CN109207243A - A kind of environment-friendly type aluminium alloy water-base cutting fluid - Google Patents

A kind of environment-friendly type aluminium alloy water-base cutting fluid Download PDF

Info

Publication number
CN109207243A
CN109207243A CN201811104049.6A CN201811104049A CN109207243A CN 109207243 A CN109207243 A CN 109207243A CN 201811104049 A CN201811104049 A CN 201811104049A CN 109207243 A CN109207243 A CN 109207243A
Authority
CN
China
Prior art keywords
parts
cutting fluid
environment
aluminium alloy
friendly type
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201811104049.6A
Other languages
Chinese (zh)
Inventor
胡次兵
兰梅菊
朱东东
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Foshan Chancheng No High Environmental Protection Technology Co Ltd
Original Assignee
Foshan Chancheng No High Environmental Protection Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Foshan Chancheng No High Environmental Protection Technology Co Ltd filed Critical Foshan Chancheng No High Environmental Protection Technology Co Ltd
Priority to CN201811104049.6A priority Critical patent/CN109207243A/en
Publication of CN109207243A publication Critical patent/CN109207243A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08—Inorganic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08—Inorganic acids or salts thereof
    • C10M2201/084—Inorganic acids or salts thereof containing sulfur, selenium or tellurium
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/124—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms containing hydroxy groups; Ethers thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/12—Polysaccharides, e.g. cellulose, biopolymers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/02—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only
    • C10M2211/024—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only aromatic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08—Amides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/14—Containing carbon-to-nitrogen double bounds, e.g. guanidines, hydrazones, semicarbazones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/044—Polyamides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/08—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions having metal-to-carbon bonds
    • C10M2227/081—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions having metal-to-carbon bonds with a metal carbon bond belonging to a ring, e.g. ferocene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/245—Soft metals, e.g. aluminum

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses a kind of environment-friendly type aluminium alloy water-base cutting fluids, belong to metal protection technical field.The present invention is by vegetable oil, lipase, poly-aspartic-acid, surfactant, maltonic acid sodium, sodium molybdate, zinc sulfate, organic acid, modified additive, carbomer, chelating agent and water are stirred, and are subsequently added into isocyanates, are stirred to get environment-friendly type aluminium alloy water-base cutting fluid；(N- amidino groups) dodecylacrylamide is mixed with methoxy poly (ethylene glycol) 1:1~2:1 in mass ratio, and 0.1~0.2 times of polyethyleneglycol derivative quality of paracide and 0.07~0.10 times of polyethyleneglycol derivative quality of ferrocene is added, it is stirred to get modified additive.Environment-friendly type aluminium alloy water-base cutting fluid provided by the invention has excellent lubricant effect, cooling effect and rustless property.

Description

A kind of environment-friendly type aluminium alloy water-base cutting fluid
Technical field
The invention discloses a kind of environment-friendly type aluminium alloy water-base cutting fluids, belong to metal protection technical field.
Background technique
Metal cutting process is most common, most widely used one kind in intermetallic composite coating.Metal cutting process refers to by machine Under conditions of bed provides necessary movement and power, metal extra on (or grinding) blank is cut off with cutter (or grinding tool), from And obtain the process of the satisfactory workpiece of shape, precision and surface quality.According to the shape, precision and surface quality of workpiece Difference, machining can be divided into vehicle, milling, brill, plane, boring, strand, drawing and grinding etc..Metal material is cut by predetermined dimension When (or grinding) processing, in order to mitigate the friction between tool and workpiece, increases lubricity, take away the heat generated by friction With improve productivity, in tool and the liquid for being cut, being injected between the metal material that is ground, referred to as metalworking fluid.Metal Cutting fluid is indispensable condiment in metal cutting process.Cutting fluid is reasonably used, then it is left that cutting speed 30% can be improved The right side reduces by 100~150 DEG C of cutting temperature, reduces cutting force 10%~30%, extends 4~5 times of cutter life, improves workpiece surface Processing quality, and processing cost can be reduced.
