CN107495357A - The preparation method and product of abalone shells water-soluble extractive and the shell of seaear - Google Patents
The preparation method and product of abalone shells water-soluble extractive and the shell of seaear Download PDFInfo
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- CN107495357A CN107495357A CN201710827147.1A CN201710827147A CN107495357A CN 107495357 A CN107495357 A CN 107495357A CN 201710827147 A CN201710827147 A CN 201710827147A CN 107495357 A CN107495357 A CN 107495357A
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- Prior art keywords
- shell
- water
- abalone shells
- abalone
- seaear
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Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000000126 substance Substances 0.000 claims abstract description 11
- 238000004519 manufacturing process Methods 0.000 claims abstract description 7
- 238000001694 spray drying Methods 0.000 claims abstract description 6
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 claims abstract description 4
- 239000000284 extract Substances 0.000 claims description 25
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 24
- 102000008186 Collagen Human genes 0.000 claims description 18
- 108010035532 Collagen Proteins 0.000 claims description 18
- 229920001436 collagen Polymers 0.000 claims description 18
- 239000002245 particle Substances 0.000 claims description 13
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 claims description 11
- 235000012907 honey Nutrition 0.000 claims description 11
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 238000012545 processing Methods 0.000 claims description 7
- JPOKAKNGULMYHZ-UILVTTEASA-N (2s)-6-amino-2-[[(2s)-2-[[(2s)-2-[[(2s)-2-[[(2s)-6-amino-2-[[(2s)-2-[[(2s)-6-amino-2-[[(2s)-6-amino-2-[[(2s)-2-amino-5-(diaminomethylideneamino)pentanoyl]amino]hexanoyl]amino]hexanoyl]amino]-3-(4-hydroxyphenyl)propanoyl]amino]hexanoyl]amino]-3-(4-hydroxyp Chemical compound C([C@@H](C(=O)N[C@@H](CCCN=C(N)N)C(=O)N[C@@H](CCCN=C(N)N)C(=O)N[C@@H](CCCCN)C(N)=O)NC(=O)[C@H](CCCCN)NC(=O)[C@H](CC=1C=CC(O)=CC=1)NC(=O)[C@H](CCCCN)NC(=O)[C@H](CCCCN)NC(=O)[C@@H](N)CCCN=C(N)N)C1=CC=C(O)C=C1 JPOKAKNGULMYHZ-UILVTTEASA-N 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 241000143510 Haliotis discus hannai Species 0.000 claims description 5
- 239000004677 Nylon Substances 0.000 claims description 5
- 239000007910 chewable tablet Substances 0.000 claims description 5
- 239000012141 concentrate Substances 0.000 claims description 5
- 235000019359 magnesium stearate Nutrition 0.000 claims description 5
- 229920001778 nylon Polymers 0.000 claims description 5
- 108090000765 processed proteins & peptides Proteins 0.000 claims description 5
- 241001489138 Haliotis diversicolor Species 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 241000237890 Haliotis Species 0.000 claims description 3
- 241001494479 Pecora Species 0.000 claims description 3
- 239000000470 constituent Substances 0.000 claims description 2
- 239000004744 fabric Substances 0.000 claims description 2
- 238000000605 extraction Methods 0.000 abstract description 9
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract description 6
- 229910052791 calcium Inorganic materials 0.000 abstract description 6
- 239000011575 calcium Substances 0.000 abstract description 6
- YASYEJJMZJALEJ-UHFFFAOYSA-N Citric acid monohydrate Chemical compound O.OC(=O)CC(O)(C(O)=O)CC(O)=O YASYEJJMZJALEJ-UHFFFAOYSA-N 0.000 abstract description 5
- 238000001354 calcination Methods 0.000 abstract description 3
- 230000036541 health Effects 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 3
- 230000003064 anti-oxidating effect Effects 0.000 abstract description 2
- 229920000858 Cyclodextrin Polymers 0.000 abstract 1
- 239000001116 FEMA 4028 Substances 0.000 abstract 1
- 235000011175 beta-cyclodextrine Nutrition 0.000 abstract 1
- 229960004853 betadex Drugs 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 239000010903 husk Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 description 19
- 230000000694 effects Effects 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- 235000001014 amino acid Nutrition 0.000 description 5
