CN107459907A - Night continues self-luminous, strong reflective type roadmarking and preparation method thereof - Google Patents

Night continues self-luminous, strong reflective type roadmarking and preparation method thereof Download PDF

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Publication number
CN107459907A
CN107459907A CN201710575578.3A CN201710575578A CN107459907A CN 107459907 A CN107459907 A CN 107459907A CN 201710575578 A CN201710575578 A CN 201710575578A CN 107459907 A CN107459907 A CN 107459907A
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CN
China
Prior art keywords
luminous
parts
roadmarking
night
reflective type
Prior art date
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Pending
Application number
CN201710575578.3A
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Chinese (zh)
Inventor
李万峰
范洪展
朱学军
祖晓阳
魏玉敏
贺晴
胡玉芹
高舒
张娜
孟喜存
苏金才
卜宝峰
曹志国
王志强
赵兰义
石英爽
王文政
王强
葛峰
张媛
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hengshui Jinhu Traffic Technology Co Ltd
Original Assignee
Hengshui Jinhu Traffic Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hengshui Jinhu Traffic Technology Co Ltd filed Critical Hengshui Jinhu Traffic Technology Co Ltd
Priority to CN201710575578.3A priority Critical patent/CN107459907A/en
Publication of CN107459907A publication Critical patent/CN107459907A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D201/00Coating compositions based on unspecified macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/22Luminous paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/16Solid spheres
    • C08K7/18Solid spheres inorganic
    • C08K7/20Glass

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Road Signs Or Road Markings (AREA)
  • Road Paving Structures (AREA)

Abstract

The invention belongs to roadmarking technical field, it is therefore an objective to provide a kind of lasting self-luminous of night, the graticule of strong reflective type.Night continues self-luminous, the preparation method of strong reflective type roadmarking is that cementing material, curing agent, filler, pigment, reflectorized material, Noctilucent material and glass microballoon are combined by a certain percentage, and layering paves in road surface.The roadmarking of the present invention, be it is a kind of can continue self-luminous and add the roadmarking that strong reflective material provides more preferable reflecting effect again, can meet original standard requirement do not paste the performance such as drying time, resistance to compression, wear-resisting, colourity in the case of, reflective function is more preferable than traditional graticule reflective, energy storage effect is more preferable, can lasting self-luminous, during driving at night, in the range of car light irradiation, reflective function is stronger, graticule is very clear, and the visual field is openr, ensures traffic safety;Light-illuminating less than in the range of also can self-luminous, guide driver advance direction, reduce the generation of traffic accident.

