CN107475489A - A kind of preparation method of skating boots skates - Google Patents
A kind of preparation method of skating boots skates Download PDFInfo
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- CN107475489A CN107475489A CN201710663149.1A CN201710663149A CN107475489A CN 107475489 A CN107475489 A CN 107475489A CN 201710663149 A CN201710663149 A CN 201710663149A CN 107475489 A CN107475489 A CN 107475489A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 239000000956 alloy Substances 0.000 claims abstract description 37
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 36
- 239000000843 powder Substances 0.000 claims abstract description 36
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 48
- 238000005253 cladding Methods 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 20
- 230000007704 transition Effects 0.000 claims description 19
- 229910003460 diamond Inorganic materials 0.000 claims description 17
- 239000010432 diamond Substances 0.000 claims description 17
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 14
- 239000011159 matrix material Substances 0.000 claims description 14
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 10
- 239000012535 impurity Substances 0.000 claims description 10
- 229910052759 nickel Inorganic materials 0.000 claims description 10
- 239000003960 organic solvent Substances 0.000 claims description 10
- 238000002203 pretreatment Methods 0.000 claims description 8
- 238000010791 quenching Methods 0.000 claims description 8
- 230000000171 quenching effect Effects 0.000 claims description 8
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- 238000005406 washing Methods 0.000 claims description 7
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 5
- 229910052786 argon Inorganic materials 0.000 claims description 5
- 238000005229 chemical vapour deposition Methods 0.000 claims description 5
- 229910052804 chromium Inorganic materials 0.000 claims description 5
- 239000007789 gas Substances 0.000 claims description 5
- 239000012943 hotmelt Substances 0.000 claims description 5
- 229910052748 manganese Inorganic materials 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 229910052758 niobium Inorganic materials 0.000 claims description 5
- 229910052594 sapphire Inorganic materials 0.000 claims description 5
- 239000004065 semiconductor Substances 0.000 claims description 5
- 229910052720 vanadium Inorganic materials 0.000 claims description 5
- 229910052726 zirconium Inorganic materials 0.000 claims description 5
- 238000012545 processing Methods 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 claims description 2
- 150000002576 ketones Chemical class 0.000 claims 1
- 238000005496 tempering Methods 0.000 claims 1
- 239000011248 coating agent Substances 0.000 abstract description 8
- 238000000576 coating method Methods 0.000 abstract description 8
- 230000003746 surface roughness Effects 0.000 abstract description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 230000008859 change Effects 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 241000276489 Merlangius merlangus Species 0.000 description 1
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 230000003026 anti-oxygenic effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63C—SKATES; SKIS; ROLLER SKATES; DESIGN OR LAYOUT OF COURTS, RINKS OR THE LIKE
- A63C1/00—Skates
- A63C1/30—Skates with special blades
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63C—SKATES; SKIS; ROLLER SKATES; DESIGN OR LAYOUT OF COURTS, RINKS OR THE LIKE
- A63C1/00—Skates
- A63C1/42—Manufacture of skates
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/20—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for blades for skates
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/34—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/46—Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/58—Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C24/00—Coating starting from inorganic powder
- C23C24/08—Coating starting from inorganic powder by application of heat or pressure and heat
- C23C24/10—Coating starting from inorganic powder by application of heat or pressure and heat with intermediate formation of a liquid phase in the layer
- C23C24/103—Coating with metallic material, i.e. metals or metal alloys, optionally comprising hard particles, e.g. oxides, carbides or nitrides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
- C23C28/34—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
- C23C28/345—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2221/00—Treating localised areas of an article
- C21D2221/02—Edge parts
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
- Chemically Coating (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The invention provides a kind of preparation method of skating boots skates, by being heat-treated to skates no-coat chip, skates different piece is set to obtain required different hardness, so as to it ensure that applying coating after, skates cutter hub, which has resistance and transmitted, pedals the rigidity and obdurability of ice strength, while blade can be sufficiently wear-resistant and has surface roughness as small as possible.Also, the no-coat chip of skates and the internal layer coating powders of alloy coat, specific alloy element component proportioning is employed, so as to significantly improve the hardness of alloy coat, there is high wearability, good rockiness and inoxidizability.
Description
Technical field
The present invention relates to field of alloy material, is to be related to a kind of preparation method of skating boots skates specifically.
