CN106317763A - High temperature and photo aging resistant plastic film - Google Patents
High temperature and photo aging resistant plastic film Download PDFInfo
- Publication number
- CN106317763A CN106317763A CN201610688562.9A CN201610688562A CN106317763A CN 106317763 A CN106317763 A CN 106317763A CN 201610688562 A CN201610688562 A CN 201610688562A CN 106317763 A CN106317763 A CN 106317763A
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- China
- Prior art keywords
- parts
- high temperature
- powder
- diethylenetriamine
- gelatin
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention discloses a high temperature and photo aging resistant plastic film. The high temperature and photo aging resistant plastic film comprises the following raw materials which are taken as components in parts by weight: 50 to 60 parts of phenolic resin, 8 to 15 parts of calcium carbonate, 1 to 4 parts of nanometer titanium dioxide, 10 to 20 parts of benzoin ethyl ether, 7 to 9 parts of nanomontmorillonite, 9 to 13 parts of melamine cyanurate, 8 to 10 parts of silicon carbide powder, 14 to 20 parts of sodium carboxymethylcellulose, 3 to 7 parts of sepiolite, 10 to 20 parts of asbestos powder, 13 to 15 parts of acetyl tributyl citrate, 2 to 3 parts of diethylene glycol monoethyl ether acetate, 1 to 2 parts of magnesium stearate, 4 to 6 parts of 3-hydroxy benzoic acid, 4 to 6 parts of diethylenetriamine, 0.2 to 0.4 part of palladium nitrate, 0.2 to 0.4 part of yttria, and 2 to 3 parts of gelatin. The product of the invention is produced by a safe formula, and can be used for manufacturing food packaging bags and the like, is high in strength while used, water and oil resistant and durable in use, and further conducive to realizing large-scale industrial production, easily mastered, and convenient in popularization and further has excellent high temperature and photo aging resistance.
Description
Technical field
The present invention relates to field of material technology, the plastic sheeting of a kind of high temperature resistant light aging resisting.
Background technology
In recent years, owing to waste plastic " white pollution " brought that be difficult to degrade is on the rise, cause global extensively
General concern, countries in the world have put into effect the relevant laws and regulations limiting or prohibitting the use of non-degradable plastic packing article successively.
The polyethylene film used in the market generally uses temperature and is less than 100 DEG C, therefore in some special dimensions
Polyethylene film will be restricted, and simultaneously under long illumination condition, polyethylene film surface there will be the phenomenons such as variable color, is
The aging quickening of film, thus have impact on service life, these aspects all greatly limit the application of polyethylene film.
Summary of the invention
It is an object of the invention to provide the plastic sheeting of a kind of high temperature resistant light aging resisting.
The purpose of the present invention can be achieved through the following technical solutions:
The plastic sheeting of a kind of high temperature resistant light aging resisting, by weight, including following raw material components: phenolic resin 50-
60 parts, calcium carbonate 8-15 part, nano titanium oxide 1-4 part, benzoin ethyl ether 10-20 part, nano imvite 7-9 part, cyanuric acid
Melamine salt 9-13 part, carborundum powder 8-10 part, sodium carboxymethyl cellulose 14-20 part, meerschaum 3-7 part, asbestos powder 10-20
Part, tributyl 2-acetylcitrate 13-15 part, diethylene glycol ether acetate alone 2-3 part, magnesium stearate 1-2 part, 3-hydroxy benzenes first
Acid 4-6 part, diethylenetriamine 4-6 part, Palladous nitrate. 0.2-0.4 part, yttrium oxide 0.2-0.4 part, gelatin 2-3 part.
Preferably, the plastic sheeting of described a kind of high temperature resistant light aging resisting, by weight, including following raw material group
Point: 50 parts of phenolic resin, calcium carbonate 8 parts, nano titanium oxide 1 part, benzoin ethyl ether 10 parts, nano imvite 7 parts, cyanuric acid
Melamine salt 9 parts, carborundum powder 8 parts, sodium carboxymethyl cellulose 14 parts, meerschaum 3 parts, 10 parts of asbestos powder, acetyl tributyl citrate
Tributyl 13 parts, diethylene glycol ether acetate alone 2 parts, magnesium stearate 1 part, 3-hydroxy benzoic acid 4 parts, diethylenetriamine 4 parts,
Palladous nitrate. 0.2 part, yttrium oxide 0.2 part, 2 parts of gelatin.
Preferably, the plastic sheeting of described a kind of high temperature resistant light aging resisting, by weight, including following raw material group
Point: 60 parts of phenolic resin, calcium carbonate 15 parts, nano titanium oxide 4 parts, benzoin ethyl ether 20 parts, nano imvite 9 parts, cyanogen are urinated
Acid melamine salt 13 parts, carborundum powder 10 parts, sodium carboxymethyl cellulose 20 parts, meerschaum 7 parts, 20 parts of asbestos powder, acetyl lemon
Lemon acid tributyl 15 parts, diethylene glycol ether acetate alone 3 parts, magnesium stearate 2 parts, 3-hydroxy benzoic acid 6 parts, diethylenetriamine
6 parts, Palladous nitrate. 0.4 part, yttrium oxide 0.4 part, 3 parts of gelatin.
Preferably, the plastic sheeting of described a kind of high temperature resistant light aging resisting, by weight, including following raw material group
Point: 55 parts of phenolic resin, calcium carbonate 12 parts, nano titanium oxide 2 parts, benzoin ethyl ether 15 parts, nano imvite 8 parts, cyanogen are urinated
Acid melamine salt 12 parts, carborundum powder 9 parts, sodium carboxymethyl cellulose 16 parts, meerschaum 4 parts, 15 parts of asbestos powder, acetyl Fructus Citri Limoniae
Acid tributyl 14 parts, diethylene glycol ether acetate alone 2 parts, magnesium stearate 1 part, 3-hydroxy benzoic acid 5 parts, diethylenetriamine 5
Part, Palladous nitrate. 0.3 part, yttrium oxide 0.3 part, 3 parts of gelatin.
Beneficial effects of the present invention: product of the present invention is that safe formula produces, and can be used to manufacture food pack etc., produces
When product use, intensity is big, water-fast, oil resistant, durable in use, is advantageously implemented large-scale industrial production simultaneously, it is easy to grasp, just
In popularization, there is the most high temperature resistant light aging resisting property.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in further detail.
Embodiment 1
The plastic sheeting of a kind of high temperature resistant light aging resisting, by weight, including following raw material components: phenolic resin 50
Part, calcium carbonate 8 parts, nano titanium oxide 1 part, benzoin ethyl ether 10 parts, nano imvite 7 parts, melamine cyanurate salt 9
Part, carborundum powder 8 parts, sodium carboxymethyl cellulose 14 parts, meerschaum 3 parts, 10 parts of asbestos powder, tributyl 2-acetylcitrate 13 parts,
Diethylene glycol ether acetate alone 2 parts, magnesium stearate 1 part, 3-hydroxy benzoic acid 4 parts, diethylenetriamine 4 parts, Palladous nitrate. 0.2
Part, yttrium oxide 0.2 part, 2 parts of gelatin.
The preparation method of the present invention is same as the prior art.
Embodiment 2
The plastic sheeting of a kind of high temperature resistant light aging resisting, by weight, including following raw material components: phenolic resin 60
Part, calcium carbonate 15 parts, nano titanium oxide 4 parts, benzoin ethyl ether 20 parts, nano imvite 9 parts, melamine cyanurate salt 13
Part, carborundum powder 10 parts, sodium carboxymethyl cellulose 20 parts, meerschaum 7 parts, 20 parts of asbestos powder, tributyl 2-acetylcitrate 15 parts,
Diethylene glycol ether acetate alone 3 parts, magnesium stearate 2 parts, 3-hydroxy benzoic acid 6 parts, diethylenetriamine 6 parts, Palladous nitrate. 0.4
Part, yttrium oxide 0.4 part, 3 parts of gelatin.