Description

Night continues self-luminous, strong reflective type roadmarking and preparation method thereof
Technical field
The invention belongs to roadmarking technical field, continues self-luminous, strong reflective type road more particularly to a kind of night Graticule and preparation method thereof.
Background technology
At present in field of traffic, there is polytype coating, these gage mark coatings have plain edition, also there is reflective type, wherein Plain edition is non-reflective at night, reflective type night can only it is reflective in the range of light-illuminating could it is clear that exceeding light scope Graticule is just can't see, it is bigger in rainy day influence so as to have influence on the safety traffic of automobile, it is very easy to cause security incident.This Goal of the invention is to improve the open property in driver's driving at night visual field, improves the guide effect of graticule, increases self-luminosity energy, is improved Reflective effect, improve the performance of graticule.
The content of the invention
To achieve the above object, the present invention adopts the following technical scheme that:
A kind of night continues self-luminous, strong reflective type roadmarking, and the roadmarking includes initial bed and optics surface layer; The optics surface layer is located above initial bed;The initial bed includes according to mass fraction:150~250 parts of cementing materials, 15~ 25 parts of curing agent, 15~25 parts of pigment, 150~250 parts of fillers;The optics surface layer includes according to mass fraction:150~250 Part cementing material, 15~25 parts of curing agent, 15~25 parts of reflectorized materials, 15~25 parts of Noctilucent materials.
Preferably, the one or more in the cementing material epoxy gluing agent, polyurethane cementing agent, resin.
Preferably, the filler is the mixing of one or more former materials of former material such as calcium powder, quartz sand, stone flour.
Preferably, the pigment includes organic pigment or inorganic pigment.
Preferably, the reflectorized material includes one or both of glass microballoon, highlighted reflectorized material.
Preferably, the glass microballoon is luminous glass microballon.
Preferably, the Noctilucent material includes one or both of long-acting noctilucent material, short-acting Noctilucent material.
Preferably, soot layer is also included above the optics surface layer;The soot layer is according to mass fraction bag Include 30~50 parts of glass microballoons.
The invention also discloses a kind of lasting self-luminous of night, the preparation method of strong reflective type roadmarking:Its feature exists In:It the described method comprises the following steps:
(1) bed material is weighed:Weigh 150~250 parts of cementing materials, 15~25 parts of curing agent, 15 respectively according to mass fraction ~25 parts of pigment and 150~250 parts of fillers are as bed material;
(2) optical surface material is weighed:Weigh 150~250 parts of cementing materials, 15~25 parts of solidifications respectively according to mass fraction Agent, 15~25 parts of reflectorized materials, 15~25 parts of Noctilucent materials are as optical surface material;
(3) stone:After cementing material in bed material, curing agent, pigment and filler are well mixed, pass through machinery under normal temperature It is layered on road, forms initial bed;Cementing material in optical surface material, curing agent, reflectorized material, Noctilucent material are mixed equal After even, it is layered under normal temperature by machinery on cured bed material, forms optics surface layer, after the solidification of optics surface layer, that is, obtains this The night of invention continues self-luminous, strong reflective type roadmarking.
Preferably, after optical surface material is layered on cured bed material by the step (3), before the solidification of optics surface layer It is further comprising the steps of:30~50 parts of glass microballoons are uniformly sprayed on optics surface layer with spraying equipment, the number is quality Number.
Compared with prior art, night of the invention, which continues self-luminous, strong reflective type roadmarking and preparation method thereof, has Following beneficial effect:
1st, two-component cementing agent is mixed with Noctilucent material reflective agent in technical scheme, to reach noctilucence and anti- Light effect, after glass microballoon spread by face enhance rainy night reflective function;Construction in layer technique is by priming paint and surface layer optical material Separate, graticule has been given full play to the noctilucence and reflective function of optical material while original warning color is kept.
2nd, night of the invention continues self-luminous, strong reflective type roadmarking is that one kind can continue self-luminous and add again by force Reflectorized material provides the roadmarking of more preferable reflecting effect, and drying time, anti-is not pasted can meet original standard requirement In the case of the performances such as pressure, wear-resisting, colourity, reflective function is more preferable than traditional graticule reflective, and energy storage effect is more preferable, can continue Self-luminous, during driving at night, in the range of car light irradiation, reflective function is stronger, and graticule is very clear, and the visual field is openr, ensures Traffic safety;It itself can also light, the effect formed as route clearance light, be guided less than in the range of in light-illuminating The direction that driver advances, reduces the generation of traffic accident.
The night to the present invention continues self-luminous below in conjunction with the accompanying drawings, reflective type roadmarking and preparation method thereof enters one by force Walk explanation.