- 150000001413 amino acids Chemical class 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 102000034240 fibrous proteins Human genes 0.000 description 4
- 108091005899 fibrous proteins Proteins 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229920001353 Dextrin Polymers 0.000 description 3
- 239000004375 Dextrin Substances 0.000 description 3
- 102000003886 Glycoproteins Human genes 0.000 description 3
- 108090000288 Glycoproteins Proteins 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 230000003078 antioxidant effect Effects 0.000 description 3
- 235000006708 antioxidants Nutrition 0.000 description 3
- 235000019425 dextrin Nutrition 0.000 description 3
- 150000004676 glycans Chemical class 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 239000005416 organic matter Substances 0.000 description 3
- 229920001282 polysaccharide Polymers 0.000 description 3
- 239000005017 polysaccharide Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000011573 trace mineral Substances 0.000 description 3
- 235000013619 trace mineral Nutrition 0.000 description 3
- DWNBOPVKNPVNQG-LURJTMIESA-N (2s)-4-hydroxy-2-(propylamino)butanoic acid Chemical compound CCCN[C@H](C(O)=O)CCO DWNBOPVKNPVNQG-LURJTMIESA-N 0.000 description 2
- 241000234427 Asparagus Species 0.000 description 2
- 235000005340 Asparagus officinalis Nutrition 0.000 description 2
- 101100396994 Drosophila melanogaster Inos gene Proteins 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- 208000001953 Hypotension Diseases 0.000 description 2
- 235000003704 aspartic acid Nutrition 0.000 description 2
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 235000013402 health food Nutrition 0.000 description 2
- 208000021822 hypotensive Diseases 0.000 description 2
- 210000001328 optic nerve Anatomy 0.000 description 2
- 235000018102 proteins Nutrition 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 108010072661 Angiotensin Amide Proteins 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- 208000002177 Cataract Diseases 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- PMMYEEVYMWASQN-DMTCNVIQSA-N Hydroxyproline Chemical compound O[C@H]1CN[C@H](C(O)=O)C1 PMMYEEVYMWASQN-DMTCNVIQSA-N 0.000 description 1
- CZGUSIXMZVURDU-JZXHSEFVSA-N Ile(5)-angiotensin II Chemical compound C([C@@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CC=1NC=NC=1)C(=O)N1[C@@H](CCC1)C(=O)N[C@@H](CC=1C=CC=CC=1)C([O-])=O)NC(=O)[C@@H](NC(=O)[C@H](CCCNC(N)=[NH2+])NC(=O)[C@@H]([NH3+])CC([O-])=O)C(C)C)C1=CC=C(O)C=C1 CZGUSIXMZVURDU-JZXHSEFVSA-N 0.000 description 1
- 108010089430 Phosphoproteins Proteins 0.000 description 1
- 102000007982 Phosphoproteins Human genes 0.000 description 1
- ONIBWKKTOPOVIA-UHFFFAOYSA-N Proline Natural products OC(=O)C1CCCN1 ONIBWKKTOPOVIA-UHFFFAOYSA-N 0.000 description 1
- 102000016611 Proteoglycans Human genes 0.000 description 1
- 108010067787 Proteoglycans Proteins 0.000 description 1
- 206010046851 Uveitis Diseases 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 230000003276 anti-hypertensive effect Effects 0.000 description 1
- 230000002959 anti-hypotensive effect Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000004087 circulation Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007850 degeneration Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- PMMYEEVYMWASQN-UHFFFAOYSA-N dl-hydroxyproline Natural products OC1C[NH2+]C(C([O-])=O)C1 PMMYEEVYMWASQN-UHFFFAOYSA-N 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000003837 high-temperature calcination Methods 0.000 description 1
- 229960002591 hydroxyproline Drugs 0.000 description 1
- 230000001077 hypotensive effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000000338 in vitro Methods 0.000 description 1
- 206010023332 keratitis Diseases 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- CSHFHJNMIMPJST-HOTGVXAUSA-N methyl (2s)-2-[[(2s)-2-[[2-[(2-aminoacetyl)amino]acetyl]amino]-3-phenylpropanoyl]amino]-4-methylpentanoate Chemical compound NCC(=O)NCC(=O)N[C@H](C(=O)N[C@@H](CC(C)C)C(=O)OC)CC1=CC=CC=C1 CSHFHJNMIMPJST-HOTGVXAUSA-N 0.000 description 1
- 230000004089 microcirculation Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 108010048734 sclerotin Proteins 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- FGMPLJWBKKVCDB-UHFFFAOYSA-N trans-L-hydroxy-proline Natural products ON1CCCC1C(O)=O FGMPLJWBKKVCDB-UHFFFAOYSA-N 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