Metalworking fluid can be divided into oil base cutting fluid and water-base cutting fluid by medium condition.Water-base cutting fluid can be divided into 3 classes, That is emulsion, synthetic cutting fluid and semi-synthetic cutting fluid (microemulsion).Oil base cutting fluid lubricity is good, and cooling effect is poor, It is mainly used for the machining of low-speed heavy cut processing and difficult-to-machine material.Emulsion cutting fluid mainly by mineral oil, emulsifier, The composition such as antirust agent, oiliness improver, extreme pressure agent, preservative and water.Emulsion cutting fluid is the lubricity of oil and the pole of rust-preventing characteristic and water Good cooling combines, and is provided simultaneously with preferable lubrication, thus for the metal cutting process of high speed underload ten Divide effective.Synthetic cutting fluid is made of water soluble anti-rust agent, oiliness improver, extreme pressure agent, surfactant and defoaming agent etc..With cream Change liquid phase ratio, synthetic cutting fluid long service life, cooling and cleaning performance is excellent, is suitble to high-speed cutting.But lubricity is owed It is good, easily cause the adhesion and abrasion of lathe movable part, and the thick residue that synthetic cutting fluid leaves will affect machine zero The movement of part.The concentrate of semi-synthetic cutting fluid is by a small amount of mineral oil, oiliness improver, extreme pressure agent, antirust agent, surfactant and anti- The composition such as rotten agent.Semi-synthetic cutting fluid has the good lubricity of emulsion cutting fluid and the good feature of synthetic cutting fluid cleaning concurrently, Long service life.For aluminium alloy water-base cutting fluid traditional at present there is also lubricant effect, cooling effect and rustless property are bad Problem also needs to study it.
Summary of the invention
The present invention solves the technical problem of: for traditional aluminium alloy water-base cutting fluid lubricant effect, cooling effect The bad problem with rustless property provides a kind of environment-friendly type aluminium alloy water-base cutting fluid.
In order to solve the above-mentioned technical problem, the technical scheme adopted by the invention is that:
A kind of environment-friendly type aluminium alloy water-base cutting fluid, is made of the raw material of following parts by weight: 10~15 parts of vegetable oil, and 0.5 ~0.8 part of lipase, 5~8 parts of poly-aspartic-acids, 5~8 parts of surfactants, 3~5 parts of maltonic acid sodium, 2~3 parts of molybdenums Sour sodium, 2~3 parts of zinc sulfate, 2~3 parts of organic acids, 5~8 parts of modified additives, 5~8 parts of carbomers, 2~3 parts of chelating agents, 3~ 5 parts of isocyanates, 40~60 parts of water；
The process for preparation of the environment-friendly type aluminium alloy water-base cutting fluid are as follows: each raw material is weighed by raw material composition, by vegetable oil, fat Enzyme, poly-aspartic-acid, surfactant, maltonic acid sodium, sodium molybdate, zinc sulfate, organic acid, modified additive, card wave Nurse, chelating agent and water are stirred, and are subsequently added into isocyanates, are stirred to get environment-friendly type aluminium alloy water-base cutting fluid.
The vegetable oil is peanut oil, sunflower oil, any one in rapeseed oil or soybean oil.
The surfactant is sarcosyl, any in hydroxypropyl cellulose sodium or sodium cellulose glycolate It is a kind of.
The organic acid is linoleic acid, any one in humic acid or rich dimension acid.
The preparation process of the modified additive are as follows: by (N- amidino groups) dodecylacrylamide and methoxy poly (ethylene glycol) The mixing of 1:1~2:1 in mass ratio, and 0.1~0.2 times of polyethyleneglycol derivative quality of paracide is added and polyethylene glycol spreads out The ferrocene that 0.07~0.10 times of biological quality, is stirred to get modified additive.
The carbomer is CARBOPOL 971, any one in CARBOPOL 974P or carbomer940.
