CN107474752A - 一种薄型双面胶的制备方法 - Google Patents

一种薄型双面胶的制备方法 Download PDF

Info

Publication number
CN107474752A
CN107474752A CN201710753730.2A CN201710753730A CN107474752A CN 107474752 A CN107474752 A CN 107474752A CN 201710753730 A CN201710753730 A CN 201710753730A CN 107474752 A CN107474752 A CN 107474752A
Authority
CN
China
Prior art keywords
parts
preparation
sensitive adhesive
sided glue
thin double
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710753730.2A
Other languages
English (en)
Inventor
王文朝
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Funan County Wei Wei Packing Material Co Ltd
Original Assignee
Funan County Wei Wei Packing Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Funan County Wei Wei Packing Material Co Ltd filed Critical Funan County Wei Wei Packing Material Co Ltd
Priority to CN201710753730.2A priority Critical patent/CN107474752A/zh
Publication of CN107474752A publication Critical patent/CN107474752A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F289/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds not provided for in groups C08F251/00 - C08F287/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/69—Polymers of conjugated dienes
    • C08G18/694—Polymers of conjugated dienes containing carboxylic ester groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
    • C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
    • C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
    • C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/124—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present on both sides of the carrier, e.g. double-sided adhesive tape
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/312—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier parameters being the characterizing feature
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2400/00—Presence of inorganic and organic materials
    • C09J2400/20—Presence of organic materials
    • C09J2400/26—Presence of textile or fabric
    • C09J2400/263—Presence of textile or fabric in the substrate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2400/00—Presence of inorganic and organic materials
    • C09J2400/20—Presence of organic materials
    • C09J2400/28—Presence of paper
    • C09J2400/283—Presence of paper in the substrate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2467/00—Presence of polyester
    • C09J2467/006—Presence of polyester in the substrate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2475/00—Presence of polyurethane

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Adhesive Tapes (AREA)

Abstract

本发明属于双面胶带制备技术领域，具体涉及一种薄型双面胶的制备方法，包括改性碳纳米管制备、压敏胶制备以及双面胶制备。本发明相比现有技术具有以下优点：本发明中在基材表面涂布压敏胶厚度限制在3‑4μm，其中碳纳米在酸性条件下改性有助于提高压敏胶的耐候性，具有高乙烯基含量的液态聚丁二烯树脂和油酸钠配合使用软化点高、内聚力大，能有效增强压敏胶的粘着力，无毒、耐老化，按照本发明中方法制备成双面胶，在总厚度低于12μm以下，其黏着力可达到1.5kg/in以上，可满足电子工业领域的相关要求。