- A23L33/10—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L17/00—Food-from-the-sea products; Fish products; Fish meal; Fish-egg substitutes; Preparation or treatment thereof
- A23L17/50—Molluscs
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Food Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Polymers & Plastics (AREA)
- Mycology (AREA)
- Marine Sciences & Fisheries (AREA)
- Zoology (AREA)
- Medicines Containing Material From Animals Or Micro-Organisms (AREA)
- Medicinal Preparation (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses the preparation method and product of a kind of abalone shells water-soluble extractive and the shell of seaear, technical matters is included using abalone shells as raw material, extracted using HTHP citric acid water, the water-soluble substances of extraction is handled by activated carbon, beta cyclodextrin embedding, spray drying are prepared into abalone shells water-soluble extractive；Residue after extraction is by rinsing, drying, calcining, crushing and be prepared into the shell of seaear；And it is prepared into eyeshield using abalone shells water-soluble extractive and the shell of seaear and replenishes the calcium the health product of dual-use function.The technology of the present invention improves conventional art and utilizes the shortcomings that insufficient to abalone husk as raw material, reduces the discharge of extraction preparation process discarded object, reduces production cost.Moreover, provide reference by with good anti-oxidation function and protect eyes function to develop new product using abalone shells with functional health care product prepared by abalone shells water-soluble extractive and the shell of seaear.
Description
Technical field
The present invention relates to processing of aquatic products accessory substance higher value application field, relates in particular to one kind and uses HTHP
Citric acid water extracts the method and product of water-soluble substances and the shell of seaear from abalone shells, and utilizes extract development function health care
The technology of product.
Background technology
The abalone yield aboundresources in Fujian Province, 2016 annual productions already exceed 100,000 tons, therefore abalone fabricated product
Kind and yield are also continuously increased to improve value-added content of product, and work in-process will necessarily produce substantial amounts of abalone shells.Abalone shells,
The also referred to as shell of seaear, animal Haliotis diversicolor, haliotis discus hannai Ino, sheep Bao, haliotis ruber, Er Bao and Bai Bao etc. shell are belonged to for Bao Kebao.Abalone
Shell is to include 95% calcium carbonate and 0.3% ~ 5% organic matter by cuticula, prismatic layer and nacre up of three layers, chemical composition.
Bao shell water-soluble organic matter is mainly by glycoprotein, phosphoprotein, the mixture of proteoglycans, glutinous polysaccharide and other protein composition.
It is reported that abalone shells water extract, which has, suppresses hypertensin conversion enzyme activity antihypertensive function, to treatment cataract, cornea
Inflammation, uveitis etc. have the effect of certain, and good antioxidation activity in vitro.China Patent Publication No. CN 101724092
B discloses a kind of method for extracting oxidation resistant water-soluble matter of abalone shell, but this method extraction yield is relatively low.It is however, most of special
Profit is primarily upon the utilization of calcium in abalone shells, but ignores the extraction of the active material in abalone shells.
The content of the invention
Water solubility is extracted from abalone shells using HTHP citric acid water it is an object of the present invention to provide one kind
The method of material and the shell of seaear, it is using abalone shells as raw material, mainly using the processing of HTHP citric acid water and high-temperature calcination
The method that method prepares abalone shells water-soluble extractive and the shell of seaear.