Brief description of the drawings
Fig. 1 is to continue self-luminous, the nighttime view of strong reflective type roadmarking night of the invention;
Fig. 2 is to continue view under self-luminous, the by force sunlight of reflective type roadmarking night of the invention;
Fig. 3 is view under the sunlight of traditional road graticule.
Embodiment
Embodiment 1
The night of the present embodiment continues self-luminous, strong reflective type roadmarking is prepared according to the following steps:
(1) bed material is weighed:Weigh 150~250 parts of cementing materials, 15~25 parts of curing agent, 15 respectively according to mass fraction ~25 parts of pigment and 150~250 parts of fillers are as bed material;
(2) optical surface material is weighed:Weigh 150~250 parts of cementing materials, 15~25 parts of solidifications respectively according to mass fraction Agent, 15~25 parts of reflectorized materials, 15~25 parts of Noctilucent materials are as optical surface material;
(3) stone:After cementing material in bed material, curing agent, pigment and filler are well mixed, road is layered under normal temperature On, form initial bed;After cementing material in optical surface material, curing agent, reflectorized material, Noctilucent material are well mixed, often It is layered under temperature on cured bed material, forms optics surface layer, after the solidification of optics surface layer, that is, the night for obtaining the present embodiment continues Self-luminous, strong reflective type roadmarking.
What is specifically weighed takes bed material and optical surface material and amount as shown in table 1, table 2.
Embodiment 2
The night of the present embodiment continues self-luminous, strong reflective type roadmarking is prepared according to the following steps:
(1) bed material is weighed:Weigh 150~250 parts of cementing materials, 15~25 parts of curing agent, 15 respectively according to mass fraction ~25 parts of pigment and 150~250 parts of fillers are as bed material;
(2) optical surface material is weighed:Weigh 150~250 parts of cementing materials, 15~25 parts of solidifications respectively according to mass fraction Agent, 15~25 parts of reflectorized materials, 15~25 parts of Noctilucent materials are as optical surface material;
(3) stone:After cementing material in bed material, curing agent, pigment and filler are well mixed, road is layered under normal temperature On, form initial bed;After cementing material in optical surface material, curing agent, reflectorized material, Noctilucent material are well mixed, often It is layered under temperature on cured bed material, forms optics surface layer;With spraying equipment by 30~50 parts of glass before the solidification of optics surface layer Glass microballon is uniformly sprayed on optics surface layer, and after the solidification of optics surface layer, that is, the night for obtaining the present embodiment continues self-luminous, strong anti- Light type roadmarking.
What is specifically weighed takes bed material and optical surface material and amount as shown in table 1, table 2.
Selection (the unit of bed material in the Examples 1 and 2 of table 1:kg)
Selection (the unit of optical surface material in the Examples 1 and 2 of table 2:kg)
Above-mentioned curing agent is Wuhan Shiquanxing Polyurethane Technology Co., Ltd.'s marking paint curing agent product, wherein implementing Example 1 uses T-8075, and embodiment 2 uses L-8050.
Fig. 1 and Fig. 2 is respectively view of the product under night and sunlight in above-described embodiment, as seen from the figure, the present invention Obtained product is in the sun, and its reflective function is more preferable than traditional graticule reflective, and energy storage effect is more preferable, can it is lasting from It is luminous;And still clear visual, the effect formed as route clearance light in the environment of night is without lamp, before guiding driver The direction entered, reduce the generation of traffic accident.
Fig. 3 is view under the sunlight of traditional road graticule, has Fig. 3 to understand that traditional road graticule is in the sun and unintelligible, Without reflective function, boundary line is not easy to recognize.
In summary, night of the invention continues self-luminous, strong reflective type roadmarking is that one kind can continue self-luminous The roadmarking that strong reflective material provides more preferable reflecting effect is added again, and drying is not pasted can meet original standard requirement In the case of the performance such as time, resistance to compression, wear-resisting, colourity, reflective function is more preferable than traditional graticule reflective, and energy storage effect is more Good, self-luminous that can be lasting, during driving at night, in the range of car light irradiation, reflective function is stronger, and graticule is very clear, and the visual field is more It is open, ensure traffic safety;It itself can also light, be formed as route clearance light less than in the range of in light-illuminating Effect, the direction for guiding driver to advance, reduces the generation of traffic accident.
Embodiment described above is only that the preferred embodiment of the present invention is described, not to the model of the present invention Enclose and be defined, on the premise of design spirit of the present invention is not departed from, technical side of the those of ordinary skill in the art to the present invention The various modifications and improvement that case is made, it all should fall into the protection domain of claims of the present invention determination.Extensive protection scope Including:Use adhesive one kind, two or more luminous marks being mixed to form with each pigment, filler, different colours Noctilucent material Line etc..

