CN107502390A - A kind of expanded liquid of reduced fuel oil and expanded reduced fuel oil - Google Patents

A kind of expanded liquid of reduced fuel oil and expanded reduced fuel oil Download PDF

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Publication number
CN107502390A
CN107502390A CN201610413848.6A CN201610413848A CN107502390A CN 107502390 A CN107502390 A CN 107502390A CN 201610413848 A CN201610413848 A CN 201610413848A CN 107502390 A CN107502390 A CN 107502390A
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fuel oil
reduced fuel
expanded
oil
expanded liquid
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智全德
刘士永
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1225—Inorganic compounds halogen containing compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1233—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1266—Inorganic compounds nitrogen containing compounds, (e.g. NH3)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/12—Inorganic compounds
    • C10L1/1275—Inorganic compounds sulfur, tellurium, selenium containing compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/24—Organic compounds containing sulfur, selenium and/or tellurium
    • C10L1/2425—Thiocarbonic acids and derivatives thereof, e.g. xanthates; Thiocarbamic acids or derivatives thereof, e.g. dithio-carbamates; Thiurams
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/30—Organic compounds compounds not mentioned before (complexes)
    • C10L1/305—Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/02—Inorganic or organic compounds containing atoms other than C, H or O, e.g. organic compounds containing heteroatoms or metal organic complexes
    • C10L2200/0204—Metals or alloys
    • C10L2200/0209—Group I metals: Li, Na, K, Rb, Cs, Fr, Cu, Ag, Au
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/02—Inorganic or organic compounds containing atoms other than C, H or O, e.g. organic compounds containing heteroatoms or metal organic complexes
    • C10L2200/0204—Metals or alloys
    • C10L2200/0213—Group II metals: Be, Mg, Ca, Sr, Ba, Ra, Zn, Cd, Hg
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/02—Inorganic or organic compounds containing atoms other than C, H or O, e.g. organic compounds containing heteroatoms or metal organic complexes
    • C10L2200/025—Halogen containing compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/02—Inorganic or organic compounds containing atoms other than C, H or O, e.g. organic compounds containing heteroatoms or metal organic complexes
    • C10L2200/0263—Sulphur containing compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/04—Organic compounds
    • C10L2200/0407—Specifically defined hydrocarbon fractions as obtained from, e.g. a distillation column
    • C10L2200/0438—Middle or heavy distillates, heating oil, gasoil, marine fuels, residua

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

The invention discloses a kind of expanded liquid of reduced fuel oil and expanded reduced fuel oil.Its use is very simple, and the expanded liquid of very effective reduced fuel oil is made with seldom kind raw material, and especially with natural goods and materials extract mosanom or xanthans and purified water, this is the raw material of the expanded liquid of reduced fuel oil of forefathers' never step.The expanded liquid energy of reduced fuel oil of the present invention enough makes fully being burnt for mink cell focus, and the heavy oil stability of emulsification is very prominent, long-term storage is not demulsified, even if it is heated to 100 °C, vibration can not all make oil, water separation even in the case of antipyretic with centrifuge, its proportioning raw material is simple and easy to get, and effect protrudes, and production cost can be greatly lowered.

Description

A kind of expanded liquid of reduced fuel oil and expanded reduced fuel oil
Technical field
The present invention relates to reduced fuel oil field of combustion technology, more particularly to a kind of expanded liquid of reduced fuel oil and expanded heavy Fuel oil.
Background technology
Oil is one of most widely used and most popular energy, and with the continuous development of society, people are to oil Demand increasingly increases, and the social wilderness demand contradiction limited with petroleum reserves also increasingly highlights, and thing followed crude oil appreciates The problem of turn into influence the future of the world economy an important factor for.As fuel, how to be effectively using petroleum resources fully The problem of countries in the world today technical staff's joint research, and it is difficult to clean-burning mink cell focus (including asphaltenes in crude oil Heavy oil, the more waste oil of solid content and oil recovery etc.) utilization be one of the problem for being wherein badly in need of solving.Difficult right heavy combustion Oil can produce the pernicious gas that substantial amounts of oxysulfide, nitrogen oxides, carbon monoxide etc. seriously pollute air in burning.
In order to improve the efficiency of combustion of reduced fuel oil, the discharge of pollutant is reduced, mink cell focus adds expanded liquid and is allowed to emulsify Solving means comparison it is more.It is not so good using the method emulsifying effectiveness of non-particle surface activating agent merely, more make A kind of multi-functional expanded liquid of heavy oil mixed with water is disclosed with compound expanded liquid, such as Chinese patent literature CN1067593, by dehydration A variety of nonionic surfactants such as Span, APES and alkyl benzene sulphonate, imine particle Type surfactant, and expanded liquid made of phenol, expanded reduced fuel oil are now with the current, and storage is not demulsified for 12 days.In addition Except using non-particle surface activating agent (it is required that HLB value≤8) and ionic surfactant also in some heavy oil bulking liquid （Cation and anion）Outside, 0-15% hydroquinones is additionally added, with 79.7~96% heavy oil, 3.99~20% water, 0.01 The expanded reduced fuel oil that~0.3% expanded liquid is configured to uses immediately.Although use a variety of surface-actives in above-mentioned heavy oil bulking liquid Agent, but emulsion stability is not satisfactory, and anti-corrosion is not accounted for, the prices of raw materials of expanded liquid are expensive, into production cost It is higher, promote the use of larger difficulty.
The content of the invention
Therefore, the technical problem to be solved in the present invention is to overcome existing heavy oil bulking liquid above shortcomings, and then There is provided that a kind of high combustion efficiency, production cost are low, pollutant discharge amount is few, and the reduced fuel oil that stable emulsifying, antiseptic property are good Expanded liquid and expanded reduced fuel oil.
To achieve the above object, the present invention uses following technical scheme：
A kind of expanded liquid of reduced fuel oil, it includes the raw material of following parts by weight：
Component A 40-400
Component B 40-400
Component C 5-100
Sodium chloride 5-100
Purified water 1000
The component A is potassium hydroxide or sodium nitrate；The component B is calcium chloride or calcium sulfate or calcium phosphate；The component C is Sodium Alginate or potassium alginate or xanthans.
Preferably, the parts by weight of the component A are 100-400.
Preferably, the parts by weight of the component B are 100-400.
Preferably, added with compound or the compound of chloride ion-containing containing magnesium ion in the expanded liquid of the reduced fuel oil.
Preferably, the parts by weight of the compound containing magnesium ion are 16-60.
Preferably, the parts by weight of the chloride ion-containing compound are 31-115.
Preferably, the purified water is the running water or industrial water or underground water after purified treatment.
A kind of expanded reduced fuel oil, the raw material of following percentage by weight is well mixed by it：
Base oil 50%-90%
Purified water 10%-50%
The expanded liquid 0.01%-0.45% of reduced fuel oil
The expanded liquid of reduced fuel oil is the expanded liquid of reduced fuel oil described in any of the above-described.
Preferably, the base oil is heavy hydrocarbon oil or crude oil or tar sand oil or oil rock is oily or industrial excessive fuel consumption.
Preferably, the percentage by weight of each raw material of the expanded reduced fuel oil is：
Base oil 70%-80%
Purified water 20%-30%
The expanded liquid 0.2%-0.4% of reduced fuel oil.
Embodiment
A kind of expanded liquid of reduced fuel oil, it includes the raw material of following parts by weight：
Component A 40-400
Component B 40-400
Component C 5-100
Sodium chloride 5-100
Purified water 1000
The component A is potassium hydroxide or sodium nitrate；The component B is calcium chloride or calcium sulfate or calcium phosphate；The component C is Sodium Alginate or potassium alginate or xanthans.
Wherein, when the parts by weight of the component A are 100-400, when the parts by weight of the component B are 100-400, the heavy The emulsifying effectiveness of the expanded liquid of fuel oil is more preferable.To water quality, there is no particular limitation, and the purified water can be running water, industrial water Or underground water, as long as by basic purified treatment.
Added with compound or the compound of chloride ion-containing containing magnesium ion in the expanded liquid of reduced fuel oil, with further Improve emulsifying effectiveness.The parts by weight of the compound containing magnesium ion are 16-60, and the parts by weight of the chloride ion-containing compound are 31-115, as long as it contains magnesium ion or chlorion, specific material type is unlimited.The expanded liquid of the present embodiment is milky Liquid, it is a kind of ionic expanded liquid
A kind of expanded reduced fuel oil, it is equal by raw material (the proportion sum of each raw material is equal to 100%) mixing of following percentage by weight It is even：
Base oil 50%-90%
Purified water 10%-50%
The expanded liquid 0.01%-0.45% of reduced fuel oil
The expanded liquid of reduced fuel oil is the expanded liquid of reduced fuel oil described in embodiment one.The base oil has no special limit System, it can be heavy hydrocarbon oil or crude oil or tar sand oil or oil rock is oily or industrial excessive fuel consumption, or excessive fuel consumption caused by other facilities.
Experiment shows, when the percentage by weight of each raw material of the expanded reduced fuel oil is：Base oil 70%-80%, purification When water 20%-30%, the expanded liquid 0.2%-0.4% of reduced fuel oil, oil quality can further improve.
The method for preparing expanded reduced fuel oil is also known to those skilled in the art.Adding purified water and be mixed with Mink cell focus in be proportionally added into expanded liquid well mixed.It can be clearly seen when use for laboratory vierics are prepared：When only When having mink cell focus and purified water, oil and water clear-cut, stirring can not change this situation：When the expanded liquid warp for adding the present invention Stirring emulsifies immediately, does not see oil, moisture circle intuitively.
Expanded reduced fuel oil with the present invention is a kind of capsule-type oil emulsion of Water-In-Oil, and expanded liquid energy of the invention enough makes Water particle is evenly dispersed in mink cell focus, and water-drop-shaped emulsion is formed in oil, and the diameter of emulsion particles is 5~25.It is this Expanded reduced fuel oil stability is fine, and micro- Microscopic observation can be clearly apparent water droplet and be dispersed in mink cell focus, and outside water droplet There is one layer " film " to live its packing, visible water droplet flashes white light under light.And the outer black heavy oil of water droplet that film packing, show Microencapsulation form, the photo shot with this can be also clearly seen, and expanded reduced fuel oil is deposited for a long time, through examining oil, water to have no point From.Expanded reduced fuel oil is heated to 100 °C, oil, water emulsification is examined as before, expanded reduced fuel oil is being heated to 80-100 °C It is lower all to make oil, water separation with centrifuge, while made corrosion test in storage, it was demonstrated that it is corrosion-free.
This expanded reduced fuel oil water particle in burning produces heavy explosion because heated, and and can of exploding makes heavy elaioleucite Sub further refinement, completely burned can be reached and noresidue, in combustion testing is carried out, carbon monoxide, sulfur-bearing chemical combination The gas contents such as thing are greatly lowered, and the thermal efficiency is significantly raised.Under identical burning condition, the present invention prepares expanded heavy When fuel oil burns in combustion furnace respectively with primary heavy oil, it is evident that expanded heavy from the peep hole of fire door front and side Matter fuel oil combustion flame is in yellow light tone, and heavy oil that can not be by comparison is blushed flame.
The characteristics of protruding of the invention, is compared with present technology：
1. use is very simple, the expanded liquid of very effective reduced fuel oil is made with seldom kind raw material, especially with Natural goods and materials extract-mosanom or xanthans and purified water, this is the original of the expanded liquid of reduced fuel oil of forefathers' never step Material.
2. preparation method using the expanded liquid of reduced fuel oil of the present invention and expanded reduced fuel oil is easily achieved water-in-oil type The emulsifying effectiveness in capsule shape water droplet emulsion, make fully being burnt for mink cell focus.
3. due to the expanded liquid of reduced fuel oil of the present invention, the heavy oil stability of emulsification is very prominent, not only long-term to deposit not Demulsification, even if being heated to 100 °C, vibration can not all make oil, water separation even in the case of antipyretic with centrifuge.
4. the expanded liquid of reduced fuel oil of the present invention and the proportioning raw material of expanded reduced fuel oil are simple and easy to get, effect protrudes, raw Production cost can be greatly lowered, and this is that prior art can not be by comparison.
In order to illustrate the protruding effect of the present invention, it is described with reference to experiment and monitoring result：
The proportioning test of the expanded liquid of the reduced fuel oil of table one is as follows：
The expanded reduced fuel oil proportioning test of table two（Embodiment 1-8）Such as following table：
Expanded reduced fuel oil charging formula is as follows
Gross calorific value：The GB/T384 of KcaL/Kg 10094
Sulphur：0.56 GB/T17040
Carbon residue：6.81 GB/T268
Moisture：24 GB/T260
90 DEG C of kinematic viscosity, the GB/T11137 of cSt 35.37
The GB/T267 of open flash point DEG C 210
100 DEG C of copper corrosion, the GB/T5096 of 3h 1
During the expanded reduced fuel oil of aglycon, 50 DEG C of thermal purification water are first added in reduced fuel oil, add expanded liquid be stirred and Its temperature is set to rise to 90 DEG C or so spray combustions the heating of expanded reduced fuel oil into during, use.
The expanded reduced fuel oil prepared to example 1,2,3,6 in table two is tested, and its data is as follows:
Primary heavy oil and the gross calorific value of expanded reduced fuel oil and the test result of moisture of 4#, 5# configuration in table two are：
Note：The above-mentioned above-mentioned inspection of test is that Liaoning Entry-Exit Inspection and Quarantine Bureau technique center is detected.
Expanded reduced fuel oil with microscope through being taken pictures, as can be seen that mink cell focus is as in scattered a word used in person's name body from being taken a picture Water droplet is to be uniformly distributed therein, and the surface covering membranoid substance of water particle, because the carbon contained in mink cell focus, sulphur, nitrogen Deng composition and purified water, the effect of the goods and materials of the material of three kinds of additions and produced film is covered in water particle surface.
Above-mentioned prepared expanded reduced fuel oil keeps aqueous oily emulsion solution state after being deposited 7 days at 25 DEG C. Expanded reduced fuel oil is heated and is kept for 100 DEG C, room temperature is down to after stopping heating（25℃）, profit does not separate, by expanded heavy Fuel Heating is placed in centrifugal separator to 80 DEG C, water-oil separating phenomenon is not also produced after centrifuging 20min with 600 turns of ∕ minutes.
The expanded reduced fuel oil (a) prepared will be appealed and reduced fuel oil adds water（b）It is individually placed to be put into respective container Once, after 5 weeks（B) experiment iron body is oxidized corrosion in, has rusty stains, and experiment iron body does not see oxidized vestige in (a).
Above-mentioned prepared expanded reduced fuel oil is burnt in heating furnace and operated, the test of its indices（Maoming Petrochemical south Center of gravity detects in extra large senior lubricant company quality）As a result it is as follows：
Instrument for testing：Bian Xiu formula gas detecting instruments.GX-94 types, Japanese Li Yan pillars commercial firm production；
Bo Liye infrared light instrument, FTIR-8101 types, Japanese Shimadzu Corporation's production；
Gas chromatograph, GC-14 types, Japanese Shimadzu Corporation's production.
At another place（Nanjing petrochemical industry Nanjing Refinery research institute）Heating furnace burning operates its test result：
Instrument for testing：Bian Xiu formula gas detecting instruments.GX-94 types, Japanese Li Yan pillars commercial firm production；
Bo Liye infrared light instrument, SMF-7612 types, Siemens production；
Gas chromatograph, SMK-38C types, Siemens production.
Example 9：
The expanded liquid composition of raw materials of reduced fuel oil is as follows：
Potassium alginate（ALginic acid potassium） 100Kg
Calcium sulfate 82Kg
Sodium nitrate 150Kg
Magnesium chloride 30Kg
Potassium hydroxide 20Kg
Purified water 1000Kg
Above-mentioned raw materials are configured to the expanded liquid of milky reduced fuel oil, mink cell focus used is mixing heavy oil, and test index is：
The GB ∕ T260 of moisture content % 0.25
The JISK ∕ -2272 of ash % 0.03
The JISK ∕ -2541 of sulphur % 2.30
The JISK ∕ 8813 of carbon % 86.44
The JISK ∕ 8813 of hydrogen % 10.38
The GB ∕ T384 of gross calorific power KcaI ∕ Kg 9313
The GB ∕ T11137 of 90 DEG C of cSt of kinematic viscosity 26.94
The GB ∕ T11137 of 95 DEG C of cSt of kinematic viscosity 37.31
Expanded reduced fuel oil is made with following weight proportion：
Purified water：Mix heavy oil：Expanded liquid=20 of reduced fuel oil：80：0.3
Its example effects 1-8 emulsified：Combustion efficiency shows the thermal efficiency compared with the mixing heavy oil of the non-expanded liquid of medium solid fuel oil Improve 10%.
Example 10：
The expanded liquid raw material proportioning of reduced fuel oil is as follows：
The Kg of sodium chloride 350
The Kg of calcium chloride 250
Xanthans 70Kg
Magnesium chloride 50Kg
Potassium hydroxide 20Kg
Purified water 1000Kg
Above-mentioned raw materials are configured to the expanded liquid of milky reduced fuel oil, with itself and mink cell focus, purified water prepares expanded reduced fuel oil, Emulsifying effectiveness and combustion efficiency are same.
Environmental effect tests table：
Simply technical scheme is explained in detail for above-mentioned embodiment, and the present invention is not only limited only to Above-described embodiment, it will be understood by those skilled in the art that it is every according to above-mentioned principle and spirit improvement on the basis of the present invention, Substitute, all should be within protection scope of the present invention.

Claims (10)

1. a kind of expanded liquid of reduced fuel oil, it is characterised in that include the raw material of following parts by weight：
Component A 40-400
Component B 40-400
Component C 5-100
Sodium chloride 5-100
Purified water 1000
The component A is potassium hydroxide or sodium nitrate；The component B is calcium chloride or calcium sulfate or calcium phosphate；The component C is Sodium Alginate or potassium alginate or xanthans.
2. the expanded liquid of reduced fuel oil according to claim 1, it is characterised in that：The parts by weight of the component A are 100- 400。
3. the expanded liquid of reduced fuel oil according to claim 1 or 2, it is characterised in that：The parts by weight of the component B are 100- 400。
4. according to any described expanded liquid of reduced fuel oil of claim 1-3, it is characterised in that：In the expanded liquid of reduced fuel oil Added with compound or the compound of chloride ion-containing containing magnesium ion.
5. the expanded liquid of reduced fuel oil according to claim 4, it is characterised in that：The parts by weight of the compound containing magnesium ion For 16-60.
6. the expanded liquid of reduced fuel oil according to claim 4, it is characterised in that：The parts by weight of the chloride ion-containing compound For 31-115.
7. according to any described expanded liquid of reduced fuel oil of claim 1-6, it is characterised in that：The purified water is by purifying Running water or industrial water or underground water after processing.
A kind of 8. expanded reduced fuel oil, it is characterised in that：The raw material of following percentage by weight is well mixed：
Base oil 50%-90%
Purified water 10%-50%
The expanded liquid 0.01%-0.45% of reduced fuel oil
The expanded liquid of reduced fuel oil is the expanded liquid of reduced fuel oil described in claim any one of 1-6.
9. expanded reduced fuel oil according to claim 8, it is characterised in that：The base oil is heavy hydrocarbon oil or crude oil Or tar sand oil or oil rock is oily or industrial excessive fuel consumption.
10. expanded reduced fuel oil according to claim 8, it is characterised in that：Each raw material of the expanded reduced fuel oil Percentage by weight is：
Base oil 70%-80%
Purified water 20%-30%
The expanded liquid 0.2%-0.4% of reduced fuel oil.
CN201610413848.6A 2016-06-14 2016-06-14 A kind of expanded liquid of reduced fuel oil and expanded reduced fuel oil Pending CN107502390A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112063423A (en) * 2019-09-11 2020-12-11 刘士永 Puffing liquid, preparation method thereof and puffing liquid fuel oil

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1818039A (en) * 2006-03-01 2006-08-16 朴仁洙 Formulating method for heavy fuel oil additive and emulsified heavy fuel oil

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1818039A (en) * 2006-03-01 2006-08-16 朴仁洙 Formulating method for heavy fuel oil additive and emulsified heavy fuel oil

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112063423A (en) * 2019-09-11 2020-12-11 刘士永 Puffing liquid, preparation method thereof and puffing liquid fuel oil

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