CN105566838A - Wear-resistant high-polymer material - Google Patents
Wear-resistant high-polymer material Download PDFInfo
- Publication number
- CN105566838A CN105566838A CN201510946883.XA CN201510946883A CN105566838A CN 105566838 A CN105566838 A CN 105566838A CN 201510946883 A CN201510946883 A CN 201510946883A CN 105566838 A CN105566838 A CN 105566838A
- Authority
- CN
- China
- Prior art keywords
- wear
- macromolecule material
- resistant macromolecule
- polymer material
- resistant high
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention relates to a wear-resistant high-polymer material. The wear-resistant high-polymer material is prepared by the following steps: mixing an ABS (acrylonitrile-butadiene-styrene) material, glass fibers, an anti-wear agent, a coupling agent, an antioxidant and a lubricant, plastifying, carrying out extrusion granulation, and cooling to prepare the wear-resistant high-polymer material. The anti-wear agent preferably adopts a PE-g-MAH (polyethylene-grafted-maleic anhydride) copolymer, and the MAH accounts for 1-3 wt% of the PE-g-MAH copolymer; the coupling agent preferably adopts KH550 or KH560; asnd the antioxidant is selected from at least one of pentaerythritol tetra[beta-(3,5-di-tert-butyl4-hydroxyphenyl)propionate], triethylene glycol bis[beta-(3-tert-butyl-4-hydroxy-5-methylphenyl)propionate], bis octadecyl-ol pentaerythritol diphosphite and tri(2,4-di-tert-butyl-phenyl)phosphite. The ABS material, glass fibers, anti-wear agent and the like are blended to prepare the wear-resistant high-polymer material, so that the wear-resistant high-polymer material has very high surface wear resistance, and overcomes the defect of insufficient wear resistance of the ABS material. The wear-resistant high-polymer material has the advantages of excellent comprehensive properties, wide application range and the like.
Description
Technical field
The present invention relates to technical field of polymer materials, be specifically related to a kind of high-abrasive material.
Background technology
ABS is vinyl cyanide, divinyl and cinnamic terpolymer, has good over-all properties, as excellent in cushion effect, stable chemical performance, Nai Gaore, fire-retardant etc., is therefore widely used in various machinery, plant and instrument and synthetic plastics material.But the surface hardness of ABS is poor, and goods are easily scraped off, life-time service can not be met.
Summary of the invention
The object of the invention is to, a kind of wear-resistant macromolecule material is provided, solves above technical problem.
Technical problem solved by the invention can realize by the following technical solutions:
Wear-resistant macromolecule material, adopts the raw material of following parts by weight to make:
The raw material of the following parts by weight of preferred employing is made:
ABS material, glass fibre, anti-wear agent, coupling agent, oxidation inhibitor, lubricant through mixing, plasticizing, extruding pelletization, cooling, are made described wear-resistant macromolecule material by the present invention.
Described anti-wear agent preferably adopts PE-g-MAH multipolymer, and in described PE-g-MAH multipolymer, the weight percent content of MAH is 1%-3%.
Described coupling agent preferably adopts KH550 or KH560.
Described oxidation inhibitor is selected from four [β-(3,5-di-t-butyl 4-hydroxy phenyl) propionic acid] pentaerythritol ester, Triethylene glycol two [β-(3-tertiary butyl-4-hydroxy-5-aminomethyl phenyl) propionic ester], at least one in two stearyl alcohol pentaerythritol diphosphites, three (2,4-di-tert-butyl-phenyl) phosphorous acid ester.
Described lubricant is at least one in silane polymer, whiteruss, solid paraffin, soap, calcium stearate fatty acid amide, tetramethylolmethane stearic acid, calcium stearate, Zinic stearas, stearic amide, methylene bis stearic amide and N, N-ethylene bis stearic acid amide.
During extruding pelletization, adopt twin screw extruder in 210 DEG C of-230 DEG C of temperature ranges, raw material dissolved blended with 170rpm-210rpm rotating speed, then extruding pelletization.
Beneficial effect: ABS material and glass fibre, anti-wear agent etc. are carried out the blended wear-resistant macromolecule material made and had very high surface abrasion resistance by the present invention, compensate for the wear-resisting not enough defect of ABS material.The advantages such as it is superior that the present invention has over-all properties, applied range.