Claims (11)

1. a kind of night continues self-luminous, strong reflective type roadmarking, it is characterised in that:The roadmarking include initial bed and Optics surface layer;The optics surface layer is located above initial bed;The initial bed includes according to mass fraction:150~250 parts cementing Material, 15~25 parts of curing agent, 15~25 parts of pigment, 150~250 parts of fillers;The optics surface layer includes according to mass fraction: 150~250 parts of cementing materials, 15~25 parts of curing agent, 15~25 parts of reflectorized materials, 15~25 parts of Noctilucent materials.
2. night according to claim 1 continues self-luminous, strong reflective type roadmarking, it is characterised in that:It is described cementing One or more in material epoxy resin cementing agent, polyurethane cementing agent, resin.
3. night according to claim 1 continues self-luminous, strong reflective type roadmarking, it is characterised in that:The filler For the mixing of one or more former materials of the former materials such as calcium powder, quartz sand, stone flour.
4. night according to claim 1 continues self-luminous, strong reflective type roadmarking, it is characterised in that:The pigment Including organic pigment or inorganic pigment.
5. night according to claim 1 continues self-luminous, strong reflective type roadmarking, it is characterised in that:It is described reflective Material includes one or both of glass microballoon, highlighted reflectorized material.
6. night according to claim 5 continues self-luminous, strong reflective type roadmarking, it is characterised in that:The glass Microballon is luminous glass microballon.
7. night according to claim 1 continues self-luminous, strong reflective type roadmarking, it is characterised in that:The noctilucence Material includes one or both of long-acting noctilucent material, short-acting Noctilucent material.
8. night according to claim 1 continues self-luminous, strong reflective type roadmarking, it is characterised in that:The optics Also include soot layer above surface layer;The soot layer includes 30~50 parts of glass microballoons according to mass fraction.
9. a kind of night continues self-luminous, the preparation method of strong reflective type roadmarking:It is characterized in that:Methods described include with Lower step:
(1) bed material is weighed:Weigh 150~250 parts of cementing materials, 15~25 parts of curing agent, 15~25 respectively according to mass fraction Part pigment and 150~250 parts of fillers are as bed material;
(2) optical surface material is weighed:Weighed respectively according to mass fraction 150~250 parts of cementing materials, 15~25 parts of curing agent, 15~25 parts of reflectorized materials, 15~25 parts of Noctilucent materials are as optical surface material;
(3) stone:After cementing material in bed material, curing agent, pigment and filler are well mixed, it is layered under normal temperature on road, Form initial bed;After cementing material in optical surface material, curing agent, reflectorized material, Noctilucent material are well mixed, under normal temperature It is layered on cured bed material, forms optics surface layer, after the solidification of optics surface layer, that is, the night for obtaining the present invention is lasting spontaneous Light, strong reflective type roadmarking.
10. night according to claim 9 continues self-luminous, strong reflective type roadmarking, it is characterised in that:
One or more in the cementing material epoxy gluing agent, polyurethane cementing agent, resin;
The filler is the mixing of one or more former materials of former material such as calcium powder, quartz sand, stone flour;
The pigment includes organic pigment or inorganic pigment;
The reflectorized material includes one or both of glass microballoon, highlighted reflectorized material;
The Noctilucent material includes one or both of long-acting noctilucent material, short-acting Noctilucent material.
11. the night according to claim 9 or 10 continues self-luminous, strong reflective type roadmarking, it is characterised in that:It is described It is further comprising the steps of before the solidification of optics surface layer after optical surface material is layered on cured bed material by step (3):With spray 30~50 parts of glass microballoons are uniformly sprayed on optics surface layer by jet device, and the number is mass fraction.
CN201710575578.3A 2017-07-14 2017-07-14 Night continues self-luminous, strong reflective type roadmarking and preparation method thereof Pending CN107459907A (en)

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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108276899A (en) * 2018-01-25 2018-07-13 天途路业集团有限公司 A kind of multicomponent spraying gage mark coating and its preparation method and application
CN109098109A (en) * 2018-07-09 2018-12-28 广东工业大学 A kind of road markings material and road pavement method
CN109189058A (en) * 2018-07-18 2019-01-11 深圳市海梁科技有限公司 A kind of multi-wavelength lacquer painting, dynamic light stream line walking navigation system and automatic driving vehicle
CN110079138A (en) * 2019-05-05 2019-08-02 南宁华之邦交通设施材料有限公司 A kind of high compactness anti-pollution gage mark coating
CN110408330A (en) * 2019-06-28 2019-11-05 江西盛富莱定向反光材料有限公司 A kind of all-weather road pearl adhesive
CN111333369A (en) * 2020-03-11 2020-06-26 沈阳建筑大学 Road traffic marking material and preparation method thereof
CN111454646A (en) * 2020-06-04 2020-07-28 云南独树林涂料有限公司 High-brightness double-component marking paint and preparation method thereof
CN111777888A (en) * 2020-07-13 2020-10-16 吉林省交通科学研究所 Self-luminous light-reflecting coating for inner wall of highway tunnel and application method
CN113045946A (en) * 2021-04-23 2021-06-29 长安大学 Pavement marking material, preparation method thereof and vehicle vision induction driving method
CN115073990A (en) * 2022-06-16 2022-09-20 广东华路交通科技有限公司 Double-sparse long-acting reflective road marking and construction method
CN115181486A (en) * 2022-08-12 2022-10-14 武汉工程大学 Long-afterglow self-luminous road marking paint and preparation method thereof
CN116731600A (en) * 2023-08-14 2023-09-12 广东伯乐路标科技有限公司 Anti-cracking hot-melting reflective marking paint and preparation device thereof
CN116948510A (en) * 2023-07-20 2023-10-27 哈尔滨工业大学 Solvent-free polyurethane-based phosphorescent road marking paint and preparation and durability evaluation method thereof

