CN107434882A - A kind of antistatic polypropylene material and preparation method thereof - Google Patents

A kind of antistatic polypropylene material and preparation method thereof Download PDF

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CN107434882A
CN107434882A CN201710822423.5A CN201710822423A CN107434882A CN 107434882 A CN107434882 A CN 107434882A CN 201710822423 A CN201710822423 A CN 201710822423A CN 107434882 A CN107434882 A CN 107434882A
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aluminium
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ester
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陆叶锋
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C08K2003/0812—Aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2231—Oxides; Hydroxides of metals of tin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2296—Oxides; Hydroxides of metals of zinc
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/001—Conductive additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/04—Antistatic

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  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
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  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

The invention is related to a kind of antistatic polypropylene material, including following raw material components：Polypropylene, copper nano-wire loads carbon fiber, nano silver wire loads tin ash, aluminium loading ZnO, polyacrylic acid isopropyl ester, the different certain herbaceous plants with big flowers ester of pentaerythritol diphosphite two, zinc stearate, copper nano-wire loads carbon fiber by carbon fiber, copper naphthenate, formaldehyde, epoxychloropropane, sodium borohydride and normal propyl alcohol reaction are made, nano silver wire loads tin ash by tin ash, oleic acid silver, ethylal and hydroxypropyl cellulose reaction are made, aluminium loading ZnO is by zinc oleate, aluminium ash, celluloid, ethanol and normal propyl alcohol reaction are made, polyacrylic acid isopropyl ester is by isopropyl acrylate, isobutyl acrylate, Isooctyl acrylate monomer, methyl methacrylate and benzoin methyl ether reaction are made.The invention has excellent antistatic behaviour and mechanical strength.

Description

A kind of antistatic polypropylene material and preparation method thereof
Technical field
The invention is related to a kind of antistatic polypropylene material and preparation method thereof.
Background technology
In general-purpose plastics, density is small, rigidity is good, cost-effective, heat resistance, nontoxic, resistance toization because it has for polypropylene Learn advantage, the polypropylene such as medicine, crystallinity are high, light transmittance is high, easily processed into type, corrosion-resistant and be widely used in car insurance The fields such as thick stick, automotive trim, tableware, cup, beverage bottle, film, water supply pipe, packaging, shopping bag.
At present, poly- third material needs further lifting in antistatic behaviour and mechanical strength.The invention is using polypropylene, Tong Na Rice noodles load carbon fiber, nano silver wire load tin ash, aluminium loading ZnO, polyacrylic acid isopropyl ester are prepared for antistatic poly- third Alkene material, by extruding, being molded, being molded, the technique such as being blow molded and be prepared into various plastic products, antistatic poly- third prepared by this method Alkene material has excellent antistatic behaviour and mechanical strength.
The content of the invention
The purpose of the invention is to provide a kind of preparation method of antistatic polypropylene material, and this method, which passes through, changes reaction Raw material and technology mode, the material of preparation have excellent antistatic behaviour and mechanical strength.
To achieve these goals, the technical scheme of the invention is as follows.
A kind of antistatic polypropylene material and preparation method thereof, specifically includes following steps：(1), by isopropyl acrylate, Isobutyl acrylate, Isooctyl acrylate monomer, methyl methacrylate and benzoin methyl ether are 80 according to quality parts ratio：55~ 71：16~29：9~17：0.3~1 is added in reactor, and mixing speed is 73~90r/min, maintenance system temperature 27~34 25min is reacted under the conditions of DEG C, product obtains polyacrylic acid isopropyl ester through 3000W lamp and high pressure mercury 3s；(2), by zinc oleate, Aluminium ash, celluloid, ethanol and normal propyl alcohol are according to quality parts ratio 100：36~46：7~19：78~97：26~43 are added to water In thermal response kettle, reaction temperature is 176~198 DEG C of 9~16h of reaction, and product washs 3 times through the 1L NaOH aqueous solution, filtering, 1L Deionized water is washed 3 times, and 1L ethanol washs 3 times, in 72 DEG C, -0.06MPa vacuum drying 5min, under nitrogen protection, product warp 200 DEG C of roasting 2h, 300 DEG C of roasting 2h, 400 DEG C of roasting 2h, 500 DEG C of roasting 2h, 600 DEG C of roasting 2h, grinding, obtain aluminium load ZnO；(3), by tin ash, oleic acid silver, ethylal and hydroxypropyl cellulose according to quality parts ratio 100：46~57： 45~66：7~15 are added in hydrothermal reaction kettle, and reaction temperature is 186~212 DEG C of 7~14h of reaction, and product is filtered, 500mL deionized waters are washed 3 times, and 500mL ethanol washs 3 times, in 56 DEG C, -0.09MPa vacuum drying 9min, that is, obtain Yin Na Rice noodles load tin ash；(4), by carbon fiber, copper naphthenate, formaldehyde, epoxychloropropane, sodium borohydride and normal propyl alcohol according to matter Measure portion rate 100：65~83：90~103：123~138：13~21：35~51 are added in hydrothermal reaction kettle, reaction temperature For 181~202 DEG C of 7~12h of reaction, product is filtered, and 500mL deionized waters are washed 3 times, and 500mL ethanol washs 3 times, in 61 DEG C, -0.08MPa vacuum drying 13min, that is, obtain copper nano-wire load carbon fiber；(5) polypropylene, copper nano-wire, are loaded into carbon Fiber, nano silver wire load tin ash, aluminium loading ZnO, polyacrylic acid isopropyl ester, two different certain herbaceous plants with big flowers of pentaerythritol diphosphite Ester, zinc stearate are according to quality parts ratio 100：0.01~0.2：0.01~0.3：0.03~0.3：33~52：3~8：2~7 add Enter into mill, with mill in 193~200 DEG C of 2~6min of hybrid reaction of temperature, with extruder in 197~220 DEG C of temperature Extruding pelletization, that is, obtain antistatic polypropylene material.
