CN107418799A - A kind of preparation method of edible oil packing plastic bottle cleaning agent - Google Patents

A kind of preparation method of edible oil packing plastic bottle cleaning agent Download PDF

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Publication number
CN107418799A
CN107418799A CN201710265289.3A CN201710265289A CN107418799A CN 107418799 A CN107418799 A CN 107418799A CN 201710265289 A CN201710265289 A CN 201710265289A CN 107418799 A CN107418799 A CN 107418799A
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China
Prior art keywords
cleaning agent
parts
preparation
auxiliary material
plastic bottle
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Pending
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CN201710265289.3A
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Chinese (zh)
Inventor
王浩
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Anhui One Taste Food Co Ltd
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Anhui One Taste Food Co Ltd
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Priority to CN201710265289.3A priority Critical patent/CN107418799A/en
Publication of CN107418799A publication Critical patent/CN107418799A/en
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D11/00Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3753Polyvinylalcohol; Ethers or esters thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3776Heterocyclic compounds, e.g. lactam
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/266Esters or carbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/268Carbohydrates or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/32Organic compounds containing nitrogen
    • C11D7/3209Amines or imines with one to four nitrogen atoms; Quaternized amines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/40Products in which the composition is not well defined
    • C11D7/44Vegetable products

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Molecular Biology (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a kind of preparation method of edible oil packing plastic bottle cleaning agent, it is related to Packaging Bottle cleaning technique field, comprises the following steps:(1) preparation of cleaning agent major ingredient, the preparation of (2) cleaning agent auxiliary material, the preparation of (3) cleaning agent.The present invention is using grape skin as primary raw material, realize the reasonable utilization of leftover bits and pieces grape skin, and organic washing auxiliary material and vegetalitas is cooperateed with to clean auxiliary material and edible oil packing plastic bottle cleaning agent is made, made cleaning agent have that cleaning performance is good, scavenging period is short and it is safe to use the characteristics of, packing plastic bottle rinses after the cleaning agent soaks 10min using clear water, ensures zero residual of cleaning agent while effectively removing attachment impurity in bottle.

Description

A kind of preparation method of edible oil packing plastic bottle cleaning agent
Technical field:
The present invention relates to Packaging Bottle cleaning technique field, and in particular to a kind of preparation of edible oil packing plastic bottle cleaning agent Method.
Background technology:
Packing plastic bottle is the widely used packing container of current edible oil packing, has the characteristics of light, recyclable.One As the packing plastic bottle that uses of edible oil processing enterprise be all by the way of outsourcing, due to packing plastic bottle in process of production Can into bottle introduce the impurity such as dust and greasy dirt, therefore carry out edible oil it is filling before need to packing plastic bottle carry out thoroughly it is clear Wash, to ensure the safety in utilization of packing plastic bottle.
At present, common plasticses Packaging Bottle cleaning method is to use WATER-WASHING METHOD, and not only water consumption is big, the row of increase cleaning waste water High-volume, and the greasy dirt class impurity for being attached to bottle inwall can not be effectively removed, and it is miscellaneous to remove greasy dirt class if adding liquid detergent Matter, although cleaning performance is good, but a large amount of water is needed to use to rinse removing liquid detergent.
The content of the invention:
The technical problems to be solved by the invention are to provide that a kind of cleaning performance is good, water consumption is few and safe to use Edible oil packing plastic bottle cleaning agent preparation method.
The technical problems to be solved by the invention are realized using following technical scheme:
A kind of preparation method of edible oil packing plastic bottle cleaning agent, comprises the following steps:
(1) preparation of cleaning agent major ingredient:Using grape wine processing fent grape skin as cleaning agent major ingredient, first to Grape Skin Pre-gelatinized wheaten starch and buckwheat powder are added in slag, 1-2h is stood after being sufficiently mixed, then gained compound is sent into and is freeze-dried In machine, micro mist is made through micronizer in gained solid after fully drying, and produces cleaning agent major ingredient;
(2) preparation of cleaning agent auxiliary material:Organic washing auxiliary material and vegetalitas are cleaned into auxiliary material with weight ratio 5:0.5-1 ratio Example mixing, and the sealing and standing 0.5-1h in 0-5 DEG C of environment, then clear-cutting forestland to room temperature, produces cleaning agent auxiliary material;
(3) preparation of cleaning agent:Cleaning agent auxiliary material is added into made cleaning agent major ingredient, 40- is warming up to after being sufficiently mixed 45 DEG C of insulation mixing 5-10min, finally naturally cool to room temperature, produce cleaning agent.
The weight consumption ratio of the grape skin, pre-gelatinized wheaten starch and buckwheat powder is 40-50:5-10:2-5.
The weight consumption ratio of the cleaning agent major ingredient and cleaning agent auxiliary material is 5-10:1-2.
The organic washing auxiliary material is made up of the raw material of following parts by weight:Polyvinylpyrrolidone 3-5 parts, ethoxy are fine Tie up plain 3-5 parts, poloxamer 1-2 parts, carbomer 1-2 parts, rilanit special 0.5-1 parts, dimethyl diallyl ammonium chloride 0.5-1 parts, polyvinyl alcohol resin 0.5-1 parts, its preparation method are:Rilanit special, dimethyl two are added into carbomer Allyl ammonium chloride and polyvinyl alcohol resin, and 110-115 DEG C of insulation mixing 15min is warming up to 5 DEG C/min programming rate, 75-80 DEG C is cooled to 5 DEG C/min cooling rate again, then adds polyvinylpyrrolidone, hydroxyethyl cellulose and pool Lip river Sha Mu, the insulation mixing 15min at 75-80 DEG C, gained mixture is blocking through vacuum compression, is most made afterwards through micronizer micro- Powder, produce organic washing auxiliary material.
The vegetalitas cleaning auxiliary material is made up of the raw material of following parts by weight:Sweet osmanthus leaf 5-10 parts, leaf of elm tree 5-10 parts, Lotus root starch 2-3 parts, pine needle meal 1-2 parts, maltodextrin 1-2 parts, fresh bamboo powder 0.5-1 parts, degumming Kelp Powder 0.5-1 parts, sodium alginate 0.5-1 parts, water 30-50 parts, its preparation method are:Xiang Shuizhong adds sweet osmanthus leaf and leaf of elm tree, and fiberizer is utilized after soaking 15min Defibrination twice, pine needle meal, fresh bamboo powder and degumming Kelp Powder is added into gained slurry repeatedly, and defibrination twice, crosses 60- repeatedly again 100 mesh sieves, lotus root starch, maltodextrin and sodium alginate are then added into gained filtrate, and be warming up to reflux state insulation mixing 5min, then room temperature is naturally cooled to, gained mixed liquor is sent into spray dryer, dries the gained ground formation powder of solid, Produce vegetalitas cleaning auxiliary material.
The power output of the fiberizer is 1.5kW.
The beneficial effects of the invention are as follows:The present invention realizes leftover bits and pieces grape skin using grape skin as primary raw material Rationally utilize, and cooperate with organic washing auxiliary material and vegetalitas to clean auxiliary material and edible oil packing plastic bottle cleaning agent is made, it is made clear Lotion have that cleaning performance is good, scavenging period is short and it is safe to use the characteristics of, packing plastic bottle soaks through the cleaning agent Rinsed after 10min using clear water, ensure zero residual of cleaning agent while effectively removing attachment impurity in bottle, greatly reduce Cleaning water consumption, the clearance rate of the interior attachment impurity of bottle are up to 99.98%.
Embodiment:
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below Specific embodiment is closed, the present invention is expanded on further.
Embodiment 1
(1) preparation of cleaning agent major ingredient:Using grape wine processing fent grape skin as cleaning agent major ingredient, first to 50 parts of Portugals 5 portions of pre-gelatinized wheaten starches and 2 parts of buckwheat powders are added in grape skin slag, 2h are stood after being sufficiently mixed, then gained compound is sent into In freeze drier, micro mist is made through micronizer in gained solid after fully drying, and produces cleaning agent major ingredient;
(2) preparation of cleaning agent auxiliary material:Organic washing auxiliary material and vegetalitas are cleaned into auxiliary material with weight ratio 5:1 ratio is mixed Close, and the sealing and standing 1h in 0-5 DEG C of environment, then clear-cutting forestland to room temperature, produces cleaning agent auxiliary material;
(3) preparation of cleaning agent:5 parts of cleaning agent auxiliary materials are added into made 40 portions of cleaning agent major ingredients, are risen after being sufficiently mixed Temperature finally naturally cools to room temperature, produces cleaning agent to 40-45 DEG C of insulation mixing 10min.
The preparation of organic washing auxiliary material:0.5 part of rilanit special, 0.5 part of dimethyl diene are added into 2 parts of carbomers Propyl ammonium chloride and 0.5 part of polyvinyl alcohol resin, and 110-115 DEG C of insulation mixing is warming up to 5 DEG C/min programming rate 15min, then 75-80 DEG C is cooled to 5 DEG C/min cooling rate, then add 5 parts of polyvinylpyrrolidones, 5 parts of ethoxys Cellulose and 1 part of poloxamer, the insulation mixing 15min at 75-80 DEG C, gained mixture is blocking through vacuum compression, most passes through afterwards Micro mist is made in micronizer, produces organic washing auxiliary material.
Vegetalitas cleans the preparation of auxiliary material:10 parts of sweet osmanthus leaves and 5 parts of leaf of elm tree are added into 30 parts of water, after soaking 15min Using power output 1.5kW fiberizer repeatedly defibrination twice, into gained slurry add 2 parts of pine needle meals, 0.5 part of fresh bamboo powder and 0.5 part of degumming Kelp Powder, again repeatedly defibrination twice, cross 60-100 mesh sieves, then into gained filtrate add 2 portions of lotus root starch, 2 parts Maltodextrin and 0.5 part of sodium alginate, and reflux state insulation mixing 5min is warming up to, then room temperature is naturally cooled to, gained mixes Close liquid to be sent into spray dryer, dry the gained ground formation powder of solid, produce vegetalitas cleaning auxiliary material.
Embodiment 2
(1) preparation of cleaning agent major ingredient:Using grape wine processing fent grape skin as cleaning agent major ingredient, first to 50 parts of Portugals 8 portions of pre-gelatinized wheaten starches and 2 parts of buckwheat powders are added in grape skin slag, 2h are stood after being sufficiently mixed, then gained compound is sent into In freeze drier, micro mist is made through micronizer in gained solid after fully drying, and produces cleaning agent major ingredient;
(2) preparation of cleaning agent auxiliary material:Organic washing auxiliary material and vegetalitas are cleaned into auxiliary material with weight ratio 5:1 ratio is mixed Close, and the sealing and standing 1h in 0-5 DEG C of environment, then clear-cutting forestland to room temperature, produces cleaning agent auxiliary material;
(3) preparation of cleaning agent:4 parts of cleaning agent auxiliary materials are added into made 40 portions of cleaning agent major ingredients, are risen after being sufficiently mixed Temperature finally naturally cools to room temperature, produces cleaning agent to 40-45 DEG C of insulation mixing 10min.
The preparation of organic washing auxiliary material:0.5 part of rilanit special, 0.5 part of dimethyl diene are added into 1 part of carbomer Propyl ammonium chloride and 0.5 part of polyvinyl alcohol resin, and 110-115 DEG C of insulation mixing is warming up to 5 DEG C/min programming rate 15min, then 75-80 DEG C is cooled to 5 DEG C/min cooling rate, then add 5 parts of polyvinylpyrrolidones, 3 parts of ethoxys Cellulose and 2 parts of poloxamers, the insulation mixing 15min at 75-80 DEG C, gained mixture is blocking through vacuum compression, most passes through afterwards Micro mist is made in micronizer, produces organic washing auxiliary material.
Vegetalitas cleans the preparation of auxiliary material:10 parts of sweet osmanthus leaves and 8 parts of leaf of elm tree are added into 50 parts of water, after soaking 15min Using power output 1.5kW fiberizer repeatedly defibrination twice, into gained slurry add 1 part of pine needle meal, 0.5 part of fresh bamboo powder and 0.5 part of degumming Kelp Powder, again repeatedly defibrination twice, cross 60-100 mesh sieves, then into gained filtrate add 2 portions of lotus root starch, 1 part Maltodextrin and 0.5 part of sodium alginate, and reflux state insulation mixing 5min is warming up to, then room temperature is naturally cooled to, gained mixes Close liquid to be sent into spray dryer, dry the gained ground formation powder of solid, produce vegetalitas cleaning auxiliary material.
Embodiment 3
Be utilized respectively embodiment 1 and the methods described of embodiment 2 prepare cleaning agent, and for buy goods wholesale into 100 volumes The cleaning of 5L edible oil packing plastic bottles, cleaning agent plus water are made into concentration 0.05g/L cleaning fluid, with grape skin freeze-dried powder For reference examples, its cleaning performance is determined, as a result as shown in table 1.
The cleaning performance of the made cleaning agent of the embodiment of the present invention of table 1
Project Embodiment 1 Embodiment 2 Reference examples
Cleaning agent dosage 10g 10g 10g
Impurity clearance rate 99.98% 99.96% 82.43%
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (6)

1. a kind of preparation method of edible oil packing plastic bottle cleaning agent, it is characterised in that comprise the following steps:
(1) preparation of cleaning agent major ingredient:Using grape wine processing fent grape skin as cleaning agent major ingredient, first into grape skin Pre-gelatinized wheaten starch and buckwheat powder are added, 1-2h is stood after being sufficiently mixed, then gained compound is sent into freeze drier, Micro mist is made through micronizer in gained solid after fully drying, and produces cleaning agent major ingredient;
(2) preparation of cleaning agent auxiliary material:Organic washing auxiliary material and vegetalitas are cleaned into auxiliary material with weight ratio 5:0.5-1 ratio is mixed Close, and the sealing and standing 0.5-1h in 0-5 DEG C of environment, then clear-cutting forestland to room temperature, produces cleaning agent auxiliary material;
(3) preparation of cleaning agent:Cleaning agent auxiliary material is added into made cleaning agent major ingredient, 40-45 DEG C is warming up to after being sufficiently mixed Insulation mixing 5-10min, finally naturally cools to room temperature, produces cleaning agent.
2. the preparation method of edible oil packing plastic bottle cleaning agent according to claim 1, it is characterised in that:The grape The weight consumption ratio of skin slag, pre-gelatinized wheaten starch and buckwheat powder is 40-50:5-10:2-5.
3. the preparation method of edible oil packing plastic bottle cleaning agent according to claim 1, it is characterised in that:The cleaning The weight consumption ratio of agent major ingredient and cleaning agent auxiliary material is 5-10:1-2.
4. the preparation method of edible oil packing plastic bottle cleaning agent according to claim 1, it is characterised in that:It is described organic Cleaning auxiliary material is made up of the raw material of following parts by weight:Polyvinylpyrrolidone 3-5 parts, hydroxyethyl cellulose 3-5 parts, Bo Luosha Nurse 1-2 parts, carbomer 1-2 parts, rilanit special 0.5-1 parts, dimethyl diallyl ammonium chloride 0.5-1 parts, polyvinyl alcohol Resin 0.5-1 parts, its preparation method are:Rilanit special, dimethyl diallyl ammonium chloride are added into carbomer and is gathered Vinyl alcohol resin, and 110-115 DEG C of insulation mixing 15min, then the drop with 5 DEG C/min are warming up to 5 DEG C/min programming rate Warm speed is cooled to 75-80 DEG C, polyvinylpyrrolidone, hydroxyethyl cellulose and poloxamer is then added, at 75-80 DEG C Insulation mixing 15min, gained mixture is blocking through vacuum compression, and micro mist most is made through micronizer afterwards, produces organic washing Auxiliary material.
5. the preparation method of edible oil packing plastic bottle cleaning agent according to claim 1, it is characterised in that:The plant Property cleaning auxiliary material be made up of the raw material of following parts by weight:Sweet osmanthus leaf 5-10 parts, leaf of elm tree 5-10 parts, lotus root starch 2-3 parts, pine needle meal 1-2 parts, maltodextrin 1-2 parts, fresh bamboo powder 0.5-1 parts, degumming Kelp Powder 0.5-1 parts, sodium alginate 0.5-1 parts, water 30-50 Part, its preparation method is:Xiang Shuizhong adds sweet osmanthus leaf and leaf of elm tree, soak after 15min using fiberizer repeatedly defibrination twice, to Pine needle meal, fresh bamboo powder and degumming Kelp Powder are added in gained slurry, defibrination twice, crosses 60-100 mesh sieves, Ran Houxiang repeatedly again Lotus root starch, maltodextrin and sodium alginate are added in gained filtrate, and is warming up to reflux state insulation mixing 5min, then natural cooling To room temperature, gained mixed liquor is sent into spray dryer, dries the gained ground formation powder of solid, and it is auxiliary to produce vegetalitas cleaning Material.
6. the preparation method of edible oil packing plastic bottle cleaning agent according to claim 5, it is characterised in that:The defibrination The power output of machine is 1.5kW.
CN201710265289.3A 2017-04-21 2017-04-21 A kind of preparation method of edible oil packing plastic bottle cleaning agent Pending CN107418799A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109055034A (en) * 2018-08-08 2018-12-21 廖家平 Liquid detergent
CN112899089A (en) * 2021-01-28 2021-06-04 郭振河 Hydrocarbon cleaning agent for cleaning HW49 waste packaging materials and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106166124A (en) * 2016-08-20 2016-11-30 界首市众鑫科技服务有限公司 A kind of cleansing milk additive utilizing food leftover bits and pieces bean dregs to prepare
CN106475378A (en) * 2016-10-19 2017-03-08 肇庆高新区飞越信息科技有限公司 A kind of label peeling agent of recycled plastic carafe
CN106497708A (en) * 2016-10-19 2017-03-15 肇庆高新区飞越信息科技有限公司 A kind of plastic bottle recovery abluent and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106166124A (en) * 2016-08-20 2016-11-30 界首市众鑫科技服务有限公司 A kind of cleansing milk additive utilizing food leftover bits and pieces bean dregs to prepare
CN106475378A (en) * 2016-10-19 2017-03-08 肇庆高新区飞越信息科技有限公司 A kind of label peeling agent of recycled plastic carafe
CN106497708A (en) * 2016-10-19 2017-03-15 肇庆高新区飞越信息科技有限公司 A kind of plastic bottle recovery abluent and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109055034A (en) * 2018-08-08 2018-12-21 廖家平 Liquid detergent
CN112899089A (en) * 2021-01-28 2021-06-04 郭振河 Hydrocarbon cleaning agent for cleaning HW49 waste packaging materials and preparation method thereof

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