CN107440920B - Deep-layer chelating beauty facial mask and preparation method thereof - Google Patents

Deep-layer chelating beauty facial mask and preparation method thereof Download PDF

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CN107440920B
CN107440920B CN201710691812.9A CN201710691812A CN107440920B CN 107440920 B CN107440920 B CN 107440920B CN 201710691812 A CN201710691812 A CN 201710691812A CN 107440920 B CN107440920 B CN 107440920B
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essential oil
mask
chelating
deep
skin
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CN107440920A (en
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陈庆
曾军堂
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Yuhuan Yimin Cosmetics Co.,Ltd.
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Yuhuan Yimin Cosmetics Co Ltd
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8105Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • A61K8/8111Homopolymers or copolymers of aliphatic olefines, e.g. polyethylene, polyisobutene; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31Hydrocarbons
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37Esters of carboxylic acids
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/64Proteins; Peptides; Derivatives or degradation products thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • A61K8/737Galactomannans, e.g. guar; Derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8176Homopolymers of N-vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/925Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of animal origin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/965Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of inanimate origin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/10Washing or bathing preparations

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
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  • General Health & Medical Sciences (AREA)
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  • Birds (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
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  • Cosmetics (AREA)

Abstract

The invention relates to the technical field of cosmetics, in particular to a deep-layer chelating beauty facial-cleaning mask and a preparation method thereof, wherein the deep-layer chelating beauty facial-cleaning mask comprises the following substances: VAE emulsion, acrylic polymer, polyvinylpyrrolidone, guar gum, surfactant, chelating agent and diatomite. The invention takes VAE emulsion, acrylic polymer, polyvinylpyrrolidone and guar gum as base materials, takes surfactant, chelating agent and diatomite as cleaning materials, and forms a micro-elastic paste by kneading, namely a deep face-cleaning mask, which is easy to be evenly smeared on the face and can form an adhesive and elastic film on the face, the adsorption force between the film and the skin is very large, bacteria, blackheads and other dirt on the surface of the skin can be adsorbed, and the mask has good affinity to the skin and little damage to the skin, after being used, the mask is directly uncovered, the adhesive property of the mask completely adheres the adsorbed dirt, and the mask is prevented from being left on the face. Convenient use and remarkable cleaning effect.

