CN108914800A - A kind of reflective curb of self-luminous-and preparation method thereof - Google Patents
A kind of reflective curb of self-luminous-and preparation method thereof Download PDFInfo
- Publication number
- CN108914800A CN108914800A CN201810867424.6A CN201810867424A CN108914800A CN 108914800 A CN108914800 A CN 108914800A CN 201810867424 A CN201810867424 A CN 201810867424A CN 108914800 A CN108914800 A CN 108914800A
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- China
- Prior art keywords
- self
- curb
- luminous
- correct
- reflective
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Links
- 238000002360 preparation method Methods 0.000 title claims description 13
- 239000000463 material Substances 0.000 claims abstract description 121
- 238000013507 mapping Methods 0.000 claims abstract description 45
- 230000000994 depressogenic effect Effects 0.000 claims abstract description 18
- 238000002156 mixing Methods 0.000 claims abstract description 13
- 239000000843 powder Substances 0.000 claims description 39
- 239000000758 substrate Substances 0.000 claims description 33
- 239000002994 raw material Substances 0.000 claims description 31
- 238000001035 drying Methods 0.000 claims description 22
- 239000004575 stone Substances 0.000 claims description 22
- 238000007711 solidification Methods 0.000 claims description 13
- 230000008023 solidification Effects 0.000 claims description 13
- 239000003960 organic solvent Substances 0.000 claims description 10
- 230000002269 spontaneous effect Effects 0.000 claims description 7
- 230000008859 change Effects 0.000 claims description 3
- 238000012545 processing Methods 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 16
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 13
- 238000005260 corrosion Methods 0.000 description 10
- 230000007797 corrosion Effects 0.000 description 10
- 238000000034 method Methods 0.000 description 9
- 239000003963 antioxidant agent Substances 0.000 description 8
- 230000003078 antioxidant effect Effects 0.000 description 8
- 235000006708 antioxidants Nutrition 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 8
- 235000019441 ethanol Nutrition 0.000 description 8
- 239000011521 glass Substances 0.000 description 8
- 239000004579 marble Substances 0.000 description 8
- 239000004408 titanium dioxide Substances 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- JGIATAMCQXIDNZ-UHFFFAOYSA-N calcium sulfide Chemical compound [Ca]=S JGIATAMCQXIDNZ-UHFFFAOYSA-N 0.000 description 7
- QENHCSSJTJWZAL-UHFFFAOYSA-N magnesium sulfide Chemical compound [Mg+2].[S-2] QENHCSSJTJWZAL-UHFFFAOYSA-N 0.000 description 7
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- 238000002310 reflectometry Methods 0.000 description 6
- 239000007822 coupling agent Substances 0.000 description 5
- 238000002513 implantation Methods 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- -1 alcohol ester Chemical class 0.000 description 4
- IWOUKMZUPDVPGQ-UHFFFAOYSA-N barium nitrate Chemical compound [Ba+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O IWOUKMZUPDVPGQ-UHFFFAOYSA-N 0.000 description 4
- 230000001795 light effect Effects 0.000 description 4
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 4
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- DHEQXMRUPNDRPG-UHFFFAOYSA-N strontium nitrate Chemical compound [Sr+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O DHEQXMRUPNDRPG-UHFFFAOYSA-N 0.000 description 4
- UBXAKNTVXQMEAG-UHFFFAOYSA-L strontium sulfate Chemical compound [Sr+2].[O-]S([O-])(=O)=O UBXAKNTVXQMEAG-UHFFFAOYSA-L 0.000 description 4
- 239000003086 colorant Substances 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 3
- 235000019341 magnesium sulphate Nutrition 0.000 description 3
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 3
- 229910052939 potassium sulfate Inorganic materials 0.000 description 3
- 235000011151 potassium sulphates Nutrition 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 description 3
- 235000011152 sodium sulphate Nutrition 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- XURCIPRUUASYLR-UHFFFAOYSA-N Omeprazole sulfide Chemical compound N=1C2=CC(OC)=CC=C2NC=1SCC1=NC=C(C)C(OC)=C1C XURCIPRUUASYLR-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- CJDPJFRMHVXWPT-UHFFFAOYSA-N barium sulfide Chemical compound [S-2].[Ba+2] CJDPJFRMHVXWPT-UHFFFAOYSA-N 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910001386 lithium phosphate Inorganic materials 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 235000010333 potassium nitrate Nutrition 0.000 description 2
