CN107394205A - Balanced type multiphase graphene-structured battery, its manufacture method and application - Google Patents
Balanced type multiphase graphene-structured battery, its manufacture method and application Download PDFInfo
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- CN107394205A CN107394205A CN201710194985.XA CN201710194985A CN107394205A CN 107394205 A CN107394205 A CN 107394205A CN 201710194985 A CN201710194985 A CN 201710194985A CN 107394205 A CN107394205 A CN 107394205A
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- graphene
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- graphite alkene
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/04—Construction or manufacture in general
- H01M10/0413—Large-sized flat cells or batteries for motive or stationary systems with plate-like electrodes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/04—Construction or manufacture in general
- H01M10/0472—Vertically superposed cells with vertically disposed plates
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
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- Inorganic Chemistry (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
The present invention discloses a kind of balanced type multiphase graphene-structured battery, its manufacture method and application, the graphene-structured battery includes anode graphite alkene, negative electrode graphene and solid electrolyte, solid electrolyte is clamped between anode graphite alkene and negative electrode graphene, it is G lines that a ground wire is drawn on solid electrolyte, it is main track that a wire is drawn on the anode graphite alkene, and it is negative wire to draw a wire on negative electrode graphene；The balanced type multiphase graphene-structured battery of the present invention, the combination of anode graphite alkene, negative electrode graphene and solid electrolyte forms the battery of balanced type power supply, this balanced type battery can produce malleation and negative pressure operated type battery, electric current shows malleation phase and negative pressure phase, that is the functional cells of balanced voltage output, application can reach economical and simple circuit design and circuit pack application on balancing circuitry, so as to reach economic benefit.
Description
Technical field
The present invention relates to graphene application technical field, more particularly to a kind of balanced type multiphase graphene-structured battery and
Its manufacture method.
Background technology
The application of graphene has been global concern, but for the research of graphene, also in the starting stage.Graphene
It is the two-dimentional new material for having very much speciality, however it is mainly in the majority in material addition in the application of this new material, to develop
Deeper and material with feature direction are only the direction of scientific and technological progress, and this requires that band function must be produced on raw material
The material of characteristic.
Anode graphite alkene is formed due to being successfully bumped into metal ion on grapheme two-dimension material lattice, in graphene two
Nonmetallic ion is bumped into dimension material lattice and forms negative electrode graphene, so inventor is marched in terms of battery using this raw material
Development.
People's information is flourishing at present, and electric energy is an irreplaceable energy source use in the application energy of machinery production etc..
In the development of prolonged application electric energy, balance electricity output is most widely used link on circuit.Often to make balance electricity output
When, the frequency conversion of complexity and covert supply line are needed on circuit production, if electric wire all carries Differential Output in itself
With ployphase voltages output battery, in theory circuit design can simplify economization, set because most of circuits need not be increased
Work and electronic component on meter, but also the power consumption needs on circuit can be reduced, harmonic effects caused by circuit are reduced, especially
With influence caused by high-frequency harmonic, the injury of growth stage is done to human health.If using balance electric source, even with multiphase work(
Battery ... the harmonic problem of energy can also greatly reduce and reduce injury, confer benefits on society.
The content of the invention
For weak point present in above-mentioned technology, it is more that the present invention provides the balanced type that a kind of capacity is big, stability is strong
Phase graphene-structured battery, its manufacture method and application.
In order to achieve the above object, a kind of balanced type multiphase graphene-structured battery of the present invention, including anode graphite alkene, the moon
Pole graphene and solid electrolyte, the solid electrolyte is clamped between anode graphite alkene and negative electrode graphene, described
It is G lines that a ground wire is drawn on solid electrolyte, and one wire of extraction is main track on the anode graphite alkene, the negative electrode stone
It is negative wire that a wire is drawn on black alkene；One group of anode graphite alkene is a phase voltage, and one group of negative electrode graphene is a phase
Position voltage, one group of solid electrolyte is a phase voltage, one group of anode graphite alkene, one group of negative electrode graphene and one group of solid-state
Electrolyte combination forms three-phase type Differential Output voltage-phase, N group anode graphites alkene, N group negative electrode graphenes and one group of solid-state
Electrolyte combination forms multiphase formula Differential Output voltage-phase, and N >=2, N group anode graphite alkene is from solid electrolyte to positive extreme direction
Laminated type progressively increases, and N group negative electrode graphenes are progressively increased from solid electrolyte to negative pole direction laminated type.
Wherein, the anode graphite alkene is the anode graphite alkene of the embedded metal ion on graphene lattice.
Wherein, the anode graphite alkene is the anode graphite alkene of the embedded manganese ion on graphene lattice.
Wherein, the negative electrode graphene is the negative electrode graphene of the embedded nonmetallic ion on graphene lattice.
Wherein, the negative electrode graphene is the negative electrode graphene of the embedded boron ion on graphene lattice.
Wherein, the voltage potential of the anode graphite alkene is+1.5V, and the voltage potential of the negative electrode graphene is -1.5V, relatively
One group of anode graphite alkene and one group of negative electrode graphene both ends between voltage potential be 3V.
Invention additionally discloses a kind of manufacture method of balanced type multiphase graphene-structured battery, comprise the following steps：
Anode graphite alkene is chosen as cell positive material, negative electrode graphene is chosen as cell negative electrode material, chooses solid-state electricity
Matter is solved as the dielectric between both positive and negative polarity；
Solid electrolyte is arranged between anode graphite alkene and negative electrode graphene；
Ground wire G lines are drawn from solid electrolyte, main track is drawn from anode graphite alkene, are drawn from negative electrode graphene negative
Line, form basic balanced output circuit structure；
Laminated type increases M group anode graphite alkene outside anode graphite alkene, and laminated type increases M group negative electrode stones outside negative electrode graphene
Black alkene, M >=1 is so as to forming polyphase equilibrium output circuit structure.
Wherein, the anode graphite alkene of selection is the anode graphite alkene of the embedded metal ion on graphene lattice, selection
Negative electrode graphene for the embedded nonmetallic ion on graphene lattice negative electrode graphene, the voltage potential of anode graphite alkene for+
1.5V, the voltage potential of negative electrode graphene is -1.5V, between relative one group of anode graphite alkene and one group of negative electrode graphene both ends
Voltage potential is 3V.
Invention additionally discloses a kind of application of balanced type multiphase graphene-structured battery, apply in terms of telephone emission, especially
It is the balance signal transmitting of the transmitting of balance electric signal and wireless radio transmission on phone.
Invention additionally discloses a kind of application of balanced type multiphase graphene-structured battery, apply on intelligent machine electric appliance material,
Motor power output especially in robot and electric automobile.
The beneficial effects of the invention are as follows：
Compared with prior art, balanced type multiphase graphene-structured battery of the invention, anode graphite alkene, negative electrode graphene and
The combination of solid electrolyte forms the battery of balanced type power supply, and this balanced type battery can produce malleation and negative pressure operated type electricity
Pond, electric current show the functional cells of malleation phase and negative pressure phase, i.e. balanced voltage output, and being applied on balancing circuitry can
To reach economical and simple circuit design and circuit pack application, so as to reach economic benefit.
Brief description of the drawings
Fig. 1 is the structure chart of balanced type multiphase graphene-structured battery of the present invention.
Main element symbol description is as follows：
10th, anode graphite alkene 11, negative electrode graphene
12nd, solid electrolyte.
Embodiment
In order to more clearly state the present invention, the present invention is further described below in conjunction with the accompanying drawings.
Refering to Fig. 1, a kind of balanced type multiphase graphene-structured battery of the present invention, including anode graphite alkene 10, negative electrode graphite
Alkene 11 and solid electrolyte 12, solid electrolyte 12 are clamped between anode graphite alkene 10 and negative electrode graphene 11, solid-state
It is G lines that a ground wire is drawn on electrolyte 12, and one wire of extraction is main track on anode graphite alkene 10, on negative electrode graphene 11
It is negative wire to draw a wire；One group of anode graphite alkene 10 is a phase voltage, and one group of negative electrode graphene 11 is a phase
Voltage, one group of solid electrolyte 12 are a phase voltage, one group of anode graphite alkene, 10, one groups of negative electrode graphenes 11 and one group
The combination of solid electrolyte 12 forms three-phase type Differential Output voltage-phase, N group anode graphites alkene 10, N group negative electrodes graphene 11 with
And one group of combination of solid electrolyte 12 forms multiphase formula Differential Output voltage-phase, N >=2, N group anode graphites alkene 10 is by solid-state electricity
Solution matter 12 is progressively increased to positive pole direction lamination formula, and N group negative electrodes graphene 11 is progressively increased from solid electrolyte 12 to negative pole direction laminated type.
It may be said that the collocation of a lamination of negative electrode and anode is exactly balance+G- structure output, positive pole+1.5V is
One phase voltage, G are a phase voltage, negative pole -1.5V and are a phase voltages.This Trinity is with regard to type into three-phase
Formula Differential Output voltage-phase！If folded outside one positive one negative again, voltage potential can form five phase voltage gesture ... i.e. from three
+ the 1.5V of phase amounts to the positive and negative change of dog days' three-phase voltage one into 6V five phase voltages plus -1.5V.So it is tired push away using 1.5V as
The three-phase voltage on basis is that 3V, five phase voltages are 6V, and that seven phase voltage is exactly 9V！Nine phase voltages reach 12V ... all the way
It is stackable up, so as to reach polyphase equilibrium output purpose.
Compared to prior art, balanced type multiphase graphene-structured battery of the invention, anode graphite alkene 10, negative electrode graphite
The combination of alkene 11 and solid electrolyte 12 forms the battery of balanced type power supply, and this balanced type battery can produce malleation and negative pressure
Operated type battery, electric current shows the functional cells of malleation phase and negative pressure phase, i.e. balanced voltage output, in balancing circuitry
Upper application can reach economical and simple circuit design and circuit pack application, so as to reach economic benefit.
Invention additionally discloses a kind of manufacture method of balanced type multiphase graphene-structured battery, comprise the following steps：
Choose anode graphite alkene 10 and be used as cell positive material, choose negative electrode graphene 11 and be used as cell negative electrode material, choose solid
State electrolyte 12 is as the dielectric between both positive and negative polarity；
Solid electrolyte 12 is arranged between anode graphite alkene 10 and negative electrode graphene 11；
Ground wire G lines are drawn from solid electrolyte 12, main track is drawn from anode graphite alkene 10, draws from negative electrode graphene 11
Go out negative wire, form basic balanced output circuit structure；
In 10 outer laminated type of anode graphite alkene increase M group anode graphites alkene 10, and increase M groups in 11 outer laminated type of negative electrode graphene
Negative electrode graphene 11, M >=1 is so as to forming polyphase equilibrium output circuit structure.
In the present embodiment, the anode graphite alkene 10 of selection is the anode graphite of the embedded metal ion on graphene lattice
Alkene 10, the negative electrode graphene 11 of selection are the negative electrode graphene 11 of the embedded nonmetallic ion on graphene lattice, anode graphite
The voltage potential of alkene 10 is+1.5V, and the voltage potential of negative electrode graphene 11 is -1.5V, relative one group of anode graphite alkene 10 and one group
Voltage potential between the both ends of negative electrode graphene 11 is 3V.
Because application negative electrode graphene 11 and anode graphite alkene 10 are made active supplying cell and can produced solely in terms of making
There is the Differential Output battery with malleation and suction type, the balance of balance electric signal and wireless radio transmission especially in phone application
Signal is launched！Known to factually trampling, the transmitting circuit for launching signal utilizes the bridge joint mode of Differential Output（BTL bridge circuits）, can
Transmitted than original transmitting up to as many as four times.I.e. original wireless transmission design is one kilometer of remote wireless remote control, has used balance
The battery of output, BTL circuit transmissions are directly used, can reach four kilometers and shake control scope.Balance electricity output scheme is demonstrated,
Easily do the power effect in terms of multiple.
We have known very well the advantage and feature functionally of balanced type power supply, solve Differential Output on many power supplys again and ask
Topic, so as to utilize Differential Output relation, it can more develop the battery of polyphase equilibrium power supply.The battery of polyphase equilibrium output, no
But can solve the problem that the application in terms of transmitting, can also solve the application on many intelligent electromechanical equipment, especially robot and
Motor applications in terms of electric automobile.Say first and motor is required in itself：The motor of the past is transformed into fast due to start at a slow speed
Speed and accelerate etc. to act in technique, promoted man invented and production frequency converter, but the appearance of frequency converter, it is covert by that time
Frequency conversion development is developed into, high frequency in a disguised form development etc. has been arrived to today, has more or less all brought harmonic problem appearance, influence people
The destruction of class health and circuit unit, to for today, or a sciences problems.If the existing balanced type power supply in power supply
Output, and be not required to largely become phase inverter circuit, the power supply that has been exported with polyphase equilibrium, problem itself just solves.We
The battery system of this polyphase equilibrium is invented, the battery main mode in future and the new technology of output main stream application must be turned into
Application technology.
Scheme above is all to bring very brand-new application scheme, and the rapidity of graphene in following battery applications
Charge characteristic, can be to solve current charging bottleneck problem in future again.Because we can correspond to every group of the small voltage side of charging respectively
Formula, or serially connected charging modes, or utilize multiphase BTL charging modes.So the graphene battery of multiphase formula structure, is future
Simple and quick charge is brought convenience, or even develops into the development of the wireless quick charge in future.
Disclosed above is only several specific embodiments of the present invention, but the present invention is not limited to this, any ability
What the technical staff in domain can think change should all fall into protection scope of the present invention.
Claims (10)
1. a kind of balanced type multiphase graphene-structured battery, it is characterised in that including anode graphite alkene, negative electrode graphene and consolidate
State electrolyte, the solid electrolyte are clamped between anode graphite alkene and negative electrode graphene, are drawn on the solid electrolyte
It is G lines to go out a ground wire, and it is main track that a wire is drawn on the anode graphite alkene, and one is drawn on the negative electrode graphene
Wire is negative wire；One group of anode graphite alkene is a phase voltage, and one group of negative electrode graphene is a phase voltage, one group of solid-state
Electrolyte is a phase voltage, and one group of anode graphite alkene, one group of negative electrode graphene and one group of solid electrolyte combine to be formed
Three-phase type Differential Output voltage-phase, N group anode graphites alkene, N group negative electrode graphenes and one group of solid electrolyte combine to be formed
Multiphase formula Differential Output voltage-phase, N >=2, N group anode graphite alkene are progressively increased from solid electrolyte to positive pole direction lamination formula, N groups
Negative electrode graphene is progressively increased from solid electrolyte to negative pole direction laminated type.
2. balanced type multiphase graphene-structured battery according to claim 1, it is characterised in that the anode graphite alkene is
The anode graphite alkene of embedded metal ion on graphene lattice.
3. balanced type multiphase graphene-structured battery according to claim 2, it is characterised in that the anode graphite alkene is
The anode graphite alkene of embedded manganese ion on graphene lattice.
4. balanced type multiphase graphene-structured battery according to claim 2, it is characterised in that the negative electrode graphene is
The negative electrode graphene of embedded nonmetallic ion on graphene lattice.
5. balanced type multiphase graphene-structured battery according to claim 4, it is characterised in that the negative electrode graphene is
The negative electrode graphene of embedded boron ion on graphene lattice.
6. balanced type multiphase graphene-structured battery according to claim 4, it is characterised in that the anode graphite alkene
Voltage potential is+1.5V, and the voltage potential of the negative electrode graphene is -1.5V, relative one group of anode graphite alkene and one group of negative electrode stone
Voltage potential between black alkene both ends is 3V.
7. a kind of manufacture method of balanced type multiphase graphene-structured battery, it is characterised in that comprise the following steps：
Anode graphite alkene is chosen as cell positive material, negative electrode graphene is chosen as cell negative electrode material, chooses solid-state electricity
Matter is solved as the dielectric between both positive and negative polarity；
Solid electrolyte is arranged between anode graphite alkene and negative electrode graphene；
Ground wire G lines are drawn from solid electrolyte, main track is drawn from anode graphite alkene, are drawn from negative electrode graphene negative
Line, form basic balanced output circuit structure；
Laminated type increases M group anode graphite alkene outside anode graphite alkene, and laminated type increases M group negative electrode stones outside negative electrode graphene
Black alkene, M >=1 is so as to forming polyphase equilibrium output circuit structure.
8. the manufacture method of balanced type multiphase graphene-structured battery according to claim 7, it is characterised in that selection
Anode graphite alkene is the anode graphite alkene of the embedded metal ion on graphene lattice, and the negative electrode graphene of selection is in graphene
The negative electrode graphene of embedded nonmetallic ion on lattice, the voltage potential of anode graphite alkene are+1.5V, the voltage potential of negative electrode graphene
For -1.5V, the voltage potential between relative one group of anode graphite alkene and one group of negative electrode graphene both ends is 3V.
9. a kind of application of balanced type multiphase graphene-structured battery, it is characterised in that apply in terms of telephone emission, especially
The balance signal transmitting of the transmitting of balance electric signal and wireless radio transmission on phone.
10. a kind of application of balanced type multiphase graphene-structured battery, it is characterised in that apply on intelligent machine electric appliance material, especially
It is the motor power output in robot and electric automobile.
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| CN201710194985.XA CN107394205A (en) | 2017-03-29 | 2017-03-29 | Balanced type multiphase graphene-structured battery, its manufacture method and application |
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| CN201710194985.XA CN107394205A (en) | 2017-03-29 | 2017-03-29 | Balanced type multiphase graphene-structured battery, its manufacture method and application |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103570009A (en) * | 2013-09-30 | 2014-02-12 | 宁波墨西科技有限公司 | Graphene capable of efficiently adsorbing organic substances and regeneration method thereof |
| CN104555999A (en) * | 2014-11-18 | 2015-04-29 | 中国科学院山西煤炭化学研究所 | Porous graphene and graphene quantum dot and preparation method of porous graphene and graphene quantum dot |
| CN105621393A (en) * | 2014-11-28 | 2016-06-01 | 中国科学院大连化学物理研究所 | Functionalized graphene material, and preparation method and application thereof |
| CN105895907A (en) * | 2016-06-22 | 2016-08-24 | 湛江市聚鑫新能源有限公司 | Graphene composite ternary cathode material and preparation method and application thereof |
-
2017
- 2017-03-29 CN CN201710194985.XA patent/CN107394205A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103570009A (en) * | 2013-09-30 | 2014-02-12 | 宁波墨西科技有限公司 | Graphene capable of efficiently adsorbing organic substances and regeneration method thereof |
| CN104555999A (en) * | 2014-11-18 | 2015-04-29 | 中国科学院山西煤炭化学研究所 | Porous graphene and graphene quantum dot and preparation method of porous graphene and graphene quantum dot |
| CN105621393A (en) * | 2014-11-28 | 2016-06-01 | 中国科学院大连化学物理研究所 | Functionalized graphene material, and preparation method and application thereof |
| CN105895907A (en) * | 2016-06-22 | 2016-08-24 | 湛江市聚鑫新能源有限公司 | Graphene composite ternary cathode material and preparation method and application thereof |
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Application publication date: 20171124 |
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