Description

一种薄型双面胶的制备方法
技术领域
本发明属于双面胶带制备技术领域，具体涉及一种薄型双面胶的制备方法。
背景技术
双面胶带是由离型膜和两面具有压敏粘性的胶层组成，随着技术的不断发展，双面胶厚度降低的同时还必须具有较高的粘结强度和内聚强度，压敏胶制品广泛应用于包装、电气电子、建筑、医疗卫生、汽车和家庭生活用品等各个行业，但现在市面上的PET双面胶大多采用传统的丙烯酸溶剂型胶水制得，厚度多为30-50μm，若减少丙烯酸溶剂型浇水的涂布厚度，粘着力也随之下降，因此，如何在降低双面胶厚度的同时保证双面胶的粘着力是现在急需解决的技术问题。
发明内容
本发明的目的是针对现有的问题，提供了一种薄型双面胶的制备方法。
本发明是通过以下技术方案实现的：一种薄型双面胶的制备方法，包括用于薄型双面胶压敏胶的制备，包括以下步骤：
（1）将碳纳米管与质量浓度为6-10%的氯化氢溶液溶液以质量比0.04-0.06:1混合，利用超声波处理成稳定悬浮液，在温度为40-50℃的条件下浸泡3-4小时，取出后反复水洗至中性，得到改性碳纳米管；
（2）将上述所得碳纳米管与丙烯酸羟乙酯、具有高乙烯基含量的液态聚丁二烯树脂和油酸钠搅拌均匀后，通过水浴加热至90-95℃，继续搅拌1-2小时，降温至65-70℃，加入异佛尔酮二异氰酸酯和叔丁基过氧化氢保温搅拌2-4小时后，继续加入增粘树脂，搅拌均匀后，自然冷却至室温，得到压敏胶；
（3）在温度为40-50℃的条件下利用线棒将压敏胶均匀涂布于基材表面，厚度均为3-4μm，在70-75℃的条件下烘烤6-10分钟即得。
作为对上述方案的进一步改进，包括以下重量份的原料：具有高乙烯基含量的液态聚丁二烯树脂15-20份，油酸钠2-5份，碳纳米管4-7份，丙烯酸羟乙酯2-6份，异佛尔酮二异氰酸酯1-2份，叔丁基过氧化氢4-6份，增粘树脂20-25份。
作为对上述方案的进一步改进，所述碳纳米管为多壁碳纳米管。
作为对上述方案的进一步改进，所述具有高乙烯基含量的液态聚丁二烯树脂中乙烯基含量大于80%，1,2-结构呈无规分布。
作为对上述方案的进一步改进，所述增粘树脂为C5石油树脂或萜烯树脂中的一种。
作为对上述方案的进一步改进，所述基材为无纺布基材、面纸基材或PET基材中的一种。
本发明相比现有技术具有以下优点：本发明中在基材表面涂布压敏胶厚度限制在3-4μm，其中碳纳米在酸性条件下改性有助于提高压敏胶的耐候性，具有高乙烯基含量的液态聚丁二烯树脂和油酸钠配合使用软化点高、内聚力大，能有效增强压敏胶的粘着力，无毒、耐老化，按照本发明中方法制备成双面胶，在总厚度低于12μm以下，其黏着力可达到1.5kg/in以上，可满足电子工业领域的相关要求。
具体实施方式
实施例1
一种薄型双面胶的制备方法，包括以下重量份的原料：具有高乙烯基含量的液态聚丁二烯树脂18份，油酸钠3份，碳纳米管6份，丙烯酸羟乙酯4份，异佛尔酮二异氰酸酯1.5份，叔丁基过氧化氢5份，增粘树脂22份；包括用于薄型双面胶压敏胶的制备，包括以下步骤：
（1）将碳纳米管与质量浓度为8%的氯化氢溶液溶液以质量比0.05:1混合，利用超声波处理成稳定悬浮液，在温度为45℃的条件下浸泡3.5小时，取出后反复水洗至中性，得到改性碳纳米管；
（2）将上述所得碳纳米管与丙烯酸羟乙酯、具有高乙烯基含量的液态聚丁二烯树脂和油酸钠搅拌均匀后，通过水浴加热至92℃，继续搅拌1.5小时，降温至68℃，加入异佛尔酮二异氰酸酯和叔丁基过氧化氢保温搅拌3小时后，继续加入增粘树脂，搅拌均匀后，自然冷却至室温，得到压敏胶；
（3）在温度为45℃的条件下利用线棒将压敏胶均匀涂布于基材表面，厚度均为3.5μm，在72℃的条件下烘烤8分钟即得。
其中，所述碳纳米管为多壁碳纳米管；所述具有高乙烯基含量的液态聚丁二烯树脂中乙烯基含量大于80%，1,2-结构呈无规分布；所述增粘树脂为C5石油树脂或萜烯树脂中的一种；所述基材为无纺布基材，厚度为3μm。
实施例2
一种薄型双面胶的制备方法，包括以下重量份的原料：具有高乙烯基含量的液态聚丁二烯树脂15份，油酸钠2份，碳纳米管4份，丙烯酸羟乙酯2份，异佛尔酮二异氰酸酯2份，叔丁基过氧化氢4份，增粘树脂20份；包括用于薄型双面胶压敏胶的制备，包括以下步骤：
（1）将碳纳米管与质量浓度为10%的氯化氢溶液溶液以质量比0.04:1混合，利用超声波处理成稳定悬浮液，在温度为40℃的条件下浸泡4小时，取出后反复水洗至中性，得到改性碳纳米管；
（2）将上述所得碳纳米管与丙烯酸羟乙酯、具有高乙烯基含量的液态聚丁二烯树脂和油酸钠搅拌均匀后，通过水浴加热至90℃，继续搅拌2小时，降温至65℃，加入异佛尔酮二异氰酸酯和叔丁基过氧化氢保温搅拌2小时后，继续加入增粘树脂，搅拌均匀后，自然冷却至室温，得到压敏胶；
（3）在温度为50℃的条件下利用线棒将压敏胶均匀涂布于基材表面，厚度均为3μm，在75℃的条件下烘烤6分钟即得。
其中，所述碳纳米管为多壁碳纳米管；所述具有高乙烯基含量的液态聚丁二烯树脂中乙烯基含量大于80%，1,2-结构呈无规分布；所述增粘树脂为C5石油树脂或萜烯树脂中的一种；所述基材为PET基材，厚度为2μm。
实施例3
一种薄型双面胶的制备方法，包括以下重量份的原料：具有高乙烯基含量的液态聚丁二烯树脂20份，油酸钠2份，碳纳米管7份，丙烯酸羟乙酯6份，异佛尔酮二异氰酸酯1份，叔丁基过氧化氢6份，增粘树脂25份；包括用于薄型双面胶压敏胶的制备，包括以下步骤：
（1）将碳纳米管与质量浓度为6%的氯化氢溶液溶液以质量比0.06:1混合，利用超声波处理成稳定悬浮液，在温度为50℃的条件下浸泡3小时，取出后反复水洗至中性，得到改性碳纳米管；
（2）将上述所得碳纳米管与丙烯酸羟乙酯、具有高乙烯基含量的液态聚丁二烯树脂和油酸钠搅拌均匀后，通过水浴加热至95℃，继续搅拌1小时，降温至70℃，加入异佛尔酮二异氰酸酯和叔丁基过氧化氢保温搅拌4小时后，继续加入增粘树脂，搅拌均匀后，自然冷却至室温，得到压敏胶；
（3）在温度为40℃的条件下利用线棒将压敏胶均匀涂布于基材表面，厚度均为4μm，在70℃的条件下烘烤10分钟即得。
其中，所述碳纳米管为多壁碳纳米管；所述具有高乙烯基含量的液态聚丁二烯树脂中乙烯基含量大于80%，1,2-结构呈无规分布；所述增粘树脂为C5石油树脂或萜烯树脂中的一种；所述基材为面纸基材，厚度为3μm。
设置对照组1，在实施例1的基础上去掉具有高乙烯基含量的液态聚丁二烯树脂，其余内容不变；设置对照组2，在实施例1的基础上去掉碳纳米管，其余内容不变；设置对照组3，在实施例1的基础上去掉步骤（1），其余内容不变；设置对照组4，直接将各原料混合后加热搅拌，得到压敏胶，步骤（3）与实施例1中相同；要求为电子产品组装需要达到的指标。
对各组双面胶性能检测得到以下结果：
表1
通过表1中数据可以看出，本发明中在保证双面胶总厚度低于12μm以下能满足市场要求，适于推广应用。