The preparation method of the present invention is same as the prior art.
Embodiment 3
The plastic sheeting of a kind of high temperature resistant light aging resisting, by weight, including following raw material components: phenolic resin 55
Part, calcium carbonate 12 parts, nano titanium oxide 2 parts, benzoin ethyl ether 15 parts, nano imvite 8 parts, melamine cyanurate salt 12
Part, carborundum powder 9 parts, sodium carboxymethyl cellulose 16 parts, meerschaum 4 parts, 15 parts of asbestos powder, tributyl 2-acetylcitrate 14 parts,
Diethylene glycol ether acetate alone 2 parts, magnesium stearate 1 part, 3-hydroxy benzoic acid 5 parts, diethylenetriamine 5 parts, Palladous nitrate. 0.3
Part, yttrium oxide 0.3 part, 3 parts of gelatin.
The preparation method of the present invention is same as the prior art.
Embodiment 4
The plastic sheeting of a kind of high temperature resistant light aging resisting, by weight, including following raw material components: phenolic resin 58
Part, calcium carbonate 11 parts, nano titanium oxide 2 parts, benzoin ethyl ether 16 parts, nano imvite 8 parts, melamine cyanurate salt 10
Part, carborundum powder 9 parts, sodium carboxymethyl cellulose 16 parts, meerschaum 4 parts, 15 parts of asbestos powder, tributyl 2-acetylcitrate 15 parts,
Diethylene glycol ether acetate alone 2 parts, magnesium stearate 2 parts, 3-hydroxy benzoic acid 6 parts, diethylenetriamine 6 parts, Palladous nitrate. 0.4
Part, yttrium oxide 0.4 part, 3 parts of gelatin.
The preparation method of the present invention is same as the prior art.
Embodiment 5
The plastic sheeting of a kind of high temperature resistant light aging resisting, by weight, including following raw material components: phenolic resin 60
Part, calcium carbonate 8 parts, nano titanium oxide 4 parts, benzoin ethyl ether 10 parts, nano imvite 7 parts, melamine cyanurate salt 13
Part, carborundum powder 8 parts, sodium carboxymethyl cellulose 20 parts, meerschaum 3 parts, 20 parts of asbestos powder, tributyl 2-acetylcitrate 13 parts,
Diethylene glycol ether acetate alone 3 parts, magnesium stearate 1 part, 3-hydroxy benzoic acid 4 parts, diethylenetriamine 6 parts, Palladous nitrate. 0.2
Part, yttrium oxide 0.4 part, 2 parts of gelatin.
The preparation method of the present invention is same as the prior art.
Claims (4)
1. the plastic sheeting of a high temperature resistant light aging resisting, it is characterised in that by weight, including following raw material components: phenol
Urea formaldehyde 50-60 part, calcium carbonate 8-15 part, nano titanium oxide 1-4 part, benzoin ethyl ether 10-20 part, nano imvite 7-9
Part, melamine cyanurate salt 9-13 part, carborundum powder 8-10 part, sodium carboxymethyl cellulose 14-20 part, meerschaum 3-7 part, stone
Continuous powder 10-20 part, tributyl 2-acetylcitrate 13-15 part, diethylene glycol ether acetate alone 2-3 part, magnesium stearate 1-2 part,
3-hydroxy benzoic acid 4-6 part, diethylenetriamine 4-6 part, Palladous nitrate. 0.2-0.4 part, yttrium oxide 0.2-0.4 part, gelatin 2-3
Part.
The plastic sheeting of a kind of high temperature resistant light aging resisting the most according to claim 1, it is characterised in that by weight,
Including following raw material components: 50 parts of phenolic resin, calcium carbonate 8 parts, nano titanium oxide 1 part, benzoin ethyl ether 10 parts, nanometer are covered
7 parts of de-soil, melamine cyanurate salt 9 parts, carborundum powder 8 parts, sodium carboxymethyl cellulose 14 parts, meerschaum 3 parts, asbestos powder 10
Part, tributyl 2-acetylcitrate 13 parts, diethylene glycol ether acetate alone 2 parts, magnesium stearate 1 part, 3-hydroxy benzoic acid 4 parts,
Diethylenetriamine 4 parts, Palladous nitrate. 0.2 part, yttrium oxide 0.2 part, 2 parts of gelatin.
