CN107418107A - A kind of plastic material and its processing technology - Google Patents

A kind of plastic material and its processing technology Download PDF

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Publication number
CN107418107A
CN107418107A CN201710881062.1A CN201710881062A CN107418107A CN 107418107 A CN107418107 A CN 107418107A CN 201710881062 A CN201710881062 A CN 201710881062A CN 107418107 A CN107418107 A CN 107418107A
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Prior art keywords
parts
plastic material
corvic
mixed
organotin
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CN201710881062.1A
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Chinese (zh)
Inventor
陈健
杨文乾
张建光
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Suzhou Futong New Material and High Tech Co Ltd
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Suzhou Futong New Material and High Tech Co Ltd
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Priority to CN201710881062.1A priority Critical patent/CN107418107A/en
Priority to PCT/CN2017/108870 priority patent/WO2019061670A1/en
Publication of CN107418107A publication Critical patent/CN107418107A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0806Silver
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of plastic material and its processing technology, plastic material includes by weight part:100 ~ 120 parts of Corvic, 2 ~ 3 parts of organotin-carboxylate, 1 ~ 2 part of polyacrylate type resin, 8 ~ 10 parts of haloflex, 5 ~ 10 parts of activated Calcium carbonate, 4 ~ 6 parts of rutile titanium dioxide, 0.5 ~ 1 part of Tissuemat E, 0.5 ~ 1 part of antibacterial bacteriostatic additive.Cost of the present invention is low, and heat endurance is good, adds rigidity, improves plasticizing quality, improves outward appearance so that section bar is smooth, and weatherability, toughness, uniformity are good, while have antibacterial bacteriostatic effect, suitable for sterile region.

Description

A kind of plastic material and its processing technology
Technical field
The present invention relates to plastic material technical field, more particularly to a kind of plastic material and its processing technology.
Background technology
Polyvinyl chloride, English abbreviation PVC, it is the thermoplastic resin being polymerized by polyethylene under initiator effect.Work The PVC molecular weight of industry production has larger dispersiveness, the reduction of molecular weight with polymerisation temperature typically in the range of 50,000 ~ 120,000 And increase, but it is poor to the stability of light and heat, more than 100 DEG C or through long-time solar exposure, it will decompose and produce chlorination Hydrogen, and further autocatalysis decomposition causes discoloration, physical and mechanical properties also declines rapidly, must be added to help in actual applications Agent is to improve the performance of each side.
PVC plastic sheet material has been popular a kind of novel light body ornament materials in the world today, is very popular Product, PVC plastic sheet material from enter Chinese market since, big and medium-sized cities obtain universal accreditation at home, and use is non- Often extensively.
Following defect be present in existing PVC plastic abnormal shape sheet material:1st, cost is higher;2nd, heat endurance is bad, becomes under low temperature It is hard brittle, easily softening relaxation under high temperature;3rd, processing characteristics, impact resistance, resistance to ag(e)ing are poor;3rd, discharged in production process Harmful substance, produce hazardous waste, finished product can discharge dioxin sour gas at high temperature, its additive in use by Gradually volatilize, pollute air.
The content of the invention
In view of the deficienciess of the prior art, the purpose of the present invention, which is that, provides a kind of plastic material and its processing work Skill, cost is low, and heat endurance is good, adds rigidity, improves plasticizing quality, improves outward appearance so that section bar is smooth, weatherability, tough Property, uniformity are good, while have antibacterial bacteriostatic effect, suitable for sterile region.
To achieve these goals, the technical solution adopted by the present invention is such:A kind of plastic material, with components by weight percent Meter includes:100 ~ 120 parts of Corvic, 2 ~ 3 parts of organotin-carboxylate, 1 ~ 2 part of polyacrylate type resin, chlorinated polyethylene 8 ~ 10 parts of alkene, 5 ~ 10 parts of activated Calcium carbonate, 4 ~ 6 parts of rutile titanium dioxide, 0.5 ~ 1 part of Tissuemat E, antibacterial bacteriostatic additive 0.5 ~ 1 part.
As a kind of preferred scheme, the density of the Corvic is 1.35 ~ 1.45g/cm3, apparent density 0.4 ~0.5 g/cm3
As a kind of preferred scheme, the Corvic is Porous-type PVC Resins, its particle diameter is 0.1 ~ 0.2mm, it is spherical in cotton.
As a kind of preferred scheme, the organotin-carboxylate is Bis(lauroyloxy)dioctyltin.
As a kind of preferred scheme, the antibacterial bacteriostatic additive is the mixture of nano zinc oxide powder and nano-silver powder.
A kind of processing technology for preparing described plastic material, comprises the following steps:
(1)Corvic of the degree of polymerization 1200 ~ 1000 is selected according to parts by weight, organotin-carboxylate is sequentially added, gathers Acrylic resin, haloflex, Tissuemat E, activated Calcium carbonate, rutile titanium dioxide, antibacterial bacteriostatic additive are carried out Mix resulting mixture;
(2)By mixture by screening to screen out oversize grain, then stand 1 ~ 2 day and cured;
(3)Mixture after standing is sent into extruder and extruded, the temperature of extruder is 150 ~ 200 DEG C;
(4)Material after extrusion is subjected to calendering formation using calender.
As a kind of preferred scheme, the step(1)First heat is mixed in the mixed pot of heat for material during middle mixing, then in cold mixed cylinder Cooling, incorporation time are 7 ~ 8 minutes, wherein temperature control is at 110 ~ 130 DEG C when hot mixed, cooling water temperature control is 13 when cold mixed ~15℃。
Compared with prior art, beneficial effects of the present invention:
1st, cost is low, and heat endurance is good, adds rigidity;
2nd, plasticizing quality is improved, improves outward appearance so that section bar is smooth, and weatherability, toughness, uniformity are good;
3rd, there is antibacterial bacteriostatic effect, suitable for sterile region;
4th, it is nontoxic, dust pollution is small, section bar weld strength is high.
Embodiment
With reference to specific embodiment, the invention will be further described.Following examples are only used for clearly illustrating Technical scheme, and can not be limited the scope of the invention with this.
Embodiment 1:
A kind of plastic material, includes by weight part:100 parts of Corvic, 2 parts of organotin-carboxylate, polyacrylic acid 1 part of esters resin, 8 parts of haloflex, 5 parts of activated Calcium carbonate, 4 parts of rutile titanium dioxide, 0.5 part of Tissuemat E, antibacterial suppression 0.5 part of bacteria additive.
Specifically, the density of the Corvic is 1.35 ~ 1.45g/cm3, apparent density be 0.4 ~ 0.5 g/cm3
Specifically, the Corvic is Porous-type PVC Resins, its particle diameter is 0.1 ~ 0.2mm, in cotton It is spherical.
Specifically, the organotin-carboxylate is Bis(lauroyloxy)dioctyltin.
Specifically, the antibacterial bacteriostatic additive is the mixture of nano zinc oxide powder and nano-silver powder.
A kind of processing technology for preparing described plastic material, comprises the following steps:
(1)Corvic of the degree of polymerization 1200 ~ 1000 is selected according to parts by weight, organotin-carboxylate is sequentially added, gathers Acrylic resin, haloflex, Tissuemat E, activated Calcium carbonate, rutile titanium dioxide, antibacterial bacteriostatic additive are carried out Mix resulting mixture;
(2)By mixture by screening to screen out oversize grain, then stand 1 day and cured;
(3)Mixture after standing is sent into extruder and extruded, the temperature of extruder is 150 DEG C;
(4)Material after extrusion is subjected to calendering formation using calender.
Specifically, the step(1)First heat is mixed in the mixed pot of heat for material during middle mixing, then is cooled down in cold mixed cylinder, mixes Time is 7 minutes, wherein temperature control is at 110 DEG C when hot mixed, cooling water temperature control is at 13 DEG C when cold mixed.
Embodiment 2:
A kind of plastic material, includes by weight part:105 parts of Corvic, 2.25 parts of organotin-carboxylate, polypropylene 1.25 parts of acid esters resinoid, 8.5 parts of haloflex, 6 parts of activated Calcium carbonate, 4.5 parts of rutile titanium dioxide, Tissuemat E 0.6 Part, 0.6 part of antibacterial bacteriostatic additive.
Specifically, the density of the Corvic is 1.35 ~ 1.45g/cm3, apparent density be 0.4 ~ 0.5 g/cm3
Specifically, the Corvic is Porous-type PVC Resins, its particle diameter is 0.1 ~ 0.2mm, in cotton It is spherical.
Specifically, the organotin-carboxylate is Bis(lauroyloxy)dioctyltin.
Specifically, the antibacterial bacteriostatic additive is the mixture of nano zinc oxide powder and nano-silver powder.
A kind of processing technology for preparing described plastic material, comprises the following steps:
(1)Corvic of the degree of polymerization 1200 ~ 1000 is selected according to parts by weight, organotin-carboxylate is sequentially added, gathers Acrylic resin, haloflex, Tissuemat E, activated Calcium carbonate, rutile titanium dioxide, antibacterial bacteriostatic additive are carried out Mix resulting mixture;
(2)By mixture by screening to screen out oversize grain, then stand 1 day and cured;
(3)Mixture after standing is sent into extruder and extruded, the temperature of extruder is 160 DEG C;
(4)Material after extrusion is subjected to calendering formation using calender.
Specifically, the step(1)First heat is mixed in the mixed pot of heat for material during middle mixing, then is cooled down in cold mixed cylinder, mixes Time is 7 minutes, wherein temperature control is at 115 DEG C when hot mixed, cooling water temperature control is at 13 DEG C when cold mixed.
Embodiment 3:
A kind of plastic material, includes by weight part:110 parts of Corvic, 2.5 parts of organotin-carboxylate, polypropylene It is 1.5 parts of acid esters resinoid, 9 parts of haloflex, 7 parts of activated Calcium carbonate, 5 parts of rutile titanium dioxide, 0.7 part of Tissuemat E, anti- 0.7 part of the antibacterial additive of bacterium.
Specifically, the density of the Corvic is 1.35 ~ 1.45g/cm3, apparent density be 0.4 ~ 0.5 g/cm3
Specifically, the Corvic is Porous-type PVC Resins, its particle diameter is 0.1 ~ 0.2mm, in cotton It is spherical.
Specifically, the organotin-carboxylate is Bis(lauroyloxy)dioctyltin.
Specifically, the antibacterial bacteriostatic additive is the mixture of nano zinc oxide powder and nano-silver powder.
A kind of processing technology for preparing described plastic material, comprises the following steps:
(1)Corvic of the degree of polymerization 1200 ~ 1000 is selected according to parts by weight, organotin-carboxylate is sequentially added, gathers Acrylic resin, haloflex, Tissuemat E, activated Calcium carbonate, rutile titanium dioxide, antibacterial bacteriostatic additive are carried out Mix resulting mixture;
(2)By mixture by screening to screen out oversize grain, then stand 1.5 days and cured;
(3)Mixture after standing is sent into extruder and extruded, the temperature of extruder is 175 DEG C;
(4)Material after extrusion is subjected to calendering formation using calender.
Specifically, the step(1)First heat is mixed in the mixed pot of heat for material during middle mixing, then is cooled down in cold mixed cylinder, mixes Time is 7.5 minutes, wherein temperature control is at 120 DEG C when hot mixed, cooling water temperature control is at 14 DEG C when cold mixed.
Embodiment 4:
A kind of plastic material, includes by weight part:115 parts of Corvic, 2.75 parts of organotin-carboxylate, polypropylene 1.75 parts of acid esters resinoid, 9.5 parts of haloflex, 8 parts of activated Calcium carbonate, 5.5 parts of rutile titanium dioxide, Tissuemat E 0.9 Part, 0.9 part of antibacterial bacteriostatic additive.
Specifically, the density of the Corvic is 1.35 ~ 1.45g/cm3, apparent density be 0.4 ~ 0.5 g/cm3
Specifically, the Corvic is Porous-type PVC Resins, its particle diameter is 0.1 ~ 0.2mm, in cotton It is spherical.
Specifically, the organotin-carboxylate is Bis(lauroyloxy)dioctyltin.
Specifically, the antibacterial bacteriostatic additive is the mixture of nano zinc oxide powder and nano-silver powder.
A kind of processing technology for preparing described plastic material, comprises the following steps:
(1)Corvic of the degree of polymerization 1200 ~ 1000 is selected according to parts by weight, organotin-carboxylate is sequentially added, gathers Acrylic resin, haloflex, Tissuemat E, activated Calcium carbonate, rutile titanium dioxide, antibacterial bacteriostatic additive are carried out Mix resulting mixture;
(2)By mixture by screening to screen out oversize grain, then stand 2 days and cured;
(3)Mixture after standing is sent into extruder and extruded, the temperature of extruder is 190 DEG C;
(4)Material after extrusion is subjected to calendering formation using calender.
Specifically, the step(1)First heat is mixed in the mixed pot of heat for material during middle mixing, then is cooled down in cold mixed cylinder, mixes Time is 8 minutes, wherein temperature control is at 125 DEG C when hot mixed, cooling water temperature control is at 15 DEG C when cold mixed.
Embodiment 5:
A kind of plastic material, includes by weight part:120 parts of Corvic, 3 parts of organotin-carboxylate, polyacrylic acid 2 parts of esters resin, 10 parts of haloflex, 10 parts of activated Calcium carbonate, 6 parts of rutile titanium dioxide, 1 part of Tissuemat E, antibacterial suppression 1 part of bacteria additive.
Specifically, the density of the Corvic is 1.35 ~ 1.45g/cm3, apparent density be 0.4 ~ 0.5 g/cm3
Specifically, the Corvic is Porous-type PVC Resins, its particle diameter is 0.1 ~ 0.2mm, in cotton It is spherical.
Specifically, the organotin-carboxylate is Bis(lauroyloxy)dioctyltin.
Specifically, the antibacterial bacteriostatic additive is the mixture of nano zinc oxide powder and nano-silver powder.
A kind of processing technology for preparing described plastic material, comprises the following steps:
(1)Corvic of the degree of polymerization 1200 ~ 1000 is selected according to parts by weight, organotin-carboxylate is sequentially added, gathers Acrylic resin, haloflex, Tissuemat E, activated Calcium carbonate, rutile titanium dioxide, antibacterial bacteriostatic additive are carried out Mix resulting mixture;
(2)By mixture by screening to screen out oversize grain, then stand 2 days and cured;
(3)Mixture after standing is sent into extruder and extruded, the temperature of extruder is 200 DEG C;
(4)Material after extrusion is subjected to calendering formation using calender.
Specifically, the step(1)First heat is mixed in the mixed pot of heat for material during middle mixing, then is cooled down in cold mixed cylinder, mixes Time is 8 minutes, wherein temperature control is at 130 DEG C when hot mixed, cooling water temperature control is at 15 DEG C when cold mixed.
Antibacterial effect measure is carried out to the plastic material of the gained of embodiment 1 ~ 5, the results are shown in Table 1.
Table 1
It is 37 DEG C that the plastic material of the gained of embodiment 1 ~ 5 is placed on into temperature, relative humidity 60%, under conditions of lamp Half a year, antibacterial effect measure is then carried out, the results are shown in Table 2.
Table 2
It is 37 DEG C that the plastic material of the gained of embodiment 1 ~ 5 is placed on into temperature, relative humidity 60%, under conditions of lamp 1 year, antibacterial effect measure is then carried out, the results are shown in Table 3.
Table 3
It is 37 DEG C that the plastic material of the gained of embodiment 1 ~ 5 is placed on into temperature, relative humidity 60%, under conditions of lamp 2 years, antibacterial effect measure is then carried out, the results are shown in Table 4.
Table 4
As can be seen that the present invention has antibacterial bacteriostatic effect from table 1 ~ 4, suitable for sterile region, while have that cost is low, it is hot Stability is good, adds rigidity, improves plasticizing quality, improves outward appearance so that section bar is smooth, and weatherability, toughness, uniformity are good Advantage.
Described above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, without departing from the technical principles of the invention, some improvement and deformation can also be made, these are improved and deformation Also it should be regarded as protection scope of the present invention.

Claims (7)

1. a kind of plastic material, it is characterised in that include by weight part:100 ~ 120 parts of Corvic, organotin carboxylic 2 ~ 3 parts of hydrochlorate, 1 ~ 2 part of polyacrylate type resin, 8 ~ 10 parts of haloflex, 5 ~ 10 parts of activated Calcium carbonate, rutile type titanium White 4 ~ 6 parts, 0.5 ~ 1 part of Tissuemat E, 0.5 ~ 1 part of antibacterial bacteriostatic additive.
A kind of 2. plastic material according to claim 1, it is characterised in that:The density of the Corvic is 1.35 ~1.45g/cm3, apparent density be 0.4 ~ 0.5 g/cm3
A kind of 3. plastic material according to any one of claim 1 or 2, it is characterised in that:The Corvic For Porous-type PVC Resins, its particle diameter is 0.1 ~ 0.2mm, spherical in cotton.
A kind of 4. plastic material according to claim 1, it is characterised in that:The organotin-carboxylate is tin dilaurate two N-octyl tin.
A kind of 5. plastic material according to claim 1, it is characterised in that:The antibacterial bacteriostatic additive is nano oxidized The mixture of zinc powder and nano-silver powder.
6. a kind of processing technology for preparing the plastic material described in claim 1, it is characterised in that comprise the following steps:
(1)Corvic of the degree of polymerization 1200 ~ 1000 is selected according to parts by weight, organotin-carboxylate is sequentially added, gathers Acrylic resin, haloflex, Tissuemat E, activated Calcium carbonate, rutile titanium dioxide, antibacterial bacteriostatic additive are carried out Mix resulting mixture;
(2)By mixture by screening to screen out oversize grain, then stand 1 ~ 2 day and cured;
(3)Mixture after standing is sent into extruder and extruded, the temperature of extruder is 150 ~ 200 DEG C;
(4)Material after extrusion is subjected to calendering formation using calender.
A kind of 7. processing technology for preparing plastic material according to claim 6, it is characterised in that:The step(1)In First heat is mixed in the mixed pot of heat for material during mixing, then is cooled down in cold mixed cylinder, and incorporation time is 7 ~ 8 minutes, wherein temperature when hot mixed Control is at 110 ~ 130 DEG C, and cooling water temperature control is at 13 ~ 15 DEG C when cold mixed.
CN201710881062.1A 2017-09-26 2017-09-26 A kind of plastic material and its processing technology Pending CN107418107A (en)

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CN201710881062.1A CN107418107A (en) 2017-09-26 2017-09-26 A kind of plastic material and its processing technology
PCT/CN2017/108870 WO2019061670A1 (en) 2017-09-26 2017-11-01 Plastic profile and method for manufacturing same

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CN111303564A (en) * 2020-04-16 2020-06-19 扬州金霞塑胶有限公司 High-antibacterial and antiviral plastic profile and preparation method thereof
CN115028938A (en) * 2022-07-08 2022-09-09 广东美橙文化发展有限公司 Ag/ZnO modified polyvinyl chloride composite antibacterial plastic and synthesis process thereof

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CN115232415A (en) * 2022-07-28 2022-10-25 苏州国宇碳纤维科技有限公司 HPVC modified material for protective tube and preparation method of HPVC cable protective tube

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CN103408861A (en) * 2013-07-18 2013-11-27 苏州富通高新材料科技股份有限公司 Plastic floor substrate and making method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111303564A (en) * 2020-04-16 2020-06-19 扬州金霞塑胶有限公司 High-antibacterial and antiviral plastic profile and preparation method thereof
CN115028938A (en) * 2022-07-08 2022-09-09 广东美橙文化发展有限公司 Ag/ZnO modified polyvinyl chloride composite antibacterial plastic and synthesis process thereof
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Application publication date: 20171201