CN107400466A - A kind of production technology of ultralow medium-temperature reinforced description film - Google Patents

A kind of production technology of ultralow medium-temperature reinforced description film Download PDF

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Publication number
CN107400466A
CN107400466A CN201710857653.5A CN201710857653A CN107400466A CN 107400466 A CN107400466 A CN 107400466A CN 201710857653 A CN201710857653 A CN 201710857653A CN 107400466 A CN107400466 A CN 107400466A
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CN
China
Prior art keywords
film
ultralow
medium
eva
master batch
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Application number
CN201710857653.5A
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Chinese (zh)
Inventor
崔九峰
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TIANJIN SUNRAY PLASTIC PRODUCT CO Ltd
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TIANJIN SUNRAY PLASTIC PRODUCT CO Ltd
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Application filed by TIANJIN SUNRAY PLASTIC PRODUCT CO Ltd filed Critical TIANJIN SUNRAY PLASTIC PRODUCT CO Ltd
Priority to CN201710857653.5A priority Critical patent/CN107400466A/en
Publication of CN107400466A publication Critical patent/CN107400466A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/04Homopolymers or copolymers of ethene
    • C09J123/08Copolymers of ethene
    • C09J123/0846Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C09J123/0853Vinylacetate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

The present invention relates to a kind of production technology of ultralow medium-temperature reinforced description film.Comprise the following steps, the step of (1) prepares master batch, melt index makees dispersant in 5 40g/10min EVA resin using macromolecule wax when master batch base material uses 190 DEG C;(2) step for being well mixed master batch with EVA resin and coupling agent, EVA resin at 190 DEG C melt index in 5 40g/10min;(3) the step of using casting film-forming Process Production EVA glass films.The invention provides a kind of production technology of ultralow medium-temperature reinforced description film, traditional PVB materials are replaced by using EVA material, employ low temperature moulding technique in process of production, manufactured glass film can at a lower temperature with glass laminating, the influence to glass film under the conditions of high temperature doubling is effectively prevent, while improves the structural strength of description film.

Description

A kind of production technology of ultralow medium-temperature reinforced description film
Technical field
The present invention relates to a kind of production technology of ultralow medium-temperature reinforced description film.
Background technology
In fields such as building decorations, doubling glass with its good characteristic such as attractive in appearance, firm obtained it is more and more extensive should With doubling glass includes the glass film layers positioned at center and the glass positioned at both sides.It is anti-pound/implosion guard is a by glass Film it is compound enter layer glass among, after HTHP gluing, the new special glass product of integrally formed sandwich. Existing its structural strength of description film is low, and the peel strength and tensile strength between glass are low.
The content of the invention
The present invention provides a kind of life of ultralow medium-temperature reinforced description film to solve technical problem present in known technology Production. art, solves problem present in background technology.
The present invention is adopted the technical scheme that to solve technical problem present in known technology:It is a kind of ultralow medium-temperature reinforced The step of production technology of description film comprises the following steps, and (1) prepares master batch, melt index when master batch base material uses 190 DEG C In 5-40g/10min EVA resin, dispersant is made using macromolecule wax;(2) master batch is mixed with EVA resin and coupling agent Even step, EVA resin at 190 DEG C melt index in 5-40g/10min;(3) casting film-forming Process Production EVA glass is used The step of film.
The advantages and positive effects of the present invention are:The invention provides a kind of production work of ultralow medium-temperature reinforced description film Skill, replace traditional PVB materials by using EVA material, employ low temperature moulding technique, manufactured glass in process of production Film can effectively prevent the influence to glass film under the conditions of high temperature doubling at a lower temperature with glass laminating, The structural strength of description film is improved simultaneously.
Preferably:Macromolecule wax described in step (1) be chosen for Tissuemat E, EVA waxes, copolymerization ester type waxes in one kind or It is a variety of.
Preferably:Coupling agent described in step (2) is chosen for aminopropyl trimethoxysilane, aminopropyltriethoxy dimethoxy Base silane, aminopropyl triethoxysilane, aminoethylaminopropyl trimethoxy silane, aminoethylaminopropyl triethoxysilane, Aminoethylaminopropyl methyl dimethoxysilane, vinyltrimethoxy silane, VTES, methacryl One or more in epoxide trimethoxy silane.
Preferably:Casting film-forming technique uses single screw extrusion machine in step (3), and extrusion temperature is 90-150 DEG C.
Embodiment
In order to further understand the content, features and effects of the present invention, it is as follows hereby to lift following examples detailed description:
Embodiment 1
(1) the step of preparing master batch, melt index is in 8g/10min EVA resin, use when master batch base material uses 190 DEG C Macromolecule wax makees dispersant;(2) step for being well mixed master batch with EVA resin and coupling agent, EVA resin melt at 190 DEG C Melt index in 12g/10min;(3) the step of using casting film-forming Process Production EVA glass films.
Wherein, the macromolecule wax described in step (1) is chosen for Tissuemat E;Coupling agent described in step (2) is chosen For aminoethylaminopropyl trimethoxy silane;Casting film-forming technique uses single screw extrusion machine in step (3), and extrusion temperature is 100℃。
Embodiment 2
(1) the step of preparing master batch, melt index is adopted in 25g/10min EVA resin when master batch base material uses 190 DEG C Make dispersant with macromolecule wax;(2) step for being well mixed master batch with EVA resin and coupling agent, EVA resin is at 190 DEG C Melt index is in 32g/10min;(3) the step of using casting film-forming Process Production EVA glass films.
Wherein, the macromolecule wax described in step (1) is chosen for Tissuemat E;Coupling agent described in step (2) is chosen For aminopropyl trimethoxysilane;Casting film-forming technique uses single screw extrusion machine in step (3), and extrusion temperature is 110 DEG C.
Embodiment 3
(1) the step of preparing master batch, melt index is adopted in 32g/10min EVA resin when master batch base material uses 190 DEG C Make dispersant with macromolecule wax;(2) step for being well mixed master batch with EVA resin and coupling agent, EVA resin is at 190 DEG C Melt index is in 38g/10min;(3) the step of using casting film-forming Process Production EVA glass films.
Wherein, the macromolecule wax described in step (1) is chosen for EVA waxes;Coupling agent described in step (2) is chosen for second Alkenyl triethoxysilane;Casting film-forming technique uses single screw extrusion machine in step (3), and extrusion temperature is 130 DEG C.

Claims (4)

1. a kind of production technology of ultralow medium-temperature reinforced description film, it is characterized in that:Comprise the following steps,
(1) the step of preparing master batch, melt index is in 5-40g/10min EVA resin, use when master batch base material uses 190 DEG C Macromolecule wax makees dispersant;
(2) step for being well mixed master batch with EVA resin and coupling agent, EVA resin at 190 DEG C melt index in 5-40g/ 10min;
(3) the step of using casting film-forming Process Production EVA glass films.
2. the production technology of ultralow medium-temperature reinforced description film as claimed in claim 1, it is characterised in that:Described in step (1) Macromolecule wax be chosen for Tissuemat E, EVA waxes, copolymerization ester type waxes in one or more.
3. the production technology of the ultralow medium-temperature reinforced description film of light modulation film as claimed in claim 1, it is characterised in that:Step (2) coupling agent described in is chosen for aminopropyl trimethoxysilane, aminopropyltriethoxy dimethoxysilane, the ethoxy of aminopropyl three Base silane, aminoethylaminopropyl trimethoxy silane, aminoethylaminopropyl triethoxysilane, aminoethylaminopropyl methyl dimethoxy In TMOS, vinyltrimethoxy silane, VTES, methacryloxy trimethoxy silane It is one or more.
4. the production technology of ultralow medium-temperature reinforced description film as claimed in claim 1, it is characterised in that:It is cast in step (3) Film-forming process uses single screw extrusion machine, and extrusion temperature is 90-150 DEG C.
CN201710857653.5A 2017-09-20 2017-09-20 A kind of production technology of ultralow medium-temperature reinforced description film Pending CN107400466A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710857653.5A CN107400466A (en) 2017-09-20 2017-09-20 A kind of production technology of ultralow medium-temperature reinforced description film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710857653.5A CN107400466A (en) 2017-09-20 2017-09-20 A kind of production technology of ultralow medium-temperature reinforced description film

Publications (1)

Publication Number Publication Date
CN107400466A true CN107400466A (en) 2017-11-28

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CN (1) CN107400466A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109796893A (en) * 2019-02-02 2019-05-24 天津三瑞塑胶制品有限公司 A kind of production technology of cladding glass special adhesive
CN109796908A (en) * 2019-02-02 2019-05-24 天津三瑞塑胶制品有限公司 A kind of production technology of ionic safety glass film
CN109810651A (en) * 2019-02-22 2019-05-28 天津三瑞塑胶制品有限公司 A kind of production technology of clear type film
CN109852292A (en) * 2019-02-02 2019-06-07 天津三瑞塑胶制品有限公司 A kind of production technology of glass plank road special adhesive
CN109880549A (en) * 2019-02-02 2019-06-14 天津三瑞塑胶制品有限公司 A kind of production technology of single plane fluoroscopy film
CN109880535A (en) * 2019-02-02 2019-06-14 天津三瑞塑胶制品有限公司 A kind of production technology of the high seep through piece of ultralow temperature

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103788883A (en) * 2014-01-23 2014-05-14 天津三瑞塑胶制品有限公司 Production method of luminous flow-line EVA laminated glass film
CN106584879A (en) * 2016-12-01 2017-04-26 天津三瑞塑胶制品有限公司 Production technology of mirror surface black decoration film
CN106634652A (en) * 2016-12-01 2017-05-10 天津三瑞塑胶制品有限公司 Production process for dimming film
CN106626651A (en) * 2016-12-01 2017-05-10 天津三瑞塑胶制品有限公司 Production process for laminating and coating adhesive film

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103788883A (en) * 2014-01-23 2014-05-14 天津三瑞塑胶制品有限公司 Production method of luminous flow-line EVA laminated glass film
CN106584879A (en) * 2016-12-01 2017-04-26 天津三瑞塑胶制品有限公司 Production technology of mirror surface black decoration film
CN106634652A (en) * 2016-12-01 2017-05-10 天津三瑞塑胶制品有限公司 Production process for dimming film
CN106626651A (en) * 2016-12-01 2017-05-10 天津三瑞塑胶制品有限公司 Production process for laminating and coating adhesive film

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109796893A (en) * 2019-02-02 2019-05-24 天津三瑞塑胶制品有限公司 A kind of production technology of cladding glass special adhesive
CN109796908A (en) * 2019-02-02 2019-05-24 天津三瑞塑胶制品有限公司 A kind of production technology of ionic safety glass film
CN109852292A (en) * 2019-02-02 2019-06-07 天津三瑞塑胶制品有限公司 A kind of production technology of glass plank road special adhesive
CN109880549A (en) * 2019-02-02 2019-06-14 天津三瑞塑胶制品有限公司 A kind of production technology of single plane fluoroscopy film
CN109880535A (en) * 2019-02-02 2019-06-14 天津三瑞塑胶制品有限公司 A kind of production technology of the high seep through piece of ultralow temperature
CN109810651A (en) * 2019-02-22 2019-05-28 天津三瑞塑胶制品有限公司 A kind of production technology of clear type film

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Application publication date: 20171128