CN107441541B - Preparation method of liquid deodorant - Google Patents
Preparation method of liquid deodorant Download PDFInfo
- Publication number
- CN107441541B CN107441541B CN201710763615.3A CN201710763615A CN107441541B CN 107441541 B CN107441541 B CN 107441541B CN 201710763615 A CN201710763615 A CN 201710763615A CN 107441541 B CN107441541 B CN 107441541B
- Authority
- CN
- China
- Prior art keywords
- acid
- salt
- metal salt
- deodorant
- liquid deodorant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
- B01D53/58—Ammonia
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/72—Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2209/00—Aspects relating to disinfection, sterilisation or deodorisation of air
- A61L2209/20—Method-related aspects
- A61L2209/21—Use of chemical compounds for treating air or the like
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/306—Organic sulfur compounds, e.g. mercaptans
Abstract
The invention relates to a preparation method of a liquid deodorant, which comprises the following steps: step (1): adding a deodorant metal salt into water at 50-100 ℃ for dissolving, stirring by using a mixer, and adding an isoniazid compound and an adipic acid compound before or after adding ferrous sulfate; step (2): adding the potassium hydroxide aqueous solution, the stabilizer and the chelating agent, stirring and cooling; and (3): and (3) cooling the mixture obtained in the step (2) to room temperature, and standing to obtain a transparent solution at the upper half part, wherein the solution is the liquid deodorant. By adopting the preparation method of the liquid deodorant, the isoniazid compound and the adipic acid compound are added, so that the deodorant metal salt, particularly ferrous salt or zinc salt, in the liquid deodorant can be stabilized, the deodorant or the freshener can be improved to decompose and remove amine, hydrogen sulfide, ammonia, mercaptan, aldehyde compounds and the like, and ammonia can not be generated.
Description
Technical Field
The invention relates to the field of deodorization, in particular to a liquid deodorant, and specifically relates to a preparation method of the liquid deodorant.
Background
In recent years, with diversification of life, improvement of living standard, change and increase of human consciousness, and the like, demands for products having high-level deodorizing function such as clothes, household goods, indoor products, various industrial materials, and the like have further increased. The existence of the malodors comprises that building materials containing chemical substances such as formaldehyde are largely used in new houses, so that the chemical substances are largely gasified and separated to cause harm; on the other hand, the odor includes kitchen odor, toilet odor, odor such as sweat odor and halitosis, pet odor, industrial waste odor, etc.
These malodors are unavoidable in human life. Therefore, methods for coping with malodors, for example, so-called masking techniques for making malodors imperceptible to humans, so-called deodorizing techniques for capturing malodorous components, and the like, have been actively studied. In the prior art, after analyzing malodorous components, sulfur-containing compounds, aldehydes, lower fatty acids, various amines and the like are reported as malodorous components.
However, some ingredients in the current deodorant and the preparation method thereof are not stable enough, so that the deodorizing effect is not good enough.
Disclosure of Invention
The present invention is to overcome the above disadvantages of the prior art and to provide a method for preparing a liquid deodorant having improved stability and enhanced deodorizing effect and flame-retardant effect.
In order to achieve the above object, the method for preparing a liquid deodorant of the present invention comprises:
the preparation method comprises the following steps:
step (1): adding a deodorant metal salt into water at 50-100 ℃ for dissolving, stirring by using a mixer, and adding an isoniazid compound and an adipic acid compound before or after adding ferrous sulfate;
step (2): adding the potassium hydroxide aqueous solution, the stabilizer and the chelating agent, stirring and cooling;
and (3): and (3) cooling the mixture obtained in the step (2) to room temperature, and standing to obtain a transparent solution at the upper half part, wherein the solution is the liquid deodorant.
Preferably, the deodorizing metal salt is one or more of metal salts composed of metals such as vanadium, manganese, iron, cobalt, titanium, nickel, manganese, copper, zinc, silver, lead, aluminum and magnesium.
Preferably, the deodorizing metal salt is one or more of inorganic acid salt and organic acid salt, the inorganic acid salt is sulfate and halide, and the organic acid salt is citrate, malate and lactate.
Preferably, the deodorizing metal salt is one or more of ferrous salt, magnesium salt or zinc salt.