The preparation method of antistatic polypropylene material described in the invention, comprises the following steps：
(1), isopropyl acrylate, isobutyl acrylate, Isooctyl acrylate monomer, methyl methacrylate and benzoin methyl ether are pressed It is 80 according to quality parts ratio：55~71：16~29：9~17：0.3~1 is added in reactor, and mixing speed is 73~90r/ Min, 25min is reacted under the conditions of 27~34 DEG C of maintenance system temperature, product obtains polypropylene through 3000W lamp and high pressure mercury 3s Isopropyl propionate；Described isobutyl acrylate and the purpose of Isooctyl acrylate monomer are in order to reduce the vitrifying of polyacrylic acid isopropyl ester Transition temperature, reduce polyacrylic crystallinity.
(2), by zinc oleate, aluminium ash, celluloid, ethanol and normal propyl alcohol according to quality parts ratio 100：36~46：7~19： 78~97：26~43 are added in hydrothermal reaction kettle, and reaction temperature is 176~198 DEG C of 9~16h of reaction, and product is through 1L NaOH The aqueous solution is washed 3 times, and filtering, 1L deionized waters are washed 3 times, and 1L ethanol washs 3 times, is dried in vacuo in 72 DEG C, -0.06MPa 5min, under nitrogen protection, product through 200 DEG C roasting 2h, 300 DEG C roasting 2h, 400 DEG C roasting 2h, 500 DEG C roasting 2h, 600 DEG C 2h is calcined, grinding, obtains aluminium loading ZnO；Described zinc oleate and the purpose of celluloid are in order to improve the dispersing uniformity of material.
(3), by tin ash, oleic acid silver, ethylal and hydroxypropyl cellulose according to quality parts ratio 100：46 ~57：45~66：7~15 are added in hydrothermal reaction kettle, and reaction temperature is 186~212 DEG C of 7~14h of reaction, and product passes through Filter, 500mL deionized waters are washed 3 times, and 500mL ethanol washs 3 times, in 56 DEG C, -0.09MPa vacuum drying 9min, that is, obtain silver Nanowire supported tin ash；While the purpose of described ethylal is in order to protect aldehyde radical, slow down nano silver wire Generating rate, improve the specific surface area of nano silver wire.
(4), by carbon fiber, copper naphthenate, formaldehyde, epoxychloropropane, sodium borohydride and normal propyl alcohol according to quality parts ratio 100：65~83：90~103：123~138：13~21：35~51 are added in hydrothermal reaction kettle, reaction temperature be 181~ 202 DEG C reaction 7~12h, product is filtered, 500mL deionized waters wash 3 times, 500mL ethanol wash 3 times, in 61 DEG C ,- 0.08MPa is dried in vacuo 13min, that is, obtains copper nano-wire load carbon fiber；Described formic acid and the purpose of sodium borohydride in order to Copper ion is reduced to copper simple substance.
(5) polypropylene, copper nano-wire, are loaded into carbon fiber, nano silver wire loads tin ash, aluminium loading ZnO, polypropylene The different certain herbaceous plants with big flowers ester of isopropyl propionate, pentaerythritol diphosphite two, zinc stearate are according to quality parts ratio 100：0.01~0.2：0.01 ~0.3：0.03~0.3：33~52：3~8：2~7 are added in mill, anti-in 193~200 DEG C of mixing of temperature with mill 2~6min is answered, with extruder in 197~220 DEG C of extruding pelletizations of temperature, that is, obtains antistatic polypropylene material.
The beneficial effect of the invention is：
1st, isobutyl acrylate and Isooctyl acrylate monomer monomer have relatively low glass transition temperature, can substantially reduce polypropylene The glass transition temperature of isopropyl propionate, assign polyacrylic acid isopropyl ester excellent toughness and amorphism, so as to reduce polyacrylic knot Brilliant degree and rigidity；
2nd, zinc oleate and celluloid can increase the viscosity of solution in ethanol, the dispersiveness of aluminium ash in the solution be improved, through high temperature After calcination process, zinc oleate decomposes generation ZnO, and aluminium ash deposition is on ZnO surfaces, after sodium hydroxide solution carrying out washing treatment, aluminium Alundum (Al2O3) in ash, which is dissolved, to be removed, and the aluminium loading ZnO of generation can improve the electric conductivity of aluminium simple substance, so as to improve polypropylene Antistatic behaviour；
3rd, ethylal is the product of Alcohol Protection formaldehyde aldehyde radical condensation, in hydrothermal reaction process, ethylal Aldehyde radical can not only be protected not chemically reacted in middle low temperature with other compounds, moreover it is possible to slow down silver ion and gone back in high temperature Former speed, the draw ratio and specific surface area of nano silver wire are controlled, because nano silver wire load tin ash has excellent three-dimensional Structure and electric conductivity, therefore, nano silver wire load tin ash can significantly improve polyacrylic antistatic property；
4th, sodium borohydride in the presence of formaldehyde, can improve its reducing property, and in hydrothermal reaction process, copper naphthenate is by hydroboration Sodium and formaldehyde reduction generation copper nano-wire, copper nano-wire are deposited on carbon fiber surface, form line opposite three-dimensional net structure, and copper is received Rice noodles can significantly improve the electric conductivity of carbon fiber, and copper nano-wire load carbon fiber can improve polyacrylic antistatic property；
5th, in polypropylene, copper nano-wire load carbon fiber, nano silver wire load tin ash, aluminium loading ZnO, polyacrylic acid isopropyl Under ester synergy, polypropylene is changed into point-to-area and line opposite conduction by point-to-point conduction, hence it is evident that improves polyacrylic conduction Performance, so as to improve polyacrylic antistatic property.
