CN107501846A - A kind of wear-resistant high polymer material - Google Patents
A kind of wear-resistant high polymer material Download PDFInfo
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- CN107501846A CN107501846A CN201710746484.8A CN201710746484A CN107501846A CN 107501846 A CN107501846 A CN 107501846A CN 201710746484 A CN201710746484 A CN 201710746484A CN 107501846 A CN107501846 A CN 107501846A
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- parts
- wear
- high polymer
- polymer material
- resistant high
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
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Abstract
The present invention relates to a kind of wear-resistant high polymer material, the wear-resistant high polymer material is made up of the component of following parts by weight：60 parts of ABS material 40 part, 40 parts of glass fibre 20 part, 5 parts of anti-wear agent 3 part, 2 parts of coupling agent 1 part, 2 parts of antioxidant 1 part, 1.5 parts of lubricant 0.5 part；Wherein, the lubricant is the mixture of calcium stearate, zinc stearate and stearic amide, and the mass ratio of calcium stearate, zinc stearate and stearic amide is 1:1.1~1.5:1.The advantage of the invention is that：The present invention by ABS material and glass fibre, anti-wear agent etc. be blended made of wear-resistant high polymer material there is very high surface abrasion resistance, compensate for the wear-resisting insufficient defect of ABS material；In addition, compared with existing wear-resistant high polymer material, the lubricant in formula uses three components synergy instead, can effectively strengthen greasy property between reinforcing material and resin, and then improves the processing type of composite, while decreases the usage amount of auxiliary agent in formula.
Description
Technical field
The invention belongs to technical field of polymer materials, more particularly to a kind of wear-resistant high polymer material.
Background technology
ABS is the terpolymer of acrylonitrile, butadiene and styrene, has good combination property, as shock resistance is strong
Height, stable chemical performance, high heat resistance, fire-retardant etc. are spent, therefore is widely used in various machinery, instrument and equipment and synthetic plastics
In material.But ABS case hardness is poor, product is easily scraped off, it is impossible to is met long-term use of.
For above-mentioned phenomenon, patent CN105017707A discloses a kind of high-abrasive material, and it uses following parts by weight
Raw material is made：35 parts -75 parts of ABS material, 20 parts -30 parts of glass fibre, 1 part -10 parts of anti-wear agent, 1 part -5 parts of coupling agent, antioxygen
0.5 part -1 part of agent, 0.5 part -1 part of lubricant.Made of ABS material and glass fibre, anti-wear agent etc. are blended the present invention
Wear-resistant high polymer material has very high surface abrasion resistance, compensate for the wear-resisting insufficient defect of ABS material.The present invention has comprehensive
Superior performance is closed, the advantages that having a wide range of application, but still suffers from the shortcomings that certain：In formula, lubricant is all in specific select
Using one pack system material auxiliary agent or bi-component material auxiliary agent, thus addition is relatively more, and fouling occurs in high polymer material
Precipitation phenomenon.
Therefore, research and development one kind can reduce auxiliary dosage in formula and high polymer material can be avoided fouling precipitation occur now
The wear-resistant high polymer material of elephant is necessary.
The content of the invention
Auxiliary dosage in formula can be reduced the technical problem to be solved in the present invention is to provide one kind and can avoid high score
There is the wear-resistant high polymer material of fouling precipitation phenomenon in sub- material.
In order to solve the above technical problems, the technical scheme is that：A kind of wear-resistant high polymer material, its innovative point exist
In：The wear-resistant high polymer material is made up of the component of following parts by weight：40 parts -60 parts of ABS material, glass fibre 20
- 40 parts of part, 3 parts -5 parts of anti-wear agent, 1 part -2 parts of coupling agent, 1 part -2 parts of antioxidant, 0.5 part -1.5 parts of lubricant；Wherein, it is described
Lubricant is the mixture of calcium stearate, zinc stearate and stearic amide, and calcium stearate, zinc stearate and stearic amide
Mass ratio be 1：1.1~1.5:1.
Further, the anti-wear agent uses PE-g-MAH copolymers, MAH weight hundred in the PE-g-MAH copolymers
It is 2%-4% to divide than content.
Further, the coupling agent is any of coupling agent KH550 or coupling agent KH560.
Further, the antioxidant is from double stearyl alcohol pentaerythritol diphosphites or three (2,4- bis- uncles
Any of butyl phenyl) phosphite ester.
