CN107488408A - A kind of Anti-static adhesive on blue piece and preparation method thereof - Google Patents
A kind of Anti-static adhesive on blue piece and preparation method thereof Download PDFInfo
- Publication number
- CN107488408A CN107488408A CN201710581032.9A CN201710581032A CN107488408A CN 107488408 A CN107488408 A CN 107488408A CN 201710581032 A CN201710581032 A CN 201710581032A CN 107488408 A CN107488408 A CN 107488408A
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D189/00—Coating compositions based on proteins; Coating compositions based on derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/02—Applications for biomedical use
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
Abstract
The present invention relates to a kind of Anti-static adhesive on medical blue piece and preparation method thereof.It after the Anti-static adhesive being prepared is coated on medical blue piece, can make blue piece that there is anlistatig effect, while show smooth exquisiteness.By the material composition of following parts by weight：400~460 parts of water, 15~25 parts of gelatin, 2~4 parts of jelly, 8~11 parts of nonionic surface active agent, 4~6 parts of anionic surfactant, 4~7 parts of brightening agent, 1~3 part of empgen BB, 30~40 parts of spectroscopic pure sodium oxide molybdena, 8~12 parts of alum.Its preparation method includes：A. jelly is configured, is 2 by weight:1 takes gelatin and empgen BB to be well mixed；B. water is added in agitated kettle and gelatin stirs 0.5~1.5 hour；C. jelly is added to stir and be heated to 50 DEG C until jelly is completely dissolved；D. nonionic surfactant quickly stirring 3 minutes are added；E. anion surfactant quickly stirring 3 minutes are added；Etc. step.
Description
Technical field
The present invention relates to a kind of adhesive, more particularly to a kind of Anti-static adhesive and its preparation on medical blue piece
Method.
Background technology
In modern medical service, image film occupies very important position, PET in medical diagnosis on disease（Poly terephthalic acid second
Diol-lipid）Material is wide in medical diagnosis because of its good heat resistance, bending strength and elasticity, its manufactured medical film
General application, but the film texture of pure PET materials is poor, and easy static electrification, the film of static electrification is not suitable for printing, and film
Between easily adsorb.PET materials are exactly that surface is sliding and gloss as another shortcoming of film, are not suitable for writing.
The content of the invention
The first object of the present invention for the easy static electrification of medical blue piece in the prior art, surface is not smooth enough the shortcomings that, carry
For a kind of Anti-static adhesive on medical blue piece, after Anti-static adhesive is coated on medical blue piece, indigo plant can be made
Piece has anlistatig effect, while shows smooth exquisiteness.
The present invention is carried out by the following technical programs：
A kind of Anti-static adhesive on medical blue piece, by the material composition of following parts by weight：400~460 parts of water, gelatin
15~25 parts, 2~4 parts of jelly, 8~11 parts of nonionic surface active agent, 4~6 parts of anionic surfactant, brightening agent
4~7 parts, 1~3 part of empgen BB, 30~40 parts of spectroscopic pure sodium oxide molybdena, 8~12 parts of alum.
Preferably, the Anti-static adhesive on medical blue piece, by the material composition of following parts by weight：Water 410~
450 parts, 18~23 parts of gelatin, 2.5~3.8 parts of jelly, 8.5~10 parts of nonionic surface active agent, anionic surface is lived
4.5~5.5 parts of agent of property, 4.5~6.5 parts of brightening agent, 1~2.5 part of empgen BB, 32~38 parts of spectroscopic pure sodium oxide molybdena,
9~11 parts of alum.
Preferably, the Anti-static adhesive on medical blue piece, by the material composition of following parts by weight：430 parts of water,
20 parts of gelatin, 3.5 parts of jelly, 9.25 parts of nonionic surface active agent, 5 parts of anion surfactant, 5.2 parts of brightening agent,
1.5 parts of empgen BB, 35 parts of spectroscopic pure sodium oxide molybdena, 10.2 parts of alum.
Preferably, described jelly is the mixture of gelatin and empgen BB, gelatin and dodecyl beet
The weight ratio of alkali is 2 ﹕ 1.
Preferably, described nonionic surface active agent is alkyl glucoside, and fatty glyceride, aliphatic acid sorb
One or more in smooth and polysorbate.
Preferably, described anionic surfactant is stearic acid, neopelex and alkyl sulfonic acid
One or more in sodium.