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CN1254738A (en) * 1998-11-25 2000-05-31 孙逸龙 Multi-purposed both reflecting and luminous colour mixture for optical marks
CN2535886Y (en) * 2002-04-01 2003-02-12 深圳市清华彩虹纳米材料高科技有限公司 Reflecting and self-light-emitting two-functional road marking paint

Patent Citations (2)

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Publication number Priority date Publication date Assignee Title
CN1254738A (en) * 1998-11-25 2000-05-31 孙逸龙 Multi-purposed both reflecting and luminous colour mixture for optical marks
CN2535886Y (en) * 2002-04-01 2003-02-12 深圳市清华彩虹纳米材料高科技有限公司 Reflecting and self-light-emitting two-functional road marking paint

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108276899A (en) * 2018-01-25 2018-07-13 天途路业集团有限公司 A kind of multicomponent spraying gage mark coating and its preparation method and application
CN109098109A (en) * 2018-07-09 2018-12-28 广东工业大学 A kind of road markings material and road pavement method
CN109098109B (en) * 2018-07-09 2021-07-06 广东工业大学 Road marking material and road paving method
CN109189058B (en) * 2018-07-18 2021-10-15 深圳市海梁科技有限公司 Multi-wavelength paint surface and dynamic optical flow line patrol navigation system and unmanned vehicle
CN109189058A (en) * 2018-07-18 2019-01-11 深圳市海梁科技有限公司 A kind of multi-wavelength lacquer painting, dynamic light stream line walking navigation system and automatic driving vehicle
CN110079138A (en) * 2019-05-05 2019-08-02 南宁华之邦交通设施材料有限公司 A kind of high compactness anti-pollution gage mark coating
CN110408330A (en) * 2019-06-28 2019-11-05 江西盛富莱定向反光材料有限公司 A kind of all-weather road pearl adhesive
CN110408330B (en) * 2019-06-28 2021-11-26 江西盛富莱光学科技股份有限公司 Adhesive for all-weather road beads
CN111333369A (en) * 2020-03-11 2020-06-26 沈阳建筑大学 Road traffic marking material and preparation method thereof
CN111454646A (en) * 2020-06-04 2020-07-28 云南独树林涂料有限公司 High-brightness double-component marking paint and preparation method thereof
CN111777888B (en) * 2020-07-13 2022-01-14 吉林省交通科学研究所 Self-luminous light-reflecting coating for inner wall of highway tunnel and application method
CN111777888A (en) * 2020-07-13 2020-10-16 吉林省交通科学研究所 Self-luminous light-reflecting coating for inner wall of highway tunnel and application method
CN113045946A (en) * 2021-04-23 2021-06-29 长安大学 Pavement marking material, preparation method thereof and vehicle vision induction driving method
CN115073990A (en) * 2022-06-16 2022-09-20 广东华路交通科技有限公司 Double-sparse long-acting reflective road marking and construction method
CN115181486A (en) * 2022-08-12 2022-10-14 武汉工程大学 Long-afterglow self-luminous road marking paint and preparation method thereof
CN116948510A (en) * 2023-07-20 2023-10-27 哈尔滨工业大学 Solvent-free polyurethane-based phosphorescent road marking paint and preparation and durability evaluation method thereof
CN116731600A (en) * 2023-08-14 2023-09-12 广东伯乐路标科技有限公司 Anti-cracking hot-melting reflective marking paint and preparation device thereof
CN116731600B (en) * 2023-08-14 2023-10-20 广东伯乐路标科技有限公司 Anti-cracking hot-melting reflective marking paint and preparation device thereof

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