Embodiment
The embodiment of the invention is described with reference to embodiment, to be better understood from the invention.
Embodiment 1
A kind of antistatic polypropylene material, its preparation method comprise the following steps：
(1) 80 parts of isopropyl acrylates, 58 parts of isobutyl acrylates, 21 parts of Isooctyl acrylate monomers, 13 parts of methacrylic acids, are weighed Methyl esters and 0.4 part of benzoin methyl ether are added in reactor, mixing speed 80r/min, under the conditions of 28 DEG C of maintenance system temperature 25min is reacted, product obtains polyacrylic acid isopropyl ester through 3000W lamp and high pressure mercury 3s；
(2), weighing 100 parts of zinc oleates, 41 parts of aluminium ashes, 13 parts of celluloids, 85 parts of ethanol and 32 parts of normal propyl alcohols, to be added to hydro-thermal anti- Answer in kettle, reaction temperature is 183 DEG C of reaction 11h, and product washs 3 times through the NaOH aqueous solution of 1L 30%, filtering, 1L deionized waters Washing 3 times, 1L ethanol wash 3 times, and in 72 DEG C, -0.06MPa vacuum drying 5min, under nitrogen protection, product is through 200 DEG C of roastings 2h is burnt, 300 DEG C of roasting 2h, 400 DEG C of roasting 2h, 500 DEG C of roasting 2h, 600 DEG C of roasting 2h, grinding, obtains aluminium loading ZnO；
(3) 100 parts of tin ash, 51 parts of oleic acid silver, 52 parts of ethylals and 9 parts of hydroxypropyl celluloses, are weighed to be added to In hydrothermal reaction kettle, reaction temperature is 196 DEG C of reaction 9h, and product is filtered, and 500mL deionized waters are washed 3 times, 500mL ethanol Washing 3 times, in 56 DEG C, -0.09MPa vacuum drying 9min, that is, obtain nano silver wire load tin ash；
(4), weigh 100 parts of carbon fibers, 76 parts of copper naphthenates, 99 parts of formaldehyde, 129 parts of epoxychloropropane, 18 parts of sodium borohydrides and 43 parts of normal propyl alcohols are added in hydrothermal reaction kettle, and reaction temperature is 196 DEG C of reaction 9h, and product is filtered, the washing of 500mL deionizations Wash 3 times, 500mL ethanol washs 3 times, in 61 DEG C, -0.08MPa vacuum drying 13min, that is, obtains copper nano-wire load carbon fiber；
(5), weigh 100 parts of polypropylene, 0.01 part of copper nano-wire load carbon fiber, 0.02 part of nano silver wire load tin ash, 0.03 part of aluminium loading ZnO, 41 parts of polyacrylic acid isopropyl esters, the different certain herbaceous plants with big flowers ester of 4 parts of pentaerythritol diphosphites two, 5 parts of zinc stearates It is added in mill, with mill in 196 DEG C of hybrid reaction 3min of temperature, with extruder in 209 DEG C of extruding pelletizations of temperature, i.e., Obtain antistatic polypropylene material.
