CN107384531A - A kind of green oil mixture - Google Patents

A kind of green oil mixture Download PDF

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Publication number
CN107384531A
CN107384531A CN201611113271.3A CN201611113271A CN107384531A CN 107384531 A CN107384531 A CN 107384531A CN 201611113271 A CN201611113271 A CN 201611113271A CN 107384531 A CN107384531 A CN 107384531A
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CN
China
Prior art keywords
oil
parts
green
mixture
oil mixture
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611113271.3A
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Chinese (zh)
Inventor
徐咸大
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SHANGHAI DELIAN CHEMICAL Co Ltd
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SHANGHAI DELIAN CHEMICAL Co Ltd
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Priority to CN201611113271.3A priority Critical patent/CN107384531A/en
Publication of CN107384531A publication Critical patent/CN107384531A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/065—Sulfides; Selenides; Tellurides
    • C10M2201/066—Molybdenum sulfide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/0206—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/124—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms containing hydroxy groups; Ethers thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/141—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/402—Castor oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/066—Thiocarbamic type compounds
    • C10M2219/068—Thiocarbamate metal salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/02—Groups 1 or 11
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/10—Groups 5 or 15
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/12—Groups 6 or 16
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/02—Pour-point; Viscosity index
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/64—Environmental friendly compositions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The present invention, which discloses a kind of green oil mixture, includes 40~70 parts of following components and parts by weight synthetic base oil, 15~30 parts of refining vegetable oil, 2~4 parts of detersive, 2~5 parts of dispersant, 2~5 parts of antioxidant, 2~4 parts of sodium citrate, 0.5~1 part of detergent alkylate sodium carbonate, 1~1.5 part of dibutyl thiocarbamic acid antimony, 1~3 part of other auxiliary agents.The green oil mixture of the present invention, by adding appropriate refining vegetable oil, reduce the influence to environment, while by the adjustment of formula, can solve the problem that because lubricants performance declines caused by after refining vegetable oil addition the problem of.

Description

A kind of green oil mixture
Technical field
The invention belongs to lubricating oil field, and in particular to a kind of green oil mixture.
Background technology
With the development of society, the consumption figure of lubricating oil rises year by year, automobile, machining, communications and transportation, metallurgy, The industries such as coal, building, lubricating oil is more and more extensive and applies in large quantities, but increasingly serious environmental problem is also following, Because current more than 95% lubricating oil is all to use oil based on mineral oil, mineral oil non-degradable can be in nature Retain and be enriched with for a long time in environment, biology is caused greatly to poison, produce severe and far-reaching environmental problem.
Green Lubricants are also known as environmentally friendly or environment tolerant lubricating oil.Refer to that lubricating oil should meet oil product The requirement of energy specification, and can are decomposed by the microorganisms into carbon dioxide and water, the lubricating oil not damaged to environment.Green lubrication The basic demand of oil is that its biodegradability will get well.And do not have eco-toxicity.Since the nineties, many countries include Europe Beautiful and Japan etc. starts Devoting Major Efforts To Developing Green Lubricants to substitute traditional mineral based lubricating oil, and develops biodegradation successively Lubricating oil.
Vegetable fat is added in conventional lubrication oil base oil and acquisition is worked as with conventional lubrication oil phase or close performance is The Main way of this area research at present.
The content of the invention
The purpose of the present invention, a kind of green oil mixture exactly is provided in order to solve the above problems, led to Cross added into lubricating oil can the method for vegetable oil of natural degradation reduce the influence to environment while solve lubrication of the invention Oil is because caused by the introducing of vegetable oil the problem of hydraulic performance decline.
The object of the present invention is achieved like this：
A kind of green oil mixture of the present invention includes following components and parts by weight：
The refining vegetable oil is at least one of refined rapeseed oil, refining castor oil and pentaerythritol ester；
The detersive is methanol, linoleic acid, calcium hydroxide, the mixture of polyisobutylene succinamide；
The dispersant be the polyisobutylene succinamide of boronation polyisobutylene succinamide or boron phosphatization extremely Few one kind；
Antioxidant is 2,6- three-level butyl -4- methylphenols, double (3,5- three-level butyl -4- hydroxy phenyls) thioethers, four (β-(3,5- three-level butyl -4- hydroxy phenyls) propionic acid) pentaerythritol ester and double Lauryl Alcohol esters, double ten four carbon alcohols esters, double 18 At least one of carbon alcohol ester；
Synthetic base oil is poly alpha olefin in a kind of above-mentioned green oil mixture.
Refining vegetable oil is refining castor oil in a kind of above-mentioned green oil mixture.
Oil mixture also includes 3~5 parts of molybdenum disulfide in a kind of above-mentioned green oil mixture Colloid.
The green oil mixture of the present invention, by adding appropriate refining vegetable oil, reduces to environment Influence, while by the adjustment of formula, can solve the problem that because lubricants performance declines caused by after refining vegetable oil addition the problem of.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
The invention discloses a kind of green oil mixture, embodiment 1~4 presses the component of the parts by weight of table 1 Prepare.
The component and part of the embodiment 1~4 of table 1
The PAO6 of said components and refining castor oil are mixed and heated to 40~55 DEG C, are stirred 50~80 points of dehydration Clock, composite foundation oil being prepared, remaining component is added in composite foundation oil after being stirred dewater treatment, is warming up to 60~70 DEG C, Stirring 120~240 minutes, finished product storage tank is added after cooling.
The lubricants performance test of embodiment 1~4 is using kinematic viscosity determination method (GB/T265), pour point measurement method (GB/ T3535), copper strip test (copper sheet, 121 DEG C, 3h) (GB/T5096), four ball milling spot diameter determination methods (1800RPM, 40Kg, 75 DEG C, 60min) (USS224/S-205), test result is as shown in table 2.
The performance test results of embodiment 1~4
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4
100 DEG C of kinematic viscosity (mm2/s) 7.203 7.194 7.198 7.211
40 DEG C of kinematic viscosity (mm2/s) 35.91 35.94 36.07 36.12
Pour point (DEG C) -57 -58 -58 -59
Corrosion test (level) 1b 1b 1b 1b
Four ball milling spot diameters (mm) 0.48 0.47 0.51 0.53
From Table 2, it can be seen that the lubricants performance of the present invention can be close to the performance of traditional lubrication oil, with vegetable oil Addition increase, lubricants performance is declined slightly, but as the increase of vegetable oil addition can realize more preferable environment protecting, Good environment protecting is realized while use can obtain appropriate performance during greasy property requires stringent environment.
Above example is used for illustrative purposes only, rather than limitation of the present invention, the technology people about technical field Member, without departing from the spirit and scope of the present invention, can also make various conversion or modification, therefore all equivalent Technical scheme should also belong to scope of the invention, should be limited by each claim.

Claims (4)

1. a kind of green oil mixture, it is characterised in that including following components and parts by weight：
The refining vegetable oil is at least one of refined rapeseed oil, refining castor oil and pentaerythritol ester；
The detersive is methanol, linoleic acid, calcium hydroxide, the mixture of polyisobutylene succinamide；
The dispersant is boronation polyisobutylene succinamide or the polyisobutylene succinamide at least one of boron phosphatization Kind；
Antioxidant be 2,6- three-level butyl -4- methylphenols, double (3,5- three-level butyl -4- hydroxy phenyls) thioethers, four (β - (3,5- three-level butyl -4- hydroxy phenyls) propionic acid) pentaerythritol ester and double Lauryl Alcohol esters, double ten four carbon alcohols esters, double 18 carbon At least one of alcohol ester.
2. a kind of green oil mixture as claimed in claim 1, it is characterised in that the synthetic base oil is poly- Alpha-olefin.
3. a kind of green oil mixture as claimed in claim 1, it is characterised in that the refining vegetable oil is essence Refine castor oil.
A kind of 4. green oil mixture as claimed in claim 1, it is characterised in that the green lubricating oil Mixture also includes 3~5 parts of molybdenum disulfide colloid.
CN201611113271.3A 2016-12-06 2016-12-06 A kind of green oil mixture Pending CN107384531A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611113271.3A CN107384531A (en) 2016-12-06 2016-12-06 A kind of green oil mixture

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611113271.3A CN107384531A (en) 2016-12-06 2016-12-06 A kind of green oil mixture

Publications (1)

Publication Number Publication Date
CN107384531A true CN107384531A (en) 2017-11-24

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611113271.3A Pending CN107384531A (en) 2016-12-06 2016-12-06 A kind of green oil mixture

Country Status (1)

Country Link
CN (1) CN107384531A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103215114A (en) * 2013-04-12 2013-07-24 广西大学 Environment-friendly type oil for heavy-duty industrial gear
CN103666680A (en) * 2013-11-22 2014-03-26 广西大学 Lubricant for dual-clutch gear box
CN104357138A (en) * 2014-09-29 2015-02-18 宁贻伟 Lubricant detergent
CN105255565A (en) * 2015-11-12 2016-01-20 杭州科技职业技术学院 Formulation for gear oil for automobile transmission

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103215114A (en) * 2013-04-12 2013-07-24 广西大学 Environment-friendly type oil for heavy-duty industrial gear
CN103666680A (en) * 2013-11-22 2014-03-26 广西大学 Lubricant for dual-clutch gear box
CN104357138A (en) * 2014-09-29 2015-02-18 宁贻伟 Lubricant detergent
CN105255565A (en) * 2015-11-12 2016-01-20 杭州科技职业技术学院 Formulation for gear oil for automobile transmission

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Application publication date: 20171124

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