It is a kind of can be resistant to high pressure from control type protector and preparation method thereof
Technical field
The present invention relates to it is a kind of can be resistant to high pressure from control type protector and preparation method thereof, category use for electronic products from
Control type protects component, and component is protected from control type especially suitable for lithium ion battery protection.
Background technology
Lithium ion battery since the advent of the world, in portable mobile apparatus such as mobile phone, notebook, tablet personal computer, digital cameras
In applied in large quantities, it is and just many in electric automobile, electric bicycle, unmanned plane, sweeper, electrodynamic balance car etc.
Application in new field.While lithium ion battery has various advantages energy, but still there is easy catching fire, quick-fried
The shortcomings of fried, particularly when being applied on electric car, because it is very huge using the quantity or volume of lithium ion battery, once
Generation is burnt or blast, or even has the danger for injuring life.
The charge and discharge protecting loop of widely used two-stage of lithium ion battery or more at present.First class of protection is added using IC mostly
MOSFET, it can substantially play every protection such as normal excessively stream, overvoltage, anti-reverse charging.But once first class of protection fails(Although this
Kind probability very little, but also still have this possibility), it is necessary to second class protection plays necessary protective effect.Second class protection is more
MOSFET is added, from a variety of components such as control type protector using PTC, Breaker, SMD Fuse, Thermal Cutoffs, IC.On
State component only has over-pressed safeguard function from control type protector substantially.
In the market from control type protector, determined by the battery core quantity of the lithium ion battery of its corresponding protection
Its model, different application scenarios have different size of protection voltage requirements, cause the model from control protector especially numerous and diverse
(From 1 string to 14 strings etc.), in actual use material easily malfunction.Has producer on the market using low string number from control type
Protector is applied to high pressure scene, reduces material procurement model.According to formula P=U2/ R, voltage is bigger, and heating power is bigger, more
Be advantageous to main conductive circuit(6)Fuse protection battery core, but have been found that heating layer hinders under high heating power in practical application
It is worth the PTC effects risen.
So market need it is a kind of can be resistant to high pressure from control type protector, you can to realize over-voltage protecting function again
High pressure scene can be used for low string number model, reduce material model.
The content of the invention
Present invention aims at provide it is a kind of can be resistant to high pressure from control type protector,
Another object of the present invention is:A kind of preparation from control type protector that can be resistant to high pressure is provided.
The object of the invention is realized by following proposal:It is a kind of can be resistant to high pressure from control type protector, including ceramics
Substrate, electrode, insulating barrier and main conductive circuit, wherein:Described ceramic substrate for rectangle, on four sides of the ceramic substrate
On be arranged with electrode one, two, three and four, the relative electrode of one pair of which is at least connected with a heating layer, on the heating layer
Provided with insulating barrier, electrode layer is covered with the insulating layer;Barrier layer is provided with least on another pair electrode, in electrode layer and barrier layer
Between connect main conductive circuit by way of welding or printing and sinter, on the main conductive circuit coat fluxing agent after will be upper
Lid is bonded in above described ceramic substrate.
The present invention has the function of conventional power current fuse, while the function of having autonomous control main conductive circuit to fuse.It is special
It is not that the design of heating layer uses parallel connection, series connection or the parallel connection of lamination side by side etc. mode, is ensureing that overall resistance is constant
In the case of, increase the resistance of a certain resistive layer or reduce resistive layer and bear voltage per unit, reach electricity when reduction is powered
The hot face temperature of resistance layer, so as to lift total withstanding voltage of product, and then realize the low string number from control type protector
Model is common to high voltage protection scene.
Ceramic substrate thickness of the present invention is not more than 0.5mm.It can be process with thin ceramic baseplate material, can be with
Be aluminum oxide, zirconium oxide etc. be primary raw material base material it is stamped or laser cutting etc. technique be processed into thickness in below 0.5mm
Ceramic substrate.
Two can be provided with described ceramic substrate or more than two heating layers are in parallel with parallel, series connection or lamination
Form, such as:Can be two resistive layers composing in parallel side by side, or more than two resistive layers being composed in series side by side,
Or more than two resistance layer laminates compose in parallel form and are connected to on a pair of comparative electrodes.
Described ceramic substrate sets the first heating layer, sets the second heating layer on described upper lid, the opposite side covered on described
A pair of electrodes is provided with, the second heating layer is connected to this and described pottery is bonded in after the second insulating barrier on electrode, being then covered with
Porcelain surface.To protect internal components.
Present invention offer is a kind of according to the above-mentioned preparation method from control type protector that can be resistant to high pressure, according to following
Step:
1)The surface of ceramic substrate symmetrical printed conductor slurry along four sides, the and of electrode one, two, three is formed after high temperature sintering
Four;
2)The printed resistor slurry between electrode three and four, forms heating layer after high temperature sintering;
3)The printed medium slurry above heating layer, insulating barrier is formed by high temperature sintering;
4)Square printed conductor slurry on the insulating layer, electrode layer is formed by high temperature sintering;
5)Either sputtering or sprays insulating material are printed on electrode one and two, high temperature sintering is used according to insulating materials species
Or low-temperature setting forms barrier layer one, two;
6)Main conductive circuit is connected by way of welding or printing and sinter between electrode layer and barrier layer one, two, in master
Fluxing agent is added above galvanic circle or does not add fluxing agent;
7)Bond and cover above ceramic substrate.
Conductor paste can be printed on after ceramic substrate and be formed after high temperature sintering by electrode using silk screen printing process, conductor paste
It can be made up of the one or more of the metal with good conductivity such as silver, platinum, palladium, gold, copper, zinc, aluminium and its oxide
Resistance slurry is printed on after ceramic substrate and formed after high temperature sintering by heating layer using silk screen printing process, and resistance slurry can be with
Ruthenium base, platinum base, one or more compositions of palladium base, heating layer can be two or more resistive layer side by side and
Connection composition, or two or more resistive layers being composed in series side by side, also or two or more resistance
Layer laminate composes in parallel.By such design in the case where ensureing that overall resistance is constant, increase a certain resistive layer resistance or
Person reduces resistive layer and bears voltage per unit, reaches the hot face temperature for reducing resistive layer when being powered, so as to lift product
Total withstanding voltage.
After dielectric paste is printed on ceramic substrate by described insulating barrier with silk screen printing process, formed after high temperature sintering.It is situated between
Chylema material can be that the inorganic non-metallic such as glass paste, ceramic slurry, glass glaze insulating materials is formed.
Described barrier layer can be lines, can be annulus, also or other irregular shapes.According to the material of selection
Difference, can either insulating materials be covered in electrode one, two, three and four by spraying coating process or sputtering technology with silk screen printing process
On, insulating materials can be the solder resist materials such as dielectric paste, solder mask, insulating resin.Reflow Soldering attachment can be crossed in product
Shi Youxiao prevents to climb tin influence main conductive circuit, so as to which safety crosses Reflow Soldering.
Described main conductive circuit can be macromolecular PTC thermistor, bimetal leaf, low-melting alloy(Such as bismuth indium tin
Alloy), high-melting-point alloy(Such as tin-lead, Xi Yin, mischzinn), fuse-link metal material(Silver, platinum, palladium, gold, copper, zinc, aluminium
Etc. metal with good conductivity and its oxide), surface mount pattern electrical fuse element etc. or alloy surface it is silver-plated
Or tin plating composite alloy.
Described fluxing agent, it is different according to design, the melting of maleic rosin Ester can be selected to be covered in leading electricity and returned
On road or diameter < 0.15mm silver-coated copper wire or nickel wire etc. are inhaled solder and are welded on above main conductive circuit.
Described upper lid selection has the characteristics that fire-retardant, high temperature resistant material, can be industrialization liquid crystal polymer LCP,
Also or ceramic substrate, epoxy resin board etc. material.
The present invention is advantageous in that:Not only there is the function of conventional power current fuse, while have the leading electricity of autonomous control
The function of loop fusing.Especially by heating layer structure design, in the case where ensureing that overall resistance is constant, increase a certain electricity
The resistance of resistance layer or the hot face temperature for bearing voltage, reaching resistive layer when reducing energization for reducing the every unit of resistive layer,
So as to lift total withstanding voltage of product, and then realize from the low string number model of control type protector and be common to high voltage protection
Scene.
Brief description of the drawings
Electrode one, two, three, four has been printed on Fig. 1 ceramic substrates;
Fig. 2 is connected with side by side and first, second heating layer in parallel between electrode three and electrode four;
Fig. 3 is covered with insulating barrier on first, second heating layer;
Fig. 4 is respectively equipped with barrier layer one, two on electrode one, two;
Fig. 5 has electrode layer on the insulating layer;
Fig. 6 is connected to main conductive circuit between electrode layer and barrier layer one, two;
Fig. 7 helps flux layer on the basis of Fig. 6 on main conductive circuit;
Fig. 8 prints electrode six, seven on upper lid in face of title;
Fig. 9 connects the second heating layer between electrode six, seven, and is covered with insulating barrier on the second heating layer;
The heating layers of Figure 10 first, second have been connected in series between side by side between electrode three and electrode four;
The heating layers of Figure 11 first, second are laminations and parallel form is connected between electrode three and electrode four;
The heating layers of Figure 12 first, second are respectively provided on ceramic substrate and upper lid.
Label declaration in figure:
11st, 12,13,14 --- electrode one, two, three, four;
15 --- electrode layer;
16th, 17 --- electrode six, seven;
2 --- ceramic substrate;
31st, 31 ', 31 ' ', 31 ' ' ' --- the first heating layer;
32nd, 32 ', 32 ' ', 32 ' ' ' --- the second heating layer;
4 --- insulating barrier;41st, 42 --- first, second-insulating barrier;
51st, 52 --- barrier layer one, two;
6 --- main conductive circuit;
7 --- fluxing agent;8 --- upper lid.
Embodiment
Embodiment 1
As printed on Fig. 1 ceramic substrates electrode one, two, three, four, Fig. 2 be connected between electrode three and electrode four side by side and
First, second heating layer in parallel, Fig. 3 are covered with insulating barrier on first, second heating layer, and Fig. 4 is set respectively on electrode one, two
There are barrier layer one, two and Fig. 5 to have on the insulating layer shown in electrode layer:
As shown in figure 1, electrode one, two, three, 4 11,12,13,14 is printed with ceramic substrate 2.
As shown in Fig. 2,3,4,5, passed through after resistance slurry is printed on into ceramic substrate 2 between electrode 3 13 and electrode 4 14
Formed with resistive layer as first, second heating layer 31,32 after high temperature sintering, the first heating layer 31 and the second heating layer 32 are simultaneously
Arrange and parallel form is connected between electrode 3 13 and electrode 4 14.Insulating barrier 4 is printed on first, second heating layer 31,32,
Barrier layer 1 and barrier layer 2 52 have been printed respectively on electrode 1 and electrode 2 12, and print electrode layer on insulating barrier 4
15。
As Fig. 6 is connected to main conductive circuit and Fig. 7 on the basis of Fig. 6 leading between electrode layer and barrier layer one, two
Helped on electrical circuit shown in flux layer:Print solder paste welding alloy forms master between electrode layer 15 and barrier layer one, 2 51,52
Galvanic circle 6, it is fluxing rosin that fluxing agent 7 has been added on alloy, then, can be on ceramic substrate 2 to protect interiors of products
Covered in bonding.
Such as, it is assumed that keep the total resistance of heating layer(5Ω)In the case of constant, two resistive layer resistances can all be 10 Ω,
In the case where the voltage at the techniques such as the thickness material of resistive layer with loading both ends is constant, resistive layer hot face temperature declines
20-50%
Under the case, there can also be heating layer for three and its mutation situation of above number.
Embodiment 2
Other are same as Example 1 for the present embodiment, simply if the heating layers one, two of Figure 10 first, second are cascades side by side
Shown in being connected between electrode three and electrode four, heating layer structure design is different.
As shown in figure 1, electrode one, two, three, 4 11,12,13,14 is printed on ceramic substrate 2.
As shown in Figure 10,3,4,5, printed between electrode 3 13 and electrode 4 14 first, second heating layer 31 ',
32 ', first, second heating layer 31 ', 32 ' is side by side and is connected in series between electrode 3 13 and electrode 4 14.
First, be printed with insulating barrier 4 on the second heating layer 31 ', 32 ', printed respectively on electrode one, 2 11,12 barrier layer one, 2 51,
52, print electrode layer 15 on insulating barrier 4.
As shown in Figure 6,7, between electrode layer 15 and barrier layer one, 2 51,52 print solder paste welding alloy formed it is leading
Electrical circuit 6, fluxing rosin 7 is added on alloy.To protect interiors of products, lid 8 can be bonded on ceramic substrate 2.
Such as, it is assumed that keep the total resistance of heating layer(5Ω)In the case of constant, two resistive layer resistances can all be 2.5 Ω,
In the case where the voltage at the techniques such as the thickness material of resistive layer with loading both ends is constant, resistive layer hot face temperature declines
10-30%。
Under the case, there can also be heating layer for three and its mutation situation of above number.
Embodiment 3
Other are same as Example 1 for the present embodiment, simply if the heating layers one, two of Figure 11 first, second are lamination and parallel form
Shown in being connected between electrode three and electrode four, heating layer structure design is different.
As shown in figure 1, electrode one, two, three, 4 11,12,13,14 is symmetrically printed on ceramic substrate 2.
As shown in Figure 11,3,4,5, first, second heating layer 31 ' is printed between electrode three, 4 13,14 ', 32 ' ',
First, the second heating layer 31 ' ', 32 ' ' is lamination and parallel form is connected between electrode three, 4 13,14.In first, second hair
Insulating barrier 4 is printed on thermosphere 31 ' ', 32 ' ', barrier layer one, 2 51,52 is printed respectively on electrode one, 2 11,12, is insulating
Print electrode layer 15 on layer 4.
As shown in Figure 6,7, between electrode layer 15 and barrier layer one, 2 51,52 print solder paste welding alloy formed it is leading
Electrical circuit 6, fluxing rosin 7 is added on alloy.To protect interiors of products, lid 8 is bonded on ceramic substrate 2.
Such as, it is assumed that keep the total resistance of heating layer(5Ω)In the case of constant, two resistive layer resistances can be 8 Ω and 6
Ω, in the case where the voltage at the techniques such as the thickness material of resistive layer with loading both ends is constant, under resistive layer hot face temperature
10-15% drops.
Embodiment 4
Other are same as Example 1 for the present embodiment, simply if the heating layers of Figure 12 first, second are to be respectively provided at ceramic substrate and upper
Cover.
As shown in figure 1, respectively symmetrically print electrode one, two, three, 4 11,12 on four sides of rectangle on ceramic substrate 2,
13,14.
As shown in Figure 12,3,4,5, the first heating layer 31 ' is printed between electrode three, 4 13,14 ' ', in the first heating layer
31 ' ' the first insulating barrier 41 is printed on ', barrier layer one, 2 51,52 is printed respectively on electrode one, 2 11,12, in insulating barrier 4
On print electrode layer 15.
As shown in Figure 6,7, between electrode layer 15 and barrier layer one, 2 51,52 print solder paste welding alloy formed it is leading
Electrical circuit 6, fluxing rosin 7 is added on alloy.
As Fig. 8 connects the second heating layer in face of title six, the seven and Fig. 9 that prints electrode on upper lid between electrode six, seven, and
It is covered with the second heating layer shown in insulating barrier, symmetrically prints electrode six, 7 16,17 on upper lid 8, on electrode six, seven
Print the second heating layer 32 ' ' ', the second insulating barrier 42 is printed on the second heating layer, finally bonds and covers on ceramic substrate 2
8, effectively to protect interiors of products structure.