Embodiment 2
A kind of antistatic polypropylene material, its preparation method comprise the following steps：
(1) 80 parts of isopropyl acrylates, 55 parts of isobutyl acrylates, 16 parts of Isooctyl acrylate monomers, 9 parts of methacrylic acids, are weighed Methyl esters and 0.3 part of benzoin methyl ether are added in reactor, mixing speed 73r/min, under the conditions of 27 DEG C of maintenance system temperature 25min is reacted, product obtains polyacrylic acid isopropyl ester through 3000W lamp and high pressure mercury 3s；
(2) 100 parts of zinc oleates, 36 parts of aluminium ashes, 7 parts of celluloids, 78 parts of ethanol and 26 parts of normal propyl alcohols, are weighed and are added to hydro-thermal reaction In kettle, reaction temperature is 176 DEG C of reaction 16h, and product washs 3 times through the NaOH aqueous solution of 1L 30%, filtering, the washing of 1L deionizations Wash 3 times, 1L ethanol washs 3 times, and in 72 DEG C, -0.06MPa vacuum drying 5min, under nitrogen protection, product is through 200 DEG C of roastings 2h, 300 DEG C of roasting 2h, 400 DEG C of roasting 2h, 500 DEG C of roasting 2h, 600 DEG C of roasting 2h, grinding, obtains aluminium loading ZnO；
(3) 100 parts of tin ash, 46 parts of oleic acid silver, 45 parts of ethylals and 7 parts of hydroxypropyl celluloses, are weighed to be added to In hydrothermal reaction kettle, reaction temperature is 186 DEG C of reaction 14h, and product is filtered, and 500mL deionized waters are washed 3 times, 500mL ethanol Washing 3 times, in 56 DEG C, -0.09MPa vacuum drying 9min, that is, obtain nano silver wire load tin ash；
(4), weigh 100 parts of carbon fibers, 65 parts of copper naphthenates, 90 parts of formaldehyde, 123 parts of epoxychloropropane, 13 parts of sodium borohydrides and 35 parts of normal propyl alcohols are added in hydrothermal reaction kettle, and reaction temperature is 181 DEG C of reaction 12h, and product is filtered, 500mL deionized waters Washing 3 times, 500mL ethanol wash 3 times, in 61 DEG C, -0.08MPa vacuum drying 13min, that is, it is fine to obtain copper nano-wire load carbon Dimension；
(5), weigh 100 parts of polypropylene, 0.01 part of copper nano-wire load carbon fiber, 0.01 part of nano silver wire load tin ash, 0.03 part of aluminium loading ZnO, 33 parts of polyacrylic acid isopropyl esters, the different certain herbaceous plants with big flowers ester of 3 parts of pentaerythritol diphosphites two, 2 parts of zinc stearates It is added in mill, with mill in 193 DEG C of hybrid reaction 6min of temperature, with extruder in 197 DEG C of extruding pelletizations of temperature, i.e., Obtain antistatic polypropylene material.
Embodiment 3
A kind of antistatic polypropylene material, its preparation method comprise the following steps：
(1) 80 parts of isopropyl acrylates, 71 parts of isobutyl acrylates, 29 parts of Isooctyl acrylate monomers, 17 parts of methacrylic acids, are weighed Methyl esters and 1 part of benzoin methyl ether are added in reactor, mixing speed 90r/min, anti-under the conditions of 34 DEG C of maintenance system temperature 25min is answered, product obtains polyacrylic acid isopropyl ester through 3000W lamp and high pressure mercury 3s；
(2), weighing 100 parts of zinc oleates, 46 parts of aluminium ashes, 19 parts of celluloids, 97 parts of ethanol and 43 parts of normal propyl alcohols, to be added to hydro-thermal anti- Answer in kettle, reaction temperature is 198 DEG C of reaction 9h, and product washs 3 times through the NaOH aqueous solution of 1L 30%, filtering, the washing of 1L deionizations Wash 3 times, 1L ethanol washs 3 times, and in 72 DEG C, -0.06MPa vacuum drying 5min, under nitrogen protection, product is through 200 DEG C of roastings 2h, 300 DEG C of roasting 2h, 400 DEG C of roasting 2h, 500 DEG C of roasting 2h, 600 DEG C of roasting 2h, grinding, obtains aluminium loading ZnO；
(3) 100 parts of tin ash, 57 parts of oleic acid silver, 66 parts of ethylals and 15 parts of hydroxypropyl celluloses, are weighed to be added to In hydrothermal reaction kettle, reaction temperature is 212 DEG C of reaction 7h, and product is filtered, and 500mL deionized waters are washed 3 times, 500mL ethanol Washing 3 times, in 56 DEG C, -0.09MPa vacuum drying 9min, that is, obtain nano silver wire load tin ash；
(4), weigh 100 parts of carbon fibers, 83 parts of copper naphthenates, 103 parts of formaldehyde, 138 parts of epoxychloropropane, 21 parts of sodium borohydrides and 51 parts of normal propyl alcohols are added in hydrothermal reaction kettle, and reaction temperature is 202 DEG C of reaction 7h, and product is filtered, the washing of 500mL deionizations Wash 3 times, 500mL ethanol washs 3 times, in 61 DEG C, -0.08MPa vacuum drying 13min, that is, obtains copper nano-wire load carbon fiber；
(5) 100 parts of polypropylene, 0.2 part of copper nano-wire load carbon fiber, 0.3 part of nano silver wire load tin ash, 0.3, are weighed Part aluminium loading ZnO, 52 parts of polyacrylic acid isopropyl esters, the different certain herbaceous plants with big flowers ester of 8 parts of pentaerythritol diphosphites two, 7 parts of zinc stearates add Into mill, with mill in 200 DEG C of hybrid reaction 2min of temperature, with extruder in 220 DEG C of extruding pelletizations of temperature, that is, obtain Antistatic polypropylene material.