Claims (6)

1.一种薄型双面胶的制备方法，包括用于薄型双面胶压敏胶的制备，其特征在于，包括以下步骤：
（1）将碳纳米管与质量浓度为6-10%的氯化氢溶液溶液以质量比0.04-0.06:1混合，利用超声波处理成稳定悬浮液，在温度为40-50℃的条件下浸泡3-4小时，取出后反复水洗至中性，得到改性碳纳米管；
（2）将上述所得碳纳米管与丙烯酸羟乙酯、具有高乙烯基含量的液态聚丁二烯树脂和油酸钠搅拌均匀后，通过水浴加热至90-95℃，继续搅拌1-2小时，降温至65-70℃，加入异佛尔酮二异氰酸酯和叔丁基过氧化氢保温搅拌2-4小时后，继续加入增粘树脂，搅拌均匀后，自然冷却至室温，得到压敏胶；
（3）在温度为40-50℃的条件下利用线棒将压敏胶均匀涂布于基材表面，厚度均为3-4μm，在70-75℃的条件下烘烤6-10分钟即得。
2.如权利要求1所述一种薄型双面胶的制备方法，其特征在于，包括以下重量份的原料：具有高乙烯基含量的液态聚丁二烯树脂15-20份，油酸钠2-5份，碳纳米管4-7份，丙烯酸羟乙酯2-6份，异佛尔酮二异氰酸酯1-2份，叔丁基过氧化氢4-6份，增粘树脂20-25份。
3.如权利要求1所述一种薄型双面胶的制备方法，其特征在于，所述碳纳米管为多壁碳纳米管。
4.如权利要求1所述一种薄型双面胶的制备方法，其特征在于，所述具有高乙烯基含量的液态聚丁二烯树脂中乙烯基含量大于80%，1,2-结构呈无规分布。
5.如权利要求1所述一种薄型双面胶的制备方法，其特征在于，所述增粘树脂为C5石油树脂或萜烯树脂中的一种。
6.如权利要求1所述一种薄型双面胶的制备方法，其特征在于，所述基材为无纺布基材、面纸基材或PET基材中的一种。
CN201710753730.2A 2017-08-29 2017-08-29 一种薄型双面胶的制备方法 Pending CN107474752A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710753730.2A CN107474752A (zh) 2017-08-29 2017-08-29 一种薄型双面胶的制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710753730.2A CN107474752A (zh) 2017-08-29 2017-08-29 一种薄型双面胶的制备方法

Publications (1)

Publication Number Publication Date
CN107474752A true CN107474752A (zh) 2017-12-15

Family

ID=60604096

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710753730.2A Pending CN107474752A (zh) 2017-08-29 2017-08-29 一种薄型双面胶的制备方法

Country Status (1)

Country Link
CN (1) CN107474752A (zh)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5910542A (en) * 1994-10-11 1999-06-08 Shell Oil Company Adhesives and sealants based on telechelic polymers and heterotelechelic block polymers with dual cure systems
CN103108891A (zh) * 2010-09-24 2013-05-15 日本曹达株式会社 末端丙烯酸改性聚丁二烯或末端丙烯酸改性氢化聚丁二烯的制造方法以及含有它们的组合物

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5910542A (en) * 1994-10-11 1999-06-08 Shell Oil Company Adhesives and sealants based on telechelic polymers and heterotelechelic block polymers with dual cure systems
CN103108891A (zh) * 2010-09-24 2013-05-15 日本曹达株式会社 末端丙烯酸改性聚丁二烯或末端丙烯酸改性氢化聚丁二烯的制造方法以及含有它们的组合物

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
仝兴存: "《电子封装热管理先进材料》", 30 April 2016, 国防工业出版社 *
任慧 等: "《微纳米含能材料》", 30 April 2015, 北京理工大学出版社 *
徐鼐: "《通用级聚乳酸的改性与加工成型》", 31 January 2016, 中国科学技术大学出版社 *

Similar Documents

Publication Publication Date Title
CN106497301B (zh) 一种石墨烯改性丙烯酸酯抗静电膜及其制备方法
CN104263275B (zh) 一种环保型不干胶标签材料
CN102559105A (zh) 一种压敏胶粘剂的制备方法
Wang et al. Bioinspired chemical design to control interfacial wet adhesion
CN107474752A (zh) 一种薄型双面胶的制备方法
CN106753162A (zh) 一种可剥离型聚氨酯压敏胶粘剂的制备方法
CN104232001B (zh) 一种有机凹凸棒土改性的水性复膜胶及其制备方法
CN109777075A (zh) 一种含碳纳米管的聚碳酸酯电磁屏蔽材料及其制备方法
CN103756585B (zh) 高粘性丙烯酸胶带的制备工艺
CN206256020U (zh) 一种胶带
CN104556727B (zh) 一种车用玻璃隔热涂料制造方法
CN104790255B (zh) 淀粉涂布胶乳及其制备方法
CN109295708A (zh) 具有抗菌杀菌作用的导电纤维的制备方法
CN103554279B (zh) 可替代明胶的复合变性淀粉及应用
CN113150309B (zh) 羧基纳米纤维素改性阴离子水性聚氨酯乳液的方法
CN109207070B (zh) 一种高耐水性的丙烯酸酯胶黏剂及其制备方法
CN108676425A (zh) 一种木质家具用纳米硅杂化疏水涂料
Carli et al. Covalent immobilization of Chondrostereum purpureum endopolygalacturonase on ferromagnetic nanoparticles: catalytic properties and biotechnological application
CN107353838B (zh) 一种耐温高黏双面胶的加工工艺
CN107523233A (zh) 一种改性淀粉胶黏剂及其制备方法
CN104694041A (zh) 一种墙体用背胶的制备方法
CN105086887A (zh) 高稳定性电子产品用胶黏剂的制造方法
CN115260934B (zh) 一种可降解烫金手账胶带的制备方法
CN105970730B (zh) 一种用于增加书册年代感的浸润液
CN108485596A (zh) 一种抗紫外线阻燃透明胶水及其制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20171215