Preferably, the amounts of the isoniazid compound and the adipic acid compound are 0.1-8 of the amount of the deodorizing metal salt, the amount of the chelating agent is 0.001-0.08 of the amount of the deodorizing metal salt, and the pH regulator is 3 x 10 of the amount of the deodorizing metal salt～4-0.5, wherein the liquid deodorant comprises 0.3-30% by mass of a deodorizing metal salt.
Preferably, the stabilizer is one or more of vitamin C, disodium sebacate, alkylamine and alcohol oxide, and ethylenediaminetetraacetic acid, the chelating agent is a water-soluble salt, and the pH regulator is an organic acid.
Preferably, the chelating agent is one or more of ethylenediamine tetra methylene phosphate, aminotrimethylene phosphonic acid, citric acid, gluconic acid, imino diacetic acid, diethyl triamino pentaacetic acid, nitrilo triacetic acid, diamino propane tetra acetic acid, hydroxyethyl imino diacetic acid, disodium sebacate and hydroxyethyl ethylenediamine triacetic acid, and the organic acid comprises one or more of unsaturated or saturated fatty acid, aliphatic dihydroxy acid, carbonyl carboxylic acid and hydroxy acid.
Preferably, the step (3) further comprises adding an alkali metal salt, wherein the alkali metal is sodium or potassium.
Preferably, the step (3) further comprises adding a toner or an antibacterial agent.
By adopting the preparation method of the liquid deodorant, the isoniazid compound and the adipic acid compound are added, so that the deodorant metal salt, particularly ferrous salt or zinc salt, in the liquid deodorant can be stabilized, the deodorant or the freshener can be improved to decompose and remove amine, hydrogen sulfide, ammonia, mercaptan, aldehyde compounds and the like, and ammonia can not be generated. Further, an alkali metal salt, that is, a complex of an alkali metal ion contained in the composition and a deodorant metal salt is added, and not only the deodorant metal salt is stabilized, but also the pH of the deodorant composition can be adjusted. The preparation method of the invention is also added with the stabilizing agent, the chelating agent and the pH regulating agent, the stabilizing agent and the chelating agent further stabilize the deodorant metal salt and enhance the deodorant effect, and the pH regulating agent can enable the deodorant composition to effectively react with the malodorous substances to remove the malodorous substances and reduce the combustible degree of the malodorous substances. The product prepared by the preparation method can be used as interior materials of building materials, furniture, household products, automobiles, airplanes and the like.
Detailed Description
In order to more clearly describe the technical contents of the present invention, the following further description is given in conjunction with specific embodiments.
The preparation method of the liquid deodorant of the invention comprises the following steps:
step (1): adding a deodorant metal salt into water at 50-100 ℃ for dissolving, stirring by using a mixer, and adding an isoniazid compound and an adipic acid compound before or after adding ferrous sulfate;
step (2): adding the potassium hydroxide aqueous solution, the stabilizer and the chelating agent, stirring and cooling;
and (3): and (3) cooling the mixture obtained in the step (2) to room temperature, and standing to obtain a transparent solution at the upper half part, wherein the solution is the liquid deodorant.
In one embodiment of the present invention, the deodorizing metal salt is one or more of metal salts of vanadium, manganese, iron, cobalt, titanium, nickel, manganese, copper, zinc, silver, lead, aluminum, and magnesium.
In one embodiment provided by the invention, the deodorizing metal salt is one or more of inorganic acid salt or organic acid salt, the inorganic acid salt is sulfate or halide, and the organic acid salt is citrate, malate or lactate.
In one embodiment of the present invention, the deodorizing metal salt is one or more of ferrous salt, magnesium salt or zinc salt.
In one embodiment of the present invention, the amounts of isoniazid compound and adipic acid compound are 0.1 to 8, the amount of chelating agent is 0.001 to 0.08, and the amount of pH regulator is 0.1 to 8, respectively, based on the amount of deodorizing metal saltAmount of odorous metal salt 3X 10～4-0.5, wherein the liquid deodorant comprises 0.3-30% by mass of a deodorizing metal salt.
In one embodiment provided by the invention, the stabilizer is one or more of vitamin C, disodium sebacate, alkylamine, alcohol oxide and ethylenediaminetetraacetic acid, the chelating agent is a water-soluble salt, and the pH regulator is an organic acid.
