CN106221060B - A kind of polyacrylamide modified polyvinyl chloride and preparation method thereof - Google Patents
A kind of polyacrylamide modified polyvinyl chloride and preparation method thereof Download PDFInfo
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- CN106221060B CN106221060B CN201610602924.8A CN201610602924A CN106221060B CN 106221060 B CN106221060 B CN 106221060B CN 201610602924 A CN201610602924 A CN 201610602924A CN 106221060 B CN106221060 B CN 106221060B
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- 229920000915 polyvinyl chloride Polymers 0.000 title claims abstract description 190
- 239000004800 polyvinyl chloride Substances 0.000 title claims abstract description 170
- 229920002401 polyacrylamide Polymers 0.000 title claims abstract description 54
- 238000002360 preparation method Methods 0.000 title claims description 21
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 58
- 239000004411 aluminium Substances 0.000 claims abstract description 54
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 54
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 54
- 239000000835 fiber Substances 0.000 claims abstract description 49
- 238000006243 chemical reaction Methods 0.000 claims abstract description 47
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 45
- 239000000843 powder Substances 0.000 claims abstract description 37
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 36
- 150000002148 esters Chemical class 0.000 claims abstract description 32
- ZHUWIYQJHBMTCY-UHFFFAOYSA-N 3-[ethoxy(2,2,2-triethoxyethoxy)silyl]propan-1-amine Chemical compound NCCC[SiH](OCC(OCC)(OCC)OCC)OCC ZHUWIYQJHBMTCY-UHFFFAOYSA-N 0.000 claims abstract description 31
- 244000052616 bacterial pathogen Species 0.000 claims abstract description 30
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 22
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 20
- 239000001110 calcium chloride Substances 0.000 claims abstract description 20
- 229910001628 calcium chloride Inorganic materials 0.000 claims abstract description 20
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 claims abstract description 19
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims abstract description 18
- 235000011114 ammonium hydroxide Nutrition 0.000 claims abstract description 18
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 18
- GXURZKWLMYOCDX-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O.OCC(CO)(CO)CO GXURZKWLMYOCDX-UHFFFAOYSA-N 0.000 claims abstract description 10
- XDJWZONZDVNKDU-UHFFFAOYSA-N 1314-24-5 Chemical compound O=POP=O XDJWZONZDVNKDU-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 54
- 238000005453 pelletization Methods 0.000 claims description 36
- 229910052757 nitrogen Inorganic materials 0.000 claims description 27
- 238000001914 filtration Methods 0.000 claims description 26
- 238000012423 maintenance Methods 0.000 claims description 25
- -1 diethyl TMOS Chemical compound 0.000 claims description 14
- 229920001596 poly (chlorostyrenes) Polymers 0.000 claims description 10
- OHRVBDRGLIWLPA-UHFFFAOYSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] dihydrogen phosphate Chemical compound OCC(CO)(CO)COP(O)(O)=O OHRVBDRGLIWLPA-UHFFFAOYSA-N 0.000 claims description 6
- 238000001125 extrusion Methods 0.000 claims description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- 239000011574 phosphorus Substances 0.000 claims description 3
- 150000001336 alkenes Chemical class 0.000 claims description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims 2
- 241001614291 Anoplistes Species 0.000 claims 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- 206010013786 Dry skin Diseases 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 239000008187 granular material Substances 0.000 claims 1
- 238000003756 stirring Methods 0.000 claims 1
- 238000004140 cleaning Methods 0.000 abstract description 5
- 238000002834 transmittance Methods 0.000 abstract description 5
- 230000001590 oxidative effect Effects 0.000 abstract description 4
- 230000010148 water-pollination Effects 0.000 abstract description 4
- 230000008901 benefit Effects 0.000 abstract description 3
- 241000304886 Bacilli Species 0.000 description 20
- 238000002156 mixing Methods 0.000 description 14
- 239000008188 pellet Substances 0.000 description 12
- FOBPTJZYDGNHLR-UHFFFAOYSA-N diphosphorus Chemical compound P#P FOBPTJZYDGNHLR-UHFFFAOYSA-N 0.000 description 10
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 10
- 239000002253 acid Substances 0.000 description 7
- 150000007513 acids Chemical class 0.000 description 7
- 239000007789 gas Substances 0.000 description 7
- 238000007254 oxidation reaction Methods 0.000 description 7
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 5
- 239000004033 plastic Substances 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 239000008346 aqueous phase Substances 0.000 description 4
- ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 description 4
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 4
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 4
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 3
- 239000000920 calcium hydroxide Substances 0.000 description 3
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 239000001506 calcium phosphate Substances 0.000 description 2
- 229910000389 calcium phosphate Inorganic materials 0.000 description 2
- 235000011010 calcium phosphates Nutrition 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 2
- 238000003746 solid phase reaction Methods 0.000 description 2
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 2
- 238000001291 vacuum drying Methods 0.000 description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005213 imbibition Methods 0.000 description 1
- 239000002649 leather substitute Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000001603 reducing effect Effects 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention is related to a kind of polyacrylamide modified polyvinyl chloride, including following raw material components：Modified polyvinyl chloride, polyvinyl chloride continuous fiber modified polyvinyl chloride, aluminium powder, modified polyvinyl chloride is by polyacrylamide, polyvinyl chloride, Arizona bacilli, calcium carbonate, the different certain herbaceous plants with big flowers ester of pentaerythritol diphosphite two and the reaction of aminopropyltriethoxy diethoxy silane are made, polyvinyl chloride continuous fiber modified polyvinyl chloride is by polyvinyl chloride continuous fiber, polyvinyl chloride, Arizona bacilli, the different certain herbaceous plants with big flowers ester of pentaerythritol diphosphite two and the reaction of aminopropyltriethoxy diethoxy silane are made, aluminium powder is by aluminium block, ethanol, cyclohexanol, water and formaldehyde reaction are made, Arizona bacilli is by diphosphorus trioxide, ammoniacal liquor, water, isopropanol and calcium chloride reaction are made.The invention has the advantages such as excellent self-cleaning property, mechanical property, anti-flammability, low water vapor transmittance, mould proof performance, compatibility, resistance to ag(e)ing, oxidative resistance, hydrophily.
