CN106497651B - A kind of engineering machinery lubricating grease and preparation method with high biological degradability - Google Patents
A kind of engineering machinery lubricating grease and preparation method with high biological degradability Download PDFInfo
- Publication number
- CN106497651B CN106497651B CN201610877918.3A CN201610877918A CN106497651B CN 106497651 B CN106497651 B CN 106497651B CN 201610877918 A CN201610877918 A CN 201610877918A CN 106497651 B CN106497651 B CN 106497651B
- Authority
- CN
- China
- Prior art keywords
- lubricating grease
- oil
- engineering machinery
- biological degradability
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/06—Mixtures of thickeners and additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/04—Elements
- C10M2201/041—Carbon; Graphite; Carbon black
- C10M2201/042—Carbon; Graphite; Carbon black halogenated, i.e. graphite fluoride
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/003—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/20—Natural rubber; Natural resins
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
- C10M2207/1265—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic used as thickening agent
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/401—Fatty vegetable or animal oils used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/084—Acrylate; Methacrylate
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2290/00—Mixtures of base materials or thickeners or additives
- C10M2290/04—Synthetic base oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/02—Pour-point; Viscosity index
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/08—Resistance to extreme temperature
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/64—Environmental friendly compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/10—Semi-solids; greasy
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The present invention relates to a kind of engineering machinery lubricating grease and preparation method with high biological degradability.Ingredient and percentage composition are as follows: 12-OH base stearic acid lithium soap 5.0%~15.2%；Add III class oil 27.7%~29.3% of hydrogen；Vegetable oil 55.3%~58.7%；Fluorographite 1.0%~4.0%；Thiodipropionate antioxidant 0.4%~1.5%；Environment-friendly type tackifier 0.4%~1.5%.Vegetable oil is thickened using 12-OH base stearic acid lithium soap and adds the mixture of III class of hydrogen oil oily, then compounds the additives such as anti-attrition, antioxygen, increasing stick and is made.Products obtained therefrom is suitable for drinking the lubrication that the requirements such as Hydraulic Projects, golf course avoid all kinds of engineering machinery to work under the conditions of environmental pollution, it can substantially reduce in construction process because lubricating grease leakage is to the pollution caused by natural environment, the lubrication state of betterment works machinery meets the mechanical service life requirement to lubricating grease.
Description
Technical field
The invention belongs to technical field of lubricating grease, in particular to it is a kind of have high biological degradability and good anti-attrition,
The engineering machinery lubricating grease and preparation method of antioxidant, resistant of high or low temperature and adhesion.
Background technique
Engineering machinery includes all kinds of excavators, loading machine, bull-dozer, rotary drill machine etc., and the lubrication of working arm pin shaft is adopted
Use lubricating grease.In engineering machinery work progress, the lubricating grease on working arm in each pin shaft to some extent will be by silt, ash
The influence of the various impurity intrusions such as dirt, moisture, while causing lubricating grease generally to leak because poorly sealed or temperature rise is excessively high
Phenomenon.In order to guarantee that pin shaft and shaft room keep good lubricating oil film, each pin shaft on working arm is needed continually to inject newly
Lubricating grease, and leak lubricating grease can not collect.If the biological degradability of lubricating grease is poor, the lubricating grease of leakage if, can be right
Construction environment causes different degrees of pollution.For drinking for the special constructions environment such as Hydraulic Projects, golf course, due to
Mankind's daily life or activity etc. are closely related, it is desirable that use Biodegradable Lubricating Greases, to avoid or utmostly reduce profit
Consistent lubricant pollution on the environment.
Engineering machinery operation under outdoor open-air atmosphere, temperature can from -20 DEG C of winter low temperature with down toward 80 DEG C of summer high temperature with
On, while the harsh conditions of heavy load, impact or shock load are subjected to, this requires lubricating grease must also have excellent subtract
The performances such as mill property, antioxidant, adhesion and resistant of high or low temperature.
The Biodegradable Lubricating Greases of the prior art, although the biodegradable rate of portioned product can reach 65% or more,
But its anti-attrition, antioxidant, high and low temperature are poor, product is easy to run off, and service life is short.Existing defect is mainly shown as
Four ball milling spot diameters >=0.58mm, Oxidation Resistance Test pressure drop >=49kPa, evaporation capacity >=0.46%, wastage >=0.7g, water leaching
Number of dropouts >=2%, winter construction cause to add lubricating grease difficulty because of the similar large viscosity of low temperature.Especially with containing organic
Phosphorus, heavy metal lead, benzene ring type compounds additive when, then bigger damaging effect is often brought to environment.It can be seen that existing
Technical products are not able to satisfy engineering machinery and change setting under the execution conditions such as rouge period in claimed environment, reduction leakage, extension
Standby lubrication.
