | Production method of natural stone texture imitating ceramic wall ground tile | |
| CN104371464B (en) | A kind of water burnt-in sand coating and preparation method thereof | |
| CN104619933B (en) | Method for the production of solid surfaces for construction | |
| MXPA04000621A (en) | Method for conditioning titanium dioxide pigments. | |
| CN109553329A (en) | A kind of composite stone matter flexible sheet material and preparation method thereof | |
| CN103709830A (en) | Colored glaze mixed negative ion ink for ink-jet printing on ceramic and preparation method thereof | |
| CN107523096A (en) | A kind of ceramics etching frosted color artistic decorative pigment | |
| CN102351486B (en) | Manufacturing process of purely inorganic artificial travertine marble blocks and apparatus thereof | |
| CN105217673B (en) | A kind of preparation method of high thixotropic silicone adhesive special-purpose nanometer activated Calcium carbonate | |
| CN102604438A (en) | Iron oxide yellow pigment with low oil absorption | |
| CN109852128A (en) | A kind of flame retardant type flexible compound coloured silk piece and preparation method thereof | |
| CN107377158A (en) | A kind of fine grading method of Moist chemical synthesis mica powder | |
| CA2688084A1 (en) | Method for processing crude bentonite | |
| CN102659129A (en) | Method for preparing ultrathin synthetic mica crystal powder | |
| CN102977692B (en) | A kind of anion bowlder paint preparation method | |
| CN102311277B (en) | Spraying apparatus for producing ceramic tiles with imitated natural stone textures | |
| CN110407217A (en) | The method of the waste lithium cell positive electrode preparation high light inorganic material of nanometer | |
| CN110423493A (en) | The preparation method of hydrophilic dry mixing colorant applied to entire body large size ceramic plate | |
| CN105602294A (en) | Method for preparing white pearlescent pigment from sericite | |
| CN108676420A (en) | A kind of processing technology and process equipment making ink raw material | |
| CN105199432A (en) | Coarse whiting production process | |
| CN109206967A (en) | A kind of processing method of coal gasification lime-ash on powder of lacquer putty for use on | |
| CN104910645A (en) | Preparation method of ultrafine calcium carbonate | |
| CN104194402A (en) | Preparation method of ultrafine calcium carbonate | |
| CN106977232A (en) | A kind of preparation method of purplish red dumb light glaze |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20171229 |