Description
Technical field
The invention is related to a kind of polyacrylamide modified polyvinyl chloride and preparation method thereof.
Background technology
Polyvinyl chloride has mechanical strength big, and organic solvent-resistant, electric insulating quality is good, does not influence water quality, good processability
Etc. advantage.Polyvinyl chloride can be molded with methods such as extrusion, injection, molding, blowings, be widely used in manufacture plastic packing box, modeling
Flitch material, plastic pipe, plastic sheeting, plastic packaging bag, artificial leather product etc..
At present, polyvinyl chloride modifying material is in self-cleaning property, mechanical property, anti-flammability, low water vapor transmittance, mould proof property
The performances such as energy, compatibility, resistance to ag(e)ing, oxidative resistance, hydrophily need further lifting.The invention uses polyvinyl chloride, Asia
Calcium phosphate, aluminium powder, polyacrylamide, calcium carbonate, polyvinyl chloride continuous fiber are prepared for polyacrylamide modified polyvinyl chloride, lead to
Cross the techniques such as extrusion, injection, molding, blowing and be prepared into various plastic products, polyacrylamide prepared by this method is modified polychlorostyrene
Vinyl material has excellent self-cleaning property, mechanical property, anti-flammability, low water vapor transmittance, mould proof performance, compatibility, resistance to
The performances such as aging, oxidative resistance, hydrophily.
The content of the invention
The purpose of the invention is to provide a kind of preparation method of polyacrylamide modified polyvinyl chloride, and this method is by changing
Become reactant feed and technology mode, the material of preparation has excellent self-cleaning property, mechanical property, anti-flammability, low steam saturating
Cross the performances such as rate, mould proof performance, compatibility, resistance to ag(e)ing, oxidative resistance, hydrophily.
To achieve these goals, the technical scheme of the invention is as follows.
A kind of polyacrylamide modified polyvinyl chloride and preparation method thereof, specifically includes following steps：(1), by three oxidations
Two phosphorus, ammoniacal liquor, water, isopropanol and calcium chloride are 100 according to quality parts ratio：156~193：200~260：65~83：93~
109 are added in reactor, and mixing speed is 1~2h of reaction under the conditions of 65~78r/min, 36~40 DEG C of maintenance system temperature,
Through filtering, 65 DEG C, -0.09MPa vacuum drying 2h under nitrogen protection, 2h are calcined in 200 DEG C, 300 DEG C are calcined 2h, 400 DEG C
2h, 500 DEG C of roastings 2h, 600 DEG C of roasting 2h are calcined, Arizona bacilli is obtained；(2), aluminium block, ethanol, cyclohexanol, water and formaldehyde are pressed
According to quality parts ratio 100：65~80：200~270：370~400：30~45 are added in ball mill, drum speed be 40~
1~3h is reacted under the conditions of 55r/min, 25~40 DEG C of maintenance system temperature, is washed 3 times through filtering, 1L ethanol, in nitrogen protection
Under, 105 DEG C of dry 3h obtain aluminium powder；(3), by polyvinyl chloride continuous fiber, polyvinyl chloride, Arizona bacilli, diphosphorous acid season penta
Four alcohol ester two different certain herbaceous plants with big flowers ester and aminopropyltriethoxy diethoxy silane are according to quality parts ratio 100：65~80：7~15：1~2：1~
3 are added in mill, with mill in 146~183 DEG C of 0.5~2h of hybrid reaction of temperature, with extruder temperature 146~
183 DEG C of extruding pelletizations, that is, obtain polyvinyl chloride continuous fiber modified polyvinyl chloride；(4), by polyacrylamide, polyvinyl chloride, Asia
The different certain herbaceous plants with big flowers ester of calcium phosphate, calcium carbonate, pentaerythritol diphosphite two and aminopropyltriethoxy diethoxy silane are according to mass fraction
Than 10：85~97：8~17：16~28：1~2：2~4 are added in mill, with mill in 146~183 DEG C of mixing of temperature
0.5~2h is reacted, with extruder in 146~183 DEG C of extruding pelletizations of temperature, that is, modified polyvinyl chloride is obtained；(5), will be modified poly-
Vinyl chloride, polyvinyl chloride continuous fiber modified polyvinyl chloride, aluminium powder are according to quality parts ratio 100：74~87：17~26 are added to
In mill, with mill in 146~183 DEG C of 0.5~2h of hybrid reaction of temperature, with extruder in 146~183 DEG C of extrusions of temperature
Granulation, that is, obtain polyacrylamide modified polyvinyl chloride pellet.
The preparation method of polyacrylamide modified polyvinyl chloride described in the invention, comprises the following steps：
(1) it is, 100 according to quality parts ratio by diphosphorus trioxide, ammoniacal liquor, water, isopropanol and calcium chloride：156~193：
200~260：65~83：93~109 are added in reactor, mixing speed be 65~78r/min, maintenance system temperature 36~
1~2h is reacted under the conditions of 40 DEG C, through filtering, 65 DEG C, -0.09MPa vacuum drying 2h, under nitrogen protection, in 200 DEG C of roastings
2h, 300 DEG C of roastings 2h, 400 DEG C of roastings 2h, 500 DEG C of roastings 2h, 600 DEG C of roasting 2h, obtains Arizona bacilli；Described ammoniacal liquor
Purpose to form calcium hydroxide to be reacted with calcium chloride, finally occurs solid phase reaction with diphosphorus trioxide, generates Arizona bacilli.
(2), by aluminium block, ethanol, cyclohexanol, water and formaldehyde according to quality parts ratio 100：65~80：200~270：370
~400：30~45 are added in ball mill, and drum speed is 40~55r/min, under the conditions of 25~40 DEG C of maintenance system temperature
1~3h is reacted, is washed 3 times through filtering, 1L ethanol, under nitrogen protection, 105 DEG C of dry 3h obtain aluminium powder；Described cyclohexanol
Purpose in order to completely cut off aqueous phase and air, prevent that air from entering aqueous phase, cause the oxidation of aluminium powder.