The chelating agent is any one in citric acid or malic acid.
The isocyanates is toluene di-isocyanate(TDI), isofoer diisocyanate or dicyclohexyl methyl hydride diisocyanate Any one in ester.
The beneficial effects of the present invention are:
The present invention is by addition modified additive and isocyanates, firstly, isocyanates is reacted with water in mixing process, it is raw At carbon dioxide and amine substance, meanwhile, modified additive have it is amphipathic, i.e. polyethylene glycol segment is hydrophilic, and poly- (N- amidine Base) dodecylacrylamide segment is hydrophobic, and for such block copolymer in system, the generation of carbon dioxide can be with the block Amidine group reaction in copolymer, and make charge on amidine group band, imitated vesicle structure inner bulk is made since like charges are mutually exclusive Product increases, secondly, expansion vesicle surface is positively charged and is gathered in around cutter at the initial stage of using, plays good lubrication Effect generates a large amount of cutting heat with the progress of cutting operation, and heat promotes the carbon dioxide in imitated vesicle structure to discharge, gas The diffusion of body carries a large amount of heat, good cooling effect is played, simultaneously as vesica is adsorbed on cutting tool aluminium The junction of alloy, it is therefore provided that the cooling effect of product is further promoted, phase after use, due to expanding vesica band Positive charge can adsorb the chip generated in cutting process, chip is avoided to be gathered in incision, influence fast dissipation cutting heat, With the progress of cutting process, vesica is heated, so that its carbon dioxide released increases, the positively charged charge of institute weakens, greatly The chip of partial size is detached from vesicle surface, and the lesser chip of partial size is still adsorbed on vesicle surface, after operation to be cut, vesica Aluminum alloy surface is adhered to and be distributed in structure, has effectively obstructed air, to improve the rustless property of system.
Specific embodiment
(N- amidino groups) dodecylacrylamide is placed in a beaker with methoxy poly (ethylene glycol) 1:1~2:1 in mass ratio, And into beaker be added 0.1~0.2 times of polyethyleneglycol derivative quality paracide and polyethyleneglycol derivative quality 0.07 ~0.10 times of ferrocene is stirred 30~50min under the conditions of revolving speed is 300~500r/min；According to parts by weight, By 10~15 parts of vegetable oil, 0.5~0.8 part of lipase, 5~8 parts of poly-aspartic-acids, 5~8 parts of surfactants, 3~5 parts Maltonic acid sodium, 2~3 parts of sodium molybdates, 2~3 parts of zinc sulfate, 2~3 parts of organic acids, 5~8 parts of modified additives, 5~8 parts of cards Wave nurse, 2~3 parts of chelating agents, 3~5 parts of isocyanates, 40~60 parts of water, by vegetable oil, lipase, poly-aspartic-acid, surface Activating agent, maltonic acid sodium, sodium molybdate, zinc sulfate, organic acid, modified additive, carbomer, chelating agent and water are placed in mixing In machine, under the conditions of revolving speed is 1100~1200r/min, it is stirred 40~60min, is subsequently added into isocyanates, in revolving speed Under the conditions of 1100~1200r/min, 40~60min is stirred to get environment-friendly type aluminium alloy water-base cutting fluid.The plant Oil is peanut oil, sunflower oil, any one in rapeseed oil or soybean oil.The surfactant is lauryl creatine acid Any one in sodium, hydroxypropyl cellulose sodium or sodium cellulose glycolate.The organic acid is linoleic acid, humic acid or rich dimension acid In any one.The carbomer is CARBOPOL 971, any one in CARBOPOL 974P or carbomer940.The chela Mixture is any one in citric acid or malic acid.The isocyanates is toluene di-isocyanate(TDI), different two isocyanide of Fu Er ketone Any one in acid esters or dicyclohexyl methyl hydride diisocyanate.