Background technology
Skating is using the skating boots with skates as instrument, with reference to personal strength and the sports events of technology.Skating is made
One of main project for Winter Olympic Games, the influence factor of its competitiveness in addition to the personal skill of skater,
Most important is exactly the performance of skates on skating boots.For example, break to pedaling the transmission capacity of ice power, plasticity_resistant deformation ability, anti-fragility
Split ability and long-time anti-wear performance etc..The physical characteristic of blade and mechanical property are to determine skates in the mechanical realization of skates
One of principal element of quality level, this is related to the surface roughness of the bulk strength of blade, the hardness of blade and tactile ice face
Deng.And research of the China for high-performance skates is more short of, either commonly skate used in fan or sportsman
The high-quality skates overwhelming majority relies on import.Therefore, development of new skating boots skates, for realizing that the design and producing of skates are autonomous
Change, promote the competitiveness of related event on ices, have important practical significance and strategic importance.
When ice is pedaled in skating, skates blade bears larger stress, slides the blade and ice face high-speed friction of middle skating boots, makes
Need often to bear larger frictional force during, after skates use a period of time, its cutting edge meeting rust, at this moment usually require
It is re-grind, it is returned to the original form.So the main reason for abrasion of skates is skating boots loss, and can be right
Skating produces a very large impact, although whetting a knife repeatedly can be wasted time and energy with being continuing with the short time.Therefore, in the prior art
The technical issues that need to address are to have suitable anti-wear performance and less while allowing the skates to have certain rigidity and toughness
Surface roughness.
The content of the invention
Metal and the respective excellent properties of high-abrasive material are exactly combined and are used by surface-coating technology, metal
Intensity is preferable with bearing capacity and anti-wear performance is relatively poor, and some other materials have very high anti-wear performance but carrying energy
Power is limited, and face coat exactly combines the two to play respective superiority, improves the overall performance of workpiece.
In order to solve the above-mentioned technical problem, the invention provides a kind of preparation method of skating boots skates, make on skating boots
Skates can have higher anti-wear performance, antioxygenic property and shock resistance.
A kind of preparation method of skating boots skates, it is characterised in that：The skates include no-coat chip, and in matrix knife
The alloy coat covered on piece, the alloy coat are divided into internal layer, transition zone and outer layer；The preparation method of the skates include with
Lower step：
(1) no-coat chip is heat-treated：Quenching Treatment and temper are carried out to described matrix blade, made close to the part of blade
Hardness is higher than the hardness of the part away from blade；
(2) pre-treatment is coated：No-coat chip after the heat treatment is put into organic solvent, with ultrasonic wave stirring and washing, then
Ultrasonic vibration in the mixed liquor being made up of diamond lap powder and acetone is put into, then blade is put into the organic solvent clearly
Wash, finally taking-up is dried up with nitrogen；
(3) alloy coat is prepared：By the way of hot melt covers, the cladding powder of the preset internal layer, its composition is ferrous alloy,
Its thickness is 0.8 ~ 1mm, and by high-power semiconductor laser, laser scanning speed is 8 ~ 10mm/s, persistently leads to argon gas protection,
After internal layer cladding terminates, the transition zone is deposited on the internal layer using the MT-CVD techniques of routine, transition composition of layer is
CrN, thickness are 0.5 ~ 1.0 μm, recycle conventional MT-CVD methods to deposit the outer layer on the transition zone, outer composition is
α-Al2O3, thickness is 2.0 ~ 2.5 μm, that is, obtains the skating boots skates finished product with alloy coat.
Described matrix blade forms comprising following element：C:1.20-1.50%, Si:1.50-1.80%, Mn:2.50-
3.50%, Ni:0.50-1.00%, Cr:2.50-3.50%, V:0.10-0.50%, surplus are Fe and inevitable impurity.
The tensile strength of the skating boots skates finished product reaches 230 ~ 250 MPa, and hardness is up to 60 ~ 65HRC, anti-wear performance ratio
No-coat chip improves 3 ~ 5 times.
The cladding powder of the internal layer forms comprising following element：C:2.50-3.50%, Si:0.50-0.80%, Zr:
2.80-3.30%, Nb:1.50-2.50%, Co:0.05-0.10%, Ni:4.50-5.50%, Al:0.50-1.50%, B:0.10-
0.20%, surplus is Fe and inevitable impurity, and meets 8.5≤Zr+Ni+Al≤9.5, and above-mentioned percentage is quality percentage
Than；The granularity of cladding powder is 100 ~ 150 μm.