(3), by polyvinyl chloride continuous fiber, polyvinyl chloride, Arizona bacilli, the different certain herbaceous plants with big flowers ester of pentaerythritol diphosphite two and
Aminopropyltriethoxy diethoxy silane is according to quality parts ratio 100：65~80：7~15：1~2：1~3 is added in mill,
With mill in 146~183 DEG C of 0.5~2h of hybrid reaction of temperature, with extruder in 146~183 DEG C of extruding pelletizations of temperature, produce
To polyvinyl chloride continuous fiber modified polyvinyl chloride；The purpose of described polyvinyl chloride continuous fiber is in order to improve polyvinyl chloride
Mechanical strength, the purpose of described Arizona bacilli is in order to improve the oxidation resistent susceptibility and ageing-resistant performance of polyvinyl chloride.
(4), by polyacrylamide, polyvinyl chloride, Arizona bacilli, calcium carbonate, the different certain herbaceous plants with big flowers ester of pentaerythritol diphosphite two
With aminopropyltriethoxy diethoxy silane according to quality parts ratio 10：85~97：8~17：16~28：1~2：2~4 are added to
In mill, with mill in 146~183 DEG C of 0.5~2h of hybrid reaction of temperature, with extruder in 146~183 DEG C of extrusions of temperature
Granulation, that is, obtain modified polyvinyl chloride, and the purpose of described calcium carbonate is in order to neutralize the hydrogen chloride gas in polyvinyl chloride and carry
The fire resistance of high polyvinyl chloride.
(5), by modified polyvinyl chloride, polyvinyl chloride continuous fiber modified polyvinyl chloride, aluminium powder according to quality parts ratio
100：74~87：17~26 are added in mill, with mill in 146~183 DEG C of 0.5~2h of hybrid reaction of temperature, with squeezing
Go out machine in 146~183 DEG C of extruding pelletizations of temperature, that is, obtain polyacrylamide modified polyvinyl chloride pellet, the purpose of described aluminium
In order to reduce the water vapor transmittance of polyvinyl chloride.
The beneficial effect of the invention is：
1st, ammoniacal liquor and calcium chloride react in diphosphorus trioxide powder solution, and newly-generated calcium hydroxide is coated on three oxidations
Two phosphorus surfaces, under nitrogen protection, when high-temperature heat treatment, solid phase reaction occurs for the diphosphorus trioxide of calcium hydroxide cladding, raw
Into Arizona bacilli, Arizona bacilli has excellent reducing property, can assign the excellent oxidation resistent susceptibility of polyvinyl chloride and resistance to old
Change performance；
2nd, in aluminium powder preparation process, the water boiled is on the one hand used for reaction dissolvent, to remove the air dissolved in water,
Prevent that it from occurring oxidation reaction with aluminium powder, on the other hand, cyclohexanol is slightly soluble in water, and density ratio water is small, can be in aqueous phase and air
Separation layer is formed between phase, prevents that air from dissolving in aqueous phase, occurs oxidation reaction with aluminium powder, moreover, cyclohexanol also has gas molten
Xie Du is small, volatilization is small, it is nontoxic, the advantage such as easily remove；
3rd, polyacrylamide has excellent water imbibition, in Blending Processes, and the water of polyacrylamide adsorption is heated
Gasification, can increase the porosity of polyvinyl chloride surface as pore creating material, can be in polychlorostyrene while polyacrylamide absorbs water
Pvdf surface one layer of hydrophilic film of formation, hydrophilic film is conducive to fluid to take away the dirty material of polyvinyl chloride surface, so as to reach polychlorostyrene
The automatically cleaning effect of pvdf surface；
4th, polyvinyl chloride can discharge hydrogen chloride gas, the hydrogen chloride of polyvinyl chloride release can during processing and use
With with calcium carbonate reaction, form calcium chloride and carbon dioxide, calcium chloride acts not only as filler and used, can also impart to gather
While vinyl chloride fire resistance, the harm that polyvinyl chloride discharges hydrogen chloride is solved；
5th, polyvinyl chloride continuous fiber has excellent mechanical property, and has excellent compatibility with polyvinyl chloride, can
To assign the excellent tensile property of polyvinyl chloride, impact property and bending property；
6th, aluminium has relatively low water vapor transmittance, can assign polyvinyl chloride excellent low steam breathability energy.
Embodiment
The embodiment of the invention is described with reference to embodiment, to be better understood from the invention.
Embodiment 1
A kind of polyacrylamide modified polyvinyl chloride, its preparation method comprises the following steps：
(1) 100 parts of diphosphorus trioxides, 172 parts of ammoniacal liquor, 236 parts of water, 71 parts of isopropanols and 95 parts of calcium chloride, are weighed to add
Into reactor, mixing speed is to react 1.2h under the conditions of 69r/min, 38 DEG C of maintenance system temperature, through filtering, 65 DEG C ,-
0.09MPa is dried in vacuo 2h, under nitrogen protection, and 2h, 300 DEG C of roastings 2h, 400 DEG C of roasting 2h, 500 DEG C of roastings are calcined in 200 DEG C
2h, 600 DEG C of roasting 2h are burnt, Arizona bacilli is obtained；
(2) 100 parts of aluminium blocks, 68 parts of ethanol, 260 parts of cyclohexanol, 385 parts of water and 37 parts of formaldehyde, are weighed and are added to ball mill
In, drum speed is to react 2h under the conditions of 43r/min, 30 DEG C of maintenance system temperature, is washed 3 times through filtering, 1L ethanol, in nitrogen
Under gas shielded, 105 DEG C of dry 3h obtain aluminium powder；
(3) 100 parts of polyvinyl chloride continuous fibers, 74 parts of polyvinyl chloride, 12 parts of Arizona bacillis, 2 parts of diphosphorous acid seasons, are weighed
The different certain herbaceous plants with big flowers ester of Doutrate two and 3 parts of aminopropyltriethoxy diethoxy silanes are added in mill, with mill in 173 DEG C of temperature
Hybrid reaction 0.7h, with extruder in 173 DEG C of extruding pelletizations of temperature, that is, obtains polyvinyl chloride continuous fiber modified polyvinyl chloride；
(4) 10 parts of polyacrylamides, 94 parts of polyvinyl chloride, 15 parts of Arizona bacillis, 24 parts of calcium carbonate, 2 part of two phosphorous, are weighed
The sour different certain herbaceous plants with big flowers ester of pentaerythritol ester two and 3 parts of aminopropyltriethoxy diethoxy silanes are added in mill, with mill in temperature
173 DEG C of hybrid reaction 0.7h, with extruder in 173 DEG C of extruding pelletizations of temperature, that is, obtain modified polyvinyl chloride；
(5) 100 parts of modified polyvinyl chlorides, 83 parts of polyvinyl chloride continuous fiber modified polyvinyl chlorides, 23 parts of aluminium powders, are weighed to add
Enter into mill, with mill in 173 DEG C of hybrid reaction 0.5h of temperature, with extruder in 173 DEG C of extruding pelletizations of temperature, produce
To polyacrylamide modified polyvinyl chloride pellet.