(N- amidino groups) dodecylacrylamide is placed in a beaker with methoxy poly (ethylene glycol) 2:1 in mass ratio, and to 0.2 times of polyethyleneglycol derivative quality of paracide and the two of 0.10 times of polyethyleneglycol derivative quality cyclopentadienyls are added in beaker Iron is stirred 50min under the conditions of revolving speed is 500r/min；According to parts by weight, by 15 parts of vegetable oil, 0.8 part of fat Enzyme, 8 parts of poly-aspartic-acids, 8 parts of surfactants, 5 parts of maltonic acid sodium, 3 parts of sodium molybdates, 3 parts of zinc sulfate, 3 parts organic Acid, 8 parts of modified additives, 8 parts of carbomers, 3 parts of chelating agents, 5 parts of isocyanates, 60 parts of water, by vegetable oil, lipase, poly- day L-aminobutanedioic acid, surfactant, maltonic acid sodium, sodium molybdate, zinc sulfate, organic acid, modified additive, carbomer, chelating Agent and water are placed in batch mixer, under the conditions of revolving speed is 1200r/min, is stirred 60min, is subsequently added into isocyanates, in Under the conditions of revolving speed is 1200r/min, 60min is stirred to get environment-friendly type aluminium alloy water-base cutting fluid.The vegetable oil is flower Oil generation.The surfactant is sarcosyl.The organic acid is linoleic acid.The carbomer is carbomer 971P.The chelating agent is citric acid.The isocyanates is toluene di-isocyanate(TDI).
(N- amidino groups) dodecylacrylamide is placed in a beaker with methoxy poly (ethylene glycol) 2:1 in mass ratio, and to 0.2 times of polyethyleneglycol derivative quality of paracide and the two of 0.10 times of polyethyleneglycol derivative quality cyclopentadienyls are added in beaker Iron is stirred 50min under the conditions of revolving speed is 500r/min；According to parts by weight, by 0.8 part of lipase, 8 parts of poly- Tianmens Aspartic acid, 8 parts of surfactants, 5 parts of maltonic acid sodium, 3 parts of sodium molybdates, 3 parts of zinc sulfate, 3 parts of organic acids, 8 parts of modifications add Add agent, 8 parts of carbomers, 3 parts of chelating agents, 5 parts of isocyanates, 60 parts of water, by lipase, poly-aspartic-acid, surfactant, Maltonic acid sodium, sodium molybdate, zinc sulfate, organic acid, modified additive, carbomer, chelating agent and water are placed in batch mixer, in Under the conditions of revolving speed is 1200r/min, it is stirred 60min, is subsequently added into isocyanates, under the conditions of revolving speed is 1200r/min, 60min is stirred to get environment-friendly type aluminium alloy water-base cutting fluid.The surfactant is sarcosyl.Institute Stating organic acid is linoleic acid.The carbomer is CARBOPOL 971.The chelating agent is citric acid.The isocyanates is toluene Diisocyanate.
(N- amidino groups) dodecylacrylamide is placed in a beaker with methoxy poly (ethylene glycol) 2:1 in mass ratio, and to 0.2 times of polyethyleneglycol derivative quality of paracide and the two of 0.10 times of polyethyleneglycol derivative quality cyclopentadienyls are added in beaker Iron is stirred 50min under the conditions of revolving speed is 500r/min；According to parts by weight, by 15 parts of vegetable oil, 8 parts of poly- lucid asparagus Propylhomoserin, 8 parts of surfactants, 5 parts of maltonic acid sodium, 3 parts of sodium molybdates, 3 parts of zinc sulfate, 3 parts of organic acids, 8 parts of modified additions Agent, 8 parts of carbomers, 3 parts of chelating agents, 5 parts of isocyanates, 60 parts of water, by vegetable oil, poly-aspartic-acid, surfactant, D- Sodium gluconate, sodium molybdate, zinc sulfate, organic acid, modified additive, carbomer, chelating agent and water are placed in batch mixer, in turn Under the conditions of speed is 1200r/min, it is stirred 60min, is subsequently added into isocyanates, under the conditions of revolving speed is 1200r/min, stirred Mixing 60min is mixed to get environment-friendly type aluminium alloy water-base cutting fluid.The vegetable oil is peanut oil.The surfactant is ten Sarkosyl sodium.The organic acid is linoleic acid.The carbomer is CARBOPOL 971.The chelating agent is citric acid. The isocyanates is toluene di-isocyanate(TDI).