In one embodiment of the present invention, the chelating agent is one or more of ethylene diamine tetra methylene phosphate, amino trimethylene phosphonic acid, citric acid, gluconic acid, iminodiacetic acid, diethyl triaminepentaacetic acid, nitrilo triacetic acid, diaminopropane tetraacetic acid, hydroxyethylimino diacetic acid, disodium sebacate, and hydroxyethylethylene diamine triacetic acid, and the organic acid includes one or more of unsaturated or saturated fatty acid, aliphatic dihydroxy acid, carbonyl carboxylic acid, and hydroxy acid.
In an embodiment of the present invention, the step (3) further includes adding an alkali metal salt, where the alkali metal is sodium or potassium.
In one embodiment of the present invention, the step (3) further includes adding a toner or an antimicrobial agent.
In the prepared aqueous solution, the content of the composition is 0.3-30 wt% for affinity reaction, preferably 0.5-20%, and more preferably 0.7-20%. The content of the composition is too small, and the deodorizing property of the deodorant is not easy to fully exert; if the content is too large, precipitates are generated after the solubility of water is exceeded, and the stability of the product is not facilitated.
The pH of the liquid deodorant is neutral, and the pH of the malodorous substance is mostly alkaline, and the pH of the aqueous solution formed by the composition is suggested to be close to neutral, and the composition can effectively react with the malodorous substance to remove the malodorous substance. The final adjustment of the pH in the aqueous solution formed by the composition can be carried out by using potassium hydroxide, calcium hydroxide, organic acid and the like, wherein the effect of using potassium hydroxide is better.
The liquid deodorant may be added with a toner such as titanium oxide or an antibacterial agent, if necessary.
The liquid deodorant can be directly diluted with water, and used as deodorant spray or air freshener. The composition forms an aqueous solution which absorbs malodorous substances in the malodorous gas, thereby extracting the malodorous substances from the gas.
The liquid deodorant is used for wallpaper, non-woven fabrics, woven fabrics or fibers, and has a deodorizing effect on ammonia gas and acetaldehyde gas after being dried, and has an effect of reducing the combustible degree of inflammable paper or fiber products. The amount of each use is about 5-10 g/m2Is most preferred. These finished products can be used as interior materials for building materials, furniture, household goods, automobiles, airplanes, and the like.
The metal constituting the deodorizing metal salt may be mainly a transition metal such as vanadium, manganese, iron, cobalt, titanium, nickel, manganese, copper, zinc, silver, or the like, and the like, or lead, aluminum, magnesium, or the like. Among these metal salts, ferrous iron or zinc has excellent deodorizing properties for amine salts, hydrogen sulfide, ammonia, mercaptans and the like. The salt in which the metal is ferrous iron contains inorganic acid salt and organic acid salt. The inorganic acid salt is ferric sulfate, ferric chloride, ferric bromide, ferric iodide, etc. The organic acid salt is malate, ferric lactate, ferric citrate, etc.
Magnesium salts of metals are also used as deodorizing metal salts. The magnesium salt is often used in combination with ferrous iron and zinc. The magnesium salt includes magnesium sulfate, magnesium chloride, magnesium carbonate, magnesium oxide carbonate hydrate, sodium magnesium sulfate, potassium magnesium sulfate, and potassium magnesium bicarbonate.
The alkali metal salt has a function of stabilizing the deodorizing metal and has flame retardancy. The alkali metal is exemplified by sodium and potassium. The deodorizing metal salt may form a complex with the basic metal salt. For example, an aqueous solution of a deodorant composition containing ferric sulfate and potassium sulfate is acid-adjusted to pH 4 to 10, and potassium aurocan, which is a divalent iron-detecting agent, is added, so that a substantially blue image is not developed.
The isoniazid compound and the adipic acid compound can be stably synthesized with ferrous iron, have good reaction on aldehydes and have flame retardance. The isoniazid compound and the adipic acid compound are contained in an amount of 0.1 to 8, preferably 0.5 to 5 equivalents per one equivalent of 1 of the deodorizing metal salt. Specifically, 100 units of ferrous sulfate contain 50 to 350 units of isoniazid compound and adipic acid compound, preferably 60 to 200 units of isoniazid compound and adipic acid compound. When the amounts of the isoniazid compound and the adipic acid compound are too large for the deodorizing metal salt, there is a risk of generation of ammonia gas or the like, and when the amounts of the isoniazid compound and the adipic acid compound are too small, the deodorizing effect is affected.