The second object of the present invention is to provide a kind of preparation method of the Anti-static adhesive on medical blue piece, bag
Include following steps：A. jelly is configured, is 2 by weight:1 takes gelatin and empgen BB to be well mixed；B. in agitated kettle
Middle addition water and gelatin stir 0.5~1.5 hour；C. jelly is added to stir and be heated to 50 DEG C until jelly is completely molten
Solution；D. nonionic surfactant quickly stirring 3 minutes are added；E. after adding the quick stirring of anion surfactant 3 minutes；
F. after adding the quick stirring of brightening agent 3 minutes；G. empgen BB is added to stir 3 minutes；H. spectroscopic pure sodium oxide molybdena is added
Stirring 3 minutes；I. alum is added to stir 3 minutes.
Empgen BB in adhesive provided by the invention be eliminate the main factor of adhesive electrostatic, its with
Introduction volume is higher in side, and the antistatic property of adhesive is better, therefore introduces 12 in the jelly of phase configuration before this invention
Alkyl betaine plays anti-static purpose, and empgen BB is introduced back into during adhesive is prepared and further eliminates glue
Glutinous agent electrostatic.
Nonionic surface active agent in adhesive provided by the invention includes hydrophilic radical (polar group) and hydrophobic
Group (non-polar group), according to similar compatibility principle, is combined with gelatin.
Gelatin in adhesive provided by the invention can make the adhesive more smooth exquisiteness in surface after coating.
Spectroscopic pure sodium oxide molybdena in adhesive provided by the invention can improve the intensity of adhesive.
The beneficial effects of the present invention are：After the adhesive of the present invention is coated on medical blue piece, there is anlistatig energy
Power, while the smooth exquisiteness of coating surface；On the other hand, described adhesive, heavy metal, halogen and harmful VOC things are not contained
Matter, thus it is environmentally safe, it is harmless.
Embodiment
Below by embodiment, technical scheme is described in further detail；
Embodiment 1：A kind of Anti-static adhesive on medical blue piece, by the material composition of following parts by weight：400 parts of water,
15 parts of gelatin, 2 parts of jelly, 8 parts of fatty glyceride, 4 parts of neopelex, 4 parts of brightening agent, empgen BB
1 part, 30 parts of spectroscopic pure sodium oxide molybdena, 8 parts of alum.
Preparation method：A. jelly is configured, is 2 by weight:1 takes gelatin and empgen BB to be well mixed；B. exist
Water is added in agitated kettle and gelatin stirs 0.5~1.5 hour；C. jelly is added to stir and be heated to 50 DEG C until jelly is complete
Fully dissolved；D. fatty glyceride quickly stirring 3 minutes are added；E. after adding the quick stirring of neopelex 3 minutes；
F. after adding the quick stirring of brightening agent 3 minutes；G. empgen BB is added to stir 3 minutes；H. spectroscopic pure sodium oxide molybdena is added
Stirring 3 minutes；I. add after alum stirs 3 minutes and produce this product.
Embodiment 2：A kind of Anti-static adhesive on medical blue piece, by the material composition of following parts by weight：Water 460
Part, 25 parts of gelatin, 4 parts of jelly, 11 parts of alkyl glucoside, 6 parts of stearic acid, 7 parts of brightening agent, 3 parts of empgen BB, spectrum
40 parts of pure zirconia sodium, 12 parts of alum.
Preparation method：A. jelly is configured, is 2 by weight:1 takes gelatin and empgen BB to be well mixed；B. exist
Water is added in agitated kettle and gelatin stirs 0.5~1.5 hour；C. jelly is added to stir and be heated to 50 DEG C until jelly is complete
Fully dissolved；D. alkyl glucoside quickly stirring 3 minutes are added；E. after adding the quick stirring of stearic acid 3 minutes；F. brightening agent is added
After quick stirring 3 minutes；G. empgen BB is added to stir 3 minutes；H. spectroscopic pure sodium oxide molybdena is added to stir 3 minutes；i.
Add after alum stirs 3 minutes and produce this product.
Embodiment 3：A kind of Anti-static adhesive on medical blue piece, by the material composition of following parts by weight：Water 410
Part, 18 parts of gelatin, 2.5 parts of jelly, smooth 8.5 parts of fat acid sorb, 4.5 parts of sodium alkyl sulfonate, 4.5 parts of brightening agent, dodecyl sweet tea
1 part of dish alkali, 32 parts of spectroscopic pure sodium oxide molybdena, 9 parts of alum.
Preparation method：A. jelly is configured, is 2 by weight:1 takes gelatin and empgen BB to be well mixed；B. exist
Water is added in agitated kettle and gelatin stirs 0.5~1.5 hour；C. jelly is added to stir and be heated to 50 DEG C until jelly is complete
Fully dissolved；D. the smooth quick stirring of fat acid sorb 3 minutes is added；E. after adding the quick stirring of sodium alkyl sulfonate 3 minutes；F. add and increase
After white agent is quickly stirred 3 minutes；G. empgen BB is added to stir 3 minutes；H. add spectroscopic pure sodium oxide molybdena and stir 3 points
Clock；I. add after alum stirs 3 minutes and produce this product.
Embodiment 4：A kind of Anti-static adhesive on medical blue piece, by the material composition of following parts by weight：Water 450
Part, 23 parts of gelatin, 3.8 parts of jelly, 10 parts of polysorbate, 5.5 parts of sodium alkyl sulfonate, 6.5 parts of brightening agent, empgen BB
2.5 parts, 38 parts of spectroscopic pure sodium oxide molybdena, 11 parts of alum.
Preparation method：A. jelly is configured, is 2 by weight:1 takes gelatin and empgen BB to be well mixed；B. exist
Water is added in agitated kettle and gelatin stirs 0.5~1.5 hour；C. jelly is added to stir and be heated to 50 DEG C until jelly is complete
Fully dissolved；D. polysorbate quickly stirring 3 minutes are added；E. after adding the quick stirring of sodium alkyl sulfonate 3 minutes；F. add and brighten
After agent is quickly stirred 3 minutes；G. empgen BB is added to stir 3 minutes；H. spectroscopic pure sodium oxide molybdena is added to stir 3 minutes；
I. add after alum stirs 3 minutes and produce this product.
Embodiment 5：A kind of Anti-static adhesive on medical blue piece, by the material composition of following parts by weight：Water 430
Part, 20 parts of gelatin, 3.5 parts of jelly, 9.25 parts of polysorbate, 5 parts of stearic acid, 5.2 parts of brightening agent, empgen BB 1.5
Part, 35 parts of spectroscopic pure sodium oxide molybdena, 10.2 parts of alum.
Preparation method：A. jelly is configured, is 2 by weight:1 takes gelatin and empgen BB to be well mixed；B. exist
Water is added in agitated kettle and gelatin stirs 0.5~1.5 hour；C. jelly is added to stir and be heated to 50 DEG C until jelly is complete
Fully dissolved；D. polysorbate quickly stirring 3 minutes are added；E. after adding the quick stirring of stearic acid 3 minutes；F. it is fast to add brightening agent
After speed stirring 3 minutes；G. empgen BB is added to stir 3 minutes；H. spectroscopic pure sodium oxide molybdena is added to stir 3 minutes；I. plus
Enter after alum stirs 3 minutes and produce this product.
Application examples：The adhesive that embodiment 1~5 is prepared pours into static pot respectively, then passes through 80um filter core
Filter back in agitated kettle, the adhesive is uniformly coated on medical blue piece, coating thickness is dry solidification at 9 μm, 125 DEG C
3min forms adhesive layer, 12~14 revs/min of stirring at low speed must be kept in agitated kettle in coating process, to prevent gluing
Agent precipitates.
Specific embodiment described herein is only to spirit explanation for example of the invention.Technology belonging to the present invention is led
The technical staff in domain can be made various modifications or supplement to described specific embodiment or be replaced using similar mode
Generation, but without departing from the spiritual of the present invention or surmount scope defined in appended claims.
Claims (7)
1. a kind of Anti-static adhesive on medical blue piece, it is characterised in that by the material composition of following parts by weight：Water
400~460 parts, 15~25 parts of gelatin, 2~4 parts of jelly, 8~11 parts of nonionic surface active agent, anionic surface activity
4~6 parts of agent, 4~7 parts of brightening agent, 1~3 part of empgen BB, 30~40 parts of spectroscopic pure sodium oxide molybdena, 8~12 parts of alum.
2. a kind of Anti-static adhesive on medical blue piece according to claim 1, it is characterised in that by following heavy
Measure the material composition of part：410~450 parts of water, 18~23 parts of gelatin, 2.5~3.8 parts of jelly, nonionic surface active agent 8.5
~10 parts, 4.5~5.5 parts of anionic surfactant, 4.5~6.5 parts of brightening agent, 1~2.5 part of empgen BB,
32~38 parts of spectroscopic pure sodium oxide molybdena, 9~11 parts of alum.
3. a kind of Anti-static adhesive on medical blue piece according to claim 1, it is characterised in that by following heavy
Measure the material composition of part：430 parts of water, 20 parts of gelatin, 3.5 parts of jelly, 9.25 parts of nonionic surface active agent, anionic surface
5 parts of activating agent, 5.2 parts of brightening agent, 1.5 parts of empgen BB, 35 parts of spectroscopic pure sodium oxide molybdena, 10.2 parts of alum.
A kind of 4. Anti-static adhesive on medical blue piece according to claim 1 or 2 or 3, it is characterised in that institute
The jelly stated is the mixture of gelatin and empgen BB, and the weight ratio of gelatin and empgen BB is 2 ﹕ 1.
A kind of 5. Anti-static adhesive on medical blue piece according to claim 1 or 2 or 3, it is characterised in that institute
The nonionic surface active agent stated is alkyl glucoside, fatty glyceride, one in fatty acid sorbitan and polysorbate
Kind is a variety of.
A kind of 6. Anti-static adhesive on medical blue piece according to claim 1 or 2 or 3, it is characterised in that institute
The anionic surfactant stated is stearic acid, the one or more in neopelex and sodium alkyl sulfonate.
A kind of 7. Anti-static adhesive on medical blue piece according to claim 1 or 2 or 3, it is characterised in that its
Preparation method is：A. jelly is configured, is 2 by weight:1 takes gelatin and empgen BB to be well mixed；B. in agitated kettle
Middle addition water and gelatin stir 0.5~1.5 hour；C. jelly is added to stir and be heated to 50 DEG C until jelly is completely molten
Solution；D. nonionic surfactant quickly stirring 3 minutes are added；E. after adding the quick stirring of anion surfactant 3 minutes；
F. after adding the quick stirring of brightening agent 3 minutes；G. empgen BB is added to stir 3 minutes；H. spectroscopic pure sodium oxide molybdena is added
Stirring 3 minutes；I. alum is added to stir 3 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710581032.9A CN107488408B (en) | 2017-07-17 | 2017-07-17 | A kind of Anti-static adhesive and preparation method thereof for blue on piece |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710581032.9A CN107488408B (en) | 2017-07-17 | 2017-07-17 | A kind of Anti-static adhesive and preparation method thereof for blue on piece |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107488408A true CN107488408A (en) | 2017-12-19 |
| CN107488408B CN107488408B (en) | 2019-05-14 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201710581032.9A Active CN107488408B (en) | 2017-07-17 | 2017-07-17 | A kind of Anti-static adhesive and preparation method thereof for blue on piece |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5888712A (en) * | 1997-12-16 | 1999-03-30 | Eastman Kodak Company | Electrically-conductive overcoat for photographic elements |
| CN1326116A (en) * | 2000-05-31 | 2001-12-12 | 富士胶片株式会社 | Silver halide color photosensitive material |
| US20030141487A1 (en) * | 2001-12-26 | 2003-07-31 | Eastman Kodak Company | Composition containing electronically conductive polymer particles |
| CN106113962A (en) * | 2016-06-26 | 2016-11-16 | 乐凯医疗科技有限公司 | A kind of material capable of repeat printing |
| CN106928847A (en) * | 2015-12-30 | 2017-07-07 | 乐凯华光印刷科技有限公司 | A kind of silver halide image exports film bottom antistatic coating fluid and its preparation method and application |
-
2017
- 2017-07-17 CN CN201710581032.9A patent/CN107488408B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5888712A (en) * | 1997-12-16 | 1999-03-30 | Eastman Kodak Company | Electrically-conductive overcoat for photographic elements |
| CN1326116A (en) * | 2000-05-31 | 2001-12-12 | 富士胶片株式会社 | Silver halide color photosensitive material |
| US20030141487A1 (en) * | 2001-12-26 | 2003-07-31 | Eastman Kodak Company | Composition containing electronically conductive polymer particles |
| CN106928847A (en) * | 2015-12-30 | 2017-07-07 | 乐凯华光印刷科技有限公司 | A kind of silver halide image exports film bottom antistatic coating fluid and its preparation method and application |
| CN106113962A (en) * | 2016-06-26 | 2016-11-16 | 乐凯医疗科技有限公司 | A kind of material capable of repeat printing |
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| Publication number | Publication date |
|---|---|
| CN107488408B (en) | 2019-05-14 |
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