CN106633345A - Production process of jade sand color film - Google Patents

Production process of jade sand color film Download PDF

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Publication number
CN106633345A
CN106633345A CN201611085050.XA CN201611085050A CN106633345A CN 106633345 A CN106633345 A CN 106633345A CN 201611085050 A CN201611085050 A CN 201611085050A CN 106633345 A CN106633345 A CN 106633345A
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China
Prior art keywords
master batch
sand
jade
color film
jade sand
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Pending
Application number
CN201611085050.XA
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Chinese (zh)
Inventor
崔九峰
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TIANJIN SUNRAY PLASTIC PRODUCT CO Ltd
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TIANJIN SUNRAY PLASTIC PRODUCT CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Priority to CN201611085050.XA priority Critical patent/CN106633345A/en
Publication of CN106633345A publication Critical patent/CN106633345A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C08L23/0853—Vinylacetate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C59/00—Surface shaping of articles, e.g. embossing; Apparatus therefor
    • B29C59/02—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing
    • B29C59/04—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing using rollers or endless belts
    • B29C59/043—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing using rollers or endless belts for profiled articles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2007/00—Flat articles, e.g. films or sheets
    • B29L2007/002—Panels; Plates; Sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04—Homopolymers or copolymers of ethene
    • C08J2423/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

The invention relates to a production process of a jade sand color film. The production process comprises the following steps: (1) preparing a jade sand master batch, wherein a master batch base material adopts EVA resin which has the melt index of 15 g/10 min to 20 g/10 min at 190 DEG C, macromolecular wax is used as a dispersing agent, the mass concentration of fine particle powder is 20 percent to 40 percent, the single particle refractive index is 1.2 to 1.7, and the average particle diameter is 3.0 [mu]m to 8.0 [mu]m; (2) carrying out extrusion forming to obtain a color jade sand master batch; (3) uniformly mixing the color jade sand master batch with the EVA resin and a coupling agent, wherein the melt index of the EVA resin is 5 g/10 min to 15 g/10 min at 190 DEG C; (4) generating the jade sand color film, wherein the extrusion temperature is controlled at 90 DEG C to 110 DEG C; (5) carrying out embossing forming, wherein the rubber roller water temperature of embossing forming equipment is controlled at 8 DEG C to 12 DEG C, a rubber roller is made of an integrated silica gel material, the hardness is controlled at 60 A to 80 A, and the mesh roughness of rubber roller sand is of 14 meshes to 18 meshes; the steel roller water temperature is controlled at 40 DEG C to 50 DEG C, and the embossing depth is 0.06 mm to 0.15 mm.