- 239000004323 potassium nitrate Substances 0.000 description 2
- DPLVEEXVKBWGHE-UHFFFAOYSA-N potassium sulfide Chemical compound [S-2].[K+].[K+] DPLVEEXVKBWGHE-UHFFFAOYSA-N 0.000 description 2
- 238000007761 roller coating Methods 0.000 description 2
- 229910001961 silver nitrate Inorganic materials 0.000 description 2
- TWQULNDIKKJZPH-UHFFFAOYSA-K trilithium;phosphate Chemical compound [Li+].[Li+].[Li+].[O-]P([O-])([O-])=O TWQULNDIKKJZPH-UHFFFAOYSA-K 0.000 description 2
- IDQBJILTOGBZCR-UHFFFAOYSA-N 1-butoxypropan-1-ol Chemical compound CCCCOC(O)CC IDQBJILTOGBZCR-UHFFFAOYSA-N 0.000 description 1
- VETPHHXZEJAYOB-UHFFFAOYSA-N 1-n,4-n-dinaphthalen-2-ylbenzene-1,4-diamine Chemical compound C1=CC=CC2=CC(NC=3C=CC(NC=4C=C5C=CC=CC5=CC=4)=CC=3)=CC=C21 VETPHHXZEJAYOB-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- OQPHEVHDBFEJRQ-UHFFFAOYSA-N [Li].P(O)(O)(O)=O Chemical compound [Li].P(O)(O)(O)=O OQPHEVHDBFEJRQ-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- COOGPNLGKIHLSK-UHFFFAOYSA-N aluminium sulfide Chemical compound [Al+3].[Al+3].[S-2].[S-2].[S-2] COOGPNLGKIHLSK-UHFFFAOYSA-N 0.000 description 1
- 230000003321 amplification Effects 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- AGBQKNBQESQNJD-UHFFFAOYSA-M lipoate Chemical group [O-]C(=O)CCCCC1CCSS1 AGBQKNBQESQNJD-UHFFFAOYSA-M 0.000 description 1
- 235000019136 lipoic acid Nutrition 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 238000003199 nucleic acid amplification method Methods 0.000 description 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000011514 reflex Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229960002663 thioctic acid Drugs 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01F—ADDITIONAL WORK, SUCH AS EQUIPPING ROADS OR THE CONSTRUCTION OF PLATFORMS, HELICOPTER LANDING STAGES, SIGNS, SNOW FENCES, OR THE LIKE
- E01F9/00—Arrangement of road signs or traffic signals; Arrangements for enforcing caution
- E01F9/50—Road surface markings; Kerbs or road edgings, specially adapted for alerting road users
- E01F9/535—Kerbs or road edgings specially adapted for alerting road users
- E01F9/541—Kerbs
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01F—ADDITIONAL WORK, SUCH AS EQUIPPING ROADS OR THE CONSTRUCTION OF PLATFORMS, HELICOPTER LANDING STAGES, SIGNS, SNOW FENCES, OR THE LIKE
- E01F9/00—Arrangement of road signs or traffic signals; Arrangements for enforcing caution
- E01F9/50—Road surface markings; Kerbs or road edgings, specially adapted for alerting road users
- E01F9/535—Kerbs or road edgings specially adapted for alerting road users
- E01F9/547—Kerbs or road edgings specially adapted for alerting road users illuminated
Abstract
The present invention provides a kind of reflective curbs of self-luminous-, including upper surface, oblique shoulder, facade, basic buried portion and base station cross face, upper surface, oblique shoulder and the facade of the curb to have Z-Correct bump mapping Z-correct structure；The depressed section of the Z-Correct bump mapping Z-correct structure is attached with self-luminescent material or reflectorized material or the reflective mixing material of self-luminous-.The reflective curb of self-luminous-provided by the invention has Z-Correct bump mapping Z-correct structure, and depressed section is attached with self-luminous and/or reflectorized material, wherein Z-Correct bump mapping Z-correct structure can assist reflectorized material to reflect from the light source of multiple angles, self-luminescent material can absorb natural light on daytime, the effect of luminous blast can be played at night, urban road edge-light degree of illuminating can be effectively promoted, the current safety of traffic is improved.
Description
Technical field
The present invention relates to the technical field of construction material, in particular to the reflective curb of a kind of self-luminous-and its preparation side
Method.
Background technique
With social and economic development, urban population rapidly increases, and city size constantly expands, and urban road is with every
The growth rate in 20% or more year is fast-developing.