Embodiment 2
A kind of polyacrylamide modified polyvinyl chloride, its preparation method comprises the following steps：
(1) 100 parts of diphosphorus trioxides, 156 parts of ammoniacal liquor, 200 parts of water, 65 parts of isopropanols and 93 parts of calcium chloride, are weighed to add
Into reactor, mixing speed is to react 1h under the conditions of 65r/min, 36 DEG C of maintenance system temperature, through filtering, 65 DEG C ,-
0.09MPa is dried in vacuo 2h, under nitrogen protection, and 2h, 300 DEG C of roastings 2h, 400 DEG C of roasting 2h, 500 DEG C of roastings are calcined in 200 DEG C
2h, 600 DEG C of roasting 2h are burnt, Arizona bacilli is obtained；
(2) 100 parts of aluminium blocks, 65 parts of ethanol, 200 parts of cyclohexanol, 370 parts of water and 30 parts of formaldehyde, are weighed and are added to ball mill
In, drum speed is to react 1h under the conditions of 40r/min, 25 DEG C of maintenance system temperature, is washed 3 times through filtering, 1L ethanol, in nitrogen
Under gas shielded, 105 DEG C of dry 3h obtain aluminium powder；
(3) 100 parts of polyvinyl chloride continuous fibers, 65 parts of polyvinyl chloride, 7 parts of Arizona bacillis, 1 part of diphosphorous acid season, are weighed
The different certain herbaceous plants with big flowers ester of Doutrate two and 1 part of aminopropyltriethoxy diethoxy silane are added in mill, with mill in 146 DEG C of temperature
Hybrid reaction 0.5h, with extruder in 146 DEG C of extruding pelletizations of temperature, that is, obtains polyvinyl chloride continuous fiber modified polyvinyl chloride；
(4) 10 parts of polyacrylamides, 85 parts of polyvinyl chloride, 87 parts of Arizona bacillis, 16 parts of calcium carbonate, 1 part of two phosphorous, are weighed
The sour different certain herbaceous plants with big flowers ester of pentaerythritol ester two and 2 parts of aminopropyltriethoxy diethoxy silanes are added in mill, with mill in temperature
146 DEG C of hybrid reaction 0.5h, with extruder in 146 DEG C of extruding pelletizations of temperature, that is, obtain modified polyvinyl chloride；
(5) 100 parts of modified polyvinyl chlorides, 74 parts of polyvinyl chloride continuous fiber modified polyvinyl chlorides, 17 parts of aluminium powders, are weighed to add
Enter into mill, with mill in 146 DEG C of hybrid reaction 0.5h of temperature, with extruder in 146 DEG C of extruding pelletizations of temperature, produce
To polyacrylamide modified polyvinyl chloride pellet.
Embodiment 3
A kind of polyacrylamide modified polyvinyl chloride, its preparation method comprises the following steps：
(1) 100 parts of diphosphorus trioxides, 193 parts of ammoniacal liquor, 260 parts of water, 83 parts of isopropanols and 109 parts of calcium chloride, are weighed to add
Into reactor, mixing speed is to react 2h under the conditions of 78r/min, 40 DEG C of maintenance system temperature, through filtering, 65 DEG C ,-
0.09MPa is dried in vacuo 2h, under nitrogen protection, and 2h, 300 DEG C of roastings 2h, 400 DEG C of roasting 2h, 500 DEG C of roastings are calcined in 200 DEG C
2h, 600 DEG C of roasting 2h are burnt, Arizona bacilli is obtained；
(2) 100 parts of aluminium blocks, 80 parts of ethanol, 270 parts of cyclohexanol, 400 parts of water and 45 parts of formaldehyde, are weighed and are added to ball mill
In, drum speed is to react 3h under the conditions of 55r/min, 40 DEG C of maintenance system temperature, is washed 3 times through filtering, 1L ethanol, in nitrogen
Under gas shielded, 105 DEG C of dry 3h obtain aluminium powder；
(3) 100 parts of polyvinyl chloride continuous fibers, 80 parts of polyvinyl chloride, 15 parts of Arizona bacillis, 2 parts of diphosphorous acid seasons, are weighed
The different certain herbaceous plants with big flowers ester of Doutrate two and 3 parts of aminopropyltriethoxy diethoxy silanes are added in mill, with mill in 183 DEG C of temperature
Hybrid reaction 2h, with extruder in 149 DEG C of extruding pelletizations of temperature, that is, obtains polyvinyl chloride continuous fiber modified polyvinyl chloride；
(4) 10 parts of polyacrylamides, 97 parts of polyvinyl chloride, 17 parts of Arizona bacillis, 28 parts of calcium carbonate, 2 part of two phosphorous, are weighed
The sour different certain herbaceous plants with big flowers ester of pentaerythritol ester two and 4 parts of aminopropyltriethoxy diethoxy silanes are added in mill, with mill in temperature
183 DEG C of hybrid reaction 2h, with extruder in 183 DEG C of extruding pelletizations of temperature, that is, obtain modified polyvinyl chloride；
(5) 100 parts of modified polyvinyl chlorides, 87 parts of polyvinyl chloride continuous fiber modified polyvinyl chlorides, 26 parts of aluminium powders, are weighed to add
Enter into mill, with mill in 183 DEG C of hybrid reaction 2h of temperature, with extruder in 183 DEG C of extruding pelletizations of temperature, that is, obtain
Polyacrylamide modified polyvinyl chloride pellet.
Embodiment 4
A kind of polyacrylamide modified polyvinyl chloride, its preparation method comprises the following steps：
(1) 100 parts of diphosphorus trioxides, 161 parts of ammoniacal liquor, 255 parts of water, 68 parts of isopropanols and 99 parts of calcium chloride, are weighed to add
Into reactor, mixing speed is to react 1.3h under the conditions of 75r/min, 39 DEG C of maintenance system temperature, through filtering, 65 DEG C ,-
0.09MPa is dried in vacuo 2h, under nitrogen protection, and 2h, 300 DEG C of roastings 2h, 400 DEG C of roasting 2h, 500 DEG C of roastings are calcined in 200 DEG C
2h, 600 DEG C of roasting 2h are burnt, Arizona bacilli is obtained；
(2) 100 parts of aluminium blocks, 69 parts of ethanol, 260 parts of cyclohexanol, 395 parts of water and 43 parts of formaldehyde, are weighed and are added to ball mill
In, drum speed is to react 2.7h under the conditions of 53r/min, 37 DEG C of maintenance system temperature, is washed 3 times through filtering, 1L ethanol,
Under nitrogen protection, 105 DEG C of dry 3h obtain aluminium powder；
(3) 100 parts of polyvinyl chloride continuous fibers, 77 parts of polyvinyl chloride, 14 parts of Arizona bacillis, 1.3 parts of diphosphorous acids, are weighed
The different certain herbaceous plants with big flowers ester of pentaerythritol ester two and 2.7 parts of aminopropyltriethoxy diethoxy silanes are added in mill, with mill in temperature
155 DEG C of hybrid reaction 1.8h, with extruder in 155 DEG C of extruding pelletizations of temperature, that is, obtain polyvinyl chloride continuous fiber and are modified polychlorostyrene
Ethene；
(4) 10 parts of polyacrylamides, 87 parts of polyvinyl chloride, 10 parts of Arizona bacillis, 22 parts of calcium carbonate, 2 part of two phosphorous, are weighed
The sour different certain herbaceous plants with big flowers ester of pentaerythritol ester two and 4 parts of aminopropyltriethoxy diethoxy silanes are added in mill, with mill in temperature
155 DEG C of hybrid reaction 1.7h, with extruder in 155 DEG C of extruding pelletizations of temperature, that is, obtain modified polyvinyl chloride；
(5) 100 parts of modified polyvinyl chlorides, 77 parts of polyvinyl chloride continuous fiber modified polyvinyl chlorides, 22 parts of aluminium powders, are weighed to add
Enter into mill, with mill in 155 DEG C of hybrid reaction 1.5h of temperature, with extruder in 155 DEG C of extruding pelletizations of temperature, produce
To polyacrylamide modified polyvinyl chloride pellet.
Embodiment 5
A kind of polyacrylamide modified polyvinyl chloride, its preparation method comprises the following steps：
(1) 100 parts of diphosphorus trioxides, 183 parts of ammoniacal liquor, 220 parts of water, 80 parts of isopropanols and 100 parts of calcium chloride, are weighed to add
Into reactor, mixing speed is to react 1.5h under the conditions of 73r/min, 37 DEG C of maintenance system temperature, through filtering, 65 DEG C ,-
0.09MPa is dried in vacuo 2h, under nitrogen protection, and 2h, 300 DEG C of roastings 2h, 400 DEG C of roasting 2h, 500 DEG C of roastings are calcined in 200 DEG C
2h, 600 DEG C of roasting 2h are burnt, Arizona bacilli is obtained；
(2) 100 parts of aluminium blocks, 76 parts of ethanol, 220 parts of cyclohexanol, 380 parts of water and 38 parts of formaldehyde, are weighed and are added to ball mill
In, drum speed is to react 2.4h under the conditions of 49r/min, 36 DEG C of maintenance system temperature, is washed 3 times through filtering, 1L ethanol,
Under nitrogen protection, 105 DEG C of dry 3h obtain aluminium powder；
(3) 100 parts of polyvinyl chloride continuous fibers, 73 parts of polyvinyl chloride, 12 parts of Arizona bacillis, 1.2 parts of diphosphorous acids, are weighed
The different certain herbaceous plants with big flowers ester of pentaerythritol ester two and 1.9 parts of aminopropyltriethoxy diethoxy silanes are added in mill, with mill in temperature
161 DEG C of hybrid reaction 1.8h, with extruder in 161 DEG C of extruding pelletizations of temperature, that is, obtain polyvinyl chloride continuous fiber and are modified polychlorostyrene
Ethene；
(4) 10 parts of polyacrylamides, 94 parts of polyvinyl chloride, 11 parts of Arizona bacillis, 25 parts of calcium carbonate, 1.6 part of two Asia, are weighed
The different certain herbaceous plants with big flowers ester of Pentaerythritol phosphate two and 3.5 parts of aminopropyltriethoxy diethoxy silanes are added in mill, are existed with mill
161 DEG C of hybrid reaction 1.6h of temperature, with extruder in 161 DEG C of extruding pelletizations of temperature, that is, obtain modified polyvinyl chloride；
(5) 100 parts of modified polyvinyl chlorides, 79 parts of polyvinyl chloride continuous fiber modified polyvinyl chlorides, 24 parts of aluminium powders, are weighed to add
Enter into mill, with mill in 161 DEG C of hybrid reaction 1.3h of temperature, with extruder in 161 DEG C of extruding pelletizations of temperature, produce
To polyacrylamide modified polyvinyl chloride pellet.
Embodiment 6
A kind of polyacrylamide modified polyvinyl chloride, its preparation method comprises the following steps：
(1) 100 parts of diphosphorus trioxides, 187 parts of ammoniacal liquor, 217 parts of water, 73 parts of isopropanols and 97 parts of calcium chloride, are weighed to add
Into reactor, mixing speed is to react 1.7h under the conditions of 70r/min, 38 DEG C of maintenance system temperature, through filtering, 65 DEG C ,-
0.09MPa is dried in vacuo 2h, under nitrogen protection, and 2h, 300 DEG C of roastings 2h, 400 DEG C of roasting 2h, 500 DEG C of roastings are calcined in 200 DEG C
2h, 600 DEG C of roasting 2h are burnt, Arizona bacilli is obtained；
(2) 100 parts of aluminium blocks, 77 parts of ethanol, 266 parts of cyclohexanol, 395 parts of water and 44 parts of formaldehyde, are weighed and are added to ball mill
In, drum speed is to react 1.6h under the conditions of 53r/min, 35 DEG C of maintenance system temperature, is washed 3 times through filtering, 1L ethanol,
Under nitrogen protection, 105 DEG C of dry 3h obtain aluminium powder；
(3) 100 parts of polyvinyl chloride continuous fibers, 75 parts of polyvinyl chloride, 12 parts of Arizona bacillis, 1.3 parts of diphosphorous acids, are weighed
The different certain herbaceous plants with big flowers ester of pentaerythritol ester two and 2.6 parts of aminopropyltriethoxy diethoxy silanes are added in mill, with mill in temperature
164 DEG C of hybrid reaction 1.7h, with extruder in 164 DEG C of extruding pelletizations of temperature, that is, obtain polyvinyl chloride continuous fiber and are modified polychlorostyrene
Ethene；
(4) 10 parts of polyacrylamides, 93 parts of polyvinyl chloride, 15 parts of Arizona bacillis, 23 parts of calcium carbonate, 1.3 part of two Asia, are weighed
The different certain herbaceous plants with big flowers ester of Pentaerythritol phosphate two and 3.7 parts of aminopropyltriethoxy diethoxy silanes are added in mill, are existed with mill
164 DEG C of hybrid reaction 1.7h of temperature, with extruder in 164 DEG C of extruding pelletizations of temperature, that is, obtain modified polyvinyl chloride；
(5) 100 parts of modified polyvinyl chlorides, 81 parts of polyvinyl chloride continuous fiber modified polyvinyl chlorides, 23 parts of aluminium powders, are weighed to add
Enter into mill, with mill in 164 DEG C of hybrid reaction 1.5h of temperature, with extruder in 164 DEG C of extruding pelletizations of temperature, produce
To polyacrylamide modified polyvinyl chloride pellet.
Embodiment 7
A kind of polyacrylamide modified polyvinyl chloride, its preparation method comprises the following steps：
(1) 100 parts of diphosphorus trioxides, 175 parts of ammoniacal liquor, 241 parts of water, 73 parts of isopropanols and 103 parts of calcium chloride, are weighed to add
Into reactor, mixing speed is to react 1.8h under the conditions of 76r/min, 38 DEG C of maintenance system temperature, through filtering, 65 DEG C ,-
0.09MPa is dried in vacuo 2h, under nitrogen protection, and 2h, 300 DEG C of roastings 2h, 400 DEG C of roasting 2h, 500 DEG C of roastings are calcined in 200 DEG C
2h, 600 DEG C of roasting 2h are burnt, Arizona bacilli is obtained；
(2) 100 parts of aluminium blocks, 79 parts of ethanol, 255 parts of cyclohexanol, 385 parts of water and 38 parts of formaldehyde, are weighed and are added to ball mill
In, drum speed is to react 1.6h under the conditions of 47r/min, 36 DEG C of maintenance system temperature, is washed 3 times through filtering, 1L ethanol,
Under nitrogen protection, 105 DEG C of dry 3h obtain aluminium powder；
(3) 100 parts of polyvinyl chloride continuous fibers, 73 parts of polyvinyl chloride, 9 parts of Arizona bacillis, 1.6 parts of diphosphorous acids, are weighed
The different certain herbaceous plants with big flowers ester of pentaerythritol ester two and 3 parts of aminopropyltriethoxy diethoxy silanes are added in mill, with mill in temperature 171
DEG C hybrid reaction 0.9h, with extruder in 171 DEG C of extruding pelletizations of temperature, that is, obtains polyvinyl chloride continuous fiber modified polyvinyl chloride
Alkene；
(4) 10 parts of polyacrylamides, 92 parts of polyvinyl chloride, 13 parts of Arizona bacillis, 25 parts of calcium carbonate, 2 part of two phosphorous, are weighed
The sour different certain herbaceous plants with big flowers ester of pentaerythritol ester two and 3 parts of aminopropyltriethoxy diethoxy silanes are added in mill, with mill in temperature
171 DEG C of hybrid reaction 0.5h, with extruder in 171 DEG C of extruding pelletizations of temperature, that is, obtain modified polyvinyl chloride；
(5) 100 parts of modified polyvinyl chlorides, 78 parts of polyvinyl chloride continuous fiber modified polyvinyl chlorides, 20 parts of aluminium powders, are weighed to add
Enter into mill, with mill in 171 DEG C of hybrid reaction 0.7h of temperature, with extruder in 171 DEG C of extruding pelletizations of temperature, produce
To polyacrylamide modified polyvinyl chloride pellet.
Embodiment 8
A kind of polyacrylamide modified polyvinyl chloride, its preparation method comprises the following steps：
(1) 100 parts of diphosphorus trioxides, 173 parts of ammoniacal liquor, 247 parts of water, 79 parts of isopropanols and 97 parts of calcium chloride, are weighed to add
Into reactor, mixing speed is to react 1.6h under the conditions of 68r/min, 39 DEG C of maintenance system temperature, through filtering, 65 DEG C ,-
0.09MPa is dried in vacuo 2h, under nitrogen protection, and 2h, 300 DEG C of roastings 2h, 400 DEG C of roasting 2h, 500 DEG C of roastings are calcined in 200 DEG C
2h, 600 DEG C of roasting 2h are burnt, Arizona bacilli is obtained；
(2) 100 parts of aluminium blocks, 73 parts of ethanol, 248 parts of cyclohexanol, 382 parts of water and 39 parts of formaldehyde, are weighed and are added to ball mill
In, drum speed is to react 1.6h under the conditions of 50r/min, 28 DEG C of maintenance system temperature, is washed 3 times through filtering, 1L ethanol,
Under nitrogen protection, 105 DEG C of dry 3h obtain aluminium powder；
(3) 100 parts of polyvinyl chloride continuous fibers, 77 parts of polyvinyl chloride, 11 parts of Arizona bacillis, 1.1 parts of diphosphorous acids, are weighed
The different certain herbaceous plants with big flowers ester of pentaerythritol ester two and 2.4 parts of aminopropyltriethoxy diethoxy silanes are added in mill, with mill in temperature
169 DEG C of hybrid reaction 1.3h, with extruder in 169 DEG C of extruding pelletizations of temperature, that is, obtain polyvinyl chloride continuous fiber and are modified polychlorostyrene
Ethene；
(4) 10 parts of polyacrylamides, 93 parts of polyvinyl chloride, 12 parts of Arizona bacillis, 25 parts of calcium carbonate, 1.3 part of two Asia, are weighed
The different certain herbaceous plants with big flowers ester of Pentaerythritol phosphate two and 2.7 parts of aminopropyltriethoxy diethoxy silanes are added in mill, are existed with mill
169 DEG C of hybrid reaction 1h of temperature, with extruder in 169 DEG C of extruding pelletizations of temperature, that is, obtain modified polyvinyl chloride；
(5) 100 parts of modified polyvinyl chlorides, 86 parts of polyvinyl chloride continuous fiber modified polyvinyl chlorides, 19 parts of aluminium powders, are weighed to add
Enter into mill, with mill in 169 DEG C of hybrid reaction 0.9h of temperature, with extruder in 169 DEG C of extruding pelletizations of temperature, produce
To polyacrylamide modified polyvinyl chloride pellet.
Embodiment 9
A kind of polyacrylamide modified polyvinyl chloride, its preparation method comprises the following steps：
(1) 100 parts of diphosphorus trioxides, 182 parts of ammoniacal liquor, 217 parts of water, 68 parts of isopropanols and 94 parts of calcium chloride, are weighed to add
Into reactor, mixing speed is to react 1.3h under the conditions of 73r/min, 38 DEG C of maintenance system temperature, through filtering, 65 DEG C ,-
0.09MPa is dried in vacuo 2h, under nitrogen protection, and 2h, 300 DEG C of roastings 2h, 400 DEG C of roasting 2h, 500 DEG C of roastings are calcined in 200 DEG C
2h, 600 DEG C of roasting 2h are burnt, Arizona bacilli is obtained；
(2) 100 parts of aluminium blocks, 73 parts of ethanol, 259 parts of cyclohexanol, 393 parts of water and 41 parts of formaldehyde, are weighed and are added to ball mill
In, drum speed is to react 2h under the conditions of 53r/min, 33 DEG C of maintenance system temperature, is washed 3 times through filtering, 1L ethanol, in nitrogen
Under gas shielded, 105 DEG C of dry 3h obtain aluminium powder；
(3) 100 parts of polyvinyl chloride continuous fibers, 69 parts of polyvinyl chloride, 12 parts of Arizona bacillis, 1.7 parts of diphosphorous acids, are weighed
The different certain herbaceous plants with big flowers ester of pentaerythritol ester two and 1.9 parts of aminopropyltriethoxy diethoxy silanes are added in mill, with mill in temperature
176 DEG C of hybrid reaction 0.9h, with extruder in 176 DEG C of extruding pelletizations of temperature, that is, obtain polyvinyl chloride continuous fiber and are modified polychlorostyrene
Ethene；
(4) 10 parts of polyacrylamides, 93 parts of polyvinyl chloride, 10 parts of Arizona bacillis, 22 parts of calcium carbonate, 1.7 part of two Asia, are weighed
The different certain herbaceous plants with big flowers ester of Pentaerythritol phosphate two and 3 parts of aminopropyltriethoxy diethoxy silanes are added in mill, with mill in temperature
176 DEG C of hybrid reaction 0.7h are spent, with extruder in 176 DEG C of extruding pelletizations of temperature, that is, modified polyvinyl chloride are obtained；
(5) 100 parts of modified polyvinyl chlorides, 82 parts of polyvinyl chloride continuous fiber modified polyvinyl chlorides, 21 parts of aluminium powders, are weighed to add
Enter into mill, with mill in 176 DEG C of hybrid reaction 0.6h of temperature, with extruder in 176 DEG C of extruding pelletizations of temperature, produce
To polyacrylamide modified polyvinyl chloride pellet.
Embodiment 10
A kind of polyacrylamide modified polyvinyl chloride, its preparation method comprises the following steps：
(1) 100 parts of diphosphorus trioxides, 174 parts of ammoniacal liquor, 237 parts of water, 69 parts of isopropanols and 95 parts of calcium chloride, are weighed to add
Into reactor, mixing speed is to react 1.5h under the conditions of 66r/min, 38 DEG C of maintenance system temperature, through filtering, 65 DEG C ,-
0.09MPa is dried in vacuo 2h, under nitrogen protection, and 2h, 300 DEG C of roastings 2h, 400 DEG C of roasting 2h, 500 DEG C of roastings are calcined in 200 DEG C
2h, 600 DEG C of roasting 2h are burnt, Arizona bacilli is obtained；
(2) 100 parts of aluminium blocks, 76 parts of ethanol, 207 parts of cyclohexanol, 376 parts of water and 34 parts of formaldehyde, are weighed and are added to ball mill
In, drum speed is to react 1.4h under the conditions of 48r/min, 29 DEG C of maintenance system temperature, is washed 3 times through filtering, 1L ethanol,
Under nitrogen protection, 105 DEG C of dry 3h obtain aluminium powder；
(3) 100 parts of polyvinyl chloride continuous fibers, 73 parts of polyvinyl chloride, 14 parts of Arizona bacillis, 1.8 parts of diphosphorous acids, are weighed
The different certain herbaceous plants with big flowers ester of pentaerythritol ester two and 1.3 parts of aminopropyltriethoxy diethoxy silanes are added in mill, with mill in temperature
180 DEG C of hybrid reaction 0.6h, with extruder in 180 DEG C of extruding pelletizations of temperature, that is, obtain polyvinyl chloride continuous fiber and are modified polychlorostyrene
Ethene；
(4) 10 parts of polyacrylamides, 88 parts of polyvinyl chloride, 13 parts of Arizona bacillis, 18 parts of calcium carbonate, 1.4 part of two Asia, are weighed
The different certain herbaceous plants with big flowers ester of Pentaerythritol phosphate two and 2.5 parts of aminopropyltriethoxy diethoxy silanes are added in mill, are existed with mill
180 DEG C of hybrid reaction 0.8h of temperature, with extruder in 180 DEG C of extruding pelletizations of temperature, that is, obtain modified polyvinyl chloride；
(5) 100 parts of modified polyvinyl chlorides, 75 parts of polyvinyl chloride continuous fiber modified polyvinyl chlorides, 24 parts of aluminium powders, are weighed to add
Enter into mill, with mill in 180 DEG C of hybrid reaction 0.7h of temperature, with extruder in 180 DEG C of extruding pelletizations of temperature, produce
To polyacrylamide modified polyvinyl chloride pellet.