The advantage of the invention is that：The present invention by ABS material and glass fibre, anti-wear agent etc. be blended made of it is wear-resisting
Damage high polymer material has very high surface abrasion resistance, compensate for the wear-resisting insufficient defect of ABS material；In addition, with it is existing wear-resisting
Damage high polymer material is compared, and the lubricant in formula uses three components synergy instead, can effectively strengthen reinforcing material and resin it
Between greasy property, and then improve the processing type of composite, while decrease the usage amount of auxiliary agent in formula；And lubricant
It is 1 from mass ratio：1.1~1.5:The mixture of 1 calcium stearate, zinc stearate and stearic amide, wherein, stearic acid
The dosage of zinc is slightly more relative to the dosage of other two components, and the quality proportioning can be while effectively lubricating performance be met, moreover it is possible to
High polymer material is enough avoided fouling precipitation phenomenon occur.
Embodiment
The following examples can make professional and technical personnel that the present invention be more fully understood, but therefore not send out this
It is bright to be limited among described scope of embodiments.
Wear-resistant high polymer material of the invention, the wear-resistant high polymer material are made up of the component of following parts by weight：
40 parts -60 parts of ABS material, 20 parts -40 parts of glass fibre, 3 parts -5 parts of anti-wear agent, 1 part -2 parts of coupling agent, 1 part -2 parts of antioxidant,
0.5 part -1.5 parts of lubricant；Wherein, the lubricant is the mixture of calcium stearate, zinc stearate and stearic amide, and firmly
The mass ratio of resin acid calcium, zinc stearate and stearic amide is 1：1.1~1.5:1.
As embodiment, more specifically embodiment is that the anti-wear agent uses PE-g-MAH copolymers, the PE-g-
MAH weight percent content is 2%-4% in MAH copolymers；Coupling agent is appointing in coupling agent KH550 or coupling agent KH560
One kind, preferably coupling agent KH550；Antioxidant is from double stearyl alcohol pentaerythritol diphosphites or three (2,4- bis- uncles
Any of butyl phenyl) phosphite ester, preferably, from three (2,4- di-tert-butyl-phenyl) phosphite esters.
The wear-resistant high polymer material of the present invention is described in detail below by specific embodiment：
Embodiment 1
The present embodiment is wear-resistant high polymer material, the wear-resistant high polymer material are made up of the component of following parts by weight：ABS
40 parts of material, 20 parts of glass fibre, 3 parts of anti-wear agent, coupling agent KH5501 parts, three (2,4- di-tert-butyl-phenyl) phosphite esters 1
Part, 0.5 part of lubricant；Wherein, the lubricant is the mixture of calcium stearate, zinc stearate and stearic amide, and stearic
The mass ratio of sour calcium, zinc stearate and stearic amide is 1： 1.1:1；Anti-wear agent uses PE-g-MAH copolymers, the PE-
MAH weight percent content is 2%-4% in g-MAH copolymers.
Embodiment 2
The present embodiment is wear-resistant high polymer material, the wear-resistant high polymer material are made up of the component of following parts by weight：ABS
40 parts of material, 20 parts of glass fibre, 3 parts of anti-wear agent, coupling agent KH5501 parts, three (2,4- di-tert-butyl-phenyl) phosphite esters 1
Part, 0.5 part of lubricant；Wherein, the lubricant is the mixture of calcium stearate, zinc stearate and stearic amide, and stearic
The mass ratio of sour calcium, zinc stearate and stearic amide is 1： 1.5:1；Anti-wear agent uses PE-g-MAH copolymers, the PE-
MAH weight percent content is 2%-4% in g-MAH copolymers.
Embodiment 3
The present embodiment is wear-resistant high polymer material, the wear-resistant high polymer material are made up of the component of following parts by weight：ABS
40 parts of material, 20 parts of glass fibre, 3 parts of anti-wear agent, coupling agent KH5501 parts, three (2,4- di-tert-butyl-phenyl) phosphite esters 1
Part, 0.5 part of lubricant；Wherein, the lubricant is the mixture of calcium stearate, zinc stearate and stearic amide, and stearic
The mass ratio of sour calcium, zinc stearate and stearic amide is 1： 1.3:1；Anti-wear agent uses PE-g-MAH copolymers, the PE-
MAH weight percent content is 2%-4% in g-MAH copolymers.
Embodiment 4
The present embodiment is wear-resistant high polymer material, the wear-resistant high polymer material are made up of the component of following parts by weight：ABS
60 parts of material, 40 parts of glass fibre, 5 parts of anti-wear agent, 2 parts of coupling agent KH550, three (2,4- di-tert-butyl-phenyl) phosphite esters 2
Part, 1.5 parts of lubricant；Wherein, the lubricant is the mixture of calcium stearate, zinc stearate and stearic amide, and stearic
The mass ratio of sour calcium, zinc stearate and stearic amide is 1： 1.3:1；Anti-wear agent uses PE-g-MAH copolymers, the PE-
MAH weight percent content is 2%-4% in g-MAH copolymers.
Embodiment 5
The present embodiment is wear-resistant high polymer material, the wear-resistant high polymer material are made up of the component of following parts by weight：ABS
50 parts of material, 30 parts of glass fibre, 4 parts of anti-wear agent, 1.5 parts of coupling agent KH550, three (2,4- di-tert-butyl-phenyl) phosphorous acid
1.5 parts of ester, 1 part of lubricant；Wherein, the lubricant is the mixture of calcium stearate, zinc stearate and stearic amide, and firmly
The mass ratio of resin acid calcium, zinc stearate and stearic amide is 1：1.3:1；Anti-wear agent uses PE-g-MAH copolymers, the PE-
MAH weight percent content is 2%-4% in g-MAH copolymers.
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The skill of the industry
For art personnel it should be appreciated that the present invention is not limited to the above embodiments, described in above-described embodiment and specification is explanation
The principle of the present invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these
Changes and improvements all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and
Its equivalent thereof.
Claims (4)
- A kind of 1. wear-resistant high polymer material, it is characterised in that：The wear-resistant high polymer material is by the group of following parts by weight It is grouped into：40 parts -60 parts of ABS material, 20 parts -40 parts of glass fibre, 3 parts -5 parts of anti-wear agent, 1 part -2 parts of coupling agent, antioxidant 1 Part -2 parts, 0.5 part -1.5 parts of lubricant；Wherein, the lubricant is the mixing of calcium stearate, zinc stearate and stearic amide Thing, and the mass ratio of calcium stearate, zinc stearate and stearic amide is 1：1.1~1.5:1.
- 2. wear-resistant high polymer material according to claim 1, it is characterised in that：The anti-wear agent is total to using PE-g-MAH Polymers, MAH weight percent content is 2%-4% in the PE-g-MAH copolymers.
- 3. wear-resistant high polymer material according to claim 1, it is characterised in that：The coupling agent is coupling agent KH550 Or any of coupling agent KH560.
- 4. wear-resistant high polymer material according to claim 1, it is characterised in that：The antioxidant is from double octadecanes Any of base alcohol pentaerythritol diphosphites or three (2,4- di-tert-butyl-phenyl) phosphite esters.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710746484.8A CN107501846A (en) | 2017-08-27 | 2017-08-27 | A kind of wear-resistant high polymer material |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710746484.8A CN107501846A (en) | 2017-08-27 | 2017-08-27 | A kind of wear-resistant high polymer material |
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| Publication Number | Publication Date |
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| CN107501846A true CN107501846A (en) | 2017-12-22 |
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| CN201710746484.8A Pending CN107501846A (en) | 2017-08-27 | 2017-08-27 | A kind of wear-resistant high polymer material |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111849070A (en) * | 2020-06-08 | 2020-10-30 | 龙云河 | Flame-retardant high polymer material |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105017707A (en) * | 2014-04-22 | 2015-11-04 | 上海纽恩特实业有限公司 | Wear resistant polymer material |
| CN105566838A (en) * | 2015-12-15 | 2016-05-11 | 安徽瑞研新材料技术研究院有限公司 | Wear-resistant high-polymer material |
-
2017
- 2017-08-27 CN CN201710746484.8A patent/CN107501846A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105017707A (en) * | 2014-04-22 | 2015-11-04 | 上海纽恩特实业有限公司 | Wear resistant polymer material |
| CN105566838A (en) * | 2015-12-15 | 2016-05-11 | 安徽瑞研新材料技术研究院有限公司 | Wear-resistant high-polymer material |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111849070A (en) * | 2020-06-08 | 2020-10-30 | 龙云河 | Flame-retardant high polymer material |
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Application publication date: 20171222 |