(N- amidino groups) dodecylacrylamide is placed in a beaker with methoxy poly (ethylene glycol) 2:1 in mass ratio, and to 0.2 times of polyethyleneglycol derivative quality of paracide and the two of 0.10 times of polyethyleneglycol derivative quality cyclopentadienyls are added in beaker Iron is stirred 50min under the conditions of revolving speed is 500r/min；According to parts by weight, by 15 parts of vegetable oil, 0.8 part of fat Enzyme, 8 parts of surfactants, 5 parts of maltonic acid sodium, 3 parts of sodium molybdates, 3 parts of zinc sulfate, 3 parts of organic acids, 8 parts of modified additives, 8 parts of carbomers, 3 parts of chelating agents, 5 parts of isocyanates, 60 parts of water, by vegetable oil, lipase, surfactant, maltonic acid Sodium, sodium molybdate, zinc sulfate, organic acid, modified additive, carbomer, chelating agent and water are placed in batch mixer, are in revolving speed Under the conditions of 1200r/min, it is stirred 60min, is subsequently added into isocyanates, under the conditions of revolving speed is 1200r/min, stirring is mixed 60min is closed to get environment-friendly type aluminium alloy water-base cutting fluid.The vegetable oil is peanut oil.The surfactant is dodecane Base sodium sarcosinate.The organic acid is linoleic acid.The carbomer is CARBOPOL 971.The chelating agent is citric acid.It is described Isocyanates is toluene di-isocyanate(TDI).
(N- amidino groups) dodecylacrylamide is placed in a beaker with methoxy poly (ethylene glycol) 2:1 in mass ratio, and to 0.2 times of polyethyleneglycol derivative quality of paracide and the two of 0.10 times of polyethyleneglycol derivative quality cyclopentadienyls are added in beaker Iron is stirred 50min under the conditions of revolving speed is 500r/min；According to parts by weight, by 15 parts of vegetable oil, 0.8 part of fat Enzyme, 8 parts of poly-aspartic-acids, 8 parts of surfactants, 5 parts of maltonic acid sodium, 3 parts of sodium molybdates, 3 parts of zinc sulfate, 8 parts of modifications Additive, 8 parts of carbomers, 3 parts of chelating agents, 5 parts of isocyanates, 60 parts of water, by vegetable oil, lipase, poly-aspartic-acid, table Face activating agent, maltonic acid sodium, sodium molybdate, zinc sulfate, modified additive, carbomer, chelating agent and water are placed in batch mixer, In revolving speed be 1200r/min under the conditions of, be stirred 60min, be subsequently added into isocyanates, in revolving speed be 1200r/min condition Under, 60min is stirred to get environment-friendly type aluminium alloy water-base cutting fluid.The vegetable oil is peanut oil.The surfactant For sarcosyl.The carbomer is CARBOPOL 971.The chelating agent is citric acid.The isocyanates is first Phenylene diisocyanate.
(N- amidino groups) dodecylacrylamide is placed in a beaker with methoxy poly (ethylene glycol) 2:1 in mass ratio, and to 0.2 times of polyethyleneglycol derivative quality of paracide and the two of 0.10 times of polyethyleneglycol derivative quality cyclopentadienyls are added in beaker Iron is stirred 50min under the conditions of revolving speed is 500r/min；According to parts by weight, by 15 parts of vegetable oil, 0.8 part of fat Enzyme, 8 parts of poly-aspartic-acids, 8 parts of surfactants, 5 parts of maltonic acid sodium, 3 parts of sodium molybdates, 3 parts of zinc sulfate, 3 parts organic Acid, 8 parts of carbomers, 3 parts of chelating agents, 5 parts of isocyanates, 60 parts of water, by vegetable oil, lipase, poly-aspartic-acid, surface is lived Property agent, maltonic acid sodium, sodium molybdate, zinc sulfate, organic acid, carbomer, chelating agent and water are placed in batch mixer, are in revolving speed Under the conditions of 1200r/min, it is stirred 60min, is subsequently added into isocyanates, under the conditions of revolving speed is 1200r/min, stirring is mixed 60min is closed to get environment-friendly type aluminium alloy water-base cutting fluid.The vegetable oil is peanut oil.The surfactant is dodecane Base sodium sarcosinate.The organic acid is linoleic acid.The carbomer is CARBOPOL 971.The chelating agent is citric acid.It is described Isocyanates is toluene di-isocyanate(TDI).
(N- amidino groups) dodecylacrylamide is placed in a beaker with methoxy poly (ethylene glycol) 2:1 in mass ratio, and to 0.2 times of polyethyleneglycol derivative quality of paracide and the two of 0.10 times of polyethyleneglycol derivative quality cyclopentadienyls are added in beaker Iron is stirred 50min under the conditions of revolving speed is 500r/min；According to parts by weight, by 15 parts of vegetable oil, 0.8 part of fat Enzyme, 8 parts of poly-aspartic-acids, 8 parts of surfactants, 5 parts of maltonic acid sodium, 3 parts of sodium molybdates, 3 parts of zinc sulfate, 3 parts organic Acid, 8 parts of modified additives, 3 parts of chelating agents, 5 parts of isocyanates, 60 parts of water, by vegetable oil, lipase, poly-aspartic-acid, table Face activating agent, maltonic acid sodium, sodium molybdate, zinc sulfate, organic acid, modified additive, chelating agent and water are placed in batch mixer, In revolving speed be 1200r/min under the conditions of, be stirred 60min, be subsequently added into isocyanates, in revolving speed be 1200r/min condition Under, 60min is stirred to get environment-friendly type aluminium alloy water-base cutting fluid.The vegetable oil is peanut oil.The surfactant For sarcosyl.The organic acid is linoleic acid.The chelating agent is citric acid.The isocyanates is toluene two Isocyanates.
(N- amidino groups) dodecylacrylamide is placed in a beaker with methoxy poly (ethylene glycol) 2:1 in mass ratio, and to 0.2 times of polyethyleneglycol derivative quality of paracide and the two of 0.10 times of polyethyleneglycol derivative quality cyclopentadienyls are added in beaker Iron is stirred 50min under the conditions of revolving speed is 500r/min；According to parts by weight, by 15 parts of vegetable oil, 0.8 part of fat Enzyme, 8 parts of poly-aspartic-acids, 8 parts of surfactants, 5 parts of maltonic acid sodium, 3 parts of sodium molybdates, 3 parts of zinc sulfate, 3 parts organic Acid, 8 parts of modified additives, 8 parts of carbomers, 3 parts of chelating agents, 60 parts of water, by vegetable oil, lipase, poly-aspartic-acid, surface Activating agent, maltonic acid sodium, sodium molybdate, zinc sulfate, organic acid, modified additive, carbomer, chelating agent and water are placed in mixing In machine, under the conditions of revolving speed is 1200r/min, 60min is stirred to get environment-friendly type aluminium alloy water-base cutting fluid.The plant Object oil is peanut oil.The surfactant is sarcosyl.The organic acid is linoleic acid.The carbomer is CARBOPOL 971.The chelating agent is citric acid.