Description

A kind of production technology of beautiful sand color film
Technical field
The present invention relates to a kind of production technology of beautiful sand color film.
Background technology
In fields such as building decorations, doubling glass has obtained more and more widely should with its good characteristic such as attractive in appearance, firm With doubling glass includes being located at the glass film layers and the glass positioned at both sides at center.Existing glass film is generally monochrome, The doubling glass that production is formed is typically also that opaque monochrome is adjusted, when needing to represent combination colour effect, typically by multicolour Doubling glass is applied in combination.However as the lifting and transformation of people's estheticism, the doubling glass of monotone can not expire The aesthetic requirement of sufficient people, people are badly in need of to represent on a piece of doubling glass the technology of the beautiful sand effect of similar astigmatism and are gone out It is existing, there is not yet above-mentioned production technology in prior art.
The content of the invention
The present invention provides a kind of production technology of beautiful sand color film to solve technical problem present in known technology.
The present invention is adopted the technical scheme that to solve technical problem present in known technology：A kind of beautiful sand coloured glue The production technology of piece is comprised the following steps, and the step of (1) prepares beautiful sand master batch, melt index exists when master batch base material adopts 190 DEG C The EVA resin of 15g/10min-20g/10min, using macromolecule wax dispersant is made, and the mass concentration of particulate powder is 20%- 40%, single-particle refractive index is 1.2-1.7, and mean particle diameter is 3.0um-8.0um；(2) by beautiful sand master batch and dyestuff powder, light Stable powder, light absorbs powder and antioxidant mixing, the colored jade sand master batch of Jing double screw extruders extrusion molding；(3) by colored jade sand The step of master batch is well mixed with EVA resin and coupling agent, EVA resin at 190 DEG C melt index in 5g/10min-15g/ 10min；(4) using casting film-forming Process Production jade sand color film the step of, extrusion temperature is controlled at 90-110 DEG C；(5) press The step of line is molded, embosses the rubber roll water temperature control of former at 8 DEG C -12 DEG C, and rubber roll is integral type silica gel material, soft durometer In 60-80A, rubber roll Grains rugosity is the mesh of 14 mesh -18 for control；The control of steel rider water temperature at 40 DEG C -50 DEG C, pattern depth 0.06mm- 0.15mm。
Advantages of the present invention and good effect are：The invention provides a kind of production technology of beautiful sand color film, utilizes Light source diffusion principle is distributed to functional particle powder in film, makes glass middle color film form micron-sized male and fomale(M＆F), These male and fomale(M＆F)s can make incident ray that deconsolidation occurs, and play astigmatism jade sand color effect.Improve the optional of doubling glass production Selecting property, whole production procedure is short and sweet, easily operated.
Preferably：Macromolecule wax described in step (1) be chosen for the one kind in Tissuemat E, EVA waxes, copolymerization ester type waxes or It is various.
Preferably：Coupling agent described in step (2) is chosen for aminopropyl trimethoxysilane, aminopropyltriethoxy dimethoxy Base silane, aminopropyl triethoxysilane, aminoethylaminopropyl trimethoxy silane, aminoethylaminopropyl triethoxysilane, Aminoethylaminopropyl methyl dimethoxysilane, vinyltrimethoxy silane, VTES, methacryl One or more in epoxide trimethoxy silane.
Specific embodiment
For the content of the invention, feature and effect of the present invention can be further appreciated that, following examples detailed description is hereby lifted as follows：
Embodiment 1：
(1) the step of preparing beautiful sand master batch, EVA tree of the melt index in 15g/10min when master batch base material adopts 190 DEG C Fat, using macromolecule wax dispersant is made, and the mass concentration of particulate powder is 25%, and single-particle refractive index is 1.3, and averaged particles are straight Footpath is 4.0um；
(1) beautiful sand master batch is mixed with dyestuff powder, light stable powder, light absorbs powder and antioxidant, Jing double screw extruders are squeezed Go out the colored jade sand master batch of shaping；
(3) the step of being well mixed colored jade sand master batch with EVA resin and coupling agent, EVA resin is melted at 190 DEG C Index is in 8g/10min；
(4) using casting film-forming Process Production jade sand color film the step of, extrusion temperature is controlled at 95 DEG C；
(5) the step of embossing shaping, embosses the rubber roll water temperature control of former at 9 DEG C, and rubber roll is integral type silica gel material Matter, in 65A, rubber roll Grains rugosity is 15 mesh for soft durometer control；The control of steel rider water temperature at 45 DEG C, pattern depth 0.09mm.
Wherein, the macromolecule wax described in step (1) is chosen for Tissuemat E；Coupling agent described in step (2) is chosen For aminoethylaminopropyl trimethoxy silane.
Embodiment 2：
(1) the step of preparing beautiful sand master batch, EVA tree of the melt index in 18g/10min when master batch base material adopts 190 DEG C Fat, using macromolecule wax dispersant is made, and the mass concentration of particulate powder is 35%, and single-particle refractive index is 1.4, and averaged particles are straight Footpath is 6.0um；
(1) beautiful sand master batch is mixed with dyestuff powder, light stable powder, light absorbs powder and antioxidant, Jing double screw extruders are squeezed Go out the colored jade sand master batch of shaping；
(3) the step of being well mixed colored jade sand master batch with EVA resin and coupling agent, EVA resin is melted at 190 DEG C Index is in 10g/10min；
(4) using casting film-forming Process Production jade sand color film the step of, extrusion temperature is controlled at 100 DEG C；
(5) the step of embossing shaping, embosses the rubber roll water temperature control of former at 9 DEG C, and rubber roll is integral type silica gel material Matter, in 75A, rubber roll Grains rugosity is 16 mesh for soft durometer control；The control of steel rider water temperature at 48 DEG C, pattern depth 0.10mm.
Wherein, the macromolecule wax described in step (1) is chosen for Tissuemat E；Coupling agent described in step (2) is chosen For aminopropyl trimethoxysilane.
Embodiment 3：
(1) the step of preparing beautiful sand master batch, EVA tree of the melt index in 20g/10min when master batch base material adopts 190 DEG C Fat, using macromolecule wax dispersant is made, and the mass concentration of particulate powder is 40%, and single-particle refractive index is 1.6, and averaged particles are straight Footpath is 7.0um；
(2) beautiful sand master batch is mixed with dyestuff powder, light stable powder, light absorbs powder and antioxidant, Jing double screw extruders are squeezed Go out the colored jade sand master batch of shaping；
(3) the step of being well mixed colored jade sand master batch with EVA resin and coupling agent, EVA resin is melted at 190 DEG C Index is in 12g/10min；
(4) using casting film-forming Process Production jade sand color film the step of, extrusion temperature is controlled at 110 DEG C；
(5) the step of embossing shaping, embosses the rubber roll water temperature control of former at 9 DEG C, and rubber roll is integral type silica gel material Matter, in 80A, rubber roll Grains rugosity is 18 mesh for soft durometer control；The control of steel rider water temperature at 50 DEG C, pattern depth 0.12mm.
Wherein, the macromolecule wax described in step (1) is chosen for EVA waxes；Coupling agent described in step (2) is chosen for second Thiazolinyl triethoxysilane.

Claims (3)

1. a kind of production technology of beautiful sand color film, is characterized in that：Comprise the following steps,
(1) the step of preparing beautiful sand master batch, melt index is 15g/10min-20g/10min's when master batch base material adopts 190 DEG C EVA resin, using macromolecule wax dispersant is made, and the mass concentration of particulate powder is 20%-40%, and single-particle refractive index is 1.2- 1.7, mean particle diameter is 3.0um-8.0um；
(2) beautiful sand master batch is mixed with dyestuff powder, light stable powder, light absorbs powder and antioxidant, Jing double screw extruders are extruded into The colored jade sand master batch of type；
(3) the step of being well mixed colored jade sand master batch with EVA resin and coupling agent, EVA resin melt index at 190 DEG C In 5g/10min-15g/10min；
(4) using casting film-forming Process Production jade sand color film the step of, extrusion temperature is controlled at 90 DEG C -110 DEG C；
(5) the step of embossing shaping, embosses the rubber roll water temperature control of former at 8 DEG C -12 DEG C, and rubber roll is integral type silica gel material Matter, in 60-80A, rubber roll Grains rugosity is the mesh of 14 mesh -18 for soft durometer control；The control of steel rider water temperature at 40 DEG C -50 DEG C, decorative pattern depth Degree 0.06mm-0.15mm.
2. the production technology of jade sand color film as claimed in claim 1, it is characterised in that：High score described in step (1) Sub- wax is chosen for one or more in Tissuemat E, EVA waxes, copolymerization ester type waxes.
3. the production technology of jade sand color film as claimed in claim 1, it is characterised in that：Coupling described in step (2) Agent is chosen for aminopropyl trimethoxysilane, aminopropyltriethoxy dimethoxysilane, aminopropyl triethoxysilane, aminoethyl ammonia Propyl trimethoxy silicane, aminoethylaminopropyl triethoxysilane, aminoethylaminopropyl methyl dimethoxysilane, vinyl One or more in trimethoxy silane, VTES, methacryloxy trimethoxy silane.
CN201611085050.XA 2016-12-01 2016-12-01 Production process of jade sand color film Pending CN106633345A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107400468A (en) * 2017-09-20 2017-11-28 天津三瑞塑胶制品有限公司 A kind of production technology of EVA self-adhesions protection film
CN107603502A (en) * 2017-09-20 2018-01-19 天津三瑞塑胶制品有限公司 A kind of production technology of EVA glass diffusion film
CN109822806A (en) * 2019-02-02 2019-05-31 天津三瑞塑胶制品有限公司 A kind of production technology of electrochromic intelligent film

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103788883A (en) * 2014-01-23 2014-05-14 天津三瑞塑胶制品有限公司 Production method of luminous flow-line EVA laminated glass film
CN105985738A (en) * 2015-02-11 2016-10-05 温州瑞阳光伏材料有限公司 Laminated glass functional glue film and preparation technology thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103788883A (en) * 2014-01-23 2014-05-14 天津三瑞塑胶制品有限公司 Production method of luminous flow-line EVA laminated glass film
CN105985738A (en) * 2015-02-11 2016-10-05 温州瑞阳光伏材料有限公司 Laminated glass functional glue film and preparation technology thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107400468A (en) * 2017-09-20 2017-11-28 天津三瑞塑胶制品有限公司 A kind of production technology of EVA self-adhesions protection film
CN107603502A (en) * 2017-09-20 2018-01-19 天津三瑞塑胶制品有限公司 A kind of production technology of EVA glass diffusion film
CN109822806A (en) * 2019-02-02 2019-05-31 天津三瑞塑胶制品有限公司 A kind of production technology of electrochromic intelligent film

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Application publication date: 20170510