Embodiment
The technique means realized to make the present invention, creation characteristic, reaching object and effect is easy to understand, setting forth the present invention further below.
Wear-resistant macromolecule material, adopts the raw material of following parts by weight to make:
ABS material, glass fibre, anti-wear agent, coupling agent, oxidation inhibitor, lubricant through mixing, plasticizing, extruding pelletization, cooling, are made wear-resistant macromolecule material by the present invention.During extruding pelletization, adopt twin screw extruder in 210 DEG C of-230 DEG C of temperature ranges, raw material dissolved blended with 170rpm-210rpm rotating speed, then extruding pelletization.
Anti-wear agent preferably adopts PE-g-MAH multipolymer, and in PE-g-MAH multipolymer, the weight percent content of MAH is 1%-3%.
Coupling agent preferably adopts KH550 or KH560.
Oxidation inhibitor is selected from four [β-(3,5-di-t-butyl 4-hydroxy phenyl) propionic acid] pentaerythritol ester, Triethylene glycol two [β-(3-tertiary butyl-4-hydroxy-5-aminomethyl phenyl) propionic ester], at least one in two stearyl alcohol pentaerythritol diphosphites, three (2,4-di-tert-butyl-phenyl) phosphorous acid ester.
Lubricant is at least one in silane polymer, whiteruss, solid paraffin, soap, calcium stearate fatty acid amide, tetramethylolmethane stearic acid, calcium stearate, Zinic stearas, stearic amide, methylene bis stearic amide and N, N-ethylene bis stearic acid amide.
Embodiment 1:
Choose the raw material of following parts by weight:
By the ABS material of above-mentioned parts by weight, glass fibre, anti-wear agent, coupling agent, oxidation inhibitor, lubricant through mixing, plasticizing, extruding pelletization, cooling, make wear-resistant macromolecule material.During extruding pelletization, adopt twin screw extruder in 210 DEG C of temperature ranges, raw material dissolved blended with 170rpm rotating speed, then extruding pelletization.
Embodiment 2:
Choose the raw material of following parts by weight:
By the ABS material of above-mentioned parts by weight, glass fibre, anti-wear agent, coupling agent, oxidation inhibitor, lubricant through mixing, plasticizing, extruding pelletization, cooling, make wear-resistant macromolecule material.During extruding pelletization, adopt twin screw extruder in 230 DEG C of temperature ranges, raw material dissolved blended with 210rpm rotating speed, then extruding pelletization.
Embodiment 3:
Choose the raw material of following parts by weight:
The raw material of the following parts by weight of preferred employing is made:
By the ABS material of above-mentioned parts by weight, glass fibre, anti-wear agent, coupling agent, oxidation inhibitor, lubricant through mixing, plasticizing, extruding pelletization, cooling, make wear-resistant macromolecule material.During extruding pelletization, adopt twin screw extruder in 220 DEG C of temperature ranges, raw material dissolved blended with 180rpm rotating speed, then extruding pelletization.
More than show and describe ultimate principle of the present invention and principal character and advantage of the present invention.The technician of the industry should understand; the present invention is not restricted to the described embodiments; what describe in above-described embodiment and specification sheets just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.Application claims protection domain is defined by appending claims and equivalent thereof.
Claims (8)
1. wear-resistant macromolecule material, is characterized in that, adopts the raw material of following parts by weight to make:
2. wear-resistant macromolecule material according to claim 1, is characterized in that: adopt the raw material of following parts by weight to make:
3. wear-resistant macromolecule material according to claim 1, is characterized in that: by ABS material, glass fibre, anti-wear agent, coupling agent, oxidation inhibitor, lubricant through mixing, plasticizing, extruding pelletization, cooling, make described wear-resistant macromolecule material.
4. wear-resistant macromolecule material according to claim 1, is characterized in that: described anti-wear agent adopts PE-g-MAH multipolymer, and in described PE-g-MAH multipolymer, the weight percent content of MAH is 1%-3%.
5. wear-resistant macromolecule material according to claim 1, is characterized in that: described coupling agent adopts KH550 or KH560.