As the chelating agent, there can be used ethylenediaminetetraacetic acid, aminotrimethylenephosphonic acid, citric acid, gluconic acid, iminodiacetic acid, diethyltriaminepentaacetic acid, nitrilotriacetic acid, diaminopropane tetraacetic acid, hydroxyethyliminodiacetic acid, disodium sebacate, hydroxyethylethylenediaminetriacetic acid, or a water-soluble salt thereof; citric acid, gluconic acid, and other acids or water-soluble salts thereof. These chelating agents may be used alone or in a mixture. Among them, disodium sebacate and aminocarboxylic acids such as acetic acid and their water-soluble salts react well. For 1 equivalent of the deodorant metal salt, 0.001 to 0.08 equivalent of the chelating agent is used, preferably 0.005 to 0.04 equivalent of the chelating agent is used. Specifically, the amount of the disodium sebacate is 0.5 to 8 parts by weight, preferably 1 to 7 parts by weight, per 100 parts by weight of the iron sulfate (7 water salt).
Organic acids include fatty acids, aliphatic dicarboxylic acids, carbonyl carboxylic acids and other unsaturated fatty acids and hydroxy acids and (isoniazid compounds and adipic compounds) and the like.
Examples of the above-listed fatty acids are formic acid, acetic acid, capric acid, propionic acid, butyric acid, valeric acid, caproic acid, enanthic acid, caprylic acid, pelargonic acid, lauric acid, myristic acid, phosphoric acid, pentadecanoic acid, palmitic acid, stearic acid, oleic acid, linoleic acid, linolenic acid, dihydroabietic acid, unsaturated fatty acids, and the like. As dicarboxylic acids, oxalic acid and the like are exemplified. As the aromatic acid, benzene acid, phthalic acid, carbonate and other unsaturated fatty acids are exemplified. In one embodiment of the present invention, 5 or more organic acids are selected and mixed. Among the above organic acids, the organic acids are odorless and have high solubility in waterThe substance affinity reaction of (1). Citric acid, malic acid, or mixed acids may be used. The organic acid content of the deodorizing metal salt is 3X 10 to 1 equivalent～40.5, preferably 2X 10- 30.01, further preferably 1X 10-30.01. Specifically, the citric acid is 0.5 to 8 parts by weight, preferably 0.1 to 5 parts by weight, based on 100 parts by weight of iron sulfate (7 parts by weight of water salt).
The composition containing an isoniazid compound and an adipic acid compound can exhibit reactivity with an aldehyde malodorous substance such as formaldehyde, and can stabilize a deodorant metal salt and make a deodorant more effective in removing the amine, hydrogen sulfide, ammonia, thiol, aldehyde malodorous substance. That is, the isoniazid compound and the adipic acid compound further improve the stability of the deodorizing metal salts such as ferrous sulfate and zinc sulfate in addition to the decomposition of the deodorizing aldehydes. The deodorizing metal salt and the isoniazid compound and the adipic acid compound may form a combination, that is, the alkali metal salt of the deodorizing metal ion and the isoniazid compound and the adipic acid compound form a ligand.
The isoniazid compound contains at least 1 amino group, for example, 2 or 3 or more amino groups in the molecule.
In one embodiment of the present invention, the deodorant is ferrous sulfate as the metal salt, potassium salt as the alkali metal salt, disodium sebacate as the chelating agent, and citric acid as the organic acid. Stirring the mixture in hot water at 50-100 ℃, and adding ferrous sulfate at normal temperature to the mixture in an amount exceeding the solubility to dissolve the ferrous sulfate. The temperature is adjusted within this range as necessary, for example, 60 ℃ or 80 ℃. For 100 weight parts of hot water, 5 to 20 weight parts of ferrous sulfate (7 water salt), 15 to 600 weight parts of potassium in potassium aqueous solution, 2.5 to 50 weight parts of isoniazid compound and adipic acid compound, 0.5 to 10 weight parts of disodium sebacate, and 0.5 to 5 weight parts of citric acid are preferably combined.
The liquid deodorant prepared by the invention has excellent deodorization performance and has flame retardant effect when being coated on paper or fiber.
By adopting the preparation method of the liquid deodorant, the isoniazid compound and the adipic acid compound are added, so that the deodorant metal salt, particularly ferrous salt or zinc salt, in the liquid deodorant can be stabilized, the deodorant or the freshener can be improved to decompose and remove amine, hydrogen sulfide, ammonia, mercaptan, aldehyde compounds and the like, and ammonia can not be generated. Further, an alkali metal salt, that is, a complex of an alkali metal ion contained in the composition and a deodorant metal salt is added, and not only the deodorant metal salt is stabilized, but also the pH of the deodorant composition can be adjusted. The preparation method of the invention is also added with the stabilizing agent, the chelating agent and the pH regulating agent, the stabilizing agent and the chelating agent further stabilize the deodorant metal salt and enhance the deodorant effect, and the pH regulating agent can enable the deodorant composition to effectively react with the malodorous substances to remove the malodorous substances and reduce the combustible degree of the malodorous substances. The product prepared by the preparation method can be used as interior materials of building materials, furniture, household products, automobiles, airplanes and the like.
In this specification, the invention has been described with reference to specific embodiments thereof. It will, however, be evident that various modifications and changes may be made thereto without departing from the broader spirit and scope of the invention. The description is thus to be regarded as illustrative instead of limiting.
Claims (9)
1. The preparation method of the liquid deodorant is characterized by comprising the following steps:
step (1): adding a deodorant metal salt into water at 50-100 ℃ to dissolve the deodorant metal salt, stirring the mixture by using a mixer, and adding an isoniazid compound and an adipic acid compound before or after adding the deodorant metal salt;
step (2): adding a potassium hydroxide aqueous solution, a stabilizer and a chelating agent, stirring and cooling;
and (3): cooling the mixture obtained in the step (2) to room temperature, standing, and enabling the upper half part to be in a transparent solution state, wherein the solution is the liquid deodorant,
the step (3) further comprises adding an alkali metal salt;
alkali metal salts of deodorizing metal ions and isoniazid compounds and adipic acid compounds form ligands;
the amount of the isoniazid compound and the adipic acid compound is 0.1-8 equivalents of the amount of the deodorant metal salt.
2. The method for producing a liquid deodorant according to claim 1, wherein the deodorizing metal salt is one or more of metal salts of vanadium, manganese, iron, cobalt, titanium, nickel, manganese, copper, zinc, silver, lead, aluminum and magnesium.
3. The method for producing a liquid deodorant according to claim 1, wherein the deodorizing metal salt is one or more of an inorganic acid salt or an organic acid salt, the inorganic acid salt is a sulfate or a halide, and the organic acid salt is a citrate, a malate or a lactate.
4. The method for producing a liquid deodorant according to claim 1, wherein the deodorizing metal salt is one or more of a ferrous salt, a magnesium salt or a zinc salt.
5. The method of producing a liquid deodorant according to claim 1, wherein the amount of the chelating agent is 0.001 to 0.08 equivalent to the amount of the deodorizing metal salt, and the liquid deodorant contains the deodorizing metal salt in an amount of 0.3 to 30% by mass.
6. The method for preparing a liquid deodorant according to claim 1 wherein the stabilizer is one or more of vitamin C, disodium sebacate, alkylamine and alcohol oxide, and ethylenediaminetetraacetic acid, and the chelating agent is a water-soluble salt.
7. The method for producing a liquid deodorant according to claim 1, wherein the chelating agent is one or more of ethylenediaminetetraacetic acid, aminotrimethylenephosphonic acid, citric acid, gluconic acid, iminodiacetic acid, diethyltriaminepentaacetic acid, nitrilotriacetic acid, diaminopropane tetra-acetic acid, hydroxyethyliminodiacetic acid, disodium sebacate, and hydroxyethylethylenediamine triacetic acid.
8. The method for producing a liquid deodorant according to claim 1, wherein the alkali metal in the alkali metal salt is sodium or potassium.
9. The method of producing a liquid deodorant according to claim 1, wherein the step (3) further comprises adding a toner or an antibacterial agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710763615.3A CN107441541B (en) | 2017-08-30 | 2017-08-30 | Preparation method of liquid deodorant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710763615.3A CN107441541B (en) | 2017-08-30 | 2017-08-30 | Preparation method of liquid deodorant |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107441541A CN107441541A (en) | 2017-12-08 |
| CN107441541B true CN107441541B (en) | 2020-04-10 |
Family
ID=60493623
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710763615.3A Expired - Fee Related CN107441541B (en) | 2017-08-30 | 2017-08-30 | Preparation method of liquid deodorant |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107441541B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111847545A (en) * | 2020-08-04 | 2020-10-30 | 武汉世纪瑞科环保科技有限公司 | Industrial sewage deodorant and preparation method thereof |
| CN112827471B (en) * | 2020-12-29 | 2023-10-31 | 南京凯创微锌环境技术有限公司 | Preparation method of deodorant for sheep farm |
| CN114259848A (en) * | 2021-12-30 | 2022-04-01 | 上海心动能科技有限公司 | Deodorant for removing odor of organic garbage and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1170793A (en) * | 1996-06-11 | 1998-01-21 | 东丽株式会社 | Deodorant fibrous material and method of producing the same |
| CN1365270A (en) * | 1999-07-26 | 2002-08-21 | 花王株式会社 | Deodorants |
| CN1387445A (en) * | 1999-11-30 | 2002-12-25 | 株式会社大鹿 | Aldehyde-deodorizing compositions |
-
2017
- 2017-08-30 CN CN201710763615.3A patent/CN107441541B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1170793A (en) * | 1996-06-11 | 1998-01-21 | 东丽株式会社 | Deodorant fibrous material and method of producing the same |
| CN1365270A (en) * | 1999-07-26 | 2002-08-21 | 花王株式会社 | Deodorants |
| CN1387445A (en) * | 1999-11-30 | 2002-12-25 | 株式会社大鹿 | Aldehyde-deodorizing compositions |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107441541A (en) | 2017-12-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2027753C (en) | Deodorizing and cleaning compositions and method | |
| CN107441541B (en) | Preparation method of liquid deodorant | |
| US20220395439A1 (en) | Antibacterial deodorant composition and production method therefor | |
| CN107503115B (en) | Method for preparing fiber material with deodorization and flame retardant functions | |
| CN107281922B (en) | Deodorant composition and process for producing the same | |
| CN107432950B (en) | Liquid deodorant and application thereof | |
| CN109982724B (en) | Deodorant agent | |
| JP2012046375A (en) | Method for generating and emitting chlorine dioxide gas | |
| US11771792B2 (en) | Compositions and methods for reducing odor | |
| CN115397477A (en) | Deodorant agent | |
| CN107503110B (en) | Fiber material with deodorization and flame retardant functions | |
| US20060269509A1 (en) | Scent eliminating composition including colloidal silver | |
| CN113828131A (en) | Preparation method of deodorant | |
| CN107432949B (en) | Deodorant composition and use thereof | |
| CN107375981B (en) | Composition for deodorizing chemical stabilizer and application thereof | |
| CN110694694A (en) | Anatase type visible light irrelevant two-in-one photocatalyst solution and preparation method thereof | |
| JP5268128B2 (en) | Deodorant composition, deodorant aqueous solution, deodorant aqueous slurry, deodorant powder composition and deodorant masterbatch | |
| KR102006328B1 (en) | Method of preparation of drug cleaning fluids for removing TVOCs and odour-causing substances | |
| JP4170155B2 (en) | Spray liquid deodorant | |
| JP5697135B2 (en) | Deodorization method | |
| JPS62117562A (en) | Aqueous deodorant solution | |
| JP2017101357A (en) | Primer deodorant and deodorant organic fiber using the same | |
| KR20100111774A (en) | Composition for non-toxic deodorant | |
| JP2001333968A (en) | Deodorant composition | |
| CN113647388A (en) | Antibacterial and deodorant air freshener and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20190926 Address after: 200433 16th Floor, 127 Guodao Road, Yangpu District, Shanghai (Centralized Registration Place) Applicant after: Shanghai Yiju Environmental Protection Technology Co.,Ltd. Address before: 201201 Shanghai Pudong New Area Heqing town and village thrifty road Wu House No. 25 Applicant before: SHANGHAI GREAT KUN ENVIRONMENTAL PROTECTION TECHNOLOGY CO.,LTD. |
|
| TA01 | Transfer of patent application right | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20200410 Termination date: 20210830 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |