CN106626651A - Production process for laminating and coating adhesive film - Google Patents
Production process for laminating and coating adhesive film Download PDFInfo
- Publication number
- CN106626651A CN106626651A CN201611085061.8A CN201611085061A CN106626651A CN 106626651 A CN106626651 A CN 106626651A CN 201611085061 A CN201611085061 A CN 201611085061A CN 106626651 A CN106626651 A CN 106626651A
- Authority
- CN
- China
- Prior art keywords
- eva
- emaa
- laminating
- 10min
- adhesive film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/306—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
Landscapes
- Laminated Bodies (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
The invention relates to a production process for a laminating and coating adhesive film. The production process comprises the following steps: firstly, preparing master match; adopting EMAA (Ethylene Methacrylic Acid) of which a melt index at the temperature of 190DEG C is 0.5 to 5g/10min as a master batch base material, adopting polymeric paraffin as a dispersing agent, and extruding by adopting a twin-screw extruder; secondly, uniformly mixing EVA (Ethylene-Vinyl Acetate) resin with a coupling agent, wherein a melt index of the EVA resin at the temperature of 190DEG C is 5 to 15g/10min; thirdly, generating the laminating and coating adhesive film by adopting a three-layer co-extrusion casting film forming technique, wherein two sides of the laminating and coating adhesive film are EMAA resin, the middle of the laminating and coating adhesive film is the EVA resin, the extrusion temperature of an EMAA screw is 90 to 130DEG C, and the extrusion temperature of an EVA screw is controlled at 60 to 90DEG C; fourthly, carrying out embossing forming; controlling the water temperature of a rubber roller of embossing forming equipment to be 8 to 12DEG C, wherein the rubber roller is made of an integrated silica gel material, the hardness is controlled at 60 to 80A, the grained roughness of the rubber roller is 14 to 18 meshes, the water temperature of a steel roller is controlled at 40 to 50DEG C, and the depth of patterns is 0.06 to 0.15mm.
Description
Technical field
The present invention relates to a kind of lamination Tu applies the production technology of bonding film.
Background technology
Automobile polishing disk, wool disk, sponge disc was originally all uncontrollable with hot melt adhesive water bonding nylon and wool.Existing layer
Pressure Tu is applied typically with hot melt adhesive or glue, time-consuming during production, and function of glue coating is uncontrollable.Therefore, one kind is produced
Can solve the problem that function of glue coating uneven, the bad control of personnel and cumbersome problem, control raw material mobility and into
The uncontrollable scheme of film, replacement glue solution wool, the deposited bonding film of the lamination Tu of sponge and nylon bonded technology seem and particularly must
Will.
The content of the invention
The present invention provides a kind of heat used in replacing lamination Tu to apply to solve technical problem present in known technology
Melt the production technology of the deposited bonding film of the lamination Tu of glue or glue, solve the technical problem of wool, sponge and nylon bonded aspect,
Lift adhesion efficiency, ensure the effect of bonding.
The present invention is adopted the technical scheme that to solve technical problem present in known technology:One kind lamination Tu applies viscous
The production technology of rubber alloy piece is comprised the following steps, and the step of (1) prepares master batch, melt index exists when master batch base material adopts 190 DEG C
The EMAA of 0.5g/10min-5g/10min, using macromolecule wax dispersant, double screw extruder extrusion are made;(2) by EVA resin
The step of being well mixed with coupling agent, EVA resin at 190 DEG C melt index in 5-15g/10min;(3) using three-layer co-extruded
The step of casting film-forming Process Production lamination Tu applies bonding film, both sides be EMAA resins, it is middle be EVA resin, EMAA screw rods
Extrusion temperature is 90 DEG C -130 DEG C, and EVA Screw Extrusions temperature control is at 60 DEG C -90 DEG C;(4) the step of embossing shaping, embosses into
At 8 DEG C -12 DEG C, rubber roll is integral type silica gel material for the rubber roll water temperature control of type equipment, and soft durometer is controlled in 60-80A, rubber roll sand
Mesh rugosity is the mesh of 14 mesh -18;The control of steel rider water temperature at 40 DEG C -50 DEG C, pattern depth 0.06mm-0.15mm.
Advantages of the present invention and good effect are:The invention provides a kind of lamination Tu applies the production technology of bonding film,
Bonding film is applied there is provided the lamination Tu of a kind of replacement hot melt adhesive or glue, wool, sponge and nylon bonded aspect is solved
Technical problem, improves adhesion efficiency, ensure that the effect of bonding.
Preferably:Macromolecule wax described in step (1) be chosen for the one kind in Tissuemat E, EVA waxes, copolymerization ester type waxes or
It is various.
Preferably:Coupling agent described in step (2) is chosen for aminopropyl trimethoxysilane, aminopropyltriethoxy dimethoxy
Base silane, aminopropyl triethoxysilane, aminoethylaminopropyl trimethoxy silane, aminoethylaminopropyl triethoxysilane,
Aminoethylaminopropyl methyl dimethoxysilane, vinyltrimethoxy silane, VTES, methacryl
One or more in epoxide trimethoxy silane.
Specific embodiment
For the content of the invention, feature and effect of the present invention can be further appreciated that, following examples detailed description is hereby lifted as follows:
EMAA is ethene-unsaturated ester copolymer, is ethene-(methyl) zinc acrylate resin also known as sarin (SURLYN) resin
Salt, sodium salt, lithium salts plasma key condensate, really a kind of modified poly ethylene.
Embodiment 1:
(1) the step of preparing master batch, melt index is adopted in the EMAA of 1.5g/10min when master batch base material adopts 190 DEG C
Macromolecule wax makees dispersant, double screw extruder extrusion;
(2) the step of EVA resin and coupling agent being well mixed, EVA resin at 190 DEG C melt index in 6g/
10min;
(3) using three-layer co-extruded casting film-forming Process Production lamination Tu apply bonding film the step of, both sides be EMAA resins,
Centre is EVA resin, and EMAA Screw Extrusions temperature is 95 DEG C, and EVA Screw Extrusions temperature control is at 65 DEG C;
(4) the step of embossing shaping, embosses the rubber roll water temperature control of former at 9 DEG C, and rubber roll is integral type silica gel material
Matter, in 65A, rubber roll Grains rugosity is 15 mesh for soft durometer control;The control of steel rider water temperature at 45 DEG C, pattern depth 0.09mm.
Wherein, the macromolecule wax described in step (1) is chosen for Tissuemat E;Coupling agent described in step (2) is chosen
For aminoethylaminopropyl trimethoxy silane.
Embodiment 2:
(1) the step of preparing master batch, melt index is adopted in the EMAA of 3.5g/10min when master batch base material adopts 190 DEG C
Macromolecule wax makees dispersant, double screw extruder extrusion;
(2) the step of EVA resin and coupling agent being well mixed, EVA resin at 190 DEG C melt index in 10g/
10min;
(3) using three-layer co-extruded casting film-forming Process Production lamination Tu apply bonding film the step of, both sides be EMAA resins,
Centre is EVA resin, and EMAA Screw Extrusions temperature is 100 DEG C, and EVA Screw Extrusions temperature control is at 75 DEG C;
(4) the step of embossing shaping, embosses the rubber roll water temperature control of former at 10 DEG C, and rubber roll is integral type silica gel material
Matter, in 75A, rubber roll Grains rugosity is 16 mesh for soft durometer control;The control of steel rider water temperature at 48 DEG C, pattern depth 0.10mm.
Wherein, the macromolecule wax described in step (1) is chosen for Tissuemat E;Coupling agent described in step (2) is chosen
For aminopropyl trimethoxysilane.
Embodiment 3:
(1) the step of preparing master batch, melt index is adopted in the EMAA of 4.5g/10min when master batch base material adopts 190 DEG C
Macromolecule wax makees dispersant, double screw extruder extrusion;
(2) the step of EVA resin and coupling agent being well mixed, EVA resin at 190 DEG C melt index in 14g/
10min;
(3) using three-layer co-extruded casting film-forming Process Production lamination Tu apply bonding film the step of, both sides be EMAA resins,
Centre is EVA resin, and EMAA Screw Extrusions temperature is 120 DEG C, and EVA Screw Extrusions temperature control is at 90 DEG C;
(4) the step of embossing shaping, embosses the rubber roll water temperature control of former at 11 DEG C, and rubber roll is integral type silica gel material
Matter, in 80A, rubber roll Grains rugosity is 17 mesh for soft durometer control;The control of steel rider water temperature at 50 DEG C, pattern depth 0.15mm.
Wherein, the macromolecule wax described in step (1) is chosen for EVA waxes;Coupling agent described in step (2) is chosen for second
Thiazolinyl triethoxysilane.
Claims (3)
1. a kind of lamination Tu applies the production technology of bonding film, it is characterized in that:Comprise the following steps,
(1) the step of preparing master batch, master batch base material adopt 190 DEG C when melt index 0.5g/10min-5g/10min EMAA,
Dispersant, double screw extruder extrusion are made using macromolecule wax;
(2) the step of EVA resin and coupling agent being well mixed, EVA resin at 190 DEG C melt index in 5-15g/10min;
(3) the step of applying bonding film using three-layer co-extruded casting film-forming Process Production lamination Tu, both sides are EMAA resins, centre
For EVA resin, EMAA Screw Extrusions temperature is 90 DEG C -130 DEG C, and EVA Screw Extrusions temperature control is at 60 DEG C -90 DEG C;
(4) the step of embossing shaping, embosses the rubber roll water temperature control of former at 8 DEG C -12 DEG C, and rubber roll is integral type silica gel material
Matter, in 60-80A, rubber roll Grains rugosity is the mesh of 14 mesh -18 for soft durometer control;The control of steel rider water temperature at 40 DEG C -50 DEG C, decorative pattern depth
Degree 0.06mm-0.15mm.
2. lamination Tu as claimed in claim 1 applies the production technology of bonding film, it is characterised in that:Described in step (1)
Macromolecule wax is chosen for one or more in Tissuemat E, EVA waxes, copolymerization ester type waxes.
3. lamination Tu as claimed in claim 1 applies the production technology of bonding film, it is characterised in that:It is characterized in that:Step
(2) coupling agent described in is chosen for aminopropyl trimethoxysilane, aminopropyltriethoxy dimethoxysilane, the ethoxy of aminopropyl three
Base silane, aminoethylaminopropyl trimethoxy silane, aminoethylaminopropyl triethoxysilane, aminoethylaminopropyl methyl dimethoxy
In TMOS, vinyltrimethoxy silane, VTES, methacryloxy trimethoxy silane
One or more.
Priority Applications (1)
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CN201611085061.8A CN106626651A (en) | 2016-12-01 | 2016-12-01 | Production process for laminating and coating adhesive film |
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CN201611085061.8A CN106626651A (en) | 2016-12-01 | 2016-12-01 | Production process for laminating and coating adhesive film |
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CN201611085061.8A Pending CN106626651A (en) | 2016-12-01 | 2016-12-01 | Production process for laminating and coating adhesive film |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107400466A (en) * | 2017-09-20 | 2017-11-28 | 天津三瑞塑胶制品有限公司 | A kind of production technology of ultralow medium-temperature reinforced description film |
CN107400468A (en) * | 2017-09-20 | 2017-11-28 | 天津三瑞塑胶制品有限公司 | A kind of production technology of EVA self-adhesions protection film |
CN107400467A (en) * | 2017-09-20 | 2017-11-28 | 天津三瑞塑胶制品有限公司 | A kind of production technology of EVA bathrooms safety door special adhesive |
CN107522935A (en) * | 2017-09-20 | 2017-12-29 | 天津三瑞塑胶制品有限公司 | A kind of production technology of EVA ultraviolet isolatings film |
CN107573865A (en) * | 2017-09-20 | 2018-01-12 | 天津三瑞塑胶制品有限公司 | A kind of anti-production technology for pounding film of EVA cross-linking types |
CN107602997A (en) * | 2017-09-20 | 2018-01-19 | 天津三瑞塑胶制品有限公司 | A kind of production technology of EVA colored solars film |
CN109796911A (en) * | 2019-02-22 | 2019-05-24 | 天津三瑞塑胶制品有限公司 | A kind of production technology of shower house professional film |
CN109852292A (en) * | 2019-02-02 | 2019-06-07 | 天津三瑞塑胶制品有限公司 | A kind of production technology of glass plank road special adhesive |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002067156A (en) * | 2000-08-30 | 2002-03-05 | C I Kasei Co Ltd | Resin tube for steel pipe lining, its manufacturing method, and lining steel pipe |
CN103205212A (en) * | 2013-04-27 | 2013-07-17 | 汕头市安德利环保科技有限公司 | EVA (Ethylene vinyl-acetate) film and manufacturing method thereof |
-
2016
- 2016-12-01 CN CN201611085061.8A patent/CN106626651A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002067156A (en) * | 2000-08-30 | 2002-03-05 | C I Kasei Co Ltd | Resin tube for steel pipe lining, its manufacturing method, and lining steel pipe |
CN103205212A (en) * | 2013-04-27 | 2013-07-17 | 汕头市安德利环保科技有限公司 | EVA (Ethylene vinyl-acetate) film and manufacturing method thereof |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107400466A (en) * | 2017-09-20 | 2017-11-28 | 天津三瑞塑胶制品有限公司 | A kind of production technology of ultralow medium-temperature reinforced description film |
CN107400468A (en) * | 2017-09-20 | 2017-11-28 | 天津三瑞塑胶制品有限公司 | A kind of production technology of EVA self-adhesions protection film |
CN107400467A (en) * | 2017-09-20 | 2017-11-28 | 天津三瑞塑胶制品有限公司 | A kind of production technology of EVA bathrooms safety door special adhesive |
CN107522935A (en) * | 2017-09-20 | 2017-12-29 | 天津三瑞塑胶制品有限公司 | A kind of production technology of EVA ultraviolet isolatings film |
CN107573865A (en) * | 2017-09-20 | 2018-01-12 | 天津三瑞塑胶制品有限公司 | A kind of anti-production technology for pounding film of EVA cross-linking types |
CN107602997A (en) * | 2017-09-20 | 2018-01-19 | 天津三瑞塑胶制品有限公司 | A kind of production technology of EVA colored solars film |
CN109852292A (en) * | 2019-02-02 | 2019-06-07 | 天津三瑞塑胶制品有限公司 | A kind of production technology of glass plank road special adhesive |
CN109796911A (en) * | 2019-02-22 | 2019-05-24 | 天津三瑞塑胶制品有限公司 | A kind of production technology of shower house professional film |
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Application publication date: 20170510 |