CN107400432A - A kind of furniture aqueous, environmental protective water-proof emulsion and preparation method thereof - Google Patents
A kind of furniture aqueous, environmental protective water-proof emulsion and preparation method thereof Download PDFInfo
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- CN107400432A CN107400432A CN201710732858.0A CN201710732858A CN107400432A CN 107400432 A CN107400432 A CN 107400432A CN 201710732858 A CN201710732858 A CN 201710732858A CN 107400432 A CN107400432 A CN 107400432A
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- environmental protective
- protective water
- proof emulsion
- bactericide
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of furniture aqueous, environmental protective water-proof emulsion and preparation method thereof, it is prepared by the component of following parts by weight：260 500 parts of fluorine-carbon modified acrylate, 80 100 parts of light-weight inorganic acoutic fibre boards, 20 60 parts of mould inhibitors, 2 10 parts of bactericide, 25 parts of defoamers, 13 parts of emulsifying agents, 25 parts of dispersants, 15 20 parts of coalescents and 150 250 parts of deionized waters.The present invention have by adding light-weight inorganic acoutic fibre board, mould inhibitor and bactericide, after emulsion film forming absorbing sound and lowering noise, sound insulation, fire prevention, insect prevention, it is mould proof the characteristics of；Also different inorfil ratios can be adjusted according to the market demand in actual production, the product for adapting to market different demands is made；Organic solvent-free volatilizees the present invention when in use, and construction safety, the feature of environmental protection is good, and emulsion film forming post-tensioning degree is high, and resistance to ag(e)ing, chemical resistance are strong, have good mechanical performance.
Description
Technical field
The present invention relates to paint field, and in particular to a kind of furniture aqueous, environmental protective water-proof emulsion and preparation method thereof.
Background technology
Coating is a kind of more long construction material of history, with the development of society, the species of coating is also more next now
It is more；It is introduced that indoor coating is broadly divided into two kinds of water paint and solvent reducible coatings.Produce the mainly solvent borne of pollution
Coating, and using environmental protection water paint can with altogether dispense with to coating pollute worry.China Association of Coatings Industry expert
Think, any solvent reducible coatings can all contain 50% or more organic solvent.Due to most of solvent reducible coatings and organic molten
All contain Benzene and its compounds in agent, Long Term Contact causes serious harm to human body.Therefore, more and more people like selecting ring
Protect nontoxic water paint.
The quality of buildings waterproof effect, key are whether waterproof material is advanced, science, durable.Traditional waterproof material
Such as pitch oiling felt, there is easy to aging, short life, difficulty of construction is big, cost is high the shortcomings of；Modified bituminous pitch coiled material, APP, SBS
Coiled material, BBI mortar waterproof materials etc. be not ageing-resistant, and water resistance is bad, and after being influenceed by temperature change, coiled material is easily de- with matrix
Open, produce breach and the shortcomings of hollowing, joint is easy to crack.The waterproof principle of these common waterproofing agents is by stopper and nozzle brick stone material
The eyelet of material is invaded with repelling the moisture of outside, because aperture is blocked, causes wall airtight, therefore works as moisture from masonry hole
When gap is discharged, it can break through the waterproof coating on surface, cause the life-span of coating very short.In addition, these materials are building complicated portion
Position is not easy to construct, and technical requirements are high, waste time and energy.In order to protect building, it is necessary to seek a kind of easy construction, can both prevent water
Divide the waterproof material for entering again breathable microporous inside not closed substrate by outside.
It is used for the water-proof emulsion various types for building surface in the market, function is single, and quality is uneven, and some contains
There are the harmful substances such as formaldehyde, benzene, human body and domestic environment can be harmful to using this water-proof emulsion, though some water-proof emulsions do not have
Noxious material, but the shortcomings of poor water resistance, adhesive force is not strong, easily foaming comes off be present, do not reach the effect of waterproof, some is built
Build surface and although carry out water-proofing treatment, but absorbing sound and lowering noise processing must be done again according to customer demand in addition, to owner or enterprise's band
Come no small economy and material damage, while also bring many troubles to client.
The content of the invention
In view of the above-mentioned deficiencies in the prior art, it is an object of the present invention to now provide, one kind is nontoxic, water resistance is strong, is not easy
Foaming comes off, and can realize furniture aqueous, environmental protective water-proof emulsion and preparation method thereof of absorbing sound and lowering noise.
In order to solve the above technical problems, the technical solution adopted by the present invention is：A kind of furniture aqueous, environmental protective water-proof emulsion,
Its innovative point is：It is prepared by the component of following parts by weight：The fluorine-carbon modified acrylate of 260-500 parts, 80-100 parts are light
The inorganic acoutic fibre board of matter, 20-60 parts mould inhibitor, 2-10 parts bactericide, 2-5 parts defoamer, 1-3 parts emulsifying agent, 2-5 parts are disperseed
Agent, 15-20 parts coalescents and 150-250 part deionized waters.
Further, the fluorine-carbon modified acrylate solid content is 50-57%, viscosity 1000-4000Pa.s.
Further, the emulsifying agent is the composite emulsifier of anionic emulsifier and nonionic emulsifier, is compounded
Ratio is 1：2-4.
Further, the anionic emulsifier is sulfo-succinic acid dioctyl sodium salt；The nonionic emulsifier
For isomery C13 AEOs, the sulfo-succinic acid dioctyl sodium salt and isomery C13 AEOs
Compound proportion is 1：1.
Further, the bactericide be coating emulsion bactericidal liquid, defoamer be defoamer N-2, dispersant is dispersant
8045th, one kind in 5040, coalescents are coalescents TEXANOL.
Another object of the present invention is to disclose a kind of preparation method of furniture aqueous, environmental protective water-proof emulsion, its innovative point
It is：Comprise the following steps that：
（1）By light-weight inorganic acoutic fibre board, mould inhibitor, defoamer, emulsifying agent, dispersant, coalescents and deionized water by weight
Measure part proportioning to add in agitator tank, be mixed evenly with rotating speed 200-350r/min, the mixing time is 1-2 hours；
（2）Rotating speed is adjusted to 4000-5000r/min on Multi-functional dispersion machine, stirs 3-4.5 hours, mixture is scattered equal
It is even；
（3）Rotating speed is adjusted to 300-450r/min, is slowly added to fluorine-carbon modified acrylate；
（4）Bactericide is added, is kept stirring for 1-2.5h；
（5）Gauze filters, tinning packaging.
Beneficial effects of the present invention are as follows：
（1）The present invention have by adding light-weight inorganic acoutic fibre board, mould inhibitor and bactericide, after emulsion film forming absorbing sound and lowering noise,
Sound insulation, fire prevention, insect prevention, it is mould proof the characteristics of；Also different inorfil ratios can be adjusted according to the market demand in actual production
Example, the product for adapting to market different demands is made.
（2）Organic solvent-free volatilizees the present invention when in use, and construction safety, the feature of environmental protection is good, and emulsion film forming post-tensioning degree is high,
Resistance to ag(e)ing, chemical resistance are strong, have good mechanical performance.
Embodiment
Embodiments of the present invention are illustrated by particular specific embodiment below, those skilled in the art can be by this explanation
Content disclosed by book understands other advantages and effect of the present invention easily.
Embodiment 1
A kind of furniture aqueous, environmental protective water-proof emulsion, is prepared by the component of following parts by weight：260 parts of fluorine-carbon modified acrylic acid
Ester, 80 parts of light-weight inorganic acoutic fibre boards, 20 parts of mould inhibitors, 2 parts of bactericide, 2 parts of defoamers, 1 part of emulsifying agent, 2 parts of dispersants, 15
Part coalescents and 150 parts of deionized waters.
Fluorine-carbon modified acrylate solid content is 50%, viscosity 1000Pa.s.
Emulsifying agent is the composite emulsifier of anionic emulsifier and nonionic emulsifier, compound proportion 1：2, it is cloudy from
Subtype emulsifying agent is sulfo-succinic acid dioctyl sodium salt；Nonionic emulsifier is isomery C13 AEOs, sulfo group
The compound proportion of succinic acid dioctyl sodium salt and isomery C13 AEOs is 1：1.
Bactericide is coating emulsion bactericidal liquid, defoamer is defoamer N-2, and dispersant is in dispersant 8045,5040
One kind, coalescents are coalescents TEXANOL.
A kind of furniture preparation method of aqueous, environmental protective water-proof emulsion, is comprised the following steps that：
（1）By light-weight inorganic acoutic fibre board, mould inhibitor, defoamer, emulsifying agent, dispersant, coalescents and deionized water by weight
Measure part proportioning to add in agitator tank, be mixed evenly with rotating speed 200r/min, mixing time is 1 hour；
（2）Rotating speed is adjusted to 4000r/min on Multi-functional dispersion machine, stirs 3 hours, mixture is uniformly dispersed；
（3）Rotating speed is adjusted to 300r/min, is slowly added to fluorine-carbon modified acrylate；
（4）Bactericide is added, is kept stirring for 1h；
（5）Gauze filters, tinning packaging.
Embodiment 2
A kind of furniture aqueous, environmental protective water-proof emulsion, is prepared by the component of following parts by weight：500 parts of fluorine-carbon modified acrylic acid
Ester, 100 parts of light-weight inorganic acoutic fibre boards, 60 parts of mould inhibitors, 10 parts of bactericide, 5 parts of defoamers, 3 parts of emulsifying agents, 5 parts of dispersants,
20 parts of coalescents and 250 parts of deionized waters.
Fluorine-carbon modified acrylate solid content is 57%, viscosity 4000Pa.s.
Emulsifying agent is the composite emulsifier of anionic emulsifier and nonionic emulsifier, compound proportion 1：4, it is cloudy from
Subtype emulsifying agent is sulfo-succinic acid dioctyl sodium salt；Nonionic emulsifier is isomery C13 AEOs, sulfo group
The compound proportion of succinic acid dioctyl sodium salt and isomery C13 AEOs is 1：1.
Bactericide is coating emulsion bactericidal liquid, defoamer is defoamer N-2, and dispersant is in dispersant 8045,5040
One kind, coalescents are coalescents TEXANOL.
A kind of furniture preparation method of aqueous, environmental protective water-proof emulsion, is comprised the following steps that：
（1）By light-weight inorganic acoutic fibre board, mould inhibitor, defoamer, emulsifying agent, dispersant, coalescents and deionized water by weight
Measure part proportioning to add in agitator tank, be mixed evenly with rotating speed 350r/min, mixing time is 2 hours；
（2）Rotating speed is adjusted to 5000r/min on Multi-functional dispersion machine, stirs 4.5 hours, mixture is uniformly dispersed；
（3）Rotating speed is adjusted to 450r/min, is slowly added to fluorine-carbon modified acrylate；
（4）Bactericide is added, is kept stirring for 2.5h；
（5）Gauze filters, tinning packaging.
Embodiment 3
A kind of furniture aqueous, environmental protective water-proof emulsion, is prepared by the component of following parts by weight：380 parts of fluorine-carbon modified acrylic acid
Ester, 90 parts of light-weight inorganic acoutic fibre boards, 40 parts of mould inhibitors, 6 parts of bactericide, 3 parts of defoamers, 3 parts of emulsifying agents, 3 parts of dispersants, 17
Part coalescents and 200 parts of deionized waters.
Ethene-vinyl acetate copolymer emulsion solid content is 53%, viscosity 2500Pa.s.
Emulsifying agent is the composite emulsifier of anionic emulsifier and nonionic emulsifier, compound proportion 1：3, it is cloudy from
Subtype emulsifying agent is sulfo-succinic acid dioctyl sodium salt；Nonionic emulsifier is isomery C13 AEOs, sulfo group
The compound proportion of succinic acid dioctyl sodium salt and isomery C13 AEOs is 1：1.
Bactericide is coating emulsion bactericidal liquid, defoamer is defoamer N-2, and dispersant is in dispersant 8045,5040
One kind, coalescents are coalescents TEXANOL.
A kind of furniture preparation method of aqueous, environmental protective water-proof emulsion, is comprised the following steps that：
（1）By light-weight inorganic acoutic fibre board, mould inhibitor, defoamer, emulsifying agent, dispersant, coalescents and deionized water by weight
Measure part proportioning to add in agitator tank, be mixed evenly with rotating speed 270r/min, mixing time is 1.5 hours；
（2）Rotating speed is adjusted to 4500r/min on Multi-functional dispersion machine, stirs 3.7 hours, mixture is uniformly dispersed；
（3）Rotating speed is adjusted to 370r/min, is slowly added to fluorine-carbon modified acrylate；
（4）Bactericide is added, is kept stirring for 1.7h；
（5）Gauze filters, tinning packaging.
The furniture aqueous, environmental protective water-proof emulsion being prepared with reference to embodiment 1, embodiment 2 and embodiment 3, detection performance
Such as following table：
| Bacteriostasis rate（%） | Solid content（%） | Viscosity（mpa.s） | Service life（/ year) | |
| Embodiment 1 | 93 | 54 | 2200 | 18 |
| Embodiment 2 | 93 | 54 | 2500 | 20 |
| Embodiment 3 | 95 | 55 | 2600 | 23 |
As seen from the above table, the solid content for the water-proof emulsion being prepared using embodiment 1, embodiment 2 and the method for embodiment 3, glue
Degree, bacteriostasis rate and service life are superior to the water-proof emulsion that commonsense method is prepared.It is superior to what commonsense method was prepared
Water-proof emulsion.
The present invention have by adding light-weight inorganic acoutic fibre board, mould inhibitor and bactericide, after emulsion film forming absorbing sound and lowering noise,
Sound insulation, fire prevention, insect prevention, it is mould proof the characteristics of；Also different inorfil ratios can be adjusted according to the market demand in actual production
Example, the product for adapting to market different demands is made；Organic solvent-free volatilizees the present invention when in use, and construction safety, the feature of environmental protection is good,
Emulsion film forming post-tensioning degree is high, and resistance to ag(e)ing, chemical resistance are strong, have good mechanical performance.
Above-described embodiment is presently preferred embodiments of the present invention, is not the limitation to technical solution of the present invention, as long as
The technical scheme that can be realized on the basis of above-described embodiment without creative work, it is regarded as falling into patent of the present invention
Rights protection scope in.
Claims (6)
- A kind of 1. furniture aqueous, environmental protective water-proof emulsion, it is characterised in that：It is prepared by the component of following parts by weight：260- 500 parts of fluorine-carbon modified acrylate, 80-100 part light-weight inorganics acoutic fibre board, 20-60 parts mould inhibitor, 2-10 parts bactericide, 2-5 Part defoamer, 1-3 parts emulsifying agent, 2-5 parts dispersant, 15-20 parts coalescents and 150-250 part deionized waters.
- A kind of 2. furniture aqueous, environmental protective water-proof emulsion according to claim 1, it is characterised in that：Described fluorine-carbon modified third Olefin(e) acid ester solid content is 50-57%, viscosity 1000-4000Pa.s.
- A kind of 3. furniture aqueous, environmental protective water-proof emulsion according to claim 1, it is characterised in that：The emulsifying agent is The composite emulsifier of anionic emulsifier and nonionic emulsifier, compound proportion 1：2-4.
- A kind of 4. furniture aqueous, environmental protective water-proof emulsion according to claim 3, it is characterised in that：The anionic breast Agent is sulfo-succinic acid dioctyl sodium salt；The nonionic emulsifier is isomery C13 AEOs, the sulphur The compound proportion of base succinic acid dioctyl sodium salt and isomery C13 AEOs is 1：1.
- A kind of 5. furniture aqueous, environmental protective water-proof emulsion according to claim 1, it is characterised in that：The bactericide is Coating emulsion bactericidal liquid, defoamer are defoamer N-2, and dispersant is one kind in dispersant 8045,5040, coalescents be into Film auxiliary agent TEXANOL.
- A kind of 6. preparation method of furniture aqueous, environmental protective water-proof emulsion as claimed in claim 1, it is characterised in that：Specific step It is rapid as follows：（1）By light-weight inorganic acoutic fibre board, mould inhibitor, defoamer, emulsifying agent, dispersant, coalescents and deionized water by weight Measure part proportioning to add in agitator tank, be mixed evenly with rotating speed 200-350r/min, the mixing time is 1-2 hours；（2）Rotating speed is adjusted to 4000-5000r/min on Multi-functional dispersion machine, stirs 3-4.5 hours, mixture is scattered equal It is even；（3）Rotating speed is adjusted to 300-450r/min, is slowly added to fluorine-carbon modified acrylate；（4）Bactericide is added, is kept stirring for 1-2.5h；（5）Gauze filters, tinning packaging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710732858.0A CN107400432A (en) | 2017-08-24 | 2017-08-24 | A kind of furniture aqueous, environmental protective water-proof emulsion and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710732858.0A CN107400432A (en) | 2017-08-24 | 2017-08-24 | A kind of furniture aqueous, environmental protective water-proof emulsion and preparation method thereof |
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| CN107400432A true CN107400432A (en) | 2017-11-28 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109096850A (en) * | 2018-06-12 | 2018-12-28 | 东莞大宝化工制品有限公司 | A kind of open air metal furniture water paint and preparation method thereof |
| CN109486256A (en) * | 2018-10-16 | 2019-03-19 | 杭州瑞艺户外休闲用品有限公司 | A kind of household plate is changed voice coating and its production technology and household plate of changing voice |
| CN111910465A (en) * | 2020-07-23 | 2020-11-10 | 江苏理文化工有限公司 | Formula of high-performance anionic surface sizing agent |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103740183A (en) * | 2013-11-05 | 2014-04-23 | 张逸飞 | Compound high-viscosity JS waterproof emulsion |
| CN103897522A (en) * | 2014-03-27 | 2014-07-02 | 桂林市和鑫防水装饰材料有限公司 | Water-based environment-friendly non-toxic and harmless elastic waterproof emulsion and preparation method thereof |
| CN105802395A (en) * | 2016-04-07 | 2016-07-27 | 桂林市和鑫防水装饰材料有限公司 | Water-based, environment-friendly, sound-absorbing, noise-reducing, high-elasticity and waterproof emulsion and preparation method thereof |
-
2017
- 2017-08-24 CN CN201710732858.0A patent/CN107400432A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103740183A (en) * | 2013-11-05 | 2014-04-23 | 张逸飞 | Compound high-viscosity JS waterproof emulsion |
| CN103897522A (en) * | 2014-03-27 | 2014-07-02 | 桂林市和鑫防水装饰材料有限公司 | Water-based environment-friendly non-toxic and harmless elastic waterproof emulsion and preparation method thereof |
| CN105802395A (en) * | 2016-04-07 | 2016-07-27 | 桂林市和鑫防水装饰材料有限公司 | Water-based, environment-friendly, sound-absorbing, noise-reducing, high-elasticity and waterproof emulsion and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109096850A (en) * | 2018-06-12 | 2018-12-28 | 东莞大宝化工制品有限公司 | A kind of open air metal furniture water paint and preparation method thereof |
| CN109486256A (en) * | 2018-10-16 | 2019-03-19 | 杭州瑞艺户外休闲用品有限公司 | A kind of household plate is changed voice coating and its production technology and household plate of changing voice |
| CN111910465A (en) * | 2020-07-23 | 2020-11-10 | 江苏理文化工有限公司 | Formula of high-performance anionic surface sizing agent |
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Application publication date: 20171128 |