CN107385894A - A kind of plant base anti-UV fabric finishing agent and its preparation technology - Google Patents
A kind of plant base anti-UV fabric finishing agent and its preparation technology Download PDFInfo
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- CN107385894A CN107385894A CN201710695183.7A CN201710695183A CN107385894A CN 107385894 A CN107385894 A CN 107385894A CN 201710695183 A CN201710695183 A CN 201710695183A CN 107385894 A CN107385894 A CN 107385894A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/11—Compounds containing epoxy groups or precursors thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/05—Cellulose or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/59—Polyamides; Polyimides
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
Abstract
The invention discloses a kind of plant base anti-UV fabric finishing agent and its preparation technology, the anti-UV fabric finishing agent includes the component of following parts by weight：Violet extract, lichens extract, bupleurum extract, bamboo extractive, Gentrin Knotweed P.E, Sage extract, vermiculite power, poly-aspartate, nano micro crystal cellulose, Aerosol OT, polyvinyl butyral resin, APG, polysorbate60, water.Fabric finishing agent prepared by the present invention is not only green, and possesses good uvioresistant performance, meet national relevant regulations standard, the fabric finishing agent possesses good water resistance simultaneously, after water-based 80 times, its uv resistance can remain at higher level, in addition, the fabric that the finishing agent arranges has to good gas permeability, wearability is good.
Description
Technical field
The invention belongs to technical field of textile chemical engineering, and in particular to a kind of plant base anti-UV fabric finishing agent and its preparation
Technique.
Background technology
In order to improve textile wearability, meet people to quality of textile products the needs of increasingly improving, improve textile
Quality generally requires to arrange textile using function additive etc., textile is had good uviolresistance, wrinkle resistant
Property, washability, shrinkproof water-based, easy-care properties, felt proofing, mothproof, antistatic behaviour etc..
In broad terms, fabric is to confer to the one or several kinds chemistry of the special wearability of textile with function additive
Additive, it is the importance for lifting textile added value.It can generally divide according to its function classification, the function additive of textile
For color fixing agent, softening agent, ultra-violet absorber, ultraviolet light screener, crease proofing agent, antistatic additive etc..
Generally, excessive ultraviolet（200-400nm）There is certain harm to fabric, dyed fabric fiber is excessive ultraviolet
Easily degraded under the radiation of line, substantially reduce its performance, and the dyestuff on fabric is chronically exposed to print and dye under daylight and held
Easily occur to fade and coloured light becomes phenomenon, substantially reduce the service life of fabric.In addition, ultraviolet human body skin is also produced it is larger
Injury, especially in summer, in order to reduce injury of the ultraviolet to skin, people are also increasingly heavy to the anti-ultraviolet function of fabric
Depending on.Generally, ultraviolet is irradiated on fabric, and these ultraviolets can respectively be partly absorbed, be reflected and be through, if knitting
Thing increases to the absorptivity and reflectivity of ultraviolet, then its transmitance is lower, and uvioresistant barrier propterty is better.Fabric uvioresistant
The mechanism of action be exactly to utilize ultraviolet absorber or ultraviolet light screener, by the absorption or reflection to ultraviolet, so as to play
To the protective action of human body.
Prior art, mainly there are benzophenone, benzotriazole, substitution triazines for fabric ultra-violet absorber
With group-substituted acrylonitrile etc..And mainly utilize zinc oxide, titanium dioxide, iron oxide, ceramics with ultraviolet light screener for fabric
The fine particles such as powder are implemented in combination with to ultraviolet reflection with fiber or fabric.But these organic uv absorbers may be brought
The problems such as human safety and environmental pollution；And the adhesion of these inorganic UV screeners and textile fabric is small, using passing through
Adhesive attachment not only increases cost in fabric face, and substantially reduce the fabric after arranging flexibility, gas permeability,
In terms of the human body comforts such as hygroscopicity, feel, drapability and washability.
Patent CN101215780A discloses a kind of knitted fabric pure natural ultra-violet radiation resisting finishing method, and it is celestial with plant
People's palm is prepared for pure plant uvioresistant finishing agent for raw material, after the dyed processing of bafta, resists containing pure plant
It is arranged using dipping method in the dressing liquid of ultraviolet finishing agent, the bafta after arrangement possesses strong and lasting
Ultra-violet radiation resisting function, it has good ecological environment compatibility, but the uvioresistant performance of the fabric through its arrangement is simultaneously
It is bad.
The content of the invention
It is an object of the invention to provide a kind of plant base anti-UV fabric finishing agent and its preparation technology, to solve with up to
A kind of few technical problem.
Technical scheme is come as follows：
A kind of plant base anti-UV fabric finishing agent, include the component of following parts by weight：Violet extract 5-16 parts, lichens carry
Take thing 2-6.5 parts, bupleurum extract 0.4-3 parts, bamboo extractive 0.7-2.5 parts, Gentrin Knotweed P.E 1.2-3.6 parts, Salvia japonica
Extract 0.6-2.2 parts, vermiculite power 1.3-3 parts, poly-aspartate 2.1-4.2 parts, nano micro crystal cellulose 0.8-3 parts, amber
Sour di-isooctyl sodium sulfonate 2.6-4 parts, polyvinyl butyral resin 0.7-2.3 parts, APG 1.1-3.5 parts, Tween-60
0.8-2.6 parts, water 120-180 parts；
The violet extract includes violet petal extract and violet seed extract；
The preparation process of the violet extract is：
1）Violet petal and violet seed are cleaned and are placed in soaking 24h in 3-5 times of water, then filter the first filtrate and
First filter material；
2）First filtrate and the filter material of half first are mixed and added into 5-8 times of decocting to boil twice, obtain filter residue and the second filtrate, will
Filter residue is placed in 55wt.% ethanol solutions soak 40min after is placed in micro-wave oven and heats 15min, filter, collect and with second
Filtrate merges；The filtrate of merging is concentrated into thick paste, and upper macroporous adsorbent resin column chromatography, first with distillation water elution, removes the
Eluent, then eluted with 45wt.% ethanol solutions, eluent is collected, then adds the 65wt.% ethanol of 6 times of parts by weight, it is quiet
Alcohol precipitation is put, filters, obtains filtrate I and the 3rd filtrate；The 85wt.% ethanol of 10 times of parts by weight is added into the 3rd filtrate, it is quiet
Alcohol precipitation is put, takes supernatant, after concentration, spray drying, filtrate II is obtained, merges filtrate I and filtrate II, be freeze-dried,
Obtain extract I；
3）Remaining first filter material is dried and crushed, is subsequently placed in 20-100U/mL cellulase solutions, in neutrallty condition
Lower room temperature places 6-24h, then filtering and filter residue is added into the mass ratioes of 10-20 times of parts by weight is 1:1 ~ 3 ethyl acetate and
In alcohol mixed solution, ultrasonic disperse 120min, 2-6h then is heated to reflux at 60 DEG C, cools down and filter, recovery filtrate is simultaneously
Freeze-drying, obtains extract II；
4）Extract I and extract II are well mixed, produce violet extract.
In above-mentioned technical proposal, the lichens extract, bupleurum extract, bamboo extractive, Gentrin Knotweed P.E, Salvia japonica
The extracting method of each extract of extract is as follows：
The extraction step of the lichens extract is：Lichens is placed in the 50-80wt.% ethanol solutions of 15-30 times of parts by weight,
3-6h is extracted at 50-70 DEG C, extracts 2-4 times, is concentrated under reduced pressure, is freeze-dried, produces lichens extract；
The extraction step of the bupleurum extract is：Radix bupleuri is placed in the water of 6-15 times of parts by weight, decocts 2h, extracted 3-5 times,
It is concentrated under reduced pressure, is freeze-dried, produces bupleurum extract；
The extraction step of the leaf of bamboo, giant knotweed and Sage extract is：The leaf of bamboo, giant knotweed or Salvia japonica are taken respectively, after drying
Crush, be subsequently placed in 20-40wt.% acetone solns, 1-3h is extracted at 50-70 DEG C and is extracted 2-4 times, filtering, is depressurized dense
Contracting, freeze-drying, is produced.
In above-mentioned technical proposal, the particle diameter of the vermiculite power is 0.1-1um.
In above-mentioned technical proposal, include the component of following parts by weight：Violet extract 6-14 parts, lichens extract 2.3-
6 parts, bupleurum extract 0.8-2.4 parts, bamboo extractive 0.9-2.1 parts, Gentrin Knotweed P.E 1.5-3.3 parts, Sage extract
1-2.1 parts, vermiculite power 1.5-2.6 parts, poly-aspartate 2.3-4 parts, nano micro crystal cellulose 1.2-2.7 parts, butanedioic acid two are different
Dioctyl sodium sulfosuccinate 2.8-3.6 parts, polyvinyl butyral resin 0.8-2 parts, APG 1.6-3.2 parts, Tween-60 1-2.5 parts,
Water 130-160 parts.
In above-mentioned technical proposal, include the component of following parts by weight：12 parts of violet extract, 5.4 parts of lichens extract,
1.9 parts of bupleurum extract, 1.4 parts of bamboo extractive, 2.6 parts of Gentrin Knotweed P.E, 1.8 parts of Sage extract, vermiculite power 2.3
Part, 3.6 parts of poly-aspartate, 1.7 parts of nano micro crystal cellulose, 3.4 parts of Aerosol OT, polyvinyl alcohol contracting fourth
1.5 parts of aldehyde, 2.5 parts of APG, 1.8 parts of Tween-60,155 parts of water.
Another technical scheme of the present invention is come as follows：
A kind of preparation technology of plant base anti-UV fabric finishing agent, comprises the following steps：
Nano micro crystal cellulose and APG are added to the water, ultrasonic disperse 30min, then magnetic agitation 2-4h, then add
Violet extract, lichens extract, bupleurum extract, bamboo extractive, Gentrin Knotweed P.E, Sage extract, poly- asparagus fern
Propylhomoserin and Tween-60, high-speed stirred 20-50min, then add vermiculite power, Aerosol OT, polyvinyl alcohol contracting
Butyraldehyde, high-speed stirred 15-30min, ultrasonic degassing process 5-30min, then high-speed stirred 5-30min, is produced.
As a result of above technical scheme, beneficial effects of the present invention are：
Fabric finishing agent prepared by the present invention is not only green, and possesses good uvioresistant performance, meets national phase
Required standard is closed, while the fabric finishing agent possesses good water resistance, after water-based 80 times, its uv resistance can be protected still
Hold in higher level, in addition, the fabric that the finishing agent is arranged has a good gas permeability, wearability is good.
Embodiment
With reference to specific embodiment, the present invention is described in further detail.Following examples are used to illustrate the present invention,
But it is not limited to the scope of the present invention.
Embodiment 1
A kind of plant base anti-UV fabric finishing agent, include the component of following parts by weight：5 parts of violet extract, lichens extraction
2 parts of thing, 0.4 part of bupleurum extract, 0.7 part of bamboo extractive, 1.2 parts of Gentrin Knotweed P.E, 0.6 part of Sage extract, vermiculite
1.3 parts of powder, 2.1 parts of poly-aspartate, 0.8 part of nano micro crystal cellulose, 2.6 parts of Aerosol OT, polyethylene
0.7 part of butyral, 1.1 parts of APG, 0.8 part of Tween-60,120 parts of water；
The particle diameter of the vermiculite power is 0.1-1um；
The violet extract includes violet petal extract and violet seed extract；
The preparation process of the violet extract is：
1）Violet petal and violet seed are cleaned and are placed in soaking 24h in 3 times of water, then filters to obtain the first filtrate and the
One filter material；
2）First filtrate and the filter material of half first are mixed and added into 5 times of decoctings to boil twice, filter residue and the second filtrate is obtained, will filter
Slag, which is placed in, to be placed in micro-wave oven after immersion 40min in 55wt.% ethanol solutions and heats 15min, is filtered, and is collected and is filtered with second
Liquid merges；The filtrate of merging is concentrated into thick paste, and upper macroporous adsorbent resin column chromatography, first with distillation water elution, removes first
Secondary eluent, then eluted with 45wt.% ethanol solutions, eluent is collected, then adds the 65wt.% ethanol of 6 times of parts by weight, is stood
Alcohol precipitation, filtering, obtains filtrate I and the 3rd filtrate；The 85wt.% ethanol of 10 times of parts by weight is added into the 3rd filtrate, is stood
Alcohol precipitation, supernatant is taken, after concentration, spray drying, obtain filtrate II, merged filtrate I and filtrate II, freeze-drying, obtain
To extract I；
3）Remaining first filter material is dried and crushed, is subsequently placed in 20U/mL cellulase solutions, in neutral conditions room
Temperature place 6h, then filtering and by filter residue add 10 times of parts by weight mass ratio be 1:1 ethyl acetate and alcohol mixed solution
In, ultrasonic disperse 120min, 2h then is heated to reflux at 60 DEG C, cools down and filter, reclaimed filtrate and be freeze-dried, must carry
Take thing II；
4）Extract I and extract II are well mixed, produce violet extract.
In above-mentioned technical proposal, the lichens extract, bupleurum extract, bamboo extractive, Gentrin Knotweed P.E, Salvia japonica
The extracting method of each extract of extract is as follows：
The extraction step of the lichens extract is：Lichens is placed in the 50wt.% ethanol solutions of 15 times of parts by weight, in 50 DEG C
Lower extraction 3h, extract 2 times, be concentrated under reduced pressure, be freeze-dried, produce lichens extract；
The extraction step of the bupleurum extract is：Radix bupleuri is placed in the water of 6 times of parts by weight, decocts 2h, extracted 3 times, decompression
Concentration, freeze-drying, produces bupleurum extract；
The extraction step of the leaf of bamboo, giant knotweed and Sage extract is：The leaf of bamboo, giant knotweed or Salvia japonica are taken respectively, after drying
Crush, be subsequently placed in 20wt.% acetone solns, 1h is extracted at 50 DEG C and is extracted 2 times, filtering, is concentrated under reduced pressure, is freeze-dried,
Produce.
The preparation technology of above-mentioned plant base anti-UV fabric finishing agent, comprises the following steps：
Nano micro crystal cellulose and APG are added to the water, ultrasonic disperse 30min, then magnetic agitation 2h, then add purple
Rowland extract, lichens extract, bupleurum extract, bamboo extractive, Gentrin Knotweed P.E, Sage extract, poly- asparagus fern ammonia
Acid and Tween-60, high-speed stirred 20min, vermiculite power, Aerosol OT, polyvinyl butyral resin are then added,
High-speed stirred 15min, ultrasonic degassing process 5min, then high-speed stirred 5min, are produced.
Embodiment 2
A kind of plant base anti-UV fabric finishing agent, include the component of following parts by weight：16 parts of violet extract, lichens extraction
6.5 parts of thing, -3 parts of bupleurum extract, 2.5 parts of bamboo extractive, 3.6 parts of Gentrin Knotweed P.E, 2.2 parts of Sage extract, vermiculite
3 parts of powder, 4.2 parts of poly-aspartate, 3 parts of nano micro crystal cellulose, 4 parts of Aerosol OT, polyvinyl alcohol contracting fourth
2.3 parts of aldehyde, 3.5 parts of APG, 2.6 parts of Tween-60,180 parts of water；
The particle diameter of the vermiculite power is 0.1-1um；
The violet extract includes violet petal extract and violet seed extract；
The preparation process of the violet extract is：
1）Violet petal and violet seed are cleaned and are placed in soaking 24h in 5 times of water, then filters to obtain the first filtrate and the
One filter material；
2）First filtrate and the filter material of half first are mixed and added into 8 times of decoctings to boil twice, filter residue and the second filtrate is obtained, will filter
Slag, which is placed in, to be placed in micro-wave oven after immersion 40min in 55wt.% ethanol solutions and heats 15min, is filtered, and is collected and is filtered with second
Liquid merges；The filtrate of merging is concentrated into thick paste, and upper macroporous adsorbent resin column chromatography, first with distillation water elution, removes first
Secondary eluent, then eluted with 45wt.% ethanol solutions, eluent is collected, then adds the 65wt.% ethanol of 6 times of parts by weight, is stood
Alcohol precipitation, filtering, obtains filtrate I and the 3rd filtrate；The 85wt.% ethanol of 10 times of parts by weight is added into the 3rd filtrate, is stood
Alcohol precipitation, supernatant is taken, after concentration, spray drying, obtain filtrate II, merged filtrate I and filtrate II, freeze-drying, obtain
To extract I；
3）Remaining first filter material is dried and crushed, is subsequently placed in 100U/mL cellulase solutions, in neutral conditions room
Temperature place 24h, then filtering and by filter residue add 20 times of parts by weight mass ratio be 1:3 ethyl acetate and alcohol mixed solution
In, ultrasonic disperse 120min, 6h then is heated to reflux at 60 DEG C, cools down and filter, reclaimed filtrate and be freeze-dried, must carry
Take thing II；
4）Extract I and extract II are well mixed, produce violet extract.
In above-mentioned technical proposal, the lichens extract, bupleurum extract, bamboo extractive, Gentrin Knotweed P.E, Salvia japonica
The extracting method of each extract of extract is as follows：
The extraction step of the lichens extract is：Lichens is placed in the 80wt.% ethanol solutions of 30 times of parts by weight, in 70 DEG C
Lower extraction 6h, extract 4 times, be concentrated under reduced pressure, be freeze-dried, produce lichens extract；
The extraction step of the bupleurum extract is：Radix bupleuri is placed in the water of 15 times of parts by weight, decocts 2h, extracted 3-5 times, subtract
Pressure concentration, freeze-drying, produces bupleurum extract；
The extraction step of the leaf of bamboo, giant knotweed and Sage extract is：The leaf of bamboo, giant knotweed or Salvia japonica are taken respectively, after drying
Crush, be subsequently placed in 40wt.% acetone solns, 3h is extracted at 70 DEG C and is extracted 4 times, filtering, is concentrated under reduced pressure, is freeze-dried,
Produce.
The preparation technology of above-mentioned plant base anti-UV fabric finishing agent, comprises the following steps：
Nano micro crystal cellulose and APG are added to the water, ultrasonic disperse 30min, then magnetic agitation 4h, then add purple
Rowland extract, lichens extract, bupleurum extract, bamboo extractive, Gentrin Knotweed P.E, Sage extract, poly- asparagus fern ammonia
Acid and Tween-60, high-speed stirred 50min, vermiculite power, Aerosol OT, polyvinyl butyral resin are then added,
High-speed stirred 30min, ultrasonic degassing process 30min, then high-speed stirred 30min, are produced.
Embodiment 3
A kind of plant base anti-UV fabric finishing agent, include the component of following parts by weight：6 parts of violet extract, lichens extraction
2.3 parts of thing, 0.8 part of bupleurum extract, 0.9 part of bamboo extractive, 1.5 parts of Gentrin Knotweed P.E, 1 part of Sage extract, vermiculite
1.5 parts of powder, 2.3 parts of poly-aspartate, 1.2 parts of nano micro crystal cellulose, 2.8 parts of Aerosol OT, polyethylene
0.8 part of butyral, 1.6 parts of APG, 1 part of Tween-60,130 parts of water；
The particle diameter of the vermiculite power is 0.1-1um；
The violet extract includes violet petal extract and violet seed extract；
The preparation process of the violet extract is：
1）Violet petal and violet seed are cleaned and are placed in soaking 24h in 4 times of water, then filters to obtain the first filtrate and the
One filter material；
2）First filtrate and the filter material of half first are mixed and added into 7 times of decoctings to boil twice, filter residue and the second filtrate is obtained, will filter
Slag, which is placed in, to be placed in micro-wave oven after immersion 40min in 55wt.% ethanol solutions and heats 15min, is filtered, and is collected and is filtered with second
Liquid merges；The filtrate of merging is concentrated into thick paste, and upper macroporous adsorbent resin column chromatography, first with distillation water elution, removes first
Secondary eluent, then eluted with 45wt.% ethanol solutions, eluent is collected, then adds the 65wt.% ethanol of 6 times of parts by weight, is stood
Alcohol precipitation, filtering, obtains filtrate I and the 3rd filtrate；The 85wt.% ethanol of 10 times of parts by weight is added into the 3rd filtrate, is stood
Alcohol precipitation, supernatant is taken, after concentration, spray drying, obtain filtrate II, merged filtrate I and filtrate II, freeze-drying, obtain
To extract I；
3）Remaining first filter material is dried and crushed, is subsequently placed in 60U/mL cellulase solutions, in neutral conditions room
Temperature place 18h, then filtering and by filter residue add 15 times of parts by weight mass ratio be 1:2 ethyl acetate and alcohol mixed solution
In, ultrasonic disperse 120min, 4h then is heated to reflux at 60 DEG C, cools down and filter, reclaimed filtrate and be freeze-dried, must extract
Thing II；
4）Extract I and extract II are well mixed, produce violet extract.
In above-mentioned technical proposal, the lichens extract, bupleurum extract, bamboo extractive, Gentrin Knotweed P.E, Salvia japonica
The extracting method of each extract of extract is as follows：
The extraction step of the lichens extract is：Lichens is placed in the 65wt.% ethanol solutions of 20 times of parts by weight, in 60 DEG C
Lower extraction 5h, extract 3 times, be concentrated under reduced pressure, be freeze-dried, produce lichens extract；
The extraction step of the bupleurum extract is：Radix bupleuri is placed in the water of 12 times of parts by weight, decocts 2h, extracted 4 times, decompression
Concentration, freeze-drying, produces bupleurum extract；
The extraction step of the leaf of bamboo, giant knotweed and Sage extract is：The leaf of bamboo, giant knotweed or Salvia japonica are taken respectively, after drying
Crush, be subsequently placed in 30wt.% acetone solns, 2h is extracted at 60 DEG C and is extracted 3 times, filtering, is concentrated under reduced pressure, is freeze-dried,
Produce.
The preparation technology of above-mentioned plant base anti-UV fabric finishing agent, comprises the following steps：
Nano micro crystal cellulose and APG are added to the water, ultrasonic disperse 30min, then magnetic agitation 3h, then add purple
Rowland extract, lichens extract, bupleurum extract, bamboo extractive, Gentrin Knotweed P.E, Sage extract, poly- asparagus fern ammonia
Acid and Tween-60, high-speed stirred 35min, vermiculite power, Aerosol OT, polyvinyl butyral resin are then added,
High-speed stirred 22min, ultrasonic degassing process 18min, then high-speed stirred 16min, are produced.
Embodiment 4
A kind of plant base anti-UV fabric finishing agent, include the component of following parts by weight：14 parts of violet extract, lichens extraction
6 parts of thing, 2.4 parts of bupleurum extract, 2.1 parts of bamboo extractive, 3.3 parts of Gentrin Knotweed P.E, 2.1 parts of Sage extract, vermiculite
2.6 parts of powder, 4 parts of poly-aspartate, 2.7 parts of nano micro crystal cellulose, 3.6 parts of Aerosol OT, polyvinyl alcohol
2 parts of butyral, 3.2 parts of APG, 2.5 parts of Tween-60,160 parts of water；
The particle diameter of the vermiculite power is 0.1-1um；
The violet extract includes violet petal extract and violet seed extract；
The preparation process of the violet extract is：
1）Violet petal and violet seed are cleaned and are placed in soaking 24h in 5 times of water, then filters to obtain the first filtrate and the
One filter material；
2）First filtrate and the filter material of half first are mixed and added into 7 times of decoctings to boil twice, filter residue and the second filtrate is obtained, will filter
Slag, which is placed in, to be placed in micro-wave oven after immersion 40min in 55wt.% ethanol solutions and heats 15min, is filtered, and is collected and is filtered with second
Liquid merges；The filtrate of merging is concentrated into thick paste, and upper macroporous adsorbent resin column chromatography, first with distillation water elution, removes first
Secondary eluent, then eluted with 45wt.% ethanol solutions, eluent is collected, then adds the 65wt.% ethanol of 6 times of parts by weight, is stood
Alcohol precipitation, filtering, obtains filtrate I and the 3rd filtrate；The 85wt.% ethanol of 10 times of parts by weight is added into the 3rd filtrate, is stood
Alcohol precipitation, supernatant is taken, after concentration, spray drying, obtain filtrate II, merged filtrate I and filtrate II, freeze-drying, obtain
To extract I；
3）Remaining first filter material is dried and crushed, is subsequently placed in 40U/mL cellulase solutions, in neutral conditions room
Temperature place 20h, then filtering and by filter residue add 18 times of parts by weight mass ratio be 1:3 ethyl acetate and alcohol mixed solution
In, ultrasonic disperse 120min, 5h then is heated to reflux at 60 DEG C, cools down and filter, reclaimed filtrate and be freeze-dried, must extract
Thing II；
4）Extract I and extract II are well mixed, produce violet extract.
In above-mentioned technical proposal, the lichens extract, bupleurum extract, bamboo extractive, Gentrin Knotweed P.E, Salvia japonica
The extracting method of each extract of extract is as follows：
The extraction step of the lichens extract is：Lichens is placed in the 70wt.% ethanol solutions of 20 times of parts by weight, in 65 DEG C
Lower extraction 4h, extract 4 times, be concentrated under reduced pressure, be freeze-dried, produce lichens extract；
The extraction step of the bupleurum extract is：Radix bupleuri is placed in the water of 15 times of parts by weight, decocts 2h, extracted 5 times, decompression
Concentration, freeze-drying, produces bupleurum extract；
The extraction step of the leaf of bamboo, giant knotweed and Sage extract is：The leaf of bamboo, giant knotweed or Salvia japonica are taken respectively, after drying
Crush, be subsequently placed in 35wt.% acetone solns, 3h is extracted at 65 DEG C and is extracted 4 times, filtering, is concentrated under reduced pressure, is freeze-dried,
Produce.
The preparation technology of above-mentioned plant base anti-UV fabric finishing agent, comprises the following steps：
Nano micro crystal cellulose and APG are added to the water, ultrasonic disperse 30min, then magnetic agitation 3h, then add purple
Rowland extract, lichens extract, bupleurum extract, bamboo extractive, Gentrin Knotweed P.E, Sage extract, poly- asparagus fern ammonia
Acid and Tween-60, high-speed stirred 45min, vermiculite power, Aerosol OT, polyvinyl butyral resin are then added,
High-speed stirred 20min, ultrasonic degassing process 25min, then high-speed stirred 20min, are produced.
Embodiment 5
A kind of plant base anti-UV fabric finishing agent, include the component of following parts by weight：12 parts of violet extract, lichens extraction
5.4 parts of thing, 1.9 parts of bupleurum extract, 1.4 parts of bamboo extractive, 2.6 parts of Gentrin Knotweed P.E, 1.8 parts of Sage extract, leech
2.3 parts of stone flour, 3.6 parts of poly-aspartate, 1.7 parts of nano micro crystal cellulose, 3.4 parts of Aerosol OT, poly- second
1.5 parts of enol butyral, 2.5 parts of APG, 1.8 parts of Tween-60,155 parts of water；
The particle diameter of the vermiculite power is 0.1-1um；
The violet extract includes violet petal extract and violet seed extract；
The violet extract, the lichens extract, bupleurum extract, bamboo extractive, Gentrin Knotweed P.E, Salvia japonica carry
The extraction step of each extract of thing is taken with embodiment 4.
The preparation technology of above-mentioned plant base anti-UV fabric finishing agent, comprises the following steps：
Nano micro crystal cellulose and APG are added to the water, ultrasonic disperse 30min, then magnetic agitation 4h, then add purple
Rowland extract, lichens extract, bupleurum extract, bamboo extractive, Gentrin Knotweed P.E, Sage extract, poly- asparagus fern ammonia
Acid and Tween-60, high-speed stirred 45min, vermiculite power, Aerosol OT, polyvinyl butyral resin are then added,
High-speed stirred 25min, ultrasonic degassing process 20min, then high-speed stirred 28min, are produced.
Comparative example 1
This comparative example in place of the difference of embodiment 1 with being：Do not add violet extract and lichens extract, other components and
Its preparation process is the same as embodiment 1.
Comparative example 2
This comparative example in place of the difference of embodiment 1 with being：Bupleurum extract, poly-aspartate and polyvinyl alcohol contracting fourth are not added
Aldehyde.
Performance test
The fabric arranged by the fabric finishing agent prepared by above example and comparative example is subjected to dependence test, wherein anti-
Ultraviolet performance test reference GB/T18830-2009《The evaluation of ultraviolet resistance of fabric》Method carry out, after textile finishing
Each performance test result it is as shown in the table：
| Initial performance | UPF（UPF） | T（UVA）/% | T（UVB）/% | Gas permeability/L/m2•s |
| Embodiment 1 | 64.3 | 1.5 | 1.1 | 351.6 |
| Embodiment 2 | 65.8 | 1.3 | 1 | 340.8 |
| Embodiment 3 | 66.1 | 1.2 | 0.9 | 346.2 |
| Embodiment 4 | 67.2 | 1.1 | 0.7 | 344.1 |
| Embodiment 5 | 67.7 | 1 | 0.6 | 350.3 |
| Comparative example 1 | 48.3 | 32.9 | 28.3 | 348.2 |
| Comparative example 2 | 59.1 | 19.5 | 11.8 | 343.7 |
Fabric through prepared by above example and comparative example finishing agent arrange after, then by washing 80 times after, its properties
Test result it is as shown in the table：
| Performance after washing 80 times | UPF（UPF） | T（UVA）/% | T（UVB）/% | Gas permeability/L/m2•s |
| Embodiment 1 | 59.5 | 2.8 | 1.6 | 351.6 |
| Embodiment 2 | 61.4 | 3.3 | 1.5 | 340.8 |
| Embodiment 3 | 62.8 | 2.2 | 1.9 | 346.2 |
| Embodiment 4 | 63.6 | 1.7 | 1.2 | 344.1 |
| Embodiment 5 | 64.2 | 1.2 | 0.9 | 350.3 |
| Comparative example 1 | 40.6 | 44.2 | 39.5 | 348.2 |
| Comparative example 2 | 32.8 | 37.5 | 41.3 | 343.7 |
From above test result, the fabric finishing agent prepared by the present invention possesses good uvioresistant performance, meets country
Relevant regulations standard, while the fabric finishing agent possesses good water resistance, after water-based 80 times, its uv resistance can be still
Higher level is maintained at, in addition, the fabric that the finishing agent is arranged has a good gas permeability, wearability is good.
Claims (6)
1. a kind of plant base anti-UV fabric finishing agent, it is characterised in that include the component of following parts by weight：Violet extracts
Thing 5-16 parts, lichens extract 2-6.5 parts, bupleurum extract 0.4-3 parts, bamboo extractive 0.7-2.5 parts, Gentrin Knotweed P.E
1.2-3.6 parts, Sage extract 0.6-2.2 parts, vermiculite power 1.3-3 parts, poly-aspartate 2.1-4.2 parts, nano microcrystalline are fine
Tie up plain 0.8-3 parts, Aerosol OT 2.6-4 parts, polyvinyl butyral resin 0.7-2.3 parts, APG 1.1-
3.5 parts, Tween-60 0.8-2.6 parts, water 120-180 parts；
The violet extract includes violet petal extract and violet seed extract；
The preparation process of the violet extract is：
1）Violet petal and violet seed are cleaned and are placed in soaking 24h in 3-5 times of water, then filter the first filtrate and
First filter material；
2）First filtrate and the filter material of half first are mixed and added into 5-8 times of decocting to boil twice, obtain filter residue and the second filtrate, will
Filter residue is placed in 55wt.% ethanol solutions soak 40min after is placed in micro-wave oven and heats 15min, filter, collect and with second
Filtrate merges；The filtrate of merging is concentrated into thick paste, and upper macroporous adsorbent resin column chromatography, first with distillation water elution, removes the
Eluent, then eluted with 45wt.% ethanol solutions, eluent is collected, then adds the 65wt.% ethanol of 6 times of parts by weight, it is quiet
Alcohol precipitation is put, filters, obtains filtrate I and the 3rd filtrate；The 85wt.% ethanol of 10 times of parts by weight is added into the 3rd filtrate, it is quiet
Alcohol precipitation is put, takes supernatant, after concentration, spray drying, filtrate II is obtained, merges filtrate I and filtrate II, be freeze-dried,
Obtain extract I；
3）Remaining first filter material is dried and crushed, is subsequently placed in 20-100U/mL cellulase solutions, in neutrallty condition
Lower room temperature places 6-24h, then filtering and filter residue is added into the mass ratioes of 10-20 times of parts by weight is 1:1 ~ 3 ethyl acetate and
In alcohol mixed solution, ultrasonic disperse 120min, 2-6h then is heated to reflux at 60 DEG C, cools down and filter, recovery filtrate is simultaneously
Freeze-drying, obtains extract II；
4）Extract I and extract II are well mixed, produce violet extract.
2. plant base anti-UV fabric finishing agent according to claim 1, it is characterised in that the lichens extract, bavin
Hu extract, bamboo extractive, Gentrin Knotweed P.E, Sage extract each extract extracting method it is as follows：
The extraction step of the lichens extract is：Lichens is placed in the 50-80wt.% ethanol solutions of 15-30 times of parts by weight,
3-6h is extracted at 50-70 DEG C, extracts 2-4 times, is concentrated under reduced pressure, is freeze-dried, produces lichens extract；
The extraction step of the bupleurum extract is：Radix bupleuri is placed in the water of 6-15 times of parts by weight, decocts 2h, extracted 3-5 times,
It is concentrated under reduced pressure, is freeze-dried, produces bupleurum extract；
The extraction step of the leaf of bamboo, giant knotweed and Sage extract is：The leaf of bamboo, giant knotweed or Salvia japonica are taken respectively, after drying
Crush, be subsequently placed in 20-40wt.% acetone solns, 1-3h is extracted at 50-70 DEG C and is extracted 2-4 times, filtering, is depressurized dense
Contracting, freeze-drying, is produced.
3. plant base anti-UV fabric finishing agent according to claim 1, it is characterised in that the particle diameter of the vermiculite power is
0.1-1um。
4. plant base anti-UV fabric finishing agent according to claim 1, it is characterised in that including following parts by weight
Component：Violet extract 6-14 parts, lichens extract 2.3-6 parts, bupleurum extract 0.8-2.4 parts, bamboo extractive 0.9-
2.1 parts, Gentrin Knotweed P.E 1.5-3.3 parts, Sage extract 1-2.1 parts, vermiculite power 1.5-2.6 parts, poly-aspartate 2.3-4
Part, nano micro crystal cellulose 1.2-2.7 parts, Aerosol OT 2.8-3.6 parts, polyvinyl butyral resin 0.8-2
Part, APG 1.6-3.2 parts, Tween-60 1-2.5 parts, water 130-160 parts.
5. plant base anti-UV fabric finishing agent according to claim 1, it is characterised in that including following parts by weight
Component：12 parts of violet extract, 5.4 parts of lichens extract, 1.9 parts of bupleurum extract, 1.4 parts of bamboo extractive, giant knotweed carry
Take 2.6 parts of thing, 1.8 parts of Sage extract, 2.3 parts of vermiculite power, 3.6 parts of poly-aspartate, 1.7 parts of nano micro crystal cellulose,
3.4 parts of Aerosol OT, 1.5 parts of polyvinyl butyral resin, 2.5 parts of APG, 1.8 parts of Tween-60, water
155 parts.
6. a kind of preparation technology of plant base anti-UV fabric finishing agent, it is characterised in that comprise the following steps：
Nano micro crystal cellulose and APG are added to the water, ultrasonic disperse 30min, then magnetic agitation 2-4h, then add
Violet extract, lichens extract, bupleurum extract, bamboo extractive, Gentrin Knotweed P.E, Sage extract, poly- asparagus fern
Propylhomoserin and Tween-60, high-speed stirred 20-50min, then add vermiculite power, Aerosol OT, polyvinyl alcohol contracting
Butyraldehyde, high-speed stirred 15-30min, ultrasonic degassing process 5-30min, then high-speed stirred 5-30min, is produced.
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