The plastic sheeting of a kind of high temperature resistant light aging resisting the most according to claim 1, it is characterised in that by weight,
Including following raw material components: 60 parts of phenolic resin, calcium carbonate 15 parts, nano titanium oxide 4 parts, benzoin ethyl ether 20 parts, nanometer
Montmorillonite 9 parts, melamine cyanurate salt 13 parts, carborundum powder 10 parts, sodium carboxymethyl cellulose 20 parts, meerschaum 7 parts, asbestos
20 parts of powder, tributyl 2-acetylcitrate 15 parts, diethylene glycol ether acetate alone 3 parts, magnesium stearate 2 parts, 3-hydroxy benzoic acid 6
Part, diethylenetriamine 6 parts, Palladous nitrate. 0.4 part, yttrium oxide 0.4 part, 3 parts of gelatin.
The plastic sheeting of a kind of high temperature resistant light aging resisting the most according to claim 1, it is characterised in that by weight,
Including following raw material components: 55 parts of phenolic resin, calcium carbonate 12 parts, nano titanium oxide 2 parts, benzoin ethyl ether 15 parts, nanometer
Montmorillonite 8 parts, melamine cyanurate salt 12 parts, carborundum powder 9 parts, sodium carboxymethyl cellulose 16 parts, meerschaum 4 parts, asbestos
15 parts of powder, tributyl 2-acetylcitrate 14 parts, diethylene glycol ether acetate alone 2 parts, magnesium stearate 1 part, 3-hydroxy benzoic acid 5
Part, diethylenetriamine 5 parts, Palladous nitrate. 0.3 part, yttrium oxide 0.3 part, 3 parts of gelatin.
Priority Applications (1)
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CN201610688562.9A CN106317763A (en) | 2016-08-18 | 2016-08-18 | High temperature and photo aging resistant plastic film |
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CN201610688562.9A CN106317763A (en) | 2016-08-18 | 2016-08-18 | High temperature and photo aging resistant plastic film |
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CN106317763A true CN106317763A (en) | 2017-01-11 |
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CN201610688562.9A Pending CN106317763A (en) | 2016-08-18 | 2016-08-18 | High temperature and photo aging resistant plastic film |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107523079A (en) * | 2017-09-05 | 2017-12-29 | 桐城市弘业塑胶有限公司 | A kind of yarn splits anti-collision foam screen sheath material |
Citations (3)
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CN104761862A (en) * | 2015-03-29 | 2015-07-08 | 桐城市福润包装材料有限公司 | Preparation method of high-polymer packaging material |
CN105237947A (en) * | 2015-11-11 | 2016-01-13 | 芜湖品通塑业科技有限公司 | Abrasion-proof plastic bag and preparation method thereof |
CN105419376A (en) * | 2015-12-29 | 2016-03-23 | 王璐 | Low-density toughing filling material for plastic film |
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2016
- 2016-08-18 CN CN201610688562.9A patent/CN106317763A/en active Pending
Patent Citations (3)
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---|---|---|---|---|
CN104761862A (en) * | 2015-03-29 | 2015-07-08 | 桐城市福润包装材料有限公司 | Preparation method of high-polymer packaging material |
CN105237947A (en) * | 2015-11-11 | 2016-01-13 | 芜湖品通塑业科技有限公司 | Abrasion-proof plastic bag and preparation method thereof |
CN105419376A (en) * | 2015-12-29 | 2016-03-23 | 王璐 | Low-density toughing filling material for plastic film |
Non-Patent Citations (2)
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CN107523079A (en) * | 2017-09-05 | 2017-12-29 | 桐城市弘业塑胶有限公司 | A kind of yarn splits anti-collision foam screen sheath material |
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Application publication date: 20170111 |
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