CN107512778A - Highly enriched environment-friendly deodorant agent and preparation method thereof - Google Patents
Highly enriched environment-friendly deodorant agent and preparation method thereof Download PDFInfo
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- CN107512778A CN107512778A CN201710839497.XA CN201710839497A CN107512778A CN 107512778 A CN107512778 A CN 107512778A CN 201710839497 A CN201710839497 A CN 201710839497A CN 107512778 A CN107512778 A CN 107512778A
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- enriched environment
- deodorant agent
- friendly deodorant
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/84—Biological processes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
- C02F3/342—Biological treatment of water, waste water, or sewage characterised by the microorganisms used characterised by the enzymes used
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
- C02F3/348—Biological treatment of water, waste water, or sewage characterised by the microorganisms used characterised by the way or the form in which the microorganisms are added or dosed
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/38—Organic compounds containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/40—Organic compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/26—Nature of the water, waste water, sewage or sludge to be treated from the processing of plants or parts thereof
- C02F2103/28—Nature of the water, waste water, sewage or sludge to be treated from the processing of plants or parts thereof from the paper or cellulose industry
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/14—NH3-N
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/02—Odour removal or prevention of malodour
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/04—Disinfection
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
Abstract
The invention discloses highly enriched environment-friendly deodorant agent and preparation method thereof, belong to pulp technology for making paper.Add chloroperoxidase in deodorant prepared by the present invention, the hydrogen peroxide in chloroperoxidase can remove nitrogen oxides and be obviously improved water quality with reaction of nitrogen oxides, the index such as ammonia nitrogen being effectively controlled in paper waste.Meanwhile the oxygen for reacting generation can react with hydrogen sulfide, generate the sulphur and water of free state.The agriculture hat bacillus added in the deodorant and streptomycete, have the characteristics that breeding is quick, vitality is strong, safe and non-toxic, the organic substance for producing foul gas, organic sulfur compound, organic nitrogen etc. can be decomposed, drastically increases the deodorizing capability and deodorization scope of deodorant.Chemical deodorizing method and biological odor removal method are used in combination, complete deodorization, operation preparation process is simple and convenient, and safe and efficient, is easy to promote the use of on a large scale, there is good development prospect.
Description
Technical field
The invention belongs to pulp technology for making paper, is related to a kind of deodorant, and in particular to highly enriched environment-friendly deodorant agent and its system
Preparation Method.
Background technology
Paper industry is raw material using timber, straw, reed, rag etc., and cellulose is isolated through HTHP boiling,
Paper pulp is made.Two production processes of slurrying and copy paper of paper waste in paper industry production.Slurrying is plant
Fiber separation in raw material comes out, and slurry is made, then through drifting, this process can produce substantial amounts of paper waste;Copy paper is handle
Pulp dilution, shaping, squeezing, drying, are made paper, and this process also easily produces paper waste.In process of production, finally
Non-cellulose part in discharge raw material turns into papermaking night.Contain lignin, cellulose, VFA etc. in night,
There is a stink, contaminative is very strong.
Prior art achieves certain progress in terms of deodorizing sterilizing, fresh air, but there is also deficiency, main performance
For:1st, prior art mainly carrys out deodorization using absorption method and masking method, and effect is not strong, and effect is not lasting, and it is dense to be only applicable to foul smell
Spend relatively low situation;2nd, can not potent strong sterilization;3rd, material source is narrow, complex process, and cost is higher.
The content of the invention
According to above the deficiencies in the prior art, the technical problems to be solved by the invention are to propose highly enriched environment-friendly deodorant agent
And preparation method thereof, the deodorant environment-friendly high-efficiency can thorough deodorization, sterilization, sterilization and purification air.
In order to achieve the above object, the present invention proposes highly enriched environment-friendly deodorant agent, including following component:Chlorine peroxide
Enzyme, stabilizer, lactic acid, citric acid, o-phenyl phenol, alkanolamide, citronella oil, Boratex, mace oil, agriculture crown bud spore bar
Bacterium, streptomycete, BTA, sodium dichloro cyanurate and deionized water.
Mentioned component is the constituent of following weight:50~120 parts of chloroperoxidase, 2~12 parts of stabilizer, lactic acid
30~50 parts, 30~50 parts of citric acid, 15~70 parts of o-phenyl phenol, 10~70 parts of alkanolamide, 30~80 parts of citronella oil, boron
Sour 20~50 parts of sodium, 20~50 parts of mace oil, 5~100 parts of bacillus of agriculture hat, 5~100 parts of streptomycete, BTA
200~300 parts of 30~50 parts, 30~50 parts of sodium dichloro cyanurate and deionized water.
Preferably, above-mentioned chloroperoxidase is 63% aqueous hydrogen peroxide solution;
Preferably, aforementioned stable agent is sodium pyrophosphate.
In order to achieve the above object, the present invention also proposes the preparation method of highly enriched environment-friendly deodorant agent, comprises the following steps:
Step 1: chloroperoxidase, stabilizer, lactic acid, citric acid and deionized water are stirred with mixer, mix,
The colourless transparent liquid stablized;
Step 2: bacillus, strepto- are preced with o-phenyl phenol, alkanolamide, citronella oil, Boratex, mace oil, agriculture
Bacterium, BTA, sodium dichloro cyanurate and deionized water are stirred with mixer, are mixed, are obtained weak yellow liquid A;
Step 3: the weak yellow liquid A in the colourless transparent liquid in above-mentioned steps one and above-mentioned steps two is stirred
Machine stirs, and mixes, and forms weak yellow liquid B, and obtain highly enriched environment-friendly deodorant agent;
Mixer in above-mentioned steps is M-200 type hydraulic tipping stirrers, and rotating speed is 30~50r/min.
Compared with prior art, beneficial effect of the present invention includes:Chlorine peroxidating is added in deodorant prepared by the present invention
Thing enzyme, the hydrogen peroxide in chloroperoxidase can remove nitrogen oxides and are obviously improved water quality, effectively with reaction of nitrogen oxides
The index such as the ammonia nitrogen controlled in paper waste.Meanwhile the oxygen for reacting generation can react with hydrogen sulfide, free state is generated
Sulphur and water.The agriculture hat bacillus added in the deodorant and streptomycete, with breeding, quick, vitality is strong, safe and non-toxic
The features such as, the organic substance for producing foul gas, organic sulfur compound, organic nitrogen etc. can be decomposed, drastically increases deodorant
Deodorizing capability and deodorization scope.O-phenyl phenol, sodium dichloro cyanurate etc. are also added into deodorant prepared by the present invention
Composition, there is the effect of good antisepsis and sterilization, the deodorant prepared using the present invention, can reduce or disable papermaking bactericide, it is complete
The effect of balance cost can be reached entirely.Highly enriched environment-friendly deodorant agent produced by the present invention is mainly for closing water production run ring
Border, this product is used in mixed way with measuring pump addition white water chest with plain boiled water, hazard substance control foul smell occurring source in decomposition water, reduced
Turbidity of sewage, make the increase of water quality light transmittance, improve clarity, decomposing harmful substances effectively can control water circulation to run.
Chemical deodorizing method and biological odor removal method are used in combination deodorant prepared by the present invention, complete deodorization, operation preparation
Process is simple and convenient, and safe and efficient, is easy to promote the use of on a large scale, there is good development prospect.
Embodiment
By the description to embodiment, to help those skilled in the art to have inventive concept of the invention, technical scheme
More complete, accurate and deep understanding.
Embodiment one
The present embodiment proposes highly enriched environment-friendly deodorant agent and preparation method thereof, comprises the following steps:
Step 1: by 50 parts of chloroperoxidase, 5 parts of sodium pyrophosphate, 30 parts of lactic acid, 30 parts of citric acid and deionized water 10
Part is stirred with mixer, is mixed, the colourless transparent liquid stablized;
Step 2: by 15 parts of o-phenyl phenol, 10 parts of alkanolamide, 30 parts of citronella oil, 20 parts of Boratex, mace oil 20
Part, 30 parts of bacillus of agriculture hat, 30 parts of streptomycete, 30 parts of BTA, 30 parts of sodium dichloro cyanurate and deionized water 200
Part is stirred with mixer, is mixed, is obtained weak yellow liquid A;
Step 3: the weak yellow liquid A in the colourless transparent liquid in above-mentioned steps one and above-mentioned steps two is stirred
Machine stirs, rotating speed 35r/min, mixes, and forms weak yellow liquid B, and obtain highly enriched environment-friendly deodorant agent.
Embodiment two
The present embodiment proposes highly enriched environment-friendly deodorant agent and preparation method thereof, comprises the following steps:
Step 1: by 80 parts of chloroperoxidase, 8 parts of sodium pyrophosphate, 40 parts of lactic acid, 40 parts of citric acid and deionized water 15
Part is stirred with mixer, is mixed, the colourless transparent liquid stablized;
Step 2: by 30 parts of o-phenyl phenol, 35 parts of alkanolamide, 60 parts of citronella oil, 35 parts of Boratex, mace oil 30
Part, 50 parts of bacillus of agriculture hat, 50 parts of streptomycete, 40 parts of BTA, 40 parts of sodium dichloro cyanurate and deionized water 240
Part is stirred with mixer, is mixed, is obtained weak yellow liquid A;
Step 3: the weak yellow liquid A in the colourless transparent liquid in above-mentioned steps one and above-mentioned steps two is stirred
Machine stirs, rotating speed 40r/min, mixes, and forms weak yellow liquid B, and obtain highly enriched environment-friendly deodorant agent.
Embodiment three
The present embodiment proposes highly enriched environment-friendly deodorant agent and preparation method thereof, comprises the following steps:
Step 1: by 120 parts of chloroperoxidase, 12 parts of sodium pyrophosphate, 50 parts of lactic acid, 50 parts of citric acid and deionized water
20 parts are stirred with mixer, are mixed, the colourless transparent liquid stablized;
Step 2: by 70 parts of o-phenyl phenol, 70 parts of alkanolamide, 80 parts of citronella oil, 50 parts of Boratex, mace oil 50
Part, 100 parts of bacillus of agriculture hat, 100 parts of streptomycete, 50 parts of BTA, 50 parts of sodium dichloro cyanurate and deionized water
280 parts are stirred with mixer, are mixed, are obtained weak yellow liquid A;
Step 3: the weak yellow liquid A in the colourless transparent liquid in above-mentioned steps one and above-mentioned steps two is stirred
Machine stirs, rotating speed 45r/min, mixes, and forms weak yellow liquid B, and obtain highly enriched environment-friendly deodorant agent.
Deodorant described in above example, can thorough deodorization, sterilization, sterilization, Yi Jijing under the cooperation of Multiple components
Change air.
To verify the performances such as the deodorizing capability of above-mentioned deodorant, bactericidal effect, the deodorant of above-described embodiment is carried out
Deodorization Experiment, experimentation and result such as following table:
The deodorant of same amount of embodiment is used in mixed way with measuring pump addition white water chest with plain boiled water, tests its deodorizing rate
And sterilizing rate, obtain following experiments data:
Embodiment one | Embodiment two | Embodiment three | |
Deodorizing rate % | 99.6 | 99.5 | 99.7 |
Sterilizing rate % | 98.3 | 98.2 | 98.5 |
Experiment can be seen that highly enriched environment-friendly deodorant agent of the present invention due to having used chlorine peroxide more than
The compositions such as enzyme, agriculture hat bacillus, streptomycete, o-phenyl phenol, sodium dichloro cyanurate, have reached thorough deodorization, have sterilized, disappear
The purpose of poison and purification air.
The present invention is exemplarily described above, it is clear that present invention specific implementation is not subject to the restrictions described above,
As long as employing the improvement of the various unsubstantialities of inventive concept and technical scheme of the present invention progress, or not improved this is sent out
Bright design and technical scheme directly applies to other occasions, within protection scope of the present invention.The protection of the present invention
Scope should be determined by the scope of protection defined in the claims.
Claims (6)
1. highly enriched environment-friendly deodorant agent, it is characterised in that the composition of the highly enriched environment-friendly deodorant agent including following parts by weight into
Point:50~120 parts of chloroperoxidase, 2~12 parts of stabilizer, 30~50 parts of lactic acid, 30~50 parts of citric acid, o-phenyl phenol
15~70 parts, 10~70 parts of alkanolamide, 30~80 parts of citronella oil, 20~50 parts of Boratex, 20~50 parts of mace oil, agriculture hat
5~100 parts of bacillus, 5~100 parts of streptomycete, 30~50 parts of BTA, 30~50 parts of sodium dichloro cyanurate and go
200~300 parts of ionized water.
2. highly enriched environment-friendly deodorant agent according to claim 1, it is characterised in that the chloroperoxidase mass fraction
For 63% aqueous hydrogen peroxide solution.
3. highly enriched environment-friendly deodorant agent according to claim 1 or 2, it is characterised in that stabilizer is sodium pyrophosphate.
4. the preparation method of highly enriched environment-friendly deodorant agent, it is characterised in that the preparation method comprises the following steps:
Step 1: chloroperoxidase, stabilizer, lactic acid, citric acid and deionized water are stirred, mix, the nothing stablized
Color transparency liquid;
Step 2: by o-phenyl phenol, alkanolamide, citronella oil, Boratex, mace oil, agriculture be preced with bacillus, streptomycete,
BTA, sodium dichloro cyanurate and deionized water stirring, mix, obtain weak yellow liquid A;
Step 3: the weak yellow liquid A in the colourless transparent liquid in above-mentioned steps one and above-mentioned steps two is stirred, mix,
Weak yellow liquid B is formed, produces highly enriched environment-friendly deodorant agent.
5. the preparation method of highly enriched environment-friendly deodorant agent according to claim 4, it is characterised in that step 1 and step 2
Described in stir and be stirred using M-200 type hydraulic tipping stirrers.
6. the preparation method of the highly enriched environment-friendly deodorant agent according to claim 4 or 5, it is characterised in that the mixer
Rotating speed be 30~50r/min.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108323528A (en) * | 2018-01-17 | 2018-07-27 | 广东通朗环保科技有限公司 | A kind of deodorant and preparation method thereof |
CN109467140A (en) * | 2018-10-15 | 2019-03-15 | 河北工程大学 | A kind of new method of urban river deodorization |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106924789A (en) * | 2017-04-27 | 2017-07-07 | 陈秋华 | A kind of paper mill deodorant |
-
2017
- 2017-09-18 CN CN201710839497.XA patent/CN107512778A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106924789A (en) * | 2017-04-27 | 2017-07-07 | 陈秋华 | A kind of paper mill deodorant |
Non-Patent Citations (1)
Title |
---|
武深树: "《畜禽粪便污染防治技术》", 31 December 2014, 湖南科学技术出版社 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108323528A (en) * | 2018-01-17 | 2018-07-27 | 广东通朗环保科技有限公司 | A kind of deodorant and preparation method thereof |
CN109467140A (en) * | 2018-10-15 | 2019-03-15 | 河北工程大学 | A kind of new method of urban river deodorization |
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