CN107523054A - A kind of plastic sheeting of ceramic polyimides complex fire resistant light aging resisting - Google Patents
A kind of plastic sheeting of ceramic polyimides complex fire resistant light aging resisting Download PDFInfo
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- CN107523054A CN107523054A CN201710882513.3A CN201710882513A CN107523054A CN 107523054 A CN107523054 A CN 107523054A CN 201710882513 A CN201710882513 A CN 201710882513A CN 107523054 A CN107523054 A CN 107523054A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
- C08L79/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
- C08L79/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2379/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups C08J2361/00 - C08J2377/00
- C08J2379/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
- C08J2379/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2401/00—Characterised by the use of cellulose, modified cellulose or cellulose derivatives
- C08J2401/08—Cellulose derivatives
- C08J2401/26—Cellulose ethers
- C08J2401/28—Alkyl ethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention discloses a kind of plastic sheeting of ceramic polyimides complex fire resistant light aging resisting, by weight, including following raw material components：50 60 parts of polyimides, 8 15 parts of calcium carbonate, 14 parts of nano titanium oxide, 10 20 parts of ceramic powder, 79 parts of nano imvite, 9 13 parts of melamine cyanurate salt, 8 10 parts of carborundum powder, 14 20 parts of sodium carboxymethylcellulose, 37 parts of sepiolite, 10 20 parts of asbestos powder, 13 15 parts of tributyl 2-acetylcitrate, 23 parts of 1,2 propane diols, 12 parts of magnesium stearate, 46 parts of 3 hydroxybenzoic acid, 46 parts of diethylenetriamine, 0.2 0.4 parts of palladium nitrate, 0.2 0.4 parts of yttria, 23 parts of gelatin.Product of the present invention produces for safety formula, can be used for manufacturing food pack etc., and intensity is big when product uses, water-fast, oil resistant, it is durable in use, while large-scale industrial production is advantageously implemented, it is easy to grasp, it is easy to promote, there is excellently high temperature resistant light aging resisting property.
Description
Technical field
The present invention relates to field of material technology, the modeling of specifically a kind of ceramics-polyimides complex fire resistant light aging resisting
Expect film.
Background technology
In recent years, it is on the rise, causes global wide because waste plastic is difficult to degraded " white pollution " that brings
General concern, countries in the world have put into effect limitation or have prohibitted the use of the relevant laws and regulations of non-degradable plastic packing article successively.
The general temperature in use of polyethylene film currently used in the market is no more than 100 DEG C, therefore in some special dimensions
Phenomena such as polyethylene film will be restricted, while under prolonged illumination condition, and discoloration occurs in polyethylene film surface, it is
The aging of film accelerate, thus have impact on service life, these aspects all greatly limit the application of polyethylene film.
The content of the invention
It is an object of the invention to provide a kind of plastic sheeting of ceramics-polyimides complex fire resistant light aging resisting.
The purpose of the present invention can be achieved through the following technical solutions：
A kind of plastic sheeting of ceramics-polyimides complex fire resistant light aging resisting, by weight, including following raw material
Component：Polyimides 50-60 parts, calcium carbonate 8-15 parts, nano titanium oxide 1-4 parts, ceramic powder 10-20 parts, nano imvite
7-9 parts, melamine cyanurate salt 9-13 parts, carborundum powder 8-10 parts, sodium carboxymethylcellulose 14-20 parts, sepiolite 3-7
Part, asbestos powder 10-20 parts, tributyl 2-acetylcitrate 13-15 parts, 1,2- propane diols 2-3 parts, magnesium stearate 1-2 parts, 3- hydroxyls
Benzoic acid 4-6 parts, diethylenetriamine 4-6 parts, palladium nitrate 0.2-0.4 parts, yttria 0.2-0.4 parts, gelatin 2-3 parts.