Adding III class oil of hydrogen is natural crude oil by being hydrocracked and the techniques such as hydrofinishing, and a kind of obtained chemical composition
More pure base oil.This base oil and the I class base oil ratio obtained by the traditional handicrafts such as solvent refining, solvent dewaxing
Compared with cryogenic property being improved, and the poisonous and harmful constituent content such as aromatic hydrocarbons, colloid, asphalitine is lower, to the bad shadow of environment bring
Sound is smaller.Vegetable oil has the characteristics that biological degradation rate, low temperature resistant, lubricity is good.Using suitable proportion plus III class oil of hydrogen with
Vegetable oil is used in combination, and can obtain the more preferably grease base oil such as biological degradability, lubricity and lower temperature resistance.
In order to improve the oxidation stability of lubricating grease, traditional technology is using amine or phenolic antioxidant.But these add
Add agent while improving the oxidation stability of lubricating grease, and can increase because of the residual of the compounds such as amine or phenols to ring
The pollution in border.Thiodipropionate antioxidant itself not only has good antioxidant, but also non-toxic, and own biological degradation rate
Height is suitable as the antioxidant of biodegradable engineering machinery lubricating grease.
Graphite is common lubricating grease anti-friction composition, and environmental sound.But the antifriction effect of general graphite is poor, no
The lubricating requirement being able to satisfy under engineering machinery harsh conditions.Lubrication is added in the fluorographite that graphite obtains after fluorination treatment
Its Wear vesistance can be significantly promoted in rouge, to meet lubrication of engineering machinery under the conditions of sharp pounding and impact load
It is required that.
Environment-friendly type tackifier such as polymethacrylates, natural rubber etc., the existing good feature of environmental protection, and lubrication can be improved
The adhesion of rouge can achieve the sealing effect for improving engineering machinery lubricating grease, reduce the purpose of lubricating grease leakage.
Using vegetable oil with plus III class of hydrogen oil mixture oil based on oil, 12-OH base stearic acid lithium soap be thickening agent, simultaneously
Fluorographite anti-friction composition, thiodipropionate antioxidant and environment-friendly type tackifier are compounded, there is high biodegrade to be made
Property and good anti-attrition, antioxidant, resistant of high or low temperature, adhesion engineering machinery lubricating grease, there is no open report at present.
Summary of the invention
The purpose of the present invention is to provide a kind of using oil based on the mixture oil for adding III class oil of hydrogen and vegetable oil, 12-OH base
Stearic acid lithium soap is thickening agent, while compounding fluorographite anti-friction composition, thiodipropionate antioxidant and environment-friendly type increasing stick
Agent, come be made with high biological degradability and good anti-attrition, antioxidant, resistant of high or low temperature, adhesion engineering machinery profit
Consistent lubricant.
Engineering machinery lubricant composition provided by the invention with high biological degradability, using composition gross weight as base
Standard, each component and percentage composition are as follows:
On the basis of preferred composition gross weight, each component content are as follows:
Engineering machinery lubricating grease provided by the invention with high biological degradability, the 12-OH base stearic acid lithium soap are
12-OH base stearic acid and lithium hydroxide through techniques such as saponification, drying, screenings and made of commercially available industrial goods.It is required that content >=
98.5%.
Engineering machinery lubricating grease provided by the invention with high biological degradability, described plus III class oil of hydrogen is petroleum distillate
Commercially available industrial goods are made by techniques such as overhydrocracking, isomerization dewaxings.It is required that 100 DEG C of dynamic viscosities be 6.5~
12.5mm2/s。
Engineering machinery lubricating grease provided by the invention with high biological degradability, the vegetable oil include natural soybean
Oil and rapeseed oil, and epoxidized soybean oil and oxidation rapeseed oil Jing Guo chemical modification.Epoxidized soybean oil is that crude soya bean oil exists
In the presence of catalyst and stabilizer, epoxidation reaction occurs with peroxycarboxylic acid and generates crude product, is made using purification.Aoxidize vegetable seed
Oil is under the conditions ofs certain catalysis etc., and natural rapeseed oil and oxygen or air are made by chemically reacting.It is above all kinds of
Vegetable oil is required to acid value≤0.5mgKOH/g.
Engineering machinery lubricating grease provided by the invention with high biological degradability, the fluorographite are that carbon and fluorine are direct
A kind of commercially available industrial goods prepared by reaction.It is required that partial size≤8 μm.
Engineering machinery lubricating grease provided by the invention with high biological degradability, the thiodipropionate antioxidant
It is commercially available industrial goods including the bimonthly cinnamic alcohol ester of thio-2 acid or thiobis propionic acid distearyl alcohol ester.By thiobis propionic acid point
It is not made with laruyl alcohol or stearyl alcohol through techniques such as esterification, crystallization, dryings.It is required that content >=99.0%.
Engineering machinery lubricating grease provided by the invention with high biological degradability, the environment-friendly type tackifier include poly- first
Base acrylate or natural rubber；Polymethacrylates is formic acid, higher alcohol etc. through esterification, distillation, purification, drying, polymerization
And obtain product, it is desired to molecular weight > 50000；Natural rubber is made of Heveatex through techniques such as supersolidification, dryings, it is desired to rubber
Hydrocarbon (polyisoprene) content >=90%.
Preparation process of the invention are as follows: will add in III class oil of hydrogen investment kettle, be warming up to 60~95 DEG C, it is hard that 12- hydroxyl is added
Resin acid lithium soap stirs 10~30min dispersed material.Vegetable oil (the 30~60% of total amount) and the material that heats up is added.When temperature liter
When to 210~220 DEG C, stop heating, temperature is kept to stir 1~5min.Remaining vegetable oil is put into kettle, object is quickly cooled down
Material.When temperature reaches 85~120 DEG C, fluorographite, thiodipropionate antioxidant, the addition of environment-friendly type tackifier is added
Agent.It stirs evenly, kettle can be gone out.Finished product is obtained after finally being ground with three-roll grinder.
The obtained lubricating grease of the present invention is using 12- hydroxy stearic acid lithium soap as thickening agent, and thickening adds III class oil of hydrogen and plants
The mixed base oil of object oil adds fluorographite anti-friction composition, thiodipropionate antioxidant and environment-friendly type tackifier, and
Obtain a kind of engineering machinery lubricating grease with high biological degradability.It, can be with by adding III class oil of hydrogen to be used in combination with vegetable oil
Obtain the ideal base oil of biological degradability, lubricity, resistant of high or low temperature.Fluorographite class antiwear additive, profit
Slip can exceed that MoS2And crystalline flake graphite, it has no adverse effects to human health, belongs to novel environment friendly antiwear additive.Thiodipropionate
Kind antioxidant small toxicity is allowed for the antioxidant of food as one kind, can effectively decompose in autoxidation chain reaction
Hydroperoxides (ROOH) interrupt oxidation reaction chain, to extend lubricating grease service life.Environment-friendly type tackifier can be effectively improved
The adhesion and leakproofness of this product.
Lubricating grease of the invention has excellent biodegradable and good anti-attrition, antioxidant, high-low temperature resistant
Property and adhesion, can both meet lubricating requirement of the engineering machinery under general job environment, and be more suitable for requiring biodegradable
Special lubricating requirement under operating environment can significantly extend lubricating grease service life.The lubricating grease cost of raw material of the invention compared with
It is low, have a wide range of application, there is good market application prospect.Products obtained therefrom is for drinking the requirement such as Hydraulic Projects, golf course
The lubrication for avoiding all kinds of engineering machinery such as the bull-dozer to work under the conditions of environmental pollution, excavator, loading machine, substantially reduces
Because lubricating grease leakage is to the pollution caused by natural environment, the lubrication state of betterment works machinery, satisfaction in construction process
Service life requirement of the machinery to lubricating grease.
Specific embodiment
Embodiment 1
The engineering machinery lubricant composition of high biological degradability, component and mass percent are as follows:
III class of hydrogen oil (100 DEG C of dynamic viscosity 6.5mm will be added2/ s) in 293g investment kettle, it is warming up to 60 DEG C, 12- hydroxyl is added
Base stearic acid lithium soap 50g stirs 30min dispersed material.Soybean oil 176g and the material that heats up is added.When temperature is raised to 210~220
DEG C when, stop heating, keep temperature stir 5min.Remaining soybean oil is put into kettle, material is quickly cooled down.Temperature reaches 120
DEG C when, be added fluorographite 40g, thio-2 acid bimonthly cinnamic alcohol ester 15g, polymethacrylates 15g.It stirs evenly
Kettle out.Finished product is obtained after finally being ground 3 times with three-roll grinder.Obtained PERFORMANCE OF GREASES is shown in Table 1.
Embodiment 2
The engineering machinery lubricant composition of high biological degradability, component and mass percent are as follows:
III class of hydrogen oil (100 DEG C of dynamic viscosity 8.5mm will be added2/ s) in 277g investment kettle, it is warming up to 95 DEG C, 12- hydroxyl is added
Base stearic acid lithium soap stirs 10min dispersed material.Oxidation rapeseed oil 352g and the material that heats up is added.When temperature is raised to 210~
At 220 DEG C, stop heating, temperature is kept to stir 1min.By in residue oxidation rapeseed oil investment kettle, it is quickly cooled down material.Temperature
When reaching 85 DEG C, fluorographite 10g, thio-2 acid double stearic alcohol ester 4g, natural rubber 4g is added.It stirs evenly, can go out
Kettle.Finished product is obtained after finally being ground 3 times with three-roll grinder.Obtained PERFORMANCE OF GREASES is shown in Table 1.
Embodiment 3
The engineering machinery lubricant composition of high biological degradability, component and mass percent are as follows:
III class of hydrogen oil (100 DEG C of dynamic viscosity 8.5mm will be added2/ s) in 280g investment kettle, it is warming up to 80 DEG C, 12- hydroxyl is added
Base stearic acid lithium soap stirs 15min dispersed material.Soybean oil 288g and the material that heats up is added.When temperature is raised to 210~220 DEG C
When, stop heating, temperature is kept to stir 2min.Remaining soybean oil is put into kettle, material is quickly cooled down.Temperature reaches 100 DEG C
When, fluorographite 10g, thio-2 acid bimonthly cinnamic alcohol ester 4g, polymethacrylates 4g is added.It stirs evenly, kettle can be gone out.
Finished product is obtained after finally being ground 3 times with three-roll grinder.Obtained PERFORMANCE OF GREASES is shown in Table 1.
Embodiment 4
The engineering machinery lubricant composition of high biological degradability, component and mass percent are as follows:
III class of hydrogen oil (100 DEG C of dynamic viscosity 7.8mm will be added2/ s) in 291g investment kettle, it is warming up to 90 DEG C, 12- hydroxyl is added
Base stearic acid lithium soap stirs 19min dispersed material.Rapeseed oil 349g and the material that heats up is added.When temperature is raised to 210~220 DEG C
When, stop heating, temperature is kept to stir 3min.Remaining rapeseed oil is put into kettle, material is quickly cooled down.Temperature reaches 88 DEG C
When, fluorographite 35g, thio-2 acid double stearic alcohol ester 12g, polymethacrylates 12g is added.It stirs evenly, can go out
Kettle.Finished product is obtained after finally being ground 3 times with three-roll grinder.Obtained PERFORMANCE OF GREASES is shown in Table 1.
Embodiment 5
The engineering machinery lubricant composition of high biological degradability, component and mass percent are as follows:
III class of hydrogen oil (100 DEG C of dynamic viscosity 12.5mm will be added2/ s) in 285g investment kettle, it is warming up to 73 DEG C, 12- hydroxyl is added
Base stearic acid lithium soap stirs 18min dispersed material.Rapeseed oil 232g and the material that heats up is added.When temperature is raised to 210~220 DEG C
When, stop heating, temperature is kept to stir 4min.Remaining rapeseed oil is put into kettle, material is quickly cooled down.Temperature reaches 107 DEG C
When, fluorographite 35g, thio-2 acid bimonthly cinnamic alcohol ester 6g, natural rubber 10g is added.It stirs evenly, kettle can be gone out.Finally
Finished product is obtained after being ground 3 times with three-roll grinder.Obtained PERFORMANCE OF GREASES is shown in Table 1.
Embodiment 6
The engineering machinery lubricant composition of high biological degradability, component and mass percent are as follows:
III class of hydrogen oil (100 DEG C of dynamic viscosity 10.1mm will be added2/ s) in 288g investment kettle, it is warming up to 68 DEG C, 12- hydroxyl is added
Base stearic acid lithium soap 110g stirs 21min dispersed material.Epoxidized soybean oil 185g and the material that heats up is added.When temperature is raised to 210
At~220 DEG C, stop heating, temperature is kept to stir 3min.Residual epoxide soybean oil is put into kettle, material is quickly cooled down.Temperature
When degree reaches 90 DEG C, fluorographite 26g, thio-2 acid double stearic alcohol ester 8g, polymethacrylates 6g is added.Stirring is equal
It is even, kettle can be gone out.Finished product is obtained after finally being ground 3 times with three-roll grinder.Obtained PERFORMANCE OF GREASES is shown in Table 1.
Comparative example 1
For commercially available Biodegradable Lubricating Greases.
Comparative example 2
For commercially available No. 2 Biodegradable Lubricating Greases.
Comparative example 3
For commercially available No. 3 Biodegradable Lubricating Greases.
Table 1
From the results shown in Table 1: the engineering machinery grease composition provided by the invention with high biological degradability
Object, not only biodegradable rate with higher, outstanding behaviours are inoxidizability, anti-attrition, adhesion compared with commercial product
It is significantly increased with performances such as high-low temperature resistants.Its biodegradable rate >=65%, and Oxidation Resistance Test pressure drop reduce
18.4% or more, four ball milling spot diameters reduce 8.6% or more, and water drenches number of dropouts reduced rate up to 66.7% or more, and wastage subtracts
Few 14.3% or more, evaporation capacity reduced rate up to 4.3% or more, the similar viscosity of low temperature (the identical trade mark compares) reduce 30.5% with
On.Compared with commercial product, lubricating grease service life can extend 1~2 times.Lubricating grease of the invention can meet -20~120 DEG C
The lubricating requirement of all kinds of engineering machinery in range, especially drinks the requirement of the construction sites such as Hydraulic Projects, golf course,
And pollution to environment can be substantially reduced.Meanwhile this product more meets ring without poisonous and harmful compounds such as organic phosphorus, Organic leadPs
Protect hygienic requirements.Product provided by the invention has a vast market foreground.
Claims (7)
1. a kind of engineering machinery lubricating grease with high biological degradability, it is characterized in that on the basis of composition gross weight, each component
Percentage composition:
Described plus III class of hydrogen 100 DEG C of dynamic viscosities of oil are 6.5~12.5mm2/s；
The vegetable oil is selected from crude soya bean oil, rapeseed oil, and epoxidized soybean oil or oxidation rapeseed oil Jing Guo chemical modification,
It is required that acid value≤0.5mgKOH/g；
The environment-friendly type tackifier includes polymethacrylates or natural rubber；Polymethacrylates requirement molecular weight >
50000, Heveatex requires polyisoprene contents >=90%.
2. lubricating grease described in claim 1, it is characterized in that on the basis of composition gross weight, each component percentage composition:
3. lubricating grease as claimed in claim 1 or 2, it is characterized in that 12-OH base lithium stearate soap content >=98.5%.
4. lubricating grease as claimed in claim 1 or 2, it is characterized in that the fluorographite requires partial size≤8 μm.
5. lubricating grease as claimed in claim 1 or 2, it is characterized in that the thiodipropionate antioxidant includes thio dipropyl
The bimonthly cinnamic alcohol ester of acid or thio-2 acid 2 stearyl ester, it is desired to content >=99.0%.
6. preparation of greases method as claimed in claim 1 or 2: it is characterized in that will add in III class oil of hydrogen investment kettle, heating
To 60~95 DEG C, 12- hydroxy stearic acid lithium soap is added, stirs 10~30min dispersed material；The 30 of addition vegetable oil total amount~
60% heating material；When temperature is raised to 210~220 DEG C, stop heating, temperature is kept to stir 1~5min；By remaining vegetable oil
It puts into kettle, cooling material；When temperature reaches 85~120 DEG C, fluorographite is added, thiodipropionate antioxidant, gathers
Methacrylic acid ester additive；It stirs evenly, kettle can be gone out, obtain finished product after three-roll grinder is ground.
7. the engineering machinery lubricating grease with high biological degradability such as claims 1 or 2 avoids environment dirt for requiring
Lubrication of bull-dozer, excavator or the loading machine to work under the conditions of dye in -20~120 DEG C of temperature ranges.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610877918.3A CN106497651B (en) | 2016-10-05 | 2016-10-05 | A kind of engineering machinery lubricating grease and preparation method with high biological degradability |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610877918.3A CN106497651B (en) | 2016-10-05 | 2016-10-05 | A kind of engineering machinery lubricating grease and preparation method with high biological degradability |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106497651A CN106497651A (en) | 2017-03-15 |
| CN106497651B true CN106497651B (en) | 2019-08-20 |
Family
ID=58294548
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610877918.3A Active CN106497651B (en) | 2016-10-05 | 2016-10-05 | A kind of engineering machinery lubricating grease and preparation method with high biological degradability |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106497651B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108841435B (en) * | 2018-07-23 | 2021-03-19 | 中国石油化工股份有限公司 | Lubricating grease composition for ultrahigh-pressure concrete pump truck and preparation method thereof |
| CN110499201A (en) * | 2019-09-24 | 2019-11-26 | 重庆化工职业学院 | Cotton picker spindle grease base plinth oil |
| CN111979029B (en) * | 2020-09-09 | 2022-04-08 | 中国科学院兰州化学物理研究所 | Composite lithium-based thickening agent, lubricating grease prepared from composite lithium-based thickening agent and preparation method of lubricating grease |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102199471A (en) * | 2010-03-25 | 2011-09-28 | 中国石油化工股份有限公司 | Environmental protection type lubricating grease composition and method for preparing same |
| CN102433195A (en) * | 2011-10-24 | 2012-05-02 | 中国石油化工股份有限公司 | Open gear lubricating grease composition |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06179889A (en) * | 1992-12-11 | 1994-06-28 | Showa Shell Sekiyu Kk | Lubricant composition for hot rolling and method for rolling using the same |
-
2016
- 2016-10-05 CN CN201610877918.3A patent/CN106497651B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102199471A (en) * | 2010-03-25 | 2011-09-28 | 中国石油化工股份有限公司 | Environmental protection type lubricating grease composition and method for preparing same |
| CN102433195A (en) * | 2011-10-24 | 2012-05-02 | 中国石油化工股份有限公司 | Open gear lubricating grease composition |
Non-Patent Citations (1)
| Title |
|---|
| 硫酯类抗氧剂的合成与应用;李杰等;《塑料助剂》;20091231(第4期);第29-33页 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106497651A (en) | 2017-03-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106497651B (en) | A kind of engineering machinery lubricating grease and preparation method with high biological degradability | |
| CN101230304B (en) | Environment-friendly type transformer oil and preparation method thereof | |
| EP3080234B1 (en) | An aqueous lubricant composition, a method for making the same and uses thereof | |
| CN103031192B (en) | Connection occlusion agent for oil extraction conical screw rod of screw pump and preparation method thereof | |
| CN103484204B (en) | Lubricating grease containing improved silica component and its preparation method | |
| CN103396865A (en) | Environment-friendly high-wear-resistance lubricating oil and preparation method thereof | |
| JP2010209129A (en) | Grease composition and rolling bearing | |
| CN101747989B (en) | Preparation method of trench-oil based metal cutting fluid | |
| Hamnas et al. | Bio-lubricants from vegetable oils: Characterization, modifications, applications and challenges–Review | |
| CN102604723B (en) | Lubricating grease composition and preparation method thereof | |
| CN107057379A (en) | A kind of solid tyre RX and preparation method | |
| CN102311722A (en) | Aliphatic acid lubricant for petroleum drilling fluid | |
| CN102787003B (en) | Compound lubricating grease and preparation method of compound lubricating grease | |
| CN107384551A (en) | A kind of high-effect wear-resistant lubricating oil and preparation method thereof | |
| CN105112144A (en) | Degradable lubricating grease | |
| CN104109568B (en) | Biodiesel is for the preparation of the application of environment-friendly metal working fluid | |
| CN105199817A (en) | Low-temperature lithium-calcium bearing lubricating grease and preparation method | |
| CN104342249A (en) | Biodegradable lubricant and preparation method thereof | |
| CN107418690A (en) | New thixotropic grease and preparation method thereof | |
| CN105733755A (en) | Lubricating grease for biomass-energy granulator | |
| CN106635279A (en) | Anti-rusting and scale-inhibiting transformer vegetable insulating oil and preparation method thereof | |
| CN107384554A (en) | A kind of environment-friendly type mechanical lubrication agent and preparation method thereof | |
| CN107760424A (en) | A kind of automation equipment biological based lubricating oil and preparation method thereof | |
| CN101899355A (en) | Lubricating oil composite with oxidation resistance and preparation method thereof | |
| CN106635247A (en) | Environment-friendly hydraulic oil composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |