CN107412003A - A kind of good light hair-washing composition of wet hair - Google Patents
A kind of good light hair-washing composition of wet hair Download PDFInfo
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/006—Antidandruff preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
- A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic
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Abstract
The invention belongs to field of daily chemicals, are related to a kind of hair-washing composition.A kind of good light hair-washing composition of wet hair, contains following raw material：Anion surfactant；Amphoteric surfactant；Cationic guar derivative, charge density are about 0.5 ~ 1.0 meq/g；And molecular weight is 400000 ~ 1500000 g/mol；Nonionic surfactant；Salt；Non-volatile conditioning agent；Suspending agent；And the pure water of surplus.The present invention by composition system framework rationally build and limitation to raw material key parameter, a kind of wet punching impression having well is provided and dry and comfortable dry hair is experienced, not anti-oil, the hair-washing composition of the accumulation degree of silicone oil is reduced, said composition has the flocculation of moderate strength and rational silicone oil deposition, composition gentle, all kinds of hair qualitys are applicable, significant effect, cost is cheap, and application is simple and direct.
Description
Technical field
The invention belongs to field of daily chemicals, are related to a kind of hair-washing composition.
Background technology
In Two-in-one shampoo at this stage, polysiloxane particle is particularly carried with flocculation so as to deposit to hair or head
Belt nurses one's health effect, has obviously two-in-one effect in a short time, this is art-recognized and can be real
Existing effect.And this effect is realized, it is most of to be achieved the goal by Cationic polysaccharide polymer.Such as extensively should on the market
The Two-in-one shampoo of flocculation is formed using cation melon gum derivative and anion surfactant, can be brought very
The obvious effect nursed one's health immediately.
Similar, there is provided the shampoo for nursing one's health effect is also known in the field.Such as Chinese Patent Application No.
00809131.5 and Chinese Patent Application No. 00808517.X discloses one kind by anion surfactant and cation Guar
The flocculation that gum derivative is formed mutually carries silicone oil particle and zpt particles, by for cationic guar derivative parameter
Preferred implementation carries the ability of effective particulate matter；Chinese Patent Application No. 201480045888.9 also disclose it is a kind of by the moon from
Sub- surfactant, amphoteric surfactant and cationic guar derivative carry selenium disulfide, ZPT and silicon
Oxygen alkane realizes the effect of anti-dandruff conditioning.
But although these utilize cation melon gum derivative and the flocculation effect ten of anion surfactant formation
It is clearly demarcated aobvious, but due to this flocculation deposition not optionally, therefore in most cases, with this type hair washing group
The wash number of compound increases, and effective particle such as polysiloxane particle etc. can be deposited progressively without being cleaned, with
The passage of time, the discomforts such as user will feel greasy, harden.
However, there is another solution at this stage, the cation-modified cellulose derivative of traditional scheme is utilized
To replace cation melon gum derivative to be flocculated, although this scheme can be effectively improved the disadvantage of working substance over-deposit
End, but often in many shampoo systems, it is difficult to accomplish its flocculating strength and carry the ability and sun of effective particulate matter
Ion melon gum derivative is matched, and therefore, the carrying capacity Shortcomings of its effective particulate matter, hair washing impact sense is also insufficient.
Applicant have discovered that if matched somebody with somebody by the optimizely select for system, the use of some raw materials is limited, while preferably
The molecular weight and charge density of cationic guar derivative, it can accomplish to wad a quilt with cotton in water-rinsing process in hair-washing composition
Coagulate condensed phase and nurse one's health wet hair sensation, and carry effective particulate matter and deposit on hair, bring the conditioning sense after doing, simultaneously
Also by regulation flocculating strength and flocculation water content, to control silicone oil to deposit, the accumulation sense of long-term use of silicone oil is reduced.
It is an object of the invention to provide a kind of hair-washing composition, by for composition system framework rationally build and
Limitation to raw material key parameter so that said composition has flocculation and the rational silicone oil deposition of moderate strength, there is provided good
Wet punching impression and dry and comfortable dry hair experience, not anti-oil, reduce the accumulation degree of silicone oil.
The content of the invention
It is an object of the invention to overcome in the prior art to flocculating strength and silicone oil depositional control improperly technical barrier,
Too strong flocculating strength and silicone oil deposition can allow the situation that the anti-fry dried food ingredients of hair is hard after long term consumer use, if too small wadding
Solidifying intensity and silicone oil deposition then can be declined the experience sense of consumption, and the wet punching of hair carries astringent sense.In order to overcome this technology to lack
Fall into, the present invention provides good wet punching impression and dry and comfortable dry hair is experienced, not anti-oil, reduces the hair washing group of the accumulation degree of silicone oil
Compound, beneficial effect caused by said composition is not caused by single raw material, but passes through the conjunction of composition system framework
Reason is built and the limitation to raw material key parameter so that there is said composition the flocculation of moderate strength and rational silicone oil to sink
Product.Composition composition is gentle, all kinds of hair qualitys is applicable, significant effect, cost is cheap, and application is simple and direct.
The present invention, which disclose, carrys out a kind of wet hair well light hair-washing composition, and the hair-washing composition, which contains, following accounts for composition
The raw material of percetage by weight proportioning：
(A) anion surfactant 9-15%；
(B) amphoteric surfactant 0.5 ~ 1.8%；
(C) cationic guar derivative 0.2 ~ 0.8%；The charge density of wherein described cationic guar derivative is about
0.5~1.0 meq/g；And molecular weight is 400000 ~ 1500000 g/mol；
(D) nonionic surfactant 0.5-1.5%；
(E) salt 0.4-1.6%；
(F) non-volatile conditioning agent 0.05-5%；
(G) suspending agent 0.01-3%；And surplus
(H) pure water.
Described anion surfactant is selected from selected from alkyl polyoxyethylene ether sulfate, glycerine monofatty ester sulfuric acid
Salt, fatty alcohol ether sulfosuccinate ester salt, N- fatty acyls amino-acid salt, fatty acyl methyl tauride, monoalkyl sulfate, list
One or more in alkyl carboxylate, alkylphosphonate.Wherein preferably at least containing alkyl polyoxyethylene ether sulfate,
Glycerine monofatty ester sulfate, fatty alcohol ether sulfosuccinate ester salt, N- fatty acyls amino-acid salt, fatty acyl methyl taurine
One or both of salt, it is known in the art that this analog anion surfactants has larger critical Packing parameter, institute here
The Packing parameter said is represented with equation below：
Wherein,The as Packing parameter of surfactant, V are surfactant hydrocarbon chain volume, and l is then critical length, a
It is then end group area；Here require to comprise at least have the anion surfactant that critical Packing parameter is at least up to more than 1/4,
Arrange in pairs or groups monoalkyl sulfate, monoalkyl carboxylate, one kind in monoalkyl phosphoric acid esters or two whether can be selectively aided in simultaneously
Kind, the surfactant of this kind of low Packing parameter of not arranging in pairs or groups is also in the protection domain of this patent.
It is found through experiments that, containing the surfactant with larger Packing parameter, helping, which reduces integral system, stimulates
Property, while can strengthen and be flocculated caused by anion surfactant, amphoteric surfactant and cationic cellulose derivative
Intensity and flocculation persistence, the technique effect to be realized in this patent have gain effect.And add and carried out auxiliary anion
Surfactant, improved foam effect and thickening effect can be brought, be added according to final composition positioning different choice.
Described amphoteric surfactant is selected from fatty acyl both sexes acetate, fatty acyl CAB, fatty acid amide hydroxyl
One or more in propylsultaine glycine betaine.Preferred fat acyl both sexes acetate and one kind in fatty acyl CAB or
Two kinds, particularly preferred fatty acyl CAB.The addition of amphoteric surfactant so that flocculating strength and flocculation persistence are entered
One step is strengthened, meanwhile, if anionic surfactant portion has the addition of the high surfactant of preferred Packing parameter, both sexes table
Face activating agent is advantageous to increase the easy modulability of composition viscosity, and it is known in the art that the addition of amphoteric surfactant, right
Performance can be achieved in foaming properties, gentle performance and technique all to have greatly improved.
The charge density of described cationic guar derivative is about 0.5 ~ 1.0 meq/g；And molecular weight is about
400000~1500000 g/mol；It is preferred that charge density is about 0.6 ~ 0.9 meq/g, and molecular weight be about 450000 ~
1300000 g/mol；Most preferably charge density is about 0.7 ~ 0.8 meq/g, and molecular weight is about 450000 ~ 1300000 g/
mol 500000~1200000 g/mol；Applicant, which tests, to be found, is using cationic guar derivative of the present invention
And compounding has in the system of cationic guar derivative, and in optimization system of the present invention of arranging in pairs or groups, it dilutes wadding
Condensed-phase shows to wrap up the effect of effective particulate matter well, while its water content for flocculating phase reaches perfect condition, therefore has
Have and good wet rush effect.After added with cationic guar derivative of the present invention, and it is final in the present invention
In the composition framework of protection, its pure water dilution range there are between 5 times -20 times can carry the visible solid of active principle
Body flocculation phase, and it can be seen that effective particulate matter such as the non-volatile conditioning agent particle and anti-dandruff particle of hair-washing composition addition
It can be flocculated and mutually wrap up or adsorb.
The nonionic surfactant be selected from coconut oil fatty acid monoethanolamide, cocounut oil acid methyl single ethanol amide,
Coconut oil diethanol amine, APG.It is preferred that coconut oil fatty acid monoethanolamide, cocounut oil acid methyl single ethanol amide.It is optimal
Coconut oil fatty acid monoethanolamide.Described nonionic surfactant helps to reduce critical micelle concentration of surfactant
Effect, improve some surface active property, if using preferable coconut oil fatty acid monoethanolamide, can either play to system
Thickening power, additionally it is possible to have the function that compounding is stable with suspending agent of the invention follow-up described, assist the formation of crystalline solid.
Described non-volatile conditioning agent is one or both of scattered polysiloxanes, ammonia end dimethyl silicone polymer
Compounding.And the viscosity of described polysiloxanes is about 300,000 viscosity to 500,000 viscosity preferably wherein, described polysiloxanes and
Ammonia end dimethyl silicone polymer is present in composition by about 0.05 micron to about 50 microns of size of particle diameter.This is also to be recognized
To be one kind of effective particulate matter, have opsonic action for hair, can mutually be wrapped up by the flocculation that be realized of the present invention absorption and
Carry to hair, salubrious two-in-one effect can be realized, the use for improving hair-washing composition is felt.
Described suspending agent is selected from acyl derivative and long chain amine oxide.Wherein, described acyl derivative is included but not
It is limited to the ethylene glycol fatty acid containing 16-22 carbon atom, long chain hydrocarbons, the long-chain ester of long chain fatty acids, long chain alkanol amides
Long-chain ester.Wherein described long chain amine oxide includes but is not limited to the dimethyl amine of 16-22 carbon atom.Preferably comprise
The fatty acid ethylene glycol diester of 18 carbon atoms.Applicant experiments prove that, flocculating degree of this suspending agent for system
Influence very little, and suspending power is very sufficient, and suspending power is provided not against yield value.
A kind of above-mentioned anti-dandruff shampoo composition for improving effective particulate matter over-deposit, except it is above-mentioned it is necessary into point it
Outside, at least one also containing following component：
Aid in suspending agent：0.01-5%；
Cationic cellulose derivative：0.01-0.5%；
Polyethylene glycol：0.01-0.3%；
Organic conditioning oil：0.01-2%；
Preservative：0.01-1%；
Essence：0.01-3%；
Viscosity modifier：0.01-4%；
Chelating agent：0.005-0.2%；
Ultra-violet absorber：0.01-2%；
Plant extracts and its derivative：0.0001-5%；
Wherein, described auxiliary suspending agent is selected from hydroxypropyl methyl cellulose, hydroxyethyl cellulose, melon gum derivative, starch
Derivative, hydroxypropyl starch phosphate, xanthan gum, the one or more in carbomer polymer；And acrylic polymer and
Its derivative, acrylic acid（Ester）Class/C10 ~ C30 alkylol acrylamide acid ester copolymers, acrylates/C10 ~ C30 alkylol acrylamide acid esters
Cross-linked copolymer emulsifying agent, acrylic acid（Ester）Analog copolymer, the cross-linked polymer of polyacrylate -1, acrylic acid（Ester）Class/tristearin
Alcohol polyethers（20）Methacrylate copolymer is not then in the range of selection.Follow-up this kind of suspending agent why is not selected, is
Applicant experiments prove that, although such suspending agent can provide good stability and yield value, for hair washing group
The flocculating strength of compound has a great impact, in order to ensure the carrying capacity of the effect of hair-washing composition and effective particulate matter, because
This does not do preferably.
The good light hair-washing composition of the wet hair of above-mentioned one kind, can arbitrary proportion hair class cosmetics are made with conventional base-material
In, State of cosmetics can be one kind in solution, suspension, solid-like.
The good light hair-washing composition of the above-mentioned wet hair of one kind, configuration and hybrid technology of its collocation method for routine,
This does not elaborate.
The present invention has the advantages that：
1st, the flocculating strength of care composition of the invention and silicone oil deposition degree are moderate, and flocculating strength can be carried effectively effectively
Particulate matter, and can play good conditioning effect.The present invention has selected the cation guar gum of low molecule amount and low charge density
Derivative, and arrange in pairs or groups and do not influence the suspension stabilizer of flocculating strength, preferably anion surfactant and amphoteric surface are lived
Property agent collocation so that can be flocculated visible solid flocculation phase in low extension rate, and this flocculation phase water content compared with
Height, this contributes to the carrying of effective particulate matter and improves shampoo overall performance.
2nd, hair-washing composition of the invention provides sensation salubrious after good wet hair is felt and be dry.Final guarantor of the invention
In the composition framework of shield, there is the higher solid flocculation of visible water content in its pure water dilution range between 5 times -20 times
Phase, this flocculation mutually bring good wet hair to feel, while arrange in pairs or groups with preferable non-volatile conditioning agent, bring dry and comfortable dry hair
Feel, not anti-oil.
3rd, the compounding synergy between hair-washing composition of the invention is obvious, by the synergy between raw material, makes
The lifting of hair-washing composition overall performance is obtained, while reduces the difficulty of technique, the excitant of system is reduced, improves thickening
Efficiency.
Brief description of the drawings
Fig. 1 is the deposition side view of embodiment and the comparative example silicone oil after five topknots are washed.
Embodiment
The present invention is described in detail with reference to the accompanying drawings and examples.
Table 1 below is 3 preferred embodiments of the present invention and 2 comparative examples.Wherein, comparative example 3 is from one kind on the market
Sell the measured Two-in-one shampoo made with cationic guar derivative.
Wherein, the parameter of cationic guar derivative is as follows：
We measure the deposition of comparative example and the embodiment silicone oil after five topknots are washed, and test result is as shown in Figure 1.From
Fig. 1 is, it is apparent that embodiment 1-3 silicone oil is deposited without increasing with the increase of wash number, and used in comparative example 1
Cationic guar derivative due to molecular weight it is excessive, cause flocculating strength too strong, water content is relatively low, causes the deposition of silicone oil
Amount is more obvious, it can also be seen that silicone oil deposition increases with the increase of wash number；Comparative example 2 employs a kind of to wadding
The far-reaching suspension stabilizer of condensed-phase, its result show that silicone oil is deposited without being well controlled, although there is silicone oil to sink
Product, but silicone oil deposition is with the increase of wash number that increased trend is more obvious, anticipated that after being cleaned multiple times
Salubrious sense will substantially reduce.The product of comparative example 3 on the market, it can also be seen that increase of the silicone oil deposition with wash number
And increase.
Claims (10)
- A kind of 1. good light hair-washing composition of wet hair, it is characterised in that the raw material containing following percetage by weight proportioning：(A) anion surfactant 9-15%；(B) amphoteric surfactant 0.5 ~ 1.8%；(C) cationic guar derivative 0.2 ~ 0.8%；The charge density of wherein described cationic guar derivative is about 0.5~1.0 meq/g；And molecular weight is 400000 ~ 1500000 g/mol；(D) nonionic surfactant 0.5-1.5%；(E) salt 0.4-1.6%；(F) non-volatile conditioning agent 0.05-5%；(G) suspending agent 0.01-3%；And surplus(H) pure water.
- 2. the good light hair-washing composition of wet hair according to claim 1, it is characterised in that：Described anionic surface Activating agent is selected from alkyl polyoxyethylene ether sulfate, glycerine monofatty ester sulfate, fatty alcohol ether sulfosuccinate ester salt, N- In fatty acyl amino-acid salt, fatty acyl methyl tauride, monoalkyl sulfate, monoalkyl carboxylate, alkylphosphonate At least one.
- 3. the good light hair-washing composition of wet hair according to claim 1, it is characterised in that：Described anionic surface The preferred alkyl polyoxyethylene ether sulfate of activating agent, glycerine monofatty ester sulfate, fatty alcohol ether sulfosuccinate ester salt, N- At least one of fatty acyl amino-acid salt, fatty acyl methyl tauride.
- 4. the good light hair-washing composition of wet hair according to claim 1, it is characterised in that：Described amphoteric surface lives Property agent in fatty acyl both sexes acetate, fatty acyl CAB, fatty acid amide hydroxypropyl sulfobetaines at least one Kind.
- 5. the good light hair-washing composition of wet hair according to claim 1, it is characterised in that：Described amphoteric surface lives Property at least one of agent preferred fat acyl both sexes acetate and fatty acyl CAB.
- 6. the good light hair-washing composition of wet hair according to claim 1, it is characterised in that：The non-ionic surface is lived Property agent is in coconut oil fatty acid monoethanolamide, cocounut oil acid methyl single ethanol amide, coconut oil diethanol amine, APG At least one.
- 7. the good light hair-washing composition of wet hair according to claim 1, it is characterised in that：The non-ionic surface is lived Property agent is coconut oil fatty acid monoethanolamide.
- 8. the good light hair-washing composition of wet hair according to claim 1, it is characterised in that：Described non-volatile tune Reason agent is one or both of scattered polysiloxanes, ammonia end dimethyl silicone polymer compounding.
- 9. the good light hair-washing composition of wet hair according to claim 1, it is characterised in that：Described suspending agent is selected from At least one of acyl derivative and long chain amine oxide.
- 10. the good light hair-washing composition of wet hair according to claim 1, it is characterised in that also containing following component At least one：Aid in suspending agent：0.01-5%；Cationic cellulose derivative：0.01-0.5%；Polyethylene glycol：0.01-0.3%；Organic conditioning oil：0.01-2%；Preservative：0.01-1%；Essence：0.01-3%；Viscosity modifier：0.01-4%；Chelating agent：0.005-0.2%；Ultra-violet absorber：0.01-2%；Plant extracts and its derivative：0.0001-5%.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109044881A (en) * | 2018-09-10 | 2018-12-21 | 花安堂生物科技集团有限公司 | A kind of pearl shining shampoo composition and a kind of preparation method of pearl shining shampoo composition |
| CN111096911A (en) * | 2020-02-17 | 2020-05-05 | 澳宝化妆品（惠州）有限公司 | Suspension composition containing liquid crystal form |
| CN114288209A (en) * | 2021-10-25 | 2022-04-08 | 纳爱斯丽水日化有限公司 | Double-layer shampoo composition and preparation method thereof |
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| CN106389154A (en) * | 2016-10-25 | 2017-02-15 | 澳宝化妆品（惠州）有限公司 | Multi-effect balanced shampoo and preparation method thereof |
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| CN1204255A (en) * | 1995-10-16 | 1999-01-06 | 普罗克特和甘保尔公司 | Conditioning shampoo compositions having improved stability |
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|---|---|---|---|---|
| CN109044881A (en) * | 2018-09-10 | 2018-12-21 | 花安堂生物科技集团有限公司 | A kind of pearl shining shampoo composition and a kind of preparation method of pearl shining shampoo composition |
| CN111096911A (en) * | 2020-02-17 | 2020-05-05 | 澳宝化妆品（惠州）有限公司 | Suspension composition containing liquid crystal form |
| CN114288209A (en) * | 2021-10-25 | 2022-04-08 | 纳爱斯丽水日化有限公司 | Double-layer shampoo composition and preparation method thereof |
| CN114288209B (en) * | 2021-10-25 | 2023-11-24 | 纳爱斯丽水日化有限公司 | Double-layer shampoo composition and preparation method thereof |
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