The performance parameter of polyacrylamide modified polyvinyl chloride made from the embodiment 1 of table 1
The above is the preferred embodiment of the invention, it is noted that for those skilled in the art
For, on the premise of the inventive principle is not departed from, some improvements and modifications can also be made, these improvements and modifications are also considered as
The protection domain of the invention.
Claims (2)
1. a kind of preparation method of polyacrylamide modified polyvinyl chloride, it is characterised in that：Including following raw material components：It is modified poly-
Vinyl chloride, polyvinyl chloride continuous fiber modified polyvinyl chloride, aluminium powder, described modified polyvinyl chloride, polyvinyl chloride continuous fiber
Modified polyvinyl chloride, the quality parts ratio of aluminium powder are 100：74~87：17~26, wherein, described modified polyvinyl chloride is by gathering
The different certain herbaceous plants with big flowers ester of acrylamide, polyvinyl chloride, Arizona bacilli, calcium carbonate, pentaerythritol diphosphite two and aminopropyltriethoxy diethyl
TMOS reaction is made, described polyacrylamide, polyvinyl chloride, Arizona bacilli, calcium carbonate, pentaerythritol diphosphite
The quality parts ratio of two different certain herbaceous plants with big flowers esters and aminopropyltriethoxy diethoxy silane is 10：85~97：8~17：16~28：1~2：2~
4, described polyvinyl chloride continuous fiber modified polyvinyl chloride is by polyvinyl chloride continuous fiber, polyvinyl chloride, Arizona bacilli, two Asias
The different certain herbaceous plants with big flowers ester of Pentaerythritol phosphate two and the reaction of aminopropyltriethoxy diethoxy silane are made, and described polyvinyl chloride is continuously fine
The quality of the different certain herbaceous plants with big flowers ester of dimension, polyvinyl chloride, Arizona bacilli, pentaerythritol diphosphite two and aminopropyltriethoxy diethoxy silane
Portion rate is 100：65~80：7~15：1~2：1~3, described aluminium powder is reacted by aluminium block, ethanol, cyclohexanol, water and formaldehyde
It is made, described aluminium block, ethanol, cyclohexanol, the quality parts ratio of water and formaldehyde are 100：65~80：200~270：370~
400：30~45, described Arizona bacilli is reacted by diphosphorus trioxide, ammoniacal liquor, water, isopropanol and calcium chloride to be made, and described three
The quality parts ratio for aoxidizing two phosphorus, ammoniacal liquor, water, isopropanol and calcium chloride is 100：156~193：200~260：65~83：93
~109.
2. a kind of preparation method of polyacrylamide modified polyvinyl chloride according to claim 1, it is characterised in that：Described
Polyacrylamide modified polyvinyl chloride is as made from following preparation method：(1), by diphosphorus trioxide, ammoniacal liquor, water, isopropanol
With calcium chloride according to quality parts ratio be 100：156~193：200~260：65~83：93~109 are added in reactor, stir
Speed is mixed for 65~78r/min, 1~2h is reacted under the conditions of 36~40 DEG C of maintenance system temperature, through filtering, 65 DEG C ,-
0.09MPa is dried in vacuo 2h, under nitrogen protection, and 2h, 300 DEG C of roastings 2h, 400 DEG C of roasting 2h, 500 DEG C of roastings are calcined in 200 DEG C
2h, 600 DEG C of roasting 2h are burnt, Arizona bacilli is obtained；(2), by aluminium block, ethanol, cyclohexanol, water and formaldehyde according to quality parts ratio
100：65~80：200~270：370~400：30~45 are added in ball mill, and drum speed is 40~55r/min, is maintained
1~3h is reacted under the conditions of 25~40 DEG C of system temperature, 3 times, under nitrogen protection, 105 DEG C of dryings are washed through filtering, 1L ethanol
3h, obtains aluminium powder；(3), by polyvinyl chloride continuous fiber, polyvinyl chloride, Arizona bacilli, the different certain herbaceous plants with big flowers of pentaerythritol diphosphite two
Ester and aminopropyltriethoxy diethoxy silane are according to quality parts ratio 100：65~80：7~15：1~2：1~3 is added to mill
In machine, with mill in 146~183 DEG C of 0.5~2h of hybrid reaction of temperature, made with extruder in 146~183 DEG C of extrusions of temperature
Grain, that is, obtain polyvinyl chloride continuous fiber modified polyvinyl chloride；(4), by polyacrylamide, polyvinyl chloride, Arizona bacilli, carbonic acid
The different certain herbaceous plants with big flowers ester of calcium, pentaerythritol diphosphite two and aminopropyltriethoxy diethoxy silane are according to quality parts ratio 10：85~97：
8~17：16~28：1~2：2~4 are added in mill, with mill in 146~183 DEG C of 0.5~2h of hybrid reaction of temperature,
With extruder in 146~183 DEG C of extruding pelletizations of temperature, that is, obtain modified polyvinyl chloride；(5), by modified polyvinyl chloride, polychlorostyrene second
Alkene continuous fiber modified polyvinyl chloride, aluminium powder are according to quality parts ratio 100：74~87：17~26 are added in mill, with opening
Mill with extruder in 146~183 DEG C of extruding pelletizations of temperature, that is, is gathered in 146~183 DEG C of 0.5~2h of hybrid reaction of temperature
Acrylic amide modified polyvinyl chloride granules.
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