It is another object of the present invention to provide product prepared by a kind of abalone shells water-soluble extractive and the shell of seaear, its
With anti-oxidant, hypotensive and calcium-enriching function.
To achieve these goals, the technical scheme is that：
The present invention is a kind of preparation method of abalone shells water-soluble extractive and the shell of seaear, is comprised the following steps：(1) extract：Bao
Fish shell adds aqueous citric acid solution by 11 ~ 13 (w/v) solid-liquid ratios, extracts the min of 20 min ~ 60, cooling at high temperature under high pressure
After to room temperature abalone shells extract and residue are filtrated to get with the mesh nylon filter screen cloth of 200 mesh ~ 400；(2) water-soluble substances
Prepare：After the abalone shells extract that step (1) obtains is handled using activated carbon, it is by being concentrated in vacuo to solid content
10% ~ 20%, 20% ~ 30% beta-schardinger dextrin of the volume of concentrate is added, spray drying is prepared into abalone shells water-soluble extractive；
(3) preparation of the shell of seaear：After the residue pure water rinse that step (1) is obtained, through processing, being cooled to room temperature, be ground into
The Abalone shell of the mesh of 120 mesh ~ 180；(4) production：The water-soluble extraction of abalone shells for taking a certain amount of step (2) to prepare
Abalone shell prepared by thing and step (3), adds collagen peptide, asparatate and honey, is well mixed, product is made
Grain, 1% ~ 5% magnesium stearate of granular mass is added, be well mixed, be pressed into chewable tablets.
In step (1), described aqueous citric acid solution mass concentration is 0.1% ~ 0.5%；HTHP refers to temperature
For 170 DEG C ~ 260 DEG C, pressure is the MPa of 1.0 MPa ~ 5.0.
In step (2), described activated carbon treatment conditions are：The addition of activated carbon is water-soluble substances extraction liquids
0.2% ~ 0.5% long-pending (w/v), the min of 20 min ~ 60 is incubated at 30 DEG C ~ 40 DEG C, then utilizes disk centrifugal separator to remove activity
Charcoal.
In step (3), described processing condition is：The filter residue that first pure water rinse is crossed, which is placed at 80 DEG C ~ 100 DEG C, to be dried
The h of dry 1 h ~ 3, then be placed at 200 DEG C ~ 300 DEG C and calcine the h of 1 h ~ 3.
In step (4), the constituent content of described product particle by weight is：Abalone shells water-soluble extractive 30% ~
40%th, Abalone shell 30% ~ 40%, collagen peptide 18% ~ 30%, asparatate 1% ~ 5%, honey 1% ~ 5%.
Described abalone shells are Haliotis diversicolor, haliotis discus hannai Ino, sheep Bao, haliotis ruber, Er Bao and Bai Bao etc. shell.
The present invention is product prepared by a kind of abalone shells water-soluble extractive and the shell of seaear, each group in described product particle
Point content is respectively：Abalone shells water-soluble extractive 30% ~ 40%, Abalone shell 30% ~ 40%, collagen peptide 18% ~ 30%, lucid asparagus
Propylhomoserin 1% ~ 5%, honey 1% ~ 5%.
After such scheme, abalone shells are handled using HTHP citric acid water due to of the invention, abalone shells
In the organic matter such as scleroprotein, collagen and glycoprotein, and part trace element can be extracted efficiently out, be left with
Calcium carbonate is also readily available less than 0.1 μm of stone and determined even if calcining, crush at a lower temperature for the abalone shells of main component
Bright Ultramicro-powder.Moreover, being main component using abalone shells water-soluble extractive and the shell of seaear is extracted, can prepare with antioxygen
The health food of change, hypotensive and calcium-enriching function, meets consumer demand.Therefore the present invention has advantages below：
1st, the present invention is comprehensively utilized using abalone shells extraction water-soluble substances and the shell of seaear, resource, is reduced environmental pollution.
2nd, abalone shells water-soluble extractive prepared by the present invention has good anti-oxidant and protect eyes function.
3rd, the calcining heat of the present invention processing shell of seaear is low, can save the energy.
4th, the dissoluble rate of calcium of the shell of seaear prepared by the present invention is high, by with good calcium-enriching function.
5th, the present invention is strengthened with abalone shells water-soluble extractive and shell of seaear product function activity, it is not easy to the moisture absorption,
It is in good taste, easily it is esthetically acceptable to the consumers.
The present invention is further illustrated for table and specific embodiment below in conjunction with the accompanying drawings.
Brief description of the drawings
Fig. 1 is the inoxidizability figure of abalone shells water-soluble extractive.
Subordinate list explanation
Table 1 forms for the amino acid of abalone shells extract.
Table 2 is the basis of abalone shells water-soluble extractive.
Embodiment
Embodiment 1
The present invention is a kind of preparation method of abalone shells water-soluble extractive and the shell of seaear, is comprised the following steps：
(1) extract：The shell of addition 1kg Haliotis diversicolors and the citric acid solution that 1L mass concentrations are 0.5% in pyroreaction kettle, instead
Answer the temperature and pressure of kettle to improve to 170 DEG C and 1.0 MPa rapidly, room temperature and pressure release, use are cooled to after the min of heat-insulation pressure keeping 60
200 mesh nylon filter screen cloths are filtrated to get abalone shells extract and residue；
(2) preparation of water-soluble substances：In the about 0.9L abalone shells extracts that step (1) obtains, 45g activated carbons are added,
60 min are incubated at 30 DEG C, then remove activated carbon using disk centrifugal separator；100 ml solid contents are obtained by vacuum concentration to contain
The concentrate of amount about 20%, adds 30 g beta-schardinger dextrins, and spray drying is prepared into abalone shells water-soluble extractive；
(3) preparation of the shell of seaear：After the filter residue pure water rinse that step (1) is obtained, it is placed at 100 DEG C and dries 1h, then put
3 h are calcined at 200 DEG C, are cooled to room temperature, are ground into the Abalone shell of 120 mesh；
(4) production：Take abalone shells water-soluble extractive 30g prepared by step (2) and Abalone shell prepared by step (3)
30 g, the g of collagen peptide 30, the g of asparatate 5 and the g of honey 5 are added, be well mixed, product particle is made, adds particle matter
5 g of amount magnesium stearate, it is well mixed, is pressed into chewable tablets.
Embodiment 2
The present invention is a kind of preparation method of abalone shells water-soluble extractive and the shell of seaear, is comprised the following steps：
(1) extract：The shell of addition 1kg haliotis discus hannai Inos and the citric acid solution that 2L mass concentrations are 0.3% in pyroreaction kettle,
The temperature and pressure of reactor is improved rapidly to 210 DEG C and 3.0 MPa, and room temperature simultaneously pressure release is cooled to after the min of heat-insulation pressure keeping 40,
Abalone shells extract and residue are filtrated to get with 300 mesh nylon filter screen cloths；
(2) preparation of water-soluble substances：In the about 1.7L abalone shells extracts that step (1) obtains, 51g activated carbons are added,
40 min are incubated at 35 DEG C, then remove activated carbon using disk centrifugal separator；150 ml solid contents are obtained by vacuum concentration to contain
The concentrate of amount about 15%, adds 32 g beta-schardinger dextrins, and spray drying is prepared into abalone shells water-soluble extractive；
(3) preparation of the shell of seaear：After the filter residue pure water rinse that step (1) is obtained, it is placed at 90 DEG C and dries 2h, then be placed on
2 h are calcined at 250 DEG C, are cooled to room temperature, are ground into the Abalone shell of 150 mesh；
(4) production：Take abalone shells water-soluble extractive 40g prepared by step (2) and Abalone shell prepared by step (3)
35 g, the g of collagen peptide 18, the g of asparatate 4 and the g of honey 3 are added, be well mixed, product particle is made, adds particle matter
3 g of amount magnesium stearate, it is well mixed, is pressed into chewable tablets.
Embodiment 3
The present invention is a kind of preparation method of abalone shells water-soluble extractive and the shell of seaear, is comprised the following steps：
(1) extract：The shell of addition 1kg haliotis discus hannai Inos and the citric acid solution that 3L mass concentrations are 0.1% in pyroreaction kettle,
The temperature and pressure of reactor is improved rapidly to 260 DEG C and 5.0 MPa, and room temperature simultaneously pressure release is cooled to after the min of heat-insulation pressure keeping 40,
Abalone shells extract and residue are filtrated to get with 300 mesh nylon filter screen cloths；
(2) preparation of water-soluble substances：In the about 2.6L abalone shells extracts that step (1) obtains, 52g activated carbons are added,
20 min are incubated at 40 DEG C, then remove activated carbon using disk centrifugal separator；220 ml solid contents are obtained by vacuum concentration to contain
The concentrate of amount about 10%, adds 44 g beta-schardinger dextrins, and spray drying is prepared into abalone shells water-soluble extractive；
(3) preparation of the shell of seaear：After the filter residue pure water rinse that step (1) is obtained, it is placed at 80 DEG C and dries 3h, then be placed on
1 h is calcined at 300 DEG C, is cooled to room temperature, is ground into the Abalone shell of 180 mesh；
(4) production：Take abalone shells water-soluble extractive 32g prepared by step (2) and Abalone shell prepared by step (3)
40 g, the g of collagen peptide 26, the g of asparatate 1 and the g of honey 1 are added, be well mixed, product particle is made, adds particle matter
1 g of amount magnesium stearate, it is well mixed, is pressed into chewable tablets.
2nd, product
The present invention is product made of a kind of subcritical water assistance enzymolysis extraction abalone proteins peptide, each group in described product particle
Point content is respectively：Abalone shells water-soluble extractive 30% ~ 40%, Abalone shell 30% ~ 40%, collagen peptide 18% ~ 30%, lucid asparagus
Propylhomoserin 1% ~ 5%, honey 1% ~ 5%.
Because aqueous citric acid solution can keep liquid condition under conditions of HTHP, the H containing higher concentration+,
There is good effect of extracting to the organic matters such as the scleroprotein in abalone shells, collagen and glycoprotein, and part trace element.
The testing result of the amino acid composition of abalone shells extract is as shown in table 1, as a result finds each in the abalone shells extract of embodiment 1 ~ 3
The ratio that certain rule is presented in amino acid declines, and this is mainly the reason for solid content declines in embodiment.It is noticeable
It is the amino acids characteristic aspartic acid content of sclerotin, amino acids characteristic glycine, the hydroxyproline of collagen
All higher with the content of proline, scleroprotein and collagen in abalone shells are all effectively extracted.
It is as shown in table 2 to the basis testing result of abalone shells water-soluble extractive.As seen from table, abalone shells are water-soluble
Extract is not only rich in albumen and polysaccharide, but also mainly comes containing the trace elements such as abundant calcium and zinc, wherein polysaccharide component
From in the addition of beta-schardinger dextrin.It is reported that collagen and scleroprotein can supplement eyes crystal in Bao shell water-soluble extractive
The effect of collagen in body, optic nerve, nethike embrane, the function of stimulating circulation.Moreover, Bao shell water-soluble extractive is also with good
Good inoxidizability (Fig. 1), can possess the albuminous degeneration for preventing eyes crystalline.Therefore, Bao shell water-soluble extractive will have
There is improvement blood microcirculation, improve the effect such as antioxidant ability of organism, protection optic nerve, and then protect eyes.
Abalone shell prepared by the present invention is canescence, free from extraneous odour.The 5 g shells of seaear are taken to be placed on 90 in 100 ml ultra-pure waters
DEG C h of water-bath 1, the shell of seaear calcium ion stripping quantity that embodiment 1 ~ 3 obtains after testing is 7.5% or so, shows that the present invention prepares
The shell of seaear has good calcium-enriching function.Therefore, according to calcium content, collagen feature amino in abalone shells water-soluble extractive
Acid and the higher reason of aspartic acid content（Table 1, table 2）, utilized by adding collagen peptide, asparatate and honey enhancing
The calcium-enriching function and mouthfeel of health food prepared by abalone shells water-soluble extractive and the shell of seaear are extracted, product is played shield
The double action that eye is replenished the calcium.
The specific embodiment of the present invention is above are only, but the design concept of the present invention is not limited thereto, it is all to utilize this structure
Think the change to present invention progress unsubstantiality, the behavior for invading the scope of the present invention all should be belonged to.
Claims (7)
- A kind of 1. preparation method of abalone shells water-soluble extractive and the shell of seaear, it is characterised in that：Comprise the following steps：(1) extract Take：Abalone shells add aqueous citric acid solution by 11 ~ 13 (w/v) solid-liquid ratios, extract the min of 20 min ~ 60 at high temperature under high pressure, It is cooled to after room temperature and is filtrated to get abalone shells extract and residue with the mesh nylon filter screen cloth of 200 mesh ~ 400；(2) water-soluble thing The preparation of matter：After the abalone shells extract that step (1) obtains is handled using activated carbon, by being concentrated in vacuo to solid content For 10% ~ 20%, 20% ~ 30% beta-schardinger dextrin of the volume of concentrate is added, spray drying is prepared into abalone shells water-soluble extractive； (3) preparation of the shell of seaear：After the residue pure water rinse that step (1) is obtained, through processing, being cooled to room temperature, be ground into The Abalone shell of the mesh of 120 mesh ~ 180；(4) production：Take abalone shells water-soluble extractive and step prepared by step (2) (3) Abalone shell prepared, collagen peptide, asparatate and honey are added, is well mixed, product particle is made, adds 1% ~ 5% magnesium stearate of product particle quality, it is well mixed, is pressed into chewable tablets.
- 2. the preparation method of abalone shells water-soluble extractive as claimed in claim 1 and the shell of seaear, it is characterised in that：In step (1) in, described aqueous citric acid solution mass concentration is 0.1% ~ 0.5%；HTHP refers to that temperature is 170 DEG C ~ 260 DEG C, Pressure is the MPa of 1.0 MPa ~ 5.0.
- 3. the preparation method of abalone shells water-soluble extractive as claimed in claim 1 and the shell of seaear, it is characterised in that：In step (2) in, described activated carbon treatment conditions are：The addition of activated carbon is the 0.2% ~ 0.5% of water-soluble substances extract volume (w/v) min of 20 min ~ 60, is incubated at 30 DEG C ~ 40 DEG C, then utilizes disk centrifugal separator to remove activated carbon.
- 4. the preparation method of abalone shells water-soluble extractive as claimed in claim 1 and the shell of seaear, it is characterised in that：In step (3) in, described processing condition is：The filter residue that first pure water rinse is crossed, which is placed at 80 DEG C ~ 100 DEG C, dries the h of 1 h ~ 3, then puts The h of 1 h ~ 3 is calcined at 200 DEG C ~ 300 DEG C.
- 5. the preparation method of abalone shells water-soluble extractive as claimed in claim 1 and the shell of seaear, it is characterised in that：In step (4) in, the constituent content of described product particle by weight is：Abalone shells water-soluble extractive 30% ~ 40%, Abalone shell 30% ~ 40%, collagen peptide 18% ~ 30%, asparatate 1% ~ 5%, honey 1% ~ 5%.
- 6. the preparation method of abalone shells water-soluble extractive as claimed in claim 1 and the shell of seaear, it is characterised in that：Its feature It is：Described abalone shells are Haliotis diversicolor, haliotis discus hannai Ino, sheep Bao, haliotis ruber, Er Bao and Bai Bao etc. shell.
- A kind of 7. product prepared by abalone shells water-soluble extractive according to claim 1 and the shell of seaear, it is characterised in that： Each component content is respectively in described product particle：Abalone shells water-soluble extractive 30% ~ 40%, Abalone shell 30% ~ 40%, Collagen peptide 18% ~ 30%, asparatate 1% ~ 5%, honey 1% ~ 5%.
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