CN107474488A - A kind of stretch-proof plastic sheeting and preparation method thereof - Google Patents
A kind of stretch-proof plastic sheeting and preparation method thereof Download PDFInfo
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- CN107474488A CN107474488A CN201710904517.7A CN201710904517A CN107474488A CN 107474488 A CN107474488 A CN 107474488A CN 201710904517 A CN201710904517 A CN 201710904517A CN 107474488 A CN107474488 A CN 107474488A
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- plastic sheeting
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- proof plastic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2469/00—Characterised by the use of polycarbonates; Derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
The invention discloses a kind of stretch-proof plastic sheeting and preparation method thereof, the stretch-proof plastic sheeting is made up of the raw material components of following parts by weight：30 40 parts of epoxy resin, 15 25 parts of makrolon, 8 15 parts of styrene acrylonitrile copolymer, 12 16 parts of aluminum-based layered nanometer material, 6 12 parts of flax fiber, 37 parts of titanium phosphate sodium, 15 parts of plasticizer, 6 10 parts of polyimide, 25 parts of stabilizer, 13 parts of polymethyl hydrogen siloxane, 8 14 parts of stearic acid, 49 parts of acetylbutyrylcellulose, 37 parts of diamine propyl group dimethyl silicone polymer, 13 parts of castor oil wax, 38 parts of polyvinylpyrrolidone.Compared with prior art, the low raw-material cost of moderate resistance drawing plastic film of the present invention, each raw material components synergy makes it have preferable tensile strength and rigidity, so as to reach more preferable using effect.
Description
Technical field
The invention belongs to thin film materials art, more particularly to a kind of stretch-proof plastic sheeting and preparation method thereof.
Background technology
Plastic sheeting is mainly used in packing and as coating layer.Plastics package and plastic packet product are commercially shared
Share it is increasing, particularly composite plastic flexible package, have been widely used for the fields such as food, medicine, chemical industry, wherein
It is again maximum with packaging for foodstuff proportion, such as beverage packaging, quick-frozen food packaging, cooking food packaging, fast food packaging
All brought great convenience Deng, these products to people's life.But the tensile resistance of existing plastic sheeting and rigidity all compared with
Difference, so as to be easily broken when causing and carrying the foreign object of constant weight, and made troubles to routine use.
The content of the invention
It is an object of the invention to provide a kind of stretch-proof plastic sheeting and preparation method thereof, the stretch-proof plastic sheeting has
The advantages that tensile resistance is strong, rigidity is good and preparation technology is simple.
To achieve the above object, the present invention provides following technical scheme：
A kind of stretch-proof plastic sheeting is made up of the raw material components of following parts by weight：Epoxy resin 30-40 parts, poly- carbonic acid
Ester 15-25 parts, SAN 8-15 parts, aluminum-based layered nanometer material 12-16 parts, flax fiber 6-12 parts, phosphorus
Sour titanium sodium 3-7 parts, plasticizer 1-5 parts, polyimide 6-10 parts, stabilizer 2-5 parts, polymethyl hydrogen siloxane 1-3 parts, stearic acid
8-14 parts, acetylbutyrylcellulose 4-9 parts, diamine propyl group dimethyl silicone polymer 3-7 parts, castor oil wax 1-3 parts, polyethylene pyrrole
Pyrrolidone 3-8 parts.
Preferably, the stretch-proof plastic sheeting is made up of the raw material components of following parts by weight：32 parts of epoxy resin, gather
22 parts of carbonic ester, 11 parts of SAN, 13 parts of aluminum-based layered nanometer material, 9 parts of flax fiber, titanium phosphate sodium 5
Part, 3 parts of plasticizer, 7 parts of polyimide, 3 parts of stabilizer, 2 parts of polymethyl hydrogen siloxane, 13 parts of stearic acid, acetate butyrate fiber
6 parts of element, 6 parts of diamine propyl group dimethyl silicone polymer, 2 parts of castor oil wax, 5 parts of polyvinylpyrrolidone.
Preferably, described stretch-proof plastic sheeting is made up of the raw material components of following parts by weight：40 parts of epoxy resin,
16 parts of makrolon, 9 parts of SAN, 14 parts of aluminum-based layered nanometer material, 10 parts of flax fiber, titanium phosphate
5 parts of sodium, 2.5 parts of plasticizer, 10 parts of polyimide, 5 parts of stabilizer, 1 part of polymethyl hydrogen siloxane, 10 parts of stearic acid, acetic acid fourth
6 parts of acid cellulose, 6 parts of diamine propyl group dimethyl silicone polymer, 3 parts of castor oil wax, 5 parts of polyvinylpyrrolidone.
Preferably, the stretch-proof plastic sheeting is made up of the raw material components of following parts by weight：30 parts of epoxy resin, gather
20 parts of carbonic ester, 13 parts of SAN, 14 parts of aluminum-based layered nanometer material, 9 parts of flax fiber, titanium phosphate sodium 3
Part, 3 parts of plasticizer, 8 parts of polyimide, 5 parts of stabilizer, 1 part of polymethyl hydrogen siloxane, 12 parts of stearic acid, acetate butyrate fiber
9 parts of element, 5 parts of diamine propyl group dimethyl silicone polymer, 3 parts of castor oil wax, 8 parts of polyvinylpyrrolidone.
The preparation method of the stretch-proof plastic sheeting, comprises the following steps：
(1) each raw material components are weighed according to ratio of weight and number；
(2) each raw material components being ready in step (1) are added in kneading machine and stirred, mixing time is
20-24 minutes, temperature control are 82-86 DEG C, obtain ready-mixed thing；
(3) the ready-mixed thing in step (2) is added in extruder, extrusion forming, cooling, obtained anti-in the present invention
Drawing plastic film finished product.
Compared with prior art, the beneficial effects of the invention are as follows：
Stretch-proof plastic sheeting in the present invention is added with 32 parts of epoxy resin, SAN, aluminum base layer
The raw materials such as shape nano material, titanium phosphate sodium, polymethyl hydrogen siloxane, diamine propyl group dimethyl silicone polymer, each raw material components
Cost is cheap and makes it have preferable tensile strength and rigidity by synergy, so as to reach more preferable using effect.
Embodiment
Technical scheme is described in detail with reference to embodiment, but protection domain is not limited thereto.
Embodiment one：
A kind of stretch-proof plastic sheeting is made up of the raw material components of following parts by weight：36 parts of epoxy resin, makrolon
23 parts, 11 parts of SAN, 14 parts of aluminum-based layered nanometer material, 7 parts of flax fiber, 5 parts of titanium phosphate sodium, increase
3 parts of agent of modeling, 8 parts of polyimide, 4 parts of stabilizer, 1 part of polymethyl hydrogen siloxane, 9 parts of stearic acid, 6 parts of acetylbutyrylcellulose,
6 parts of diamine propyl group dimethyl silicone polymer, 3 parts of castor oil wax, 55 parts of polyvinylpyrrolidone.
The preparation method of the stretch-proof plastic sheeting, comprises the following steps：
(1) each raw material components are weighed according to ratio of weight and number；
(2) each raw material components being ready in step (1) are added in kneading machine and stirred, mixing time is
20-24 minutes, temperature control are 82-86 DEG C, obtain ready-mixed thing；
(3) the ready-mixed thing in step (2) is added in extruder, extrusion forming, cooling, obtained anti-in the present invention
Drawing plastic film finished product.
Embodiment two：
A kind of stretch-proof plastic sheeting is made up of the raw material components of following parts by weight：32 parts of epoxy resin, makrolon
22 parts, 11 parts of SAN, 13 parts of aluminum-based layered nanometer material, 9 parts of flax fiber, 5 parts of titanium phosphate sodium, increase
3 parts of agent of modeling, 7 parts of polyimide, 3 parts of stabilizer, 2 parts of polymethyl hydrogen siloxane, 13 parts of stearic acid, 6 parts of acetylbutyrylcellulose,
6 parts of diamine propyl group dimethyl silicone polymer, 2 parts of castor oil wax, 5 parts of polyvinylpyrrolidone.
The preparation method of the stretch-proof plastic sheeting, comprises the following steps：
(1) each raw material components are weighed according to ratio of weight and number；
(2) each raw material components being ready in step (1) are added in kneading machine and stirred, mixing time is
20-24 minutes, temperature control are 82-86 DEG C, obtain ready-mixed thing；
(3) the ready-mixed thing in step (2) is added in extruder, extrusion forming, cooling, obtained anti-in the present invention
Drawing plastic film finished product.
Embodiment three：
A kind of stretch-proof plastic sheeting is made up of the raw material components of following parts by weight：40 parts of epoxy resin, makrolon
16 parts, 9 parts of SAN, 14 parts of aluminum-based layered nanometer material, 10 parts of flax fiber, 5 parts of titanium phosphate sodium, increase
Mould 2.5 parts of agent, 10 parts of polyimide, 5 parts of stabilizer, 1 part of polymethyl hydrogen siloxane, 10 parts of stearic acid, acetylbutyrylcellulose 6
Part, 6 parts of diamine propyl group dimethyl silicone polymer, 3 parts of castor oil wax, 5 parts of polyvinylpyrrolidone.
The preparation method of the stretch-proof plastic sheeting, comprises the following steps：
(1) each raw material components are weighed according to ratio of weight and number；
(2) each raw material components being ready in step (1) are added in kneading machine and stirred, mixing time is
20-24 minutes, temperature control are 82-86 DEG C, obtain ready-mixed thing；
(3) the ready-mixed thing in step (2) is added in extruder, extrusion forming, cooling, obtained anti-in the present invention
Drawing plastic film finished product.
Example IV：
A kind of stretch-proof plastic sheeting is made up of the raw material components of following parts by weight：30 parts of epoxy resin, makrolon
20 parts, 13 parts of SAN, 14 parts of aluminum-based layered nanometer material, 9 parts of flax fiber, 3 parts of titanium phosphate sodium, increase
3 parts of agent of modeling, 8 parts of polyimide, 5 parts of stabilizer, 1 part of polymethyl hydrogen siloxane, 12 parts of stearic acid, 9 parts of acetylbutyrylcellulose,
5 parts of diamine propyl group dimethyl silicone polymer, 3 parts of castor oil wax, 8 parts of polyvinylpyrrolidone.
The preparation method of the stretch-proof plastic sheeting, comprises the following steps：
(1) each raw material components are weighed according to ratio of weight and number；
(2) each raw material components being ready in step (1) are added in kneading machine and stirred, mixing time is
20-24 minutes, temperature control are 82-86 DEG C, obtain ready-mixed thing；
(3) the ready-mixed thing in step (2) is added in extruder, extrusion forming, cooling, obtained anti-in the present invention
Drawing plastic film finished product.
Embodiment five：
A kind of stretch-proof plastic sheeting is made up of the raw material components of following parts by weight：30 parts of epoxy resin, makrolon
15 parts, 8 parts of SAN, 12 parts of aluminum-based layered nanometer material, 6 parts of flax fiber, 3 parts of titanium phosphate sodium, plasticising
1 part of agent, 6 parts of polyimide, 2 parts of stabilizer, 1 part of polymethyl hydrogen siloxane, 8 parts of stearic acid, 4 parts of acetylbutyrylcellulose are double
3 parts of amine propyl group dimethyl silicone polymer, 1 part of castor oil wax, 3 parts of polyvinylpyrrolidone.
The preparation method of the stretch-proof plastic sheeting, comprises the following steps：
(1) each raw material components are weighed according to ratio of weight and number；
(2) each raw material components being ready in step (1) are added in kneading machine and stirred, mixing time is
20-24 minutes, temperature control are 82-86 DEG C, obtain ready-mixed thing；
(3) the ready-mixed thing in step (2) is added in extruder, extrusion forming, cooling, obtained anti-in the present invention
Drawing plastic film finished product.