6. wear-resistant macromolecule material according to claim 1, it is characterized in that: described oxidation inhibitor is selected from four [β-(3,5-di-t-butyl 4-hydroxy phenyl) propionic acid] pentaerythritol ester, Triethylene glycol two [β-(3-tertiary butyl-4-hydroxy-5-aminomethyl phenyl) propionic ester], at least one in two stearyl alcohol pentaerythritol diphosphites, three (2,4-di-tert-butyl-phenyl) phosphorous acid ester.
7. wear-resistant macromolecule material according to claim 1, it is characterized in that: described lubricant is at least one in silane polymer, whiteruss, solid paraffin, soap, calcium stearate fatty acid amide, tetramethylolmethane stearic acid, calcium stearate, Zinic stearas, stearic amide, methylene bis stearic amide and N, N-ethylene bis stearic acid amide.
8. wear-resistant macromolecule material according to claim 1, is characterized in that: during extruding pelletization, adopts twin screw extruder in 210 DEG C of-230 DEG C of temperature ranges, dissolves raw material blended with 170rpm-210rpm rotating speed, then extruding pelletization.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510946883.XA CN105566838A (en) | 2015-12-15 | 2015-12-15 | Wear-resistant high-polymer material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510946883.XA CN105566838A (en) | 2015-12-15 | 2015-12-15 | Wear-resistant high-polymer material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105566838A true CN105566838A (en) | 2016-05-11 |
Family
ID=55877511
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510946883.XA Withdrawn CN105566838A (en) | 2015-12-15 | 2015-12-15 | Wear-resistant high-polymer material |
Country Status (1)
| Country | Link |
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| CN (1) | CN105566838A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107189326A (en) * | 2017-05-27 | 2017-09-22 | 南通成山高分子材料有限公司 | A kind of wear-resistant macromolecule material |
| CN107383755A (en) * | 2017-08-27 | 2017-11-24 | 南通成山高分子材料有限公司 | A kind of environment-friendly type wear-resistant macromolecule material |
| CN107383756A (en) * | 2017-08-27 | 2017-11-24 | 南通成山高分子材料有限公司 | A kind of wear-resistant macromolecule material |
| CN107501846A (en) * | 2017-08-27 | 2017-12-22 | 南通成山高分子材料有限公司 | A kind of wear-resistant high polymer material |
| CN107501848A (en) * | 2017-08-27 | 2017-12-22 | 南通成山高分子材料有限公司 | A kind of preparation method of environment-friendly type wear-resistant macromolecule material |
| CN107501847A (en) * | 2017-08-27 | 2017-12-22 | 南通成山高分子材料有限公司 | A kind of preparation method of wear-resistant macromolecule material |
| CN107523003A (en) * | 2017-08-27 | 2017-12-29 | 南通成山高分子材料有限公司 | A kind of preparation method of wear-resistant high polymer material |
-
2015
- 2015-12-15 CN CN201510946883.XA patent/CN105566838A/en not_active Withdrawn
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107189326A (en) * | 2017-05-27 | 2017-09-22 | 南通成山高分子材料有限公司 | A kind of wear-resistant macromolecule material |
| CN107383755A (en) * | 2017-08-27 | 2017-11-24 | 南通成山高分子材料有限公司 | A kind of environment-friendly type wear-resistant macromolecule material |
| CN107383756A (en) * | 2017-08-27 | 2017-11-24 | 南通成山高分子材料有限公司 | A kind of wear-resistant macromolecule material |
| CN107501846A (en) * | 2017-08-27 | 2017-12-22 | 南通成山高分子材料有限公司 | A kind of wear-resistant high polymer material |
| CN107501848A (en) * | 2017-08-27 | 2017-12-22 | 南通成山高分子材料有限公司 | A kind of preparation method of environment-friendly type wear-resistant macromolecule material |
| CN107501847A (en) * | 2017-08-27 | 2017-12-22 | 南通成山高分子材料有限公司 | A kind of preparation method of wear-resistant macromolecule material |
| CN107523003A (en) * | 2017-08-27 | 2017-12-29 | 南通成山高分子材料有限公司 | A kind of preparation method of wear-resistant high polymer material |
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| C06 | Publication | ||
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| WW01 | Invention patent application withdrawn after publication | ||
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Application publication date: 20160511 |