Embodiment 4
A kind of antistatic polypropylene material, its preparation method comprise the following steps：
(1) 80 parts of isopropyl acrylates, 60 parts of isobutyl acrylates, 25 parts of Isooctyl acrylate monomers, 15 parts of methacrylic acids, are weighed Methyl esters and 0.6 part of benzoin methyl ether are added in reactor, mixing speed 85r/min, under the conditions of 30 DEG C of maintenance system temperature 25min is reacted, product obtains polyacrylic acid isopropyl ester through 3000W lamp and high pressure mercury 3s；
(2), weighing 100 parts of zinc oleates, 45 parts of aluminium ashes, 18 parts of celluloids, 90 parts of ethanol and 40 parts of normal propyl alcohols, to be added to hydro-thermal anti- Answer in kettle, reaction temperature is 185 DEG C of reaction 12h, and product washs 3 times through the NaOH aqueous solution of 1L 30%, filtering, 1L deionized waters Washing 3 times, 1L ethanol wash 3 times, and in 72 DEG C, -0.06MPa vacuum drying 5min, under nitrogen protection, product is through 200 DEG C of roastings 2h is burnt, 300 DEG C of roasting 2h, 400 DEG C of roasting 2h, 500 DEG C of roasting 2h, 600 DEG C of roasting 2h, grinding, obtains aluminium loading ZnO；
(3) 100 parts of tin ash, 55 parts of oleic acid silver, 63 parts of ethylals and 9 parts of hydroxypropyl celluloses, are weighed to be added to In hydrothermal reaction kettle, reaction temperature is 191 DEG C of reaction 9h, and product is filtered, and 500mL deionized waters are washed 3 times, 500mL ethanol Washing 3 times, in 56 DEG C, -0.09MPa vacuum drying 9min, that is, obtain nano silver wire load tin ash；
(4), weigh 100 parts of carbon fibers, 80 parts of copper naphthenates, 101 parts of formaldehyde, 135 parts of epoxychloropropane, 16 parts of sodium borohydrides and 50 parts of normal propyl alcohols are added in hydrothermal reaction kettle, and reaction temperature is 186 DEG C of reaction 8h, and product is filtered, the washing of 500mL deionizations Wash 3 times, 500mL ethanol washs 3 times, in 61 DEG C, -0.08MPa vacuum drying 13min, that is, obtains copper nano-wire load carbon fiber；
(5), weigh 100 parts of polypropylene, 0.08 part of copper nano-wire load carbon fiber, 0.02 part of nano silver wire load tin ash, 0.04 part of aluminium loading ZnO, 51 parts of polyacrylic acid isopropyl esters, the different certain herbaceous plants with big flowers ester of 7 parts of pentaerythritol diphosphites two, 4 parts of zinc stearates It is added in mill, with mill in 194 DEG C of hybrid reaction 4min of temperature, with extruder in 199 DEG C of extruding pelletizations of temperature, i.e., Obtain antistatic polypropylene material.
Embodiment 5
A kind of antistatic polypropylene material, its preparation method comprise the following steps：
(1) 80 parts of isopropyl acrylates, 61 parts of isobutyl acrylates, 26 parts of Isooctyl acrylate monomers, 10 parts of methacrylic acids, are weighed Methyl esters and 0.7 part of benzoin methyl ether are added in reactor, mixing speed 77r/min, under the conditions of 32 DEG C of maintenance system temperature 25min is reacted, product obtains polyacrylic acid isopropyl ester through 3000W lamp and high pressure mercury 3s；
(2) 100 parts of zinc oleates, 37 parts of aluminium ashes, 9 parts of celluloids, 79 parts of ethanol and 41 parts of normal propyl alcohols, are weighed and are added to hydro-thermal reaction In kettle, reaction temperature is 181 DEG C of reaction 10h, and product washs 3 times through the NaOH aqueous solution of 1L 30%, filtering, the washing of 1L deionizations Wash 3 times, 1L ethanol washs 3 times, and in 72 DEG C, -0.06MPa vacuum drying 5min, under nitrogen protection, product is through 200 DEG C of roastings 2h, 300 DEG C of roasting 2h, 400 DEG C of roasting 2h, 500 DEG C of roasting 2h, 600 DEG C of roasting 2h, grinding, obtains aluminium loading ZnO；
(3) 100 parts of tin ash, 53 parts of oleic acid silver, 62 parts of ethylals and 13 parts of hydroxypropyl celluloses, are weighed to be added to In hydrothermal reaction kettle, reaction temperature is 198 DEG C of reaction 12h, and product is filtered, and 500mL deionized waters are washed 3 times, 500mL ethanol Washing 3 times, in 56 DEG C, -0.09MPa vacuum drying 9min, that is, obtain nano silver wire load tin ash；
(4), weigh 100 parts of carbon fibers, 74 parts of copper naphthenates, 96 parts of formaldehyde, 129 parts of epoxychloropropane, 17 parts of sodium borohydrides and 38 parts of normal propyl alcohols are added in hydrothermal reaction kettle, and reaction temperature is 185 DEG C of reaction 11h, and product is filtered, 500mL deionized waters Washing 3 times, 500mL ethanol wash 3 times, in 61 DEG C, -0.08MPa vacuum drying 13min, that is, it is fine to obtain copper nano-wire load carbon Dimension；
(5), weigh 100 parts of polypropylene, 0.15 part of copper nano-wire load carbon fiber, 0.08 part of nano silver wire load tin ash, 0.09 part of aluminium loading ZnO, 44 parts of polyacrylic acid isopropyl esters, the different certain herbaceous plants with big flowers ester of 7 parts of pentaerythritol diphosphites two, 6 parts of zinc stearates It is added in mill, with mill in 195 DEG C of hybrid reaction 4min of temperature, with extruder in 206 DEG C of extruding pelletizations of temperature, i.e., Obtain antistatic polypropylene material.