Preferably, step (1) no-coat chip heat treatment, hardening heat are 400 ~ 500 DEG C, temperature is 200 ~
300℃；Using wherein top-stitching as boundary on described matrix blade, make the part of blade close to no-coat chip and away from blade
Part is different temperature after Quenching Treatment, then carries out temper, so that the hardness close to the part of blade is high
Hardness in the part away from blade.
Preferably, step (2) the coating pre-treatment：No-coat chip after the heat treatment is put into organic solvent,
With ultrasonic wave stirring and washing 10-15 minutes, ultrasonic vibration in the mixed liquor being made up of diamond lap powder and acetone is placed into
10 ~ 20 minutes, the wherein weight of diamond lap powder and the volume ratio of acetone was：Diamond lap powder：Acetone=1.5 ~ 2mg:
1ml, then blade is put into the organic solvent and cleaned 15 minutes, finally taking-up is dried up with nitrogen.
Preferably, the organic solvent in the step (2) is that one or both of acetone, isopropyl acetone, absolute ethyl alcohol are mixed
Close.
It is an advantage of the invention that：The application obtains skates different piece by being heat-treated to skates no-coat chip
Required different hardness, so as to it ensure that applying coating after, skates cutter hub has resistance and transmits the rigidity for pedaling ice strength
And obdurability, while blade can be sufficiently wear-resistant and has surface roughness as small as possible.The no-coat chip of the application skates
With the internal layer coating powders of alloy coat, specific alloy element component proportioning is employed, so as to significantly improve alloy coat
Hardness, there is high wearability, good rockiness and inoxidizability.
Embodiment
With reference to embodiment and comparative example, the present invention is described in more detail.
Embodiment 1：
A kind of preparation method of skating boots skates, it is characterised in that：The skates include no-coat chip, and on no-coat chip
The alloy coat of covering, the alloy coat are divided into internal layer, transition zone and outer layer；The preparation method of the skates includes following step
Suddenly：
(1) no-coat chip is heat-treated, and hardening heat is 500 DEG C, and temperature is 300 DEG C；With wherein on described matrix blade
Top-stitching is boundary, and it is different temperature after Quenching Treatment to make the part of blade close to no-coat chip and the part away from blade
Degree, then carries out temper, so that the hardness close to the part of blade is higher than the hardness of the part away from blade；
(2) pre-treatment is coated：No-coat chip after the heat treatment is put into acetone, with ultrasonic wave stirring and washing 15 minutes,
Place into the weight of ultrasonic vibration 10 minutes, wherein diamond lap powder in the mixed liquor being made up of diamond lap powder and acetone
Measure and be with the volume ratio of acetone：Diamond lap powder：Acetone=1.5mg:1ml, then blade is put into the acetone and cleans 15 points
Clock, finally taking-up are dried up with nitrogen；
(3) alloy coat is prepared：By the way of hot melt covers, the cladding powder of the preset internal layer, its composition is ferrous alloy,
Its thickness is 0.8mm, and the cladding powder of the internal layer forms comprising following element：C:3.00%, Si:0.70%, Zr:3.00%,
Nb:1.50%, Co:0.08%, Ni:4.80%, Al:1.00%, B:0.10%, surplus is Fe and inevitable impurity, above-mentioned percentage
Than for mass percent；The granularity of cladding powder is 150 μm, and by high-power semiconductor laser, laser scanning speed is
8mm/s, persistently lead to argon gas protection, after internal layer cladding terminates, institute is deposited on the internal layer using the MT-CVD techniques of routine
Transition zone is stated, transition composition of layer is CrN, and thickness is 1.0 μm, recycles conventional MT-CVD methods to deposit institute on the transition zone
Outer layer is stated, outer composition is α-Al2O3, thickness is 2.5 μm, that is, obtains the skating boots skates finished product with alloy coat；
Described matrix blade forms comprising following element：C:1.30%, Si:1.60%, Mn:2.50%, Ni:0.50%, Cr:3.00%,
V:0.30%, surplus is Fe and inevitable impurity；
The tensile strength of the skating boots skates finished product reaches 240MPa, and hardness reaches 65HRC, and anti-wear performance improves than no-coat chip
5 times.
Embodiment 2：
A kind of preparation method of skating boots skates, it is characterised in that：The skates include no-coat chip, and on no-coat chip
The alloy coat of covering, the alloy coat are divided into internal layer, transition zone and outer layer；The preparation method of the skates includes following step
Suddenly：
(1) no-coat chip is heat-treated, and hardening heat is 450 DEG C, and temperature is 250 DEG C；With wherein on described matrix blade
Top-stitching is boundary, and it is different temperature after Quenching Treatment to make the part of blade close to no-coat chip and the part away from blade
Degree, then carries out temper, so that the hardness close to the part of blade is higher than the hardness of the part away from blade；
(2) pre-treatment is coated：No-coat chip after the heat treatment is put into acetone, with ultrasonic wave stirring and washing 13 minutes,
Place into the weight of ultrasonic vibration 15 minutes, wherein diamond lap powder in the mixed liquor being made up of diamond lap powder and acetone
Measure and be with the volume ratio of acetone：Diamond lap powder：Acetone=1.5mg:1ml, then blade is put into the acetone and cleans 15 points
Clock, finally taking-up are dried up with nitrogen；
(3) alloy coat is prepared：By the way of hot melt covers, the cladding powder of the preset internal layer, its composition is ferrous alloy,
Its thickness is 0.8mm, and the cladding powder of the internal layer forms comprising following element：C:3.50%, Si:0.50%, Zr:2.80%,
Nb:1.50%, Co:0.07%, Ni:4.80%, Al:1.00%, B:0.20%, surplus is Fe and inevitable impurity, above-mentioned percentage
Than for mass percent；The granularity of cladding powder is 130 μm, and by high-power semiconductor laser, laser scanning speed is
10mm/s, persistently lead to argon gas protection, after internal layer cladding terminates, institute is deposited on the internal layer using the MT-CVD techniques of routine
Transition zone is stated, transition composition of layer is CrN, and thickness is 0.5 μm, recycles conventional MT-CVD methods to deposit institute on the transition zone
Outer layer is stated, outer composition is α-Al2O3, thickness is 2.0 μm, that is, obtains the skating boots skates finished product with alloy coat；
Described matrix blade forms comprising following element：C:1.20%, Si:1.80%, Mn:2.50%, Ni:0.50%, Cr:
2.50%, V:0.30%, surplus is Fe and inevitable impurity；
The tensile strength of the skating boots skates finished product reaches 250MPa, and hardness reaches 65HRC, and anti-wear performance improves than no-coat chip
5 times.
Embodiment 3：
A kind of preparation method of skating boots skates, it is characterised in that：The skates include no-coat chip, and on no-coat chip
The alloy coat of covering, the alloy coat are divided into internal layer, transition zone and outer layer；The preparation method of the skates includes following step
Suddenly：
(1) no-coat chip is heat-treated, and hardening heat is 400 DEG C, and temperature is 200 DEG C；With wherein on described matrix blade
Top-stitching is boundary, and it is different temperature after Quenching Treatment to make the part of blade close to no-coat chip and the part away from blade
Degree, then carries out temper, so that the hardness close to the part of blade is higher than the hardness of the part away from blade；
(2) pre-treatment is coated：No-coat chip after the heat treatment is put into acetone, with ultrasonic wave stirring and washing 15 minutes,
Place into the weight of ultrasonic vibration 20 minutes, wherein diamond lap powder in the mixed liquor being made up of diamond lap powder and acetone
Measure and be with the volume ratio of acetone：Diamond lap powder：Acetone=2mg:1ml, then blade is put into the acetone and cleans 15 points
Clock, finally taking-up are dried up with nitrogen；
(3) alloy coat is prepared：By the way of hot melt covers, the cladding powder of the preset internal layer, its composition is ferrous alloy,
Its thickness is 1mm, and the cladding powder of the internal layer forms comprising following element：C:2.50%, Si:0.50%, Zr:2.80%, Nb:
2.50%, Co:0.05%, Ni:5.50%, Al:0.50%, B:0.10%, surplus is Fe and inevitable impurity, above-mentioned percentage
For mass percent；The granularity of cladding powder is 100 μm, passes through high-power semiconductor laser, laser scanning speed 8mm/
S, persistently lead to argon gas protection, after internal layer cladding terminates, the mistake is deposited on the internal layer using the MT-CVD techniques of routine
Layer is crossed, transition composition of layer is CrN, and thickness is 0.5 μm, recycles conventional MT-CVD methods to be deposited on the transition zone described outer
Layer, outer composition is α-Al2O3, thickness is 2.0 μm, that is, obtains the skating boots skates finished product with alloy coat；
Described matrix blade forms comprising following element：C:1.20%, Si:1.50%, Mn:3.50%, Ni:1.00%, Cr:2.50%,
V:0.10%, surplus is Fe and inevitable impurity；
The tensile strength of the skating boots skates finished product reaches 230MPa, and hardness reaches 60HRC, and anti-wear performance improves than no-coat chip
3 times.
Comparative example 1：
The internal layer cladding powder of elemental composition and content of the present invention, particularly Zr+Ni+Al contents be will differ from more than 9.5 or small
When 8.5, after being prepared using same processing step, the tensile strength of resulting skates is only 150MPa, and hardness is
45HRC, anti-wear performance are not obviously improved.
Comparative example 2：
The no-coat chip of elemental composition and content of the present invention is will differ from, it is resulting after being prepared using same processing step
The tensile strength of skates is only 180MPa, hardness 45HRC, and anti-wear performance is not obviously improved.
Comparative example 3：
By elemental composition and content alloy powder raw material same as Example 1, during without heat treatment to no-coat chip, only
Using coating pre-treatment and alloy coat step is prepared, the tensile strength of the skates obtained by it is only 180MPa, and hardness is
50HRC, anti-wear performance are not obviously improved.
The internal layer of the no-coat chip of the application skates and alloy coat applies it can be seen from embodiment 1-3 and comparative example 1-3
Whiting end, it is specific alloy element component proportioning of the applicant by repeated tests checking, not only element species is entered
Considering on capable effect, performance and finished product, has also done certain research to the synergy between each element, so as to significantly
The hardness of no-coat chip and alloy coat is improved, there is high wearability, good rockiness and inoxidizability.
Also, the heat treatment that the application is carried out to skates no-coat chip is proposed first by applicant, the processing step
Skates different piece is obtained required different hardness, and considered according to skating boots handling characteristics and acrobatic roller skating,
After ensure that applying coating, skates cutter hub has resistance and transmits the rigidity and obdurability for pedaling ice strength, while blade can be sufficient
It is enough wear-resisting and there is surface roughness as small as possible.
Although an embodiment of the present invention has been shown and described, it will be understood by those skilled in the art that：Not
In the case of departing from the principle and objective of the present invention a variety of change, modification, replacement and modification can be carried out to these embodiments, this
The scope of invention is limited by claim and its equivalent.
Claims (5)
- A kind of 1. preparation method of skating boots skates, it is characterised in that：The skates include no-coat chip, and in no-coat chip The alloy coat of upper covering, the alloy coat are divided into internal layer, transition zone and outer layer；The preparation method of the skates includes following Step：(1) no-coat chip is heat-treated：Quenching Treatment and temper are carried out to described matrix blade, made close to the part of blade Hardness is higher than the hardness of the part away from blade；(2) pre-treatment is coated：No-coat chip after the heat treatment is put into organic solvent, with ultrasonic wave stirring and washing, then Ultrasonic vibration in the mixed liquor being made up of diamond lap powder and acetone is put into, then blade is put into the organic solvent clearly Wash, finally taking-up is dried up with nitrogen；(3) alloy coat is prepared：By the way of hot melt covers, the cladding powder of the preset internal layer, its composition is ferrous alloy, Its thickness is 0.8 ~ 1mm, and by high-power semiconductor laser, laser scanning speed is 8 ~ 10mm/s, persistently leads to argon gas protection, After internal layer cladding terminates, the transition zone is deposited on the internal layer using the MT-CVD techniques of routine, transition composition of layer is CrN, thickness are 0.5 ~ 1.0 μm, recycle conventional MT-CVD methods to deposit the outer layer on the transition zone, outer composition is α-Al2O3, thickness is 2.0 ~ 2.5 μm, that is, obtains the skating boots skates finished product with alloy coat；Described matrix blade forms comprising following element：C:1.20-1.50%, Si:1.50-1.80%, Mn:2.50-3.50%, Ni:0.50-1.00%, Cr:2.50-3.50%, V:0.10-0.50%, surplus are Fe and inevitable impurity；The tensile strength of the skating boots skates finished product reaches 230 ~ 250 MPa, and hardness compares matrix up to 60 ~ 65HRC, anti-wear performance Blade improves 3 ~ 5 times.
- 2. according to the preparation method described in claim 1-2, it is characterised in that：The cladding powder of the internal layer includes following element Composition：C:2.50-3.50%, Si:0.50-0.80%, Zr:2.80-3.30%, Nb:1.50-2.50%, Co:0.05-0.10%, Ni: 4.50-5.50%, Al:0.50-1.50%, B:0.10-0.20%, surplus is Fe and inevitable impurity, and meets 8.5≤Zr+ Ni+Al≤9.5, above-mentioned percentage are mass percent；The granularity of cladding powder is 100 ~ 150 μm.
- 3. according to the preparation method described in claim 1-2, it is characterised in that：Step (1) the no-coat chip heat treatment, quenching Temperature is 400 ~ 500 DEG C, and temperature is 200 ~ 300 DEG C；Using wherein top-stitching as boundary on described matrix blade, make close to base The part of the blade of body blade and the part of remote blade are different temperature after Quenching Treatment, are then carried out at tempering Reason, so that the hardness close to the part of blade is higher than the hardness of the part away from blade.
- 4. according to the preparation method described in claim 1-3, it is characterised in that：The step (2) coats pre-treatment：By the heat No-coat chip after processing is put into organic solvent, with ultrasonic wave stirring and washing 10-15 minutes, is placed into by diamond lap powder And ultrasonic vibration 10 ~ 20 minutes, the wherein weight of diamond lap powder and the volume ratio of acetone in the mixed liquor that is formed of acetone For：Diamond lap powder：Acetone=1.5 ~ 2mg:1ml, then blade is put into the organic solvent and cleaned 15 minutes, finally take Go out and dried up with nitrogen.
- 5. the preparation method according to Claims 1-4, it is characterised in that：Organic solvent in the step (2) is third One or both of ketone, isopropyl acetone, absolute ethyl alcohol mix.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019173959A1 (en) * | 2018-03-13 | 2019-09-19 | 杭州联和工具制造有限公司 | Tool having cutting edge and method for manufacturing same |
| CN111270165A (en) * | 2020-02-18 | 2020-06-12 | 北京科技大学 | Method for manufacturing material of speed skating blade |
| CN111283204A (en) * | 2020-02-18 | 2020-06-16 | 北京科技大学 | Preparation method of chromium-molybdenum-vanadium type quick-skating skates material |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100201088A1 (en) * | 2009-02-06 | 2010-08-12 | Martin Newman | Compressive coatings for ice skate blades and methods for applying the same |
| CN202096689U (en) * | 2010-12-24 | 2012-01-04 | 上海天瓷新材料科技有限公司 | Novel ceramic ice skate blade |
| CN202460066U (en) * | 2012-02-01 | 2012-10-03 | 北京体育大学 | Multi-arc ion plating abrasion-resistant smoothening ice skate blade |
| US20130175772A1 (en) * | 2010-09-30 | 2013-07-11 | Technique Surface Lab Inc. | Ice skate blades and method for improving performances thereof |
-
2017
- 2017-08-05 CN CN201710663149.1A patent/CN107475489B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100201088A1 (en) * | 2009-02-06 | 2010-08-12 | Martin Newman | Compressive coatings for ice skate blades and methods for applying the same |
| US20130175772A1 (en) * | 2010-09-30 | 2013-07-11 | Technique Surface Lab Inc. | Ice skate blades and method for improving performances thereof |
| CN202096689U (en) * | 2010-12-24 | 2012-01-04 | 上海天瓷新材料科技有限公司 | Novel ceramic ice skate blade |
| CN202460066U (en) * | 2012-02-01 | 2012-10-03 | 北京体育大学 | Multi-arc ion plating abrasion-resistant smoothening ice skate blade |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019173959A1 (en) * | 2018-03-13 | 2019-09-19 | 杭州联和工具制造有限公司 | Tool having cutting edge and method for manufacturing same |
| CN111270165A (en) * | 2020-02-18 | 2020-06-12 | 北京科技大学 | Method for manufacturing material of speed skating blade |
| CN111283204A (en) * | 2020-02-18 | 2020-06-16 | 北京科技大学 | Preparation method of chromium-molybdenum-vanadium type quick-skating skates material |
| CN111270165B (en) * | 2020-02-18 | 2020-12-22 | 北京科技大学 | Method for manufacturing material of speed skating blade |
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| CN107475489B (en) | 2018-10-09 |
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