Currently, appearance of city is maked rapid progress, and beautifying city space has become the necessity of urban construction.In urban road
In Construction Practice, road edge is provided with the curb higher than road surface 150-200mm.Curb is that garage is distinguished on road surface
The boundary in road, pavement, greenery patches, isolation strip and road other parts plays and ensures pedestrian, vehicular traffic safety and guarantee road surface
Neat in edge and protection roadbed, the effect for protecting road surface.
Downtown roads generally all have street lamp facility, but since the natural color of curb stone material itself is with extinction work
With at the night of dim light, the curb of road edge is difficult to clearly be recognized by driver.Road construction and traffic administration institute
Automobile scratches and hits curb to door in order to prevent, draws white or yellow reflecting marking line in the position of road surface close to curb
It plays a warning role.But since the tag line of these whites or yellow generally uses thermoplastic resin material, this material is in sunlight
Irradiation, rain erosion are gradually desalinated in wheel friction process, and mark warning function gradually weakens.
Have great importance so researching and developing a kind of curb with self-luminous and/or reflection action.
Summary of the invention
In view of this, it is an object of that present invention to provide reflective curbs of a kind of self-luminous-and preparation method thereof.The present invention mentions
The reflective curb of the self-luminous-of confession has reflex to the light source of multiple angles, natural light is can absorb on daytime, in night lamp
Reflective blast and/or spontaneous light effect are good under light action.
In order to achieve the above-mentioned object of the invention, the present invention provides following technical scheme：
A kind of reflective curb of self-luminous-, including upper surface, oblique shoulder, facade, basic buried portion and base station cross face,
It is characterized in that, the upper surface of the curb, oblique shoulder and facade have Z-Correct bump mapping Z-correct structure；
The depressed section surface of the Z-Correct bump mapping Z-correct structure is attached with self-luminescent material and/or reflectorized material.
Preferably, the reflectorized material is by including that the raw material of following mass percent is prepared：
The organic solvent of surplus.
Preferably, the self-luminescent material is luminescent powder.
Preferably, when the depressed section of the Z-Correct bump mapping Z-correct structure is attached with self-luminescent material and reflectorized material, it is described from
The mass ratio of luminescent material and reflectorized material is 1:0.5~5.
Preferably, the self-luminescent material of the depressed section attachment and/or the thickness of reflectorized material independently are 20~50 μ
m。
Preferably, the height of projection of the Z-Correct bump mapping Z-correct structure is 1~3mm；Cup depth is 1~3mm.
The present invention provides the preparation methods of the reflective curb of self-luminous-described in above scheme, include the following steps：
(1) it is poured in a mold after mixing curb substrate material, obtains curb stone foundation base；In the mould structure
The position of corresponding upper surface, oblique shoulder and facade is provided with Z-Correct bump mapping Z-correct structure；
(2) the curb stone foundation base is dried, obtains curb substrate；
(3) the curb substrate Z-Correct bump mapping Z-correct knot is implanted into after mixing the raw material of self-luminescent material and/or reflectorized material
The depressed section of structure obtains the reflective curb of self-luminous-after solidification.
Preferably, the drying includes natural drying or heat drying；The temperature of the heat drying is 80~200 DEG C；
The time of the natural drying >=72h.
Preferably, the cured temperature is 80~200 DEG C, and the cured time is 10~20min.
It preferably, further include to the curb substrate carry out table for being attached with self-luminous and/or reflectorized material after the solidification
Facing sand light processing.
The present invention provides a kind of reflective curb of self-luminous-, including upper surface, oblique shoulder, facade, basic buried portion and
Base station cross face, upper surface, oblique shoulder and the facade of the curb have Z-Correct bump mapping Z-correct structure；The Z-Correct bump mapping Z-correct structure it is recessed
Sunken part of the surface is attached with self-luminescent material and/or reflectorized material.The reflective curb of self-luminous-provided by the invention has bumps
Texture structure, and depressed section is attached with self-luminous and/or reflectorized material, wherein Z-Correct bump mapping Z-correct structure can assist reflectorized material pair
Light source from multiple angles is reflected, and self-luminescent material can absorb natural light on daytime, can play luminous increasing at night
Bright effect can effectively promote urban road edge-light degree of illuminating, and improve the current safety of traffic；Further, the present invention provides
The reflective curb good in oxidation resistance of self-luminous-, corrosion-resistant and good weatherability, it is applied widely, can be applied to road edge,
Bridge edge, airfield runway edge etc. have the place of warning and blast demand.
The present invention provides the preparation method of the reflective curb of self-luminous-described in above scheme, preparation method of the invention
Simply, step is few, at low cost.