Embodiment 6
A kind of antistatic polypropylene material, its preparation method comprise the following steps：
(1) 80 parts of isopropyl acrylates, 56 parts of isobutyl acrylates, 17 parts of Isooctyl acrylate monomers, 12 parts of methacrylic acids, are weighed Methyl esters and 0.4 part of benzoin methyl ether are added in reactor, mixing speed 86r/min, under the conditions of 33 DEG C of maintenance system temperature 25min is reacted, product obtains polyacrylic acid isopropyl ester through 3000W lamp and high pressure mercury 3s；
(2) 100 parts of zinc oleates, 45 parts of aluminium ashes, 8 parts of celluloids, 79 parts of ethanol and 43 parts of normal propyl alcohols, are weighed and are added to hydro-thermal reaction In kettle, reaction temperature is 189 DEG C of reaction 13h, and product washs 3 times through the NaOH aqueous solution of 1L 30%, filtering, the washing of 1L deionizations Wash 3 times, 1L ethanol washs 3 times, and in 72 DEG C, -0.06MPa vacuum drying 5min, under nitrogen protection, product is through 200 DEG C of roastings 2h, 300 DEG C of roasting 2h, 400 DEG C of roasting 2h, 500 DEG C of roasting 2h, 600 DEG C of roasting 2h, grinding, obtains aluminium loading ZnO；
(3) 100 parts of tin ash, 55 parts of oleic acid silver, 63 parts of ethylals and 14 parts of hydroxypropyl celluloses, are weighed to be added to In hydrothermal reaction kettle, reaction temperature is 209 DEG C of reaction 13h, and product is filtered, and 500mL deionized waters are washed 3 times, 500mL ethanol Washing 3 times, in 56 DEG C, -0.09MPa vacuum drying 9min, that is, obtain nano silver wire load tin ash；
(4), weigh 100 parts of carbon fibers, 79 parts of copper naphthenates, 102 parts of formaldehyde, 133 parts of epoxychloropropane, 17 parts of sodium borohydrides and 47 parts of normal propyl alcohols are added in hydrothermal reaction kettle, and reaction temperature is 194 DEG C of reaction 11h, and product is filtered, 500mL deionized waters Washing 3 times, 500mL ethanol wash 3 times, in 61 DEG C, -0.08MPa vacuum drying 13min, that is, it is fine to obtain copper nano-wire load carbon Dimension；
(5), weigh 100 parts of polypropylene, 0.17 part of copper nano-wire load carbon fiber, 0.2 part of nano silver wire load tin ash, 0.25 part of aluminium loading ZnO, 51 parts of polyacrylic acid isopropyl esters, the different certain herbaceous plants with big flowers ester of 6 parts of pentaerythritol diphosphites two, 3 parts of zinc stearates It is added in mill, with mill in 198 DEG C of hybrid reaction 5min of temperature, with extruder in 210 DEG C of extruding pelletizations of temperature, i.e., Obtain antistatic polypropylene material.
Embodiment 7
A kind of antistatic polypropylene material, its preparation method comprise the following steps：
(1) 80 parts of isopropyl acrylates, 67 parts of isobutyl acrylates, 27 parts of Isooctyl acrylate monomers, 13 parts of methacrylic acids, are weighed Methyl esters and 0.4 part of benzoin methyl ether are added in reactor, mixing speed 88r/min, under the conditions of 31 DEG C of maintenance system temperature 25min is reacted, product obtains polyacrylic acid isopropyl ester through 3000W lamp and high pressure mercury 3s；
(2) 100 parts of zinc oleates, 39 parts of aluminium ashes, 9 parts of celluloids, 82 parts of ethanol and 36 parts of normal propyl alcohols, are weighed and are added to hydro-thermal reaction In kettle, reaction temperature is 193 DEG C of reaction 10h, and product washs 3 times through the NaOH aqueous solution of 1L 30%, filtering, the washing of 1L deionizations Wash 3 times, 1L ethanol washs 3 times, and in 72 DEG C, -0.06MPa vacuum drying 5min, under nitrogen protection, product is through 200 DEG C of roastings 2h, 300 DEG C of roasting 2h, 400 DEG C of roasting 2h, 500 DEG C of roasting 2h, 600 DEG C of roasting 2h, grinding, obtains aluminium loading ZnO；
(3) 100 parts of tin ash, 55 parts of oleic acid silver, 52 parts of ethylals and 13 parts of hydroxypropyl celluloses, are weighed to be added to In hydrothermal reaction kettle, reaction temperature is 210 DEG C of reaction 11h, and product is filtered, and 500mL deionized waters are washed 3 times, 500mL ethanol Washing 3 times, in 56 DEG C, -0.09MPa vacuum drying 9min, that is, obtain nano silver wire load tin ash；
(4), weigh 100 parts of carbon fibers, 80 parts of copper naphthenates, 96 parts of formaldehyde, 136 parts of epoxychloropropane, 19 parts of sodium borohydrides and 44 parts of normal propyl alcohols are added in hydrothermal reaction kettle, and reaction temperature is 201 DEG C of reaction 8h, and product is filtered, the washing of 500mL deionizations Wash 3 times, 500mL ethanol washs 3 times, in 61 DEG C, -0.08MPa vacuum drying 13min, that is, obtains copper nano-wire load carbon fiber；
(5), weigh 100 parts of polypropylene, 0.16 part of copper nano-wire load carbon fiber, 0.13 part of nano silver wire load tin ash, 0.26 part of aluminium loading ZnO, 51 parts of polyacrylic acid isopropyl esters, the different certain herbaceous plants with big flowers ester of 7 parts of pentaerythritol diphosphites two, 3 parts of zinc stearates It is added in mill, with mill in 198 DEG C of hybrid reaction 5min of temperature, with extruder in 212 DEG C of extruding pelletizations of temperature, i.e., Obtain antistatic polypropylene material.
Embodiment 8
A kind of antistatic polypropylene material, its preparation method comprise the following steps：
(1) 80 parts of isopropyl acrylates, 69 parts of isobutyl acrylates, 23 parts of Isooctyl acrylate monomers, 11 parts of methacrylic acids, are weighed Methyl esters and 0.8 part of benzoin methyl ether are added in reactor, mixing speed 87r/min, under the conditions of 33 DEG C of maintenance system temperature 25min is reacted, product obtains polyacrylic acid isopropyl ester through 3000W lamp and high pressure mercury 3s；
(2) 100 parts of zinc oleates, 45 parts of aluminium ashes, 9 parts of celluloids, 93 parts of ethanol and 43 parts of normal propyl alcohols, are weighed and are added to hydro-thermal reaction In kettle, reaction temperature is 189 DEG C of reaction 14h, and product washs 3 times through the NaOH aqueous solution of 1L 30%, filtering, the washing of 1L deionizations Wash 3 times, 1L ethanol washs 3 times, and in 72 DEG C, -0.06MPa vacuum drying 5min, under nitrogen protection, product is through 200 DEG C of roastings 2h, 300 DEG C of roasting 2h, 400 DEG C of roasting 2h, 500 DEG C of roasting 2h, 600 DEG C of roasting 2h, grinding, obtains aluminium loading ZnO；
(3) 100 parts of tin ash, 51 parts of oleic acid silver, 62 parts of ethylals and 9 parts of hydroxypropyl celluloses, are weighed to be added to In hydrothermal reaction kettle, reaction temperature is 209 DEG C of reaction 13h, and product is filtered, and 500mL deionized waters are washed 3 times, 500mL ethanol Washing 3 times, in 56 DEG C, -0.09MPa vacuum drying 9min, that is, obtain nano silver wire load tin ash；
(4), weigh 100 parts of carbon fibers, 81 parts of copper naphthenates, 100 parts of formaldehyde, 130 parts of epoxychloropropane, 20 parts of sodium borohydrides and 45 parts of normal propyl alcohols are added in hydrothermal reaction kettle, and reaction temperature is 190 DEG C of reaction 10h, and product is filtered, 500mL deionized waters Washing 3 times, 500mL ethanol wash 3 times, in 61 DEG C, -0.08MPa vacuum drying 13min, that is, it is fine to obtain copper nano-wire load carbon Dimension；
(5), weigh 100 parts of polypropylene, 0.12 part of copper nano-wire load carbon fiber, 0.3 part of nano silver wire load tin ash, 0.08 part of aluminium loading ZnO, 47 parts of polyacrylic acid isopropyl esters, the different certain herbaceous plants with big flowers ester of 6 parts of pentaerythritol diphosphites two, 7 parts of zinc stearates It is added in mill, with mill in 199 DEG C of hybrid reaction 3min of temperature, with extruder in 218 DEG C of extruding pelletizations of temperature, i.e., Obtain antistatic polypropylene material.
Reference examples 1
In this reference examples, polyacrylic acid isopropyl ester is not added, and other components and preparation method are same as Example 1.
Reference examples 2
In this reference examples, aluminium loading ZnO is not added, and other components and preparation method are same as Example 1.
Reference examples 3
In this reference examples, nano silver wire load tin ash is not added, other components and preparation method are same as Example 1.
Reference examples 4
In this reference examples, copper nano-wire load carbon fiber is not added, other components and preparation method are same as Example 1.
Reference examples 5
In this reference examples, from the polyacrylic acid isopropyl ester in plain polypropylene acid esters alternate embodiment 1, other components in formula It is same as Example 1 with preparation method.
Reference examples 6
In this reference examples, the aluminium loading ZnO selected in formula in common ZnO alternate embodiments 1, other components and preparation method with Embodiment 1 is identical.
Reference examples 7
The nano silver wire load tin ash selected in this reference examples, in formula in common tin ash alternate embodiment 1, it is other Component is same as Example 1 with preparation method.
Reference examples 8
The copper nano-wire load carbon fiber selected in this reference examples, in formula in common carbon fibers alternate embodiment 1, other components It is same as Example 1 with preparation method.
The performance parameter of antistatic polypropylene material made from the embodiment 1 of table 1 and reference examples 1~8
Embodiment 1 Reference examples 1 Reference examples 2 Reference examples 3 Reference examples 4 Reference examples 5 Reference examples 6 Reference examples 7 Reference examples 8
Sheet resistance/Ω 106 106 108 1010 1013 106 108 1012 1015
Impact strength/J/m 361 101 317 298 236 109 302 335 217
Described above is the preferred embodiment of the invention, it is noted that for those skilled in the art, On the premise of the inventive principle is not departed from, some improvements and modifications can also be made, these improvements and modifications are also considered as the hair Bright protection domain.