Description

Deep-layer chelating beauty facial mask and preparation method thereof
Technical Field
The invention relates to the technical field of cosmetics, in particular to a deep chelating beauty facial mask and a preparation method thereof.
Background
Everyone in real life wants to have healthy white and tender skin. The skin is one of the important organs of the human body and protects the health of the human body, so that the human body has the cosmetics for caring the skin from old times. Along with the improvement of the life quality of people and the pursuit of people for beauty, cosmetics are more and more in variety. The facial mask is an important content in skin care, and is applied regularly according to various skin characteristics, so that oily skin can be degreased, large pores can be converged, withered and wrinkled skin can recover luster, and inflammation of pimpled skin can be inhibited. The facial mask makes skin look fresh, smooth, white and tender after being used, because when the facial mask is applied to the skin, the facial mask generates affinity with the skin, the skin temperature rises along with the gradual drying of the facial mask, the blood circulation is accelerated, the skin is tightened and the tension is strengthened, sebum and moisture secreted by the skin reversely permeate into a horny layer, the epidermis is soft and stretched, pores are naturally opened, the secretion and metabolism of sweat glands are promoted, the oxygen content of the skin is increased, products of metabolism of epidermal cells and accumulated grease substances are favorably eliminated by the skin, active ingredients in the facial mask permeate into the skin to be absorbed by the skin and are simultaneously connected with the skin, when the facial mask is eliminated, aged cutin on the skin and deep dirt in the pores are simultaneously discharged, and the skin is fresh and clean. The water in the facial mask permeates into the horny layer of the skin epidermis, so that the skin becomes soft, and the skin is naturally bright and elastic. The mask is generally classified into a mud type mask, a peel type mask, a jelly type mask, a cream type mask, a cloth type mask, and the like; the cloth type facial mask has no cleaning effect and is not suitable for people needing deep skin cleaning, and other facial masks have certain cleaning effect; but the use method is that the skin cleaning cream is applied to the skin, dried for 20-40 minutes and then taken off or washed off, so that the purposes of cleaning and protecting the skin are achieved.
The increasing pressure of work and life and environmental pollution make the skin of many people face the threat of sub-health. Various skin diseases occur frequently, which is associated with the lack of various nutrients to the skin. Modern people do not exercise and pay attention to diet all day long, and some people have long developed facial muscle drop symptoms due to two proteins in the dermis layer of the skin: collagen and elastin, which support the skin to be plump and tight. After age 25, these two proteins naturally decrease due to aging process of the human body, supporting force of the skin is also decreased, elasticity is decreased, and thus laxity and wrinkles occur.
The radiation sources such as a keyboard, a computer screen, a mobile phone and the like directly influence the stability and disorder of the endocrine system of the human body, so that the skin metabolism is irregular, and the like.
In addition, with the increasing pollution of the atmosphere, the destruction of the ozone layer, and the damage of ultraviolet rays to human bodies become a problem to be paid attention. Ultraviolet UV-C (200-290 nm); ultraviolet UV-B (290-320 nm); ultraviolet UV-A (320-400 nm). UV-C can be completely absorbed by the earth atmosphere, UV-B is only partially absorbed by the ozone layer of the atmosphere, UV-A is not absorbed by the atmosphere, and the ultraviolet rays on the earth surface are composed of more than 90% of UV-A and less than 10% of UVB. The damage to human skin is extremely severe. It often appears as skin burn, causing erythema, aging, and even inducing vitiligo or canceration. Therefore, the ultraviolet-proof skin care product becomes a daily necessity.
The existing sunscreen skin care products mostly adopt TiO2, ZnO or benzophenone, methylene diphenylphthalate, benzotriazole and cinnamic acid vinegar as additives, and the energy absorption characteristics of the additives are utilized to absorb ultraviolet rays and reduce the harm caused by ultraviolet radiation. However, benzophenone, dibenzophthalein methane, benzotriazol and cinnamic acid vinegar chemical sunscreen agents are small molecular chemical substances, and have poor light stability, are easy to oxidize and deteriorate, have serious performance attenuation during sun protection, are easy to permeate into skin to cause skin allergy, and have special requirements on applicable people, so that the application of the sunscreen agents is limited. TiO2 and ZnO have poor biocompatibility, are easy to block pores and are difficult to contact with the skin all the year round. Therefore, the ultraviolet-proof skin care products are developed towards the biological property and stability.
With the growth of the global cosmetic market and the increasing demand of consumers, there are also new trends in the global cosmetic market: 1. the environment is protected, and with the increasing global environment protection call, the requirement of consumers on the safety of cosmetics is higher and higher; 2. safety, the safety of the cosmetics is not only related to physical and mental health of consumers, but also related to life and death of enterprises and industries; 3. natural plant, especially herbal ingredients; 4. anti-aging and sun protection; 5. an efficacy cosmetic. Washing the face is a common cleaning method in daily life. However, the impurities are difficult to completely remove by simple face washing, and particularly, the skin care products and the like enter pores, so that the pores are easily blocked, the secretion of oil and water and oil of the skin is disordered, and the puzzling skin problems such as acne, comedo, blackhead and the like are caused. Thus, in addition to conventional facial washing, deep washing of the face is often required once a week. The existing deep cleaning mainly adopts a face cleaning cream or an interface mask cream, but the face cleaning mask cream needs to be eluted after face cleaning is finished, so that the face cleaning mask cream is difficult to clean, even causes dirty residues on the face, and is very inconvenient to use.
Disclosure of Invention
The invention aims to provide a deep chelating beauty facial mask which is convenient to use and has a remarkable cleaning effect, aiming at the defects that the existing deep cleaning mainly adopts a facial cleaning cream or an interface facial mask cream, but the facial cleaning facial mask cream is required to be eluted after the facial cleaning is finished, so that the cleaning is difficult, even the facial dirt residue is caused, and the use is inconvenient.
In order to solve the problems, the invention adopts the following technical scheme:
a deep chelating beauty facial mask comprises the following substances: VAE emulsion, acrylic polymer, polyvinylpyrrolidone, guar gum, surfactant, chelating agent and diatomite.
The VAE emulsion is the vinyl acetate-ethylene copolymer emulsion for short. The inventor of the present invention found that, in the course of long-term research on cleansing facial masks, a thin film can be formed on the face after mixing the VAE emulsion, the acrylic polymer, the polyvinylpyrrolidone and the guar gum in a certain ratio, the adsorption force between the thin film and the skin is large, the dirt such as bacteria and blackheads on the surface of the skin can be adsorbed, and the cleansing facial mask has good affinity to the skin and little damage to the skin.
In the invention, the proportion of each substance has great influence on the performance of the facial mask, and preferably, the deep-layer chelating beauty facial-cleaning facial mask comprises the following substances in parts by weight: 10-35 parts of VAE emulsion, 15-28 parts of acrylic polymer, 5-32 parts of polyvinylpyrrolidone, 5-30 parts of guar gum, 2-6 parts of surfactant, 3-8 parts of chelating agent and 2-18 parts of diatomite.
More preferably, the deep chelating beauty facial mask comprises the following substances in parts by weight: 15-25 parts of VAE emulsion, 18-26 parts of acrylic polymer, 10-28 parts of polyvinylpyrrolidone, 8-16 parts of guar gum, 2-6 parts of surfactant, 3-8 parts of chelating agent and 5-12 parts of diatomite.
The surfactant can improve the compatibility of all the substances in a mixed system and improve the fusion degree among all the substances, so that all the substances can be uniformly dispersed, wherein the surfactant is at least one of ammonium salt, pyridinium, PEG, POE and stearic acid.
Preferably, the chelating agent is at least one of ethylenediaminetetraacetic acid, nitrilotriacetic acid, diethylenetriaminepentaacetic acid, citric acid, tartaric acid, and glucono-I acid, 1,2,3, -tetracarboxylcyclopentane, 2-oxoacetoxymalonic acid, and 2-oxoacetoxysuccinic acid.
In order to increase the function of the mask, preferably, the deep-seated chelating facial cleansing mask further comprises at least one of fibroblast growth factor, penetrant, healing agent, preservative, plant essential oil, humectant, emulsifier, film former, thickener and lecithin.
The oil crop matrix raw material has a large proportion in the formula of the cosmetic, has the effects of softening, lubricating and purifying the skin, has a friction effect on the skin surface, forms a hydrophobic film to protect the skin, can prevent the invasion of external harmful substances, and can inhibit the evaporation of water on the skin surface in cold; can be used as a fat-reducing agent for protecting skin, and can also be used as a solvent for special components. In addition, the plant essential oil contains aromatic odor and can be pleasant to the mind and body, and the plant essential oil is at least one of olive oil, coconut oil, camellia oil, jojoba oil, rose essential oil, lavender essential oil, jasmine essential oil, rosemary essential oil, bergamot essential oil, basil essential oil, clove essential oil, citronella essential oil, sweet orange essential oil, tea tree essential oil, sage essential oil, eucalyptus essential oil, grapefruit essential oil, geranium essential oil, mint essential oil, lemon essential oil, chamomile essential oil and marjoram essential oil.
The deep-layer chelating beauty facial cleaning mask provided by the invention also comprises a penetrating agent, and in the invention, the lecithin is at least one of soybean lecithin, egg yolk lecithin, distearoyl phosphatidylcholine, palmitoyl phosphatidylcholine, phosphatidylserine, phosphatidic acid and hydrogenated lecithin.
The deep chelating beauty facial mask provided by the invention further comprises a penetrating agent, wherein the penetrating agent is selected from one or more of potassium chloride, sodium sulfate and sodium chloride, and potassium chloride is preferred.
The deep chelating beauty facial mask provided by the invention also comprises a humectant, wherein the humectant is at least one of glycerol, propylene glycol, butanediol, pentanediol, hexanediol, octanediol, decanediol, hydroxyethyl urea, betaine, sodium pyrrolidone carboxylate, hyaluronic acid and salt, plant polysaccharides, stearyl alcohol, stearic acid, isopropyl palmitate, polydimethylsiloxane and sweet almond oil.
The deep chelating beauty facial mask provided by the invention also comprises an emulsifier, wherein the emulsifier is selected from at least one of glyceryl stearate, polysorbate-20, sorbitan sesquioleate, glyceryl oleate and polyglycerol-3 polyricinoleate.
The deep-seated chelating cosmetic facial mask provided by the invention also comprises a healing agent, and in the invention, the healing agent is preferably allantoin.
The deep chelating beauty facial mask provided by the invention also comprises a preservative, and in the invention, the preservative is preferably DP-300.
The deep chelating beauty facial mask provided by the invention also comprises a thickening agent, wherein the thickening agent is selected from one or more of hydroxyethyl cellulose, polyvinyl alcohol, xanthan gum, magnesium aluminum silicate, acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer, pectin and carbomer;
a preparation method of a deep chelating beauty facial mask comprises the following steps:
(1) ultrasonically dispersing and uniformly mixing VAE emulsion, acrylic polymer, polyvinylpyrrolidone and guar gum in an organic solvent, and then preserving heat for 15-120 min at 60-80 ℃; obtaining a mixed system;
(2) adding a surfactant, a chelating agent, diatomite and water into the mixed system, keeping the temperature at 50-80 ℃ for 30-240 min, homogenizing at a high speed for 20min, cooling, and discharging when the temperature is reduced to 38 ℃.
In order to increase the compatibility of the facial mask and the skin, the pH value of the discharged product is preferably controlled within the range of 5.0-6.5.
In the step (1), the organic solvent is one or more of ethanol, ethylene glycol, propylene glycol, glycerol, white mineral oil, isopropyl palmitate, ethyl acetate, acetone ester, white oil, sea buckthorn oil and avocado oil, preferably glycerol, white mineral oil, isopropyl palmitate and lanolin, wherein 3 components of white mineral oil, isopropyl palmitate and lanolin are mixed for use, so that the skin-moistening effect is good.
Compared with the prior art, the deep chelating beauty facial mask and the preparation method thereof have the outstanding characteristics and excellent effects that:
the invention takes VAE emulsion, acrylic polymer, polyvinylpyrrolidone and guar gum as base materials, takes surfactant, chelating agent and diatomite as cleaning materials, and forms a micro-elastic paste by kneading, namely a deep face-cleaning mask, which is easy to be evenly smeared on the face and can form an adhesive and elastic film on the face, the adsorption force between the film and the skin is very large, bacteria, blackheads and other dirt on the surface of the skin can be adsorbed, and the mask has good affinity to the skin and little damage to the skin, after being used, the mask is directly uncovered, the adhesive property of the mask completely adheres the adsorbed dirt, and the mask is prevented from being left on the face. Convenient use and remarkable cleaning effect.

Claims (4)

1. The deep chelating beauty facial mask is characterized by comprising the following substances in parts by weight: 15-25 parts of VAE emulsion, 18-26 parts of acrylic polymer, 10-28 parts of polyvinylpyrrolidone, 8-16 parts of guar gum, 2-6 parts of surfactant, 3-8 parts of chelating agent and 5-12 parts of diatomite;
also comprises at least one of fibroblast growth factor, penetrant, healing agent, preservative, plant essential oil, humectant, film forming agent, emulsifier and lecithin;
the chelating agent is at least one of ethylenediamine tetraacetic acid, nitrilotriacetic acid, diethylenetriamine pentaacetic acid, citric acid, tartaric acid and gluconic acid I, 2-oxyacetic acid-base malonic acid and 2-oxyacetic acid-base butyric acid;
the deep chelating beauty facial mask is prepared by the following method:
(1) ultrasonically dispersing and uniformly mixing VAE emulsion, acrylic polymer, polyvinylpyrrolidone and guar gum in an organic solvent, and then preserving heat for 15-120 min at 60-80 ℃; obtaining a mixed system;
(2) adding a surfactant, a chelating agent and diatomite into the mixed system, keeping the temperature at 50-80 ℃ for 30-240 min, homogenizing at a high speed for 20min, cooling, discharging when the temperature is reduced to 38 ℃, and controlling the pH value range of a discharged product to be 5.0-6.5.
2. The deep-chelating facial cleansing mask as claimed in claim 1, wherein the surfactant is at least one of ammonium salts, pyridinium salts, PEG, POE and stearic acid.
3. The deep-chelating beauty facial mask as claimed in claim 1, wherein the plant essential oil is at least one of olive oil, coconut oil, camellia oil, jojoba oil, rose essential oil, lavender essential oil, jasmine essential oil, rosemary essential oil, bergamot essential oil, basil essential oil, clove essential oil, citronella essential oil, sweet orange essential oil, tea tree essential oil, sage essential oil, eucalyptus essential oil, grapefruit essential oil, geranium essential oil, mint essential oil, lemon essential oil, chamomile essential oil, and marjoram essential oil.
4. The deep-chelating facial cleansing mask as claimed in claim 1, wherein the lecithin is at least one of soybean lecithin, egg yolk lecithin, distearoylphosphatidylcholine, palmitoylphosphatidylcholine, phosphatidylserine, phosphatidic acid, and hydrogenated lecithin.
CN201710691812.9A 2017-08-14 2017-08-14 Deep-layer chelating beauty facial mask and preparation method thereof Active CN107440920B (en)

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CN108815005B (en) * 2018-07-27 2020-11-24 华南理工大学 Cellulose-doped nano-whisker deep-cleaning pasty mask and preparation method thereof
CN113956556A (en) * 2021-10-14 2022-01-21 江苏馨德高分子材料股份有限公司 Low-smoke halogen-free flame-retardant polyolefin sheath material and preparation method thereof
CN117653563B (en) * 2023-12-13 2024-06-04 奥俐莱雅(广东)家化科技有限公司 Recombinant collagen peptide with high transdermal property and preparation process and application thereof

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Publication number Priority date Publication date Assignee Title
CN1861038A (en) * 2004-12-28 2006-11-15 强生消费者公司 Skin treatment articles and methods
CN102210641A (en) * 2010-04-08 2011-10-12 周想燕 Negative ion beauty care mask and manufacturing method thereof
CN104546613A (en) * 2015-01-20 2015-04-29 王雪林 Mineral-plant nanometer facial mask
CN105726413A (en) * 2016-04-01 2016-07-06 湖南欧泊丽化妆品有限公司 Active diatom mineral mud mask and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1861038A (en) * 2004-12-28 2006-11-15 强生消费者公司 Skin treatment articles and methods
CN102210641A (en) * 2010-04-08 2011-10-12 周想燕 Negative ion beauty care mask and manufacturing method thereof
CN104546613A (en) * 2015-01-20 2015-04-29 王雪林 Mineral-plant nanometer facial mask
CN105726413A (en) * 2016-04-01 2016-07-06 湖南欧泊丽化妆品有限公司 Active diatom mineral mud mask and preparation method thereof

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Denomination of invention: A deep chelating beauty cleansing facial mask and its preparation method

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Denomination of invention: A deep chelating beauty cleansing facial mask and its preparation method

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