Embodiment six：
A kind of stretch-proof plastic sheeting is made up of the raw material components of following parts by weight：40 parts of epoxy resin, makrolon
25 parts, 15 parts of SAN, 16 parts of aluminum-based layered nanometer material, 12 parts of flax fiber, 7 parts of titanium phosphate sodium, increase
Mould 5 parts of agent, 10 parts of polyimide, 5 parts of stabilizer, 3 parts of polymethyl hydrogen siloxane, 14 parts of stearic acid, acetylbutyrylcellulose 9
Part, 7 parts of diamine propyl group dimethyl silicone polymer, 3 parts of castor oil wax, 8 parts of polyvinylpyrrolidone.
The preparation method of the stretch-proof plastic sheeting, comprises the following steps：
(1) each raw material components are weighed according to ratio of weight and number；
(2) each raw material components being ready in step (1) are added in kneading machine and stirred, mixing time is
20-24 minutes, temperature control are 82-86 DEG C, obtain ready-mixed thing；
(3) the ready-mixed thing in step (2) is added in extruder, extrusion forming, cooling, obtained anti-in the present invention
Drawing plastic film finished product.
Embodiment seven：
A kind of stretch-proof plastic sheeting is made up of the raw material components of following parts by weight：36 parts of epoxy resin, makrolon
18 parts, 12 parts of SAN, 13 parts of aluminum-based layered nanometer material, 7 parts of flax fiber, 6 parts of titanium phosphate sodium, increase
3 parts of agent of modeling, 8 parts of polyimide, 3 parts of stabilizer, 2 parts of polymethyl hydrogen siloxane, 12 parts of stearic acid, 6 parts of acetylbutyrylcellulose,
5 parts of diamine propyl group dimethyl silicone polymer, 2 parts of castor oil wax, 6 parts of polyvinylpyrrolidone.
The preparation method of the stretch-proof plastic sheeting, comprises the following steps：
(1) each raw material components are weighed according to ratio of weight and number；
(2) each raw material components being ready in step (1) are added in kneading machine and stirred, mixing time is
20-24 minutes, temperature control are 82-86 DEG C, obtain ready-mixed thing；
(3) the ready-mixed thing in step (2) is added in extruder, extrusion forming, cooling, obtained anti-in the present invention
Drawing plastic film finished product.
Finally illustrate, the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted, although with reference to compared with
The present invention is described in detail good embodiment, it will be understood by those within the art that, can be to the skill of the present invention
Art scheme is modified or equivalent substitution, and without departing from the objective and scope of the technical program, it all should cover in the present invention
Right among.
Claims (5)
1. a kind of stretch-proof plastic sheeting, it is characterised in that be made up of the raw material components of following parts by weight：Epoxy resin 30-
40 parts, makrolon 15-25 parts, SAN 8-15 parts, aluminum-based layered nanometer material 12-16 parts, flax fibre
Tie up 6-12 parts, titanium phosphate sodium 3-7 parts, plasticizer 1-5 parts, polyimide 6-10 parts, stabilizer 2-5 parts, polymethyl hydrogen siloxane
1-3 parts, stearic acid 8-14 parts, acetylbutyrylcellulose 4-9 parts, diamine propyl group dimethyl silicone polymer 3-7 parts, castor oil wax 1-
3 parts, polyvinylpyrrolidone 3-8 parts.
2. a kind of stretch-proof plastic sheeting according to claim 1, it is characterised in that by the raw material group of following parts by weight
Divide and be made：32 parts of epoxy resin, 22 parts of makrolon, 11 parts of SAN, aluminum-based layered nanometer material 13
Part, 9 parts of flax fiber, 5 parts of titanium phosphate sodium, 3 parts of plasticizer, 7 parts of polyimide, 3 parts of stabilizer, 2 parts of polymethyl hydrogen siloxane,
13 parts of stearic acid, 6 parts of acetylbutyrylcellulose, 6 parts of diamine propyl group dimethyl silicone polymer, 2 parts of castor oil wax, polyvinyl pyrrole
5 parts of alkanone.
3. a kind of stretch-proof plastic sheeting according to claim 1, it is characterised in that by the raw material group of following parts by weight
Divide and be made：40 parts of epoxy resin, 16 parts of makrolon, 9 parts of SAN, 14 parts of aluminum-based layered nanometer material,
10 parts of flax fiber, 5 parts of titanium phosphate sodium, 2.5 parts of plasticizer, 10 parts of polyimide, 5 parts of stabilizer, polymethyl hydrogen siloxane 1
Part, 10 parts of stearic acid, 6 parts of acetylbutyrylcellulose, 6 parts of diamine propyl group dimethyl silicone polymer, 3 parts of castor oil wax, polyethylene
5 parts of pyrrolidones.
4. a kind of stretch-proof plastic sheeting according to claim 1, it is characterised in that by the raw material group of following parts by weight
Divide and be made：30 parts of epoxy resin, 20 parts of makrolon, 13 parts of SAN, aluminum-based layered nanometer material 14
Part, 9 parts of flax fiber, 3 parts of titanium phosphate sodium, 3 parts of plasticizer, 8 parts of polyimide, 5 parts of stabilizer, 1 part of polymethyl hydrogen siloxane,
12 parts of stearic acid, 9 parts of acetylbutyrylcellulose, 5 parts of diamine propyl group dimethyl silicone polymer, 3 parts of castor oil wax, polyvinyl pyrrole
8 parts of alkanone.
5. the preparation method of the stretch-proof plastic sheeting according to any one of claim 1-4, it is characterised in that including with
Lower step：
(1) each raw material components are weighed according to ratio of weight and number；
(2) each raw material components being ready in step (1) are added in kneading machine and stirred, mixing time 20-
24 minutes, temperature control was 82-86 DEG C, obtains ready-mixed thing；
(3) the ready-mixed thing in step (2) is added in extruder, extrusion forming, cooling, obtains the stretch-proof in the present invention
Plastic sheeting finished product.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710904517.7A CN107474488A (en) | 2017-09-29 | 2017-09-29 | A kind of stretch-proof plastic sheeting and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710904517.7A CN107474488A (en) | 2017-09-29 | 2017-09-29 | A kind of stretch-proof plastic sheeting and preparation method thereof |
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| CN107474488A true CN107474488A (en) | 2017-12-15 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108659334A (en) * | 2018-05-03 | 2018-10-16 | 芜湖天科生物科技有限公司 | A kind of tear-resistant plastic film for wrapping and preparation method thereof |
| CN111647254A (en) * | 2020-07-26 | 2020-09-11 | 惠州志合包装材料有限公司 | Formula of stretch-resistant and non-cracking plastic film |
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| CN104844910A (en) * | 2015-06-03 | 2015-08-19 | 苏州靖羽新材料有限公司 | Anti-oil film material and preparation method thereof |
| CN104877310A (en) * | 2015-06-03 | 2015-09-02 | 苏州靖羽新材料有限公司 | Fold-resistant white plastic film and preparation method thereof |
| CN106147003A (en) * | 2016-08-08 | 2016-11-23 | 安徽松泰包装材料有限公司 | A kind of plastic film for wrapping and preparation method thereof |
| CN106188971A (en) * | 2016-08-11 | 2016-12-07 | 安徽松泰包装材料有限公司 | A kind of plastic sheeting and preparation method thereof |
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2017
- 2017-09-29 CN CN201710904517.7A patent/CN107474488A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104262839A (en) * | 2014-09-16 | 2015-01-07 | 青岛市高科专利技术转移平台有限公司 | Anti-stretching plastic thin film |
| CN104844910A (en) * | 2015-06-03 | 2015-08-19 | 苏州靖羽新材料有限公司 | Anti-oil film material and preparation method thereof |
| CN104877310A (en) * | 2015-06-03 | 2015-09-02 | 苏州靖羽新材料有限公司 | Fold-resistant white plastic film and preparation method thereof |
| CN106147003A (en) * | 2016-08-08 | 2016-11-23 | 安徽松泰包装材料有限公司 | A kind of plastic film for wrapping and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108659334A (en) * | 2018-05-03 | 2018-10-16 | 芜湖天科生物科技有限公司 | A kind of tear-resistant plastic film for wrapping and preparation method thereof |
| CN111647254A (en) * | 2020-07-26 | 2020-09-11 | 惠州志合包装材料有限公司 | Formula of stretch-resistant and non-cracking plastic film |
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