Claims (3)

  1. A kind of 1. preparation method of antistatic polypropylene material, it is characterised in that：Including following raw material components：Polypropylene, Tong Na Rice noodles load carbon fiber, nano silver wire load tin ash, aluminium loading ZnO, polyacrylic acid isopropyl ester, diphosphorous acid pentaerythrite The different certain herbaceous plants with big flowers ester of ester two, zinc stearate, described polypropylene, copper nano-wire load carbon fiber, nano silver wire load tin ash, aluminium are born It is 100 to carry ZnO, polyacrylic acid isopropyl ester, the different certain herbaceous plants with big flowers ester of pentaerythritol diphosphite two, the quality parts ratio of zinc stearate： 0.01~0.2：0.01~0.3：0.03~0.3：33~52：3~8：2~7, wherein, described copper nano-wire load carbon fiber It is made by the reaction of carbon fiber, copper naphthenate, formaldehyde, epoxychloropropane, sodium borohydride and normal propyl alcohol, described carbon fiber, cycloalkanes Sour copper, formaldehyde, epoxychloropropane, the quality parts ratio of sodium borohydride and normal propyl alcohol are 100：65~83：90~103：123~ 138：13~21：35~51, described nano silver wire load tin ash by tin ash, oleic acid silver, ethylal and Hydroxypropyl cellulose reaction is made, described tin ash, oleic acid silver, the mass parts of ethylal and hydroxypropyl cellulose Number is than being 100：46~57：45~66：7~15, described aluminium loading ZnO is by zinc oleate, aluminium ash, celluloid, ethanol and positive third Alcohol reaction is made, and described zinc oleate, aluminium ash, celluloid, the quality parts ratio of ethanol and normal propyl alcohol are 100：36~46：7~ 19：78~97：26~43, described polyacrylic acid isopropyl ester is different pungent by isopropyl acrylate, isobutyl acrylate, acrylic acid Ester, methyl methacrylate and benzoin methyl ether reaction are made, described isopropyl acrylate, isobutyl acrylate, acrylic acid The quality parts ratio of different monooctyl ester, methyl methacrylate and benzoin methyl ether is 80：55~71：16~29：9~17：0.3~1.
  2. A kind of 2. preparation method of antistatic polypropylene material according to claim 1, it is characterised in that：Described antistatic Polypropylene material is as made from following preparation method：(1) it is, that isopropyl acrylate, isobutyl acrylate, acrylic acid is different pungent Ester, methyl methacrylate and benzoin methyl ether are 80 according to quality parts ratio：55~71：16~29：9~17：0.3~1 adds Enter into reactor, mixing speed is 73~90r/min, reacts 25min, product under the conditions of 27~34 DEG C of maintenance system temperature Through 3000W lamp and high pressure mercury 3s, polyacrylic acid isopropyl ester is obtained；(2), by zinc oleate, aluminium ash, celluloid, ethanol and positive third Alcohol is according to quality parts ratio 100：36~46：7~19：78~97：26~43 are added in hydrothermal reaction kettle, and reaction temperature is 176~198 DEG C of 9~16h of reaction, product are washed 3 times through the 1L NaOH aqueous solution, and filtering, 1L deionized waters are washed 3 times, 1L ethanol Washing 3 times, in 72 DEG C, -0.06MPa vacuum drying 5min, under nitrogen protection, product is through 200 DEG C of roasting 2h, 300 DEG C of roastings 2h, 400 DEG C of roasting 2h, 500 DEG C of roasting 2h, 600 DEG C of roasting 2h, grinding, obtains aluminium loading ZnO；(3), by tin ash, oleic acid Silver, ethylal and hydroxypropyl cellulose are according to quality parts ratio 100：46~57：45~66：7~15 are added to hydro-thermal In reactor, reaction temperature is 186~212 DEG C of 7~14h of reaction, and product is filtered, and 500mL deionized waters are washed 3 times, 500mL Ethanol washs 3 times, in 56 DEG C, -0.09MPa vacuum drying 9min, that is, obtains nano silver wire load tin ash；(4) it is, that carbon is fine Dimension, copper naphthenate, formaldehyde, epoxychloropropane, sodium borohydride and normal propyl alcohol are according to quality parts ratio 100：65~83：90~103： 123~138：13~21：35~51 are added in hydrothermal reaction kettle, and reaction temperature is 181~202 DEG C and reacts 7~12h, product Filtered, 500mL deionized waters are washed 3 times, and 500mL ethanol washs 3 times, are dried in vacuo 13min in 61 DEG C, -0.08MPa, i.e., Obtain copper nano-wire load carbon fiber；(5), by polypropylene, copper nano-wire load carbon fiber, nano silver wire load tin ash, The different certain herbaceous plants with big flowers ester of aluminium loading ZnO, polyacrylic acid isopropyl ester, pentaerythritol diphosphite two, zinc stearate are according to quality parts ratio 100：0.01~0.2：0.01~0.3：0.03~0.3：33~52：3~8：2~7 are added in mill, with mill in temperature 193~200 DEG C of 2~6min of hybrid reaction are spent, with extruder in 197~220 DEG C of extruding pelletizations of temperature, that is, obtain antistatic poly- third Alkene material.
  3. A kind of 3. preparation method of antistatic polypropylene material according to claim 2, it is characterised in that：Described NaOH water Solution concentration is 30%（wt.%）.
CN201710822423.5A 2017-09-13 2017-09-13 A kind of antistatic polypropylene material and preparation method thereof Withdrawn CN107434882A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108690224A (en) * 2018-05-29 2018-10-23 杭州鼎好新材料有限公司 A kind of high-strength polypropylene paper material and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108690224A (en) * 2018-05-29 2018-10-23 杭州鼎好新材料有限公司 A kind of high-strength polypropylene paper material and preparation method thereof

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Application publication date: 20171205