Preferably, the plastic sheeting of described a kind of ceramics-polyimides complex fire resistant light aging resisting, by weight
Meter, including following raw material components：50 parts of polyimides, 8 parts of calcium carbonate, 1 part of nano titanium oxide, ceramic powder 10 part, nanometer cover
De- 7 parts of soil, 9 parts of melamine cyanurate salt, 8 parts of carborundum powder, 14 parts of sodium carboxymethylcellulose, 3 parts of sepiolite, asbestos powder 10
Part, 13 parts of tributyl 2-acetylcitrate, 2 parts of 1,2- propane diols, 1 part of magnesium stearate, 4 parts of 3- hydroxybenzoic acids, diethylenetriamine 4
Part, 0.2 part of palladium nitrate, 0.2 part of yttria, 2 parts of gelatin.
Preferably, the plastic sheeting of described a kind of ceramics-polyimides complex fire resistant light aging resisting, by weight
Meter, including following raw material components：60 parts of polyimides, 15 parts of calcium carbonate, 4 parts of nano titanium oxide, ceramic powder 20 part, nanometer cover
De- 9 parts of soil, 13 parts of melamine cyanurate salt, 10 parts of carborundum powder, 20 parts of sodium carboxymethylcellulose, 7 parts of sepiolite, asbestos powder
20 parts, 15 parts of tributyl 2-acetylcitrate, 3 parts of 1,2- propane diols, 2 parts of magnesium stearate, 6 parts of 3- hydroxybenzoic acids, divinyl three
6 parts of amine, 0.4 part of palladium nitrate, 0.4 part of yttria, 3 parts of gelatin.
Preferably, the plastic sheeting of described a kind of ceramics-polyimides complex fire resistant light aging resisting, by weight
Meter, including following raw material components：55 parts of polyimides, 12 parts of calcium carbonate, 2 parts of nano titanium oxide, ceramic powder 15 part, nanometer cover
De- 8 parts of soil, 12 parts of melamine cyanurate salt, 9 parts of carborundum powder, 16 parts of sodium carboxymethylcellulose, 4 parts of sepiolite, asbestos powder
15 parts, 14 parts of tributyl 2-acetylcitrate, 2 parts of 1,2- propane diols, 1 part of magnesium stearate, 5 parts of 3- hydroxybenzoic acids, divinyl three
5 parts of amine, 0.3 part of palladium nitrate, 0.3 part of yttria, 3 parts of gelatin.
Beneficial effects of the present invention：Product of the present invention produces for safety formula, can be used for manufacturing food pack etc., produce
Intensity is big when product use, water-fast, oil resistant, durable in use, while is advantageously implemented large-scale industrial production, is easy to grasp, just
In popularization, there is excellently high temperature resistant light aging resisting property.
Embodiment
The present invention is described in further detail with reference to specific embodiment.
Embodiment 1
A kind of plastic sheeting of ceramics-polyimides complex fire resistant light aging resisting, by weight, including following raw material
Component：50 parts of polyimides, 8 parts of calcium carbonate, 1 part of nano titanium oxide, 10 parts of ceramic powder, 7 parts of nano imvite, cyanuric acid three
9 parts of paracyanogen amine salt, 8 parts of carborundum powder, 14 parts of sodium carboxymethylcellulose, 3 parts of sepiolite, 10 parts of asbestos powder, acetyl tributyl citrate three
13 parts of butyl ester, 2 parts of 1,2- propane diols, 1 part of magnesium stearate, 4 parts of 3- hydroxybenzoic acids, 4 parts of diethylenetriamine, 0.2 part of palladium nitrate,
0.2 part of yttria, 2 parts of gelatin.
The preparation method of the present invention is same as the prior art.
Embodiment 2
A kind of plastic sheeting of ceramics-polyimides complex fire resistant light aging resisting, by weight, including following raw material
Component：60 parts of polyimides, 15 parts of calcium carbonate, 4 parts of nano titanium oxide, 20 parts of ceramic powder, 9 parts of nano imvite, cyanuric acid
13 parts of melamine salt, 10 parts of carborundum powder, 20 parts of sodium carboxymethylcellulose, 7 parts of sepiolite, 20 parts of asbestos powder, acetyl lemon
Sour 15 parts of tributyl, 3 parts of 1,2- propane diols, 2 parts of magnesium stearate, 6 parts of 3- hydroxybenzoic acids, 6 parts of diethylenetriamine, palladium nitrate
0.4 part, 0.4 part of yttria, 3 parts of gelatin.
The preparation method of the present invention is same as the prior art.
Embodiment 3
A kind of plastic sheeting of ceramics-polyimides complex fire resistant light aging resisting, by weight, including following raw material
Component：55 parts of polyimides, 12 parts of calcium carbonate, 2 parts of nano titanium oxide, 15 parts of ceramic powder, 8 parts of nano imvite, cyanuric acid
12 parts of melamine salt, 9 parts of carborundum powder, 16 parts of sodium carboxymethylcellulose, 4 parts of sepiolite, 15 parts of asbestos powder, acetyl tributyl citrate
14 parts of tributyl, 2 parts of 1,2- propane diols, 1 part of magnesium stearate, 5 parts of 3- hydroxybenzoic acids, 5 parts of diethylenetriamine, palladium nitrate 0.3
Part, 0.3 part of yttria, 3 parts of gelatin.
The preparation method of the present invention is same as the prior art.
Embodiment 4
A kind of plastic sheeting of ceramics-polyimides complex fire resistant light aging resisting, by weight, including following raw material
Component：58 parts of polyimides, 11 parts of calcium carbonate, 2 parts of nano titanium oxide, 16 parts of ceramic powder, 8 parts of nano imvite, cyanuric acid
10 parts of melamine salt, 9 parts of carborundum powder, 16 parts of sodium carboxymethylcellulose, 4 parts of sepiolite, 15 parts of asbestos powder, acetyl tributyl citrate
15 parts of tributyl, 2 parts of 1,2- propane diols, 2 parts of magnesium stearate, 6 parts of 3- hydroxybenzoic acids, 6 parts of diethylenetriamine, palladium nitrate 0.4
Part, 0.4 part of yttria, 3 parts of gelatin.
The preparation method of the present invention is same as the prior art.
Embodiment 5
A kind of plastic sheeting of ceramics-polyimides complex fire resistant light aging resisting, by weight, including following raw material
Component：60 parts of polyimides, 8 parts of calcium carbonate, 4 parts of nano titanium oxide, 10 parts of ceramic powder, 7 parts of nano imvite, cyanuric acid three
13 parts of paracyanogen amine salt, 8 parts of carborundum powder, 20 parts of sodium carboxymethylcellulose, 3 parts of sepiolite, 20 parts of asbestos powder, acetyl tributyl citrate three
13 parts of butyl ester, 3 parts of 1,2- propane diols, 1 part of magnesium stearate, 4 parts of 3- hydroxybenzoic acids, 6 parts of diethylenetriamine, 0.2 part of palladium nitrate,
0.4 part of yttria, 2 parts of gelatin.
The preparation method of the present invention is same as the prior art.
Claims (4)
- A kind of 1. plastic sheeting of ceramics-polyimides complex fire resistant light aging resisting, it is characterised in that by weight, bag Include following raw material components：Polyimides 50-60 parts, calcium carbonate 8-15 parts, nano titanium oxide 1-4 parts, ceramic powder 10-20 parts, Nano imvite 7-9 parts, melamine cyanurate salt 9-13 parts, carborundum powder 8-10 parts, sodium carboxymethylcellulose 14-20 parts, Sepiolite 3-7 parts, asbestos powder 10-20 parts, tributyl 2-acetylcitrate 13-15 parts, 1,2- propane diols 2-3 parts, magnesium stearate 1-2 Part, 3- hydroxybenzoic acid 4-6 parts, diethylenetriamine 4-6 parts, palladium nitrate 0.2-0.4 parts, yttria 0.2-0.4 parts, gelatin 2-3 parts.
- 2. a kind of plastic sheeting of ceramics according to claim 1-polyimides complex fire resistant light aging resisting, its feature It is, by weight, including following raw material components：50 parts of polyimides, 8 parts of calcium carbonate, 1 part of nano titanium oxide, ceramics 10 parts of powder, 7 parts of nano imvite, 9 parts of melamine cyanurate salt, 8 parts of carborundum powder, 14 parts of sodium carboxymethylcellulose, Hai Pao 3 parts of stone, 10 parts of asbestos powder, 13 parts of tributyl 2-acetylcitrate, 2 parts of 1,2- propane diols, 1 part of magnesium stearate, 3- hydroxybenzoic acids 4 Part, 4 parts of diethylenetriamine, 0.2 part of palladium nitrate, 0.2 part of yttria, 2 parts of gelatin.
- 3. a kind of plastic sheeting of ceramics according to claim 1-polyimides complex fire resistant light aging resisting, its feature It is, by weight, including following raw material components：60 parts of polyimides, 15 parts of calcium carbonate, 4 parts of nano titanium oxide, ceramics 20 parts of powder, 9 parts of nano imvite, 13 parts of melamine cyanurate salt, 10 parts of carborundum powder, 20 parts of sodium carboxymethylcellulose, sea 7 parts of afrodite, 20 parts of asbestos powder, 15 parts of tributyl 2-acetylcitrate, 3 parts of 1,2- propane diols, 2 parts of magnesium stearate, 3- hydroxy benzenes first 6 parts of acid, 6 parts of diethylenetriamine, 0.4 part of palladium nitrate, 0.4 part of yttria, 3 parts of gelatin.
- 4. a kind of plastic sheeting of ceramics according to claim 1-polyimides complex fire resistant light aging resisting, its feature It is, by weight, including following raw material components：55 parts of polyimides, 12 parts of calcium carbonate, 2 parts of nano titanium oxide, ceramics 15 parts of powder, 8 parts of nano imvite, 12 parts of melamine cyanurate salt, 9 parts of carborundum powder, 16 parts of sodium carboxymethylcellulose, Hai Pao 4 parts of stone, 15 parts of asbestos powder, 14 parts of tributyl 2-acetylcitrate, 2 parts of 1,2- propane diols, 1 part of magnesium stearate, 3- hydroxybenzoic acids 5 Part, 5 parts of diethylenetriamine, 0.3 part of palladium nitrate, 0.3 part of yttria, 3 parts of gelatin.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710882513.3A CN107523054A (en) | 2017-09-26 | 2017-09-26 | A kind of plastic sheeting of ceramic polyimides complex fire resistant light aging resisting |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710882513.3A CN107523054A (en) | 2017-09-26 | 2017-09-26 | A kind of plastic sheeting of ceramic polyimides complex fire resistant light aging resisting |
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| CN107523054A true CN107523054A (en) | 2017-12-29 |
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| CN201710882513.3A Pending CN107523054A (en) | 2017-09-26 | 2017-09-26 | A kind of plastic sheeting of ceramic polyimides complex fire resistant light aging resisting |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111100456A (en) * | 2018-10-29 | 2020-05-05 | 合肥杰事杰新材料股份有限公司 | Anti-aging and mildew-proof polyimide material and preparation method thereof |
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| CN101955667A (en) * | 2009-07-15 | 2011-01-26 | 北京化工大学 | Heat-resisting high-dielectric constant inorganic/polymer composite film |
| CN102627833A (en) * | 2012-04-01 | 2012-08-08 | 浙江华正新材料股份有限公司 | Environment-friendly fire-resistant insulating material and manufacturing method thereof |
| CN103012821A (en) * | 2011-09-20 | 2013-04-03 | 达胜科技股份有限公司 | Polyimide film |
| CN103242657A (en) * | 2013-05-23 | 2013-08-14 | 江苏亚宝绝缘材料股份有限公司 | Polyimide film |
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2017
- 2017-09-26 CN CN201710882513.3A patent/CN107523054A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1763134A (en) * | 2005-10-24 | 2006-04-26 | 浙江大学 | High dielectric constant polyimide/ceramic complex film and its preparation method |
| CN101955667A (en) * | 2009-07-15 | 2011-01-26 | 北京化工大学 | Heat-resisting high-dielectric constant inorganic/polymer composite film |
| CN103012821A (en) * | 2011-09-20 | 2013-04-03 | 达胜科技股份有限公司 | Polyimide film |
| CN102627833A (en) * | 2012-04-01 | 2012-08-08 | 浙江华正新材料股份有限公司 | Environment-friendly fire-resistant insulating material and manufacturing method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111100456A (en) * | 2018-10-29 | 2020-05-05 | 合肥杰事杰新材料股份有限公司 | Anti-aging and mildew-proof polyimide material and preparation method thereof |
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Application publication date: 20171229 |