Detailed description of the invention
Fig. 1 is the schematic perspective view of the reflective curb of self-luminous-of the present invention；
Fig. 2 is the cross section structure schematic diagram of the reflective curb of self-luminous-of the present invention；
In FIG. 1 to FIG. 2：The upper surface 1-, 2- oblique shoulder, 3- facade, the basis 4- buried portion, 5- base station cross section, 6- are spontaneous
Light and/or reflectorized material, 7- curb substrate, 8- Z-Correct bump mapping Z-correct structure.
Specific embodiment
The present invention provides a kind of reflective curb of self-luminous-, including upper surface, oblique shoulder, facade, basic buried portion and
Base station cross face；Upper surface, oblique shoulder and the facade towards road direction of the curb have Z-Correct bump mapping Z-correct structure；The bumps
The depressed section surface of texture structure is attached with self-luminescent material and/or reflectorized material.
The present invention does not have particular/special requirement to the shape of the reflective curb of the self-luminous-, ripe using those skilled in the art
The curb shape known, specific shape is as shown in Figure 1, include upper surface, oblique shoulder, facade, basic buried portion and base
Platform cross face, the present invention do not have the specific size of the upper surface, oblique shoulder, facade, basic buried portion and base station cross face
Particular/special requirement is preferably adjusted according to the size that application needs in a specific embodiment of the present invention.
Upper surface, oblique shoulder and the facade towards road direction of curb provided by the invention have Z-Correct bump mapping Z-correct structure.?
In the present invention, the height of projection of the Z-Correct bump mapping Z-correct structure is preferably 1~3mm, more preferably 2mm, and cup depth is preferably 1~
3mm, more preferably 2mm.The present invention does not have particular/special requirement to the shape of the Z-Correct bump mapping Z-correct structure, specifically can be straight line
Shape, circle, triangle, square or other irregular geometry solid figures.The Z-Correct bump mapping Z-correct of plate surface of the present invention
Structure can reflect the light source from all angles, can effectively promote urban road edge-light degree of illuminating, and improve traffic
Current safety.
The depressed section of the Z-Correct bump mapping Z-correct structure of curb provided by the invention is attached with self-luminescent material and/or reflective material
Material.In the present invention, the self-luminescent material and/or reflectorized material are preferably 20~50 μ in the thickness of the attachment of depressed section
M, more preferably 30~40 μm.
In the present invention, the self-luminescent material is preferably luminescent powder, and the present invention is preferably carried out according to the color of luminescent powder
It prepares.
In the present invention, when the luminescent powder is red noctilucent powder, the red noctilucent powder preferably includes barium sulfate 45
~55g, 30~50g of magnesium sulfate, 1~3g of lithium phosphate, 1~3g of copper nitrate, more preferably barium sulfate 50g, magnesium sulfate 40g, phosphoric acid
Lithium 2g, copper nitrate 2g.
In the present invention, when the luminescent powder is blue noctilucent powder, the blue noctilucent powder preferably includes calcium sulfide 50
~68 grams, 4~6 grams of sodium sulphate, 4~6 grams of potassium sulfate, 9~11 grams of strontium sulfate, 7~8 grams of sodium chloride, 1 gram of silver nitrate, magnesium sulfide 9
~10 grams, more preferably 60~65 grams of calcium sulfide, 5 grams of sodium sulphate, 5 grams of potassium sulfate, 10 grams of strontium sulfate, 7.5 grams of sodium chloride, nitric acid
1 gram, 9.5 grams of magnesium sulfide of silver.
In the present invention, when the luminescent powder is purple noctilucent powder, the purple noctilucent powder preferably includes calcium sulfide 62
~64 grams, 25~27 grams of magnesium sulfide, 9~10 grams of vulcanized sodium, 1 gram of strontium nitrate, more preferably 63 grams of calcium sulfide, 26 grams of magnesium sulfide,
9.5 grams of vulcanized sodium, 1 gram of strontium nitrate.
In the present invention, when the luminescent powder is green noctilucent powder, the green noctilucent powder preferably includes calcium sulfide 54
~56 grams, 1 gram of potassium sulfide, 9~10 grams of vulcanized sodium, 10~14 grams of barium nitrate, 11~14 grams of indium nitrate, more preferably calcium sulfide 55
Gram, 1 gram of potassium sulfide, 9.5 grams of vulcanized sodium, 12 grams of barium nitrate, 12 grams of indium nitrate.
In the present invention, when the luminescent powder is yellow noctilucent powder, the yellow noctilucent powder preferably includes barium sulphide 54
~56 grams, 39~41 grams of magnesium sulfide, 1~3 gram of aluminium sulfide, 1 gram of potassium nitrate, more preferably 55 grams of barium sulphide, 40 grams of magnesium sulfide, sulphur
Change 2 grams of aluminium, 1 gram of potassium nitrate.
In the present invention when above-mentioned luminescent powder requirement is larger, it is by the proportional amplification of the quality of above-mentioned each raw material
It can.
In the present invention, the reflectorized material is preferably by including that the component of following mass percent is prepared：
The organic solvent of surplus.
The raw material of reflective material layer provided by the invention preferably includes blanc fixe 26~38%, and more preferable 30~35%.
In the present invention, the partial size of the blanc fixe is preferably 300~700 mesh, more preferably 400~600 mesh, most preferably 500
Mesh；Blanc fixe acid-alkali-corrosive-resisting is good, and light scattered reflection is functional.
The raw material of reflectorized material provided by the invention preferably includes titanium dioxide 5~15%, more preferably 10~13%.At this
In invention, the partial size of the titanium dioxide is preferably 300~700 mesh, more preferably 400~600 mesh, most preferably 500 mesh.
The preferred raw material of reflectorized material provided by the invention preferably includes pearl powder 7~15%, more preferably 8~12%.
In the present invention, the partial size of the pearl powder is preferably 300~700 mesh, more preferably 400~600 mesh, most preferably 500 mesh.
The raw material of reflectorized material provided by the invention preferably include glass marble microballon powder 13~28%, more preferably 15~
25%.In the present invention, the partial size of the glass marble microballon powder is preferably 300~700 mesh, more preferably 400~600 mesh, most
Preferably 500 mesh.
In the present invention, the titanium dioxide, pearl powder and glass marble microballon powder covering power height, strong coloring force, refractive index are high,
And thermal stability and anti-ultraviolet property are good, and the content of titanium dioxide, pearl powder and glass marble microballon powder is controlled in above-mentioned model
In enclosing, the reflecting properties of reflective material layer can be increased.
The raw material of reflectorized material provided by the invention preferably includes antioxidant 2~5%, preferably 3~4%.In this hair
In bright, the antioxidant is preferably lipoic acid, methyl silicone, antioxidant 1010, antioxidant 1076, irgasfos 168, antioxidant
164, one or more of antioxidant DNP；The present invention improves the anti-aging property of reflectorized material by addition antioxidant.
Reflective material layer provided by the invention preferably includes coupling agent 0.5~3.5%, more preferably 1~2%.In this hair
In bright, the coupling agent is preferably kh560.The present invention is crosslinked and product waterproof, moisture-proof function by adding coupler reinforcement
Energy.
The raw material of reflectorized material provided by the invention preferably includes coalescing agent 6~10%, preferably 7~9%.In this hair
In bright, the coalescing agent is preferably one or more of propandiol butyl ether, propylene glycol methyl ether acetate and alcohol ester 12.This
Invention is combined together various powders and solvent in reflectorized material by adding coalescing agent, increases fastness.
Reflectorized material provided by the invention preferably includes the organic solvent of surplus.In the present invention, the organic solvent is excellent
It is selected as alcohol organic solvent.
Blanc fixe of the present invention, titanium dioxide, pearl powder, glass marble microballon powder, antioxidant, coalescing agent, coupling
The source of agent and organic solvent does not have particular/special requirement, uses commercially available above-mentioned substance.
In the present invention, when the reflective mixing material of the self-luminous-is mixed to get by self-luminescent material and reflectorized material, institute
Stating the mass ratio of self-luminescent material and reflectorized material in the reflective mixing material of self-luminous-is preferably 1:0.5~5, more preferably 1:
1。
In the present invention, when the depressed section in Z-Correct bump mapping Z-correct structure is attached with self-luminous and reflectorized material simultaneously
When, curb provided by the invention has self-luminous and reflection function simultaneously, provided by the invention when only attachment is one of
Curb then only has a kind of corresponding function；In a specific embodiment of the present invention, it can be determined according to the requirement of practical matter
In the type of the material of depressed section attachment；Self-luminous and/or reflectorized material are attached to the recessed of Z-Correct bump mapping Z-correct structure by the present invention
Concave portion point, can prevent external force from scraping or wearing causes self-luminous and reflecting effect to be lost.
The present invention provides the preparation methods of the reflective curb of self-luminous-described in above scheme, include the following steps：
(1) it is poured in a mold after mixing curb substrate material, obtains curb stone foundation base；In the mould structure
Corresponding upper surface, oblique shoulder and facade are provided with Z-Correct bump mapping Z-correct structure, make the upper surface of the curb stone foundation base, oblique shoulder and vertical
Face forms Z-Correct bump mapping Z-correct structure；
(2) the curb stone foundation base is dried, obtains curb substrate；
(3) the curb substrate Z-Correct bump mapping Z-correct knot is implanted into after mixing the raw material of self-luminescent material and/or reflectorized material
The depressed section of structure obtains the reflective curb of self-luminous-after solidification.
The present invention pours in a mold after mixing curb substrate material, obtains curb stone foundation base.In the present invention,
Upper surface, oblique shoulder and facade are corresponded in the mould structure is provided with Z-Correct bump mapping Z-correct structure, makes the curb stone foundation base
Upper surface, oblique shoulder and facade form Z-Correct bump mapping Z-correct structure, the cup depth and height of projection of the Z-Correct bump mapping Z-correct structure and above-mentioned
Scheme is consistent, and details are not described herein.
The present invention does not have particular/special requirement to the curb substrate material, uses raw material system well known to those skilled in the art
Standby curb substrate；In the present invention, in terms of every cubic metre, the curb substrate material is preferably included：Cement 300~
480kg, 150~170kg of water, 1600~1800kg of filler；The filler be preferably sandstone, mine tailings, lithotome particle or
Building castoff；In a specific embodiment of the present invention, it is also preferable to include colorants for the curb substrate material, by the way that color is added
Material makes curb substrate embody different colors；The present invention does not have particular/special requirement to the type and additive amount of the colorant, can root
It is determined according to the requirement to color.
The present invention does not have particular/special requirement to the specific method poured, uses the side of pouring well known to those skilled in the art
Method, in the specific embodiment of this field, will the curb substrate material mix after pour into mold, by vibration or
Raw material is compacted by extruding, thus desired product shape.
After the completion of pouring, the present invention is preferably demoulded, and obtains the wet base of curb stone foundation.Tool of the present invention to the demoulding
Body method does not have particular/special requirement, can be by the wet base of curb stone foundation from mold using method well known to those skilled in the art
Complete abjection.
After the completion of demoulding, the wet base of curb stone foundation is dried the present invention, obtains curb substrate.In the present invention,
The drying preferably includes natural drying or heat drying；The natural drying is preferably spontaneously dried at room temperature, this
Invent the natural drying time preferably >=72h, more preferably 80~100h.In the present invention, the heat drying is preferred
For heat radiation drying or steam heating；The temperature of the heat drying is preferably 80~200 DEG C, and more preferably 100~150 DEG C；
In heat drying process of the invention, after heating 10~20min, basic base can achieve the state of substantially dry.In this hair
In bright specific embodiment, first basic base can be thermally dried, after substantially dry, then be dried in a natural environment solid
Change.
After obtaining curb substrate, after the present invention mixes the raw material of self-luminescent material and/or reflectorized material described in implantation
The depressed section of curb substrate Z-Correct bump mapping Z-correct structure, obtains the reflective curb of self-luminous-after solidification.In the present invention, described
The raw material of self-luminescent material and reflectorized material is consistent with above scheme, and details are not described herein；When by self-luminescent material and reflective material
When material is implanted into jointly, the ratio between gross mass and the gross mass of reflectorized material raw material of the self-luminescent material raw material are preferably 1:0.5
~5, more preferably 1:1.
The present invention preferably passes through the recessed portion that raw material is implanted into the curb substrate Z-Correct bump mapping Z-correct structure by spraying or roller coating
Point；The present invention does not have particular/special requirement to the specific method of the spraying or roller coating, uses spraying well known to those skilled in the art
Or rolling process, self-luminescent material and/or reflectorized material can be attached to depressed section, and form the thickness of requirement.
After the completion of implantation, the present invention solidifies the curb for being attached with self-luminous and/or reflective wet stock, arrives spontaneous
The reflective curb of light-.In the present invention, the cured temperature is preferably 80~200 DEG C, and more preferably 100~180 DEG C, most
Preferably 150 DEG C；The cured time is preferably 10~20min, more preferably 13~15min.
After the completion of solidification, the present invention it is also preferable to include will be attached with the curb substrate of self-luminous and/or reflectorized material into
The processing of row sanding surface.The specific method that the present invention handles the sanding surface does not have particular/special requirement, uses art technology
Sanding surface processing method known to personnel.The present invention is handled by sanding surface, by the variegated removal of product surface.
Reflective curb of self-luminous-provided by the invention and preparation method thereof is carried out specifically below with reference to embodiment
It is bright, but they cannot be interpreted as limiting the scope of the present invention.
Embodiment 1
Reflectorized material raw material components：Blanc fixe 36wt%, titanium dioxide 10wt%, pearl powder 13wt%, glass marble microballon
Powder 20wt%, antioxidant (irgasfos 168) 3wt%, coalescing agent (alcohol ester 12) 10wt%, coupling agent (kh560)
3wt%, the organic solvent (ethyl alcohol) of surplus；
Self-luminescent material material component：Red noctilucent powder：Barium sulfate 50g, magnesium sulfate 40g, lithium phosphate 2g, copper nitrate 2g；
(1) it is poured in a mold after mixing curb substrate material, obtains curb stone foundation base, mold corresponding positions install
It is equipped with triangle Z-Correct bump mapping Z-correct structure, upper surface, oblique shoulder and the facade of curb stone foundation base is made to form Z-Correct bump mapping Z-correct structure；
(2) curb stone foundation base is carried out to steam drying 10min at 100 DEG C, it is then dry through 72h in the natural environment
Solidification, reaches intensity requirement, obtains curb substrate；
(3) raw material of self-luminescent material and reflectorized material is mixed into (self-luminescent material total mass of raw material：Reflectorized material raw material
Gross mass is 1:1) it is sprayed after, by the recess of self-luminescent material and reflectorized material implantation curb substrate Z-Correct bump mapping Z-correct structure
Part obtains the reflective curb of self-luminous-in 100 DEG C of solidification 20min.
Using the reflectivity of the reflectance test instrument detection reflective curb of self-luminous-, can obtain reflectivity is 90% or more,
Night is observed the reflective curb of self-luminous-, shows that spontaneous light effect is obvious；To the corrosion resistant of the reflective curb of self-luminous-
Corrosion is detected, and the reflective curb of the self-luminous-obtained as the result is shown has good corrosion-resistant under conditions of pH is 4~10
Property.
Embodiment 2
Reflectorized material raw material components：Blanc fixe 33wt%, titanium dioxide 11wt%, pearl powder 14wt%, glass marble microballon
Powder 21wt%, antioxidant (irgasfos 168) 2wt%, coalescing agent (alcohol ester 12) 8wt%, coupling agent (kh560) 3wt%,
The organic solvent (ethyl alcohol) of surplus；
Self-luminescent material material component：Blue noctilucent powder：60~65 grams of calcium sulfide, 5 grams of sodium sulphate, 5 grams of potassium sulfate, sulfuric acid
10 grams of strontium, 7.5 grams of sodium chloride, 1 gram of silver nitrate, 9.5 grams of magnesium sulfide；
(1) it is poured in a mold after mixing curb substrate material, obtains curb stone foundation base, mold corresponding positions install
It is equipped with round Z-Correct bump mapping Z-correct structure, upper surface, oblique shoulder and the facade of curb stone foundation base is made to form Z-Correct bump mapping Z-correct structure；
(2) curb stone foundation base is carried out to steam drying 10min at 200 DEG C, it is then dry through 72h in the natural environment
Solidification, reaches intensity requirement, obtains curb substrate；
(3) raw material of self-luminescent material and reflectorized material is mixed into (self-luminescent material total mass of raw material：Reflectorized material raw material
Gross mass is 1:1) it is sprayed after, by the recess of self-luminescent material and reflectorized material implantation curb substrate Z-Correct bump mapping Z-correct structure
Part obtains the reflective curb of self-luminous-in 200 DEG C of solidification 10min.
Using the reflectivity of the reflectance test instrument detection reflective curb of self-luminous-, can obtain reflectivity is 90% or more,
Night is observed the reflective curb of self-luminous-, shows that spontaneous light effect is obvious；To the corrosion resistant of the reflective curb of self-luminous-
Corrosion is detected, and the reflective curb of the self-luminous-obtained as the result is shown has good corrosion-resistant under conditions of pH is 4~10
Property.
Embodiment 3
Reflectorized material raw material components：Blanc fixe 28wt%, titanium dioxide 13wt%, pearl powder 15wt%, glass marble microballon
Powder 23wt%, antioxidant (irgasfos 168) 2wt%, coalescing agent (alcohol ester 12) 8wt%, coupling agent (kh560) 3wt%,
The organic solvent (ethyl alcohol) of surplus；
(1) it is poured in a mold after mixing curb substrate material, obtains curb stone foundation base, mold corresponding positions install
It is equipped with square Z-Correct bump mapping Z-correct structure, upper surface, oblique shoulder and the facade of curb stone foundation base is made to form Z-Correct bump mapping Z-correct structure；
(2) curb stone foundation base is subjected to steam drying at 150 DEG C, then in the natural environment through 72h dry solidification,
Reach intensity requirement, obtains curb substrate；
(3) raw material of self-luminescent material and reflectorized material is mixed into (self-luminescent material total mass of raw material：Reflectorized material raw material
Gross mass is 1:1) it is sprayed after, by the recess of self-luminescent material and reflectorized material implantation curb substrate Z-Correct bump mapping Z-correct structure
Part obtains the reflective curb of self-luminous-in 150 DEG C of solidification 15min.
Using the reflectivity of the reflectance test instrument detection reflective curb of self-luminous-, can obtain reflectivity is 90% or more,
Night is observed the reflective curb of self-luminous-, shows that spontaneous light effect is obvious；To the corrosion resistant of the reflective curb of self-luminous-
Corrosion is detected, and the reflective curb of the self-luminous-obtained as the result is shown has good corrosion-resistant under conditions of pH is 4~10
Property.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also answered
It is considered as protection scope of the present invention.
Claims (10)
1. a kind of reflective curb of self-luminous-, including upper surface, oblique shoulder, facade, basic buried portion and base station cross face,
It is characterized in that, upper surface, oblique shoulder and the facade of the curb have Z-Correct bump mapping Z-correct structure；
The depressed section surface of the Z-Correct bump mapping Z-correct structure is attached with self-luminescent material and/or reflectorized material.
2. the reflective curb of self-luminous-according to claim 1, which is characterized in that the reflectorized material is by including following
The raw material of mass percent is prepared：
The organic solvent of surplus.
3. the reflective curb of self-luminous-according to claim 1, which is characterized in that the self-luminescent material is luminescent powder.
4. the reflective curb of self-luminous-according to claim 1, which is characterized in that the recess of the Z-Correct bump mapping Z-correct structure
When part is attached with self-luminescent material and reflectorized material, the mass ratio of the self-luminescent material and reflectorized material is 1:0.5~5.
5. the reflective curb of self-luminous-according to claim 1, which is characterized in that the depressed section adheres to spontaneous
The thickness of luminescent material and/or reflectorized material independently is 20~50 μm.
6. the reflective curb of self-luminous-according to claim 1 or 5, which is characterized in that the Z-Correct bump mapping Z-correct structure it is convex
Playing height is 1~3mm；Cup depth is 1~3mm.
7. the preparation method of the reflective curb of self-luminous-described in claim 1~6 any one, includes the following steps：
(1) it is poured in a mold after mixing curb substrate material, obtains curb stone foundation base；It is corresponding in the mould structure
The position of upper surface, oblique shoulder and facade is provided with Z-Correct bump mapping Z-correct structure；
(2) the curb stone foundation base is dried, obtains curb substrate；
(3) the curb substrate Z-Correct bump mapping Z-correct structure is implanted into after mixing the raw material of self-luminescent material and/or reflectorized material
Depressed section obtains the reflective curb of self-luminous-after solidification.
8. preparation method according to claim 7, which is characterized in that the drying includes natural drying or heat drying；
The temperature of the heat drying is 80~200 DEG C；The time of the natural drying >=72h.
9. preparation method according to claim 7, which is characterized in that the cured temperature is 80~200 DEG C, described solid
The time of change is 10~20min.
10. preparation method according to claim 7, which is characterized in that further include to being attached with self-luminous after the solidification
And/or the curb substrate of reflectorized material carries out sanding surface processing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810867424.6A CN108914800A (en) | 2018-08-02 | 2018-08-02 | A kind of reflective curb of self-luminous-and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810867424.6A CN108914800A (en) | 2018-08-02 | 2018-08-02 | A kind of reflective curb of self-luminous-and preparation method thereof |
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| CN108914800A true CN108914800A (en) | 2018-11-30 |
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| CN201810867424.6A Pending CN108914800A (en) | 2018-08-02 | 2018-08-02 | A kind of reflective curb of self-luminous-and preparation method thereof |
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| CN113480911A (en) * | 2021-06-04 | 2021-10-08 | 天途路业集团有限公司 | Preparation method of novel primer |
| CN114736573A (en) * | 2022-04-29 | 2022-07-12 | 温州环诺新材料科技有限公司 | Road pile surface coating method |
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Application publication date: 20181130 |