(N- amidino groups) dodecylacrylamide is placed in a beaker with methoxy poly (ethylene glycol) 2:1 in mass ratio, and to 0.2 times of polyethyleneglycol derivative quality of paracide and the two of 0.10 times of polyethyleneglycol derivative quality cyclopentadienyls are added in beaker Iron is stirred 50min under the conditions of revolving speed is 500r/min；According to parts by weight, by 15 parts of vegetable oil, 0.8 part of fat Enzyme, 8 parts of poly-aspartic-acids, 8 parts of surfactants, 5 parts of maltonic acid sodium, 3 parts of sodium molybdates, 3 parts of zinc sulfate, 3 parts organic Acid, 8 parts of modified additives, 8 parts of carbomers, 3 parts of chelating agents, 5 parts of isocyanates, 60 parts of water, by vegetable oil, lipase, poly- day L-aminobutanedioic acid, surfactant, maltonic acid sodium, sodium molybdate, zinc sulfate, organic acid, modified additive, carbomer, chelating Agent and water are placed in batch mixer, under the conditions of revolving speed is 1200r/min, is stirred 60min, is subsequently added into isocyanates, in Under the conditions of revolving speed is 1200r/min, 60min is stirred to get environment-friendly type aluminium alloy water-base cutting fluid.The vegetable oil is flower Oil generation.The surfactant is sarcosyl.The organic acid is linoleic acid.The carbomer is carbomer 971P.The chelating agent is citric acid.The isocyanates is toluene di-isocyanate(TDI).
Comparative example: the water-base cutting fluid of Dongguan rush-resisting material Co., Ltd production.
1 to 8 gained cutting fluid of example and comparative example product are subjected to performance detection, the specific detection method is as follows:
The rustless property and cooling performance of above-mentioned cutting fluid are detected according to GB/T6144-85；Manufactured and designed using Tsinghua University Ball-disk-type friction wear test machine testing friction and wear behavior.Specific testing result is as shown in table 1:
Table 1: performance detection table
Detection content Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Example 8 Comparative example
Non-corrosive points 10 9 8.5 9 9 8 8.5 9 7.5
Coefficient of friction 0.143 0.195 0.203 0.187 0.193 0.205 0.186 0.185 0.251
Thermal coefficient W/(mK) 2.05 1.45 1.52 1.36 1.25 0.99 1.12 1.08 0.79
It is cooling by 1 testing result of table it is found that present invention gained environment-friendly type aluminium alloy water-base cutting fluid has excellent lubricant effect Effect and rustless property.

Claims (8)

1. a kind of environment-friendly type aluminium alloy water-base cutting fluid, it is characterised in that: be made of the raw material of following parts by weight: 10~15 Part vegetable oil, 0.5~0.8 part of lipase, 5~8 parts of poly-aspartic-acids, 5~8 parts of surfactants, 3~5 parts of D-Glucoses Sour sodium, 2~3 parts of sodium molybdates, 2~3 parts of zinc sulfate, 2~3 parts of organic acids, 5~8 parts of modified additives, 5~8 parts of carbomers, 2~ 3 parts of chelating agents, 3~5 parts of isocyanates, 40~60 parts of water；
The process for preparation of the environment-friendly type aluminium alloy water-base cutting fluid are as follows: each raw material is weighed by raw material composition, by vegetable oil, fat Enzyme, poly-aspartic-acid, surfactant, maltonic acid sodium, sodium molybdate, zinc sulfate, organic acid, modified additive, card wave Nurse, chelating agent and water are stirred, and are subsequently added into isocyanates, are stirred to get environment-friendly type aluminium alloy water-base cutting fluid.
2. a kind of environment-friendly type aluminium alloy water-base cutting fluid according to claim 1, it is characterised in that: the vegetable oil is peanut Any one in oil, sunflower oil, rapeseed oil or soybean oil.
3. a kind of environment-friendly type aluminium alloy water-base cutting fluid according to claim 1, it is characterised in that: the surfactant is Any one in sarcosyl, hydroxypropyl cellulose sodium or sodium cellulose glycolate.
4. a kind of environment-friendly type aluminium alloy water-base cutting fluid according to claim 1, it is characterised in that: the organic acid is sub- oil Acid, humic acid or any one rich tieed up in acid.
5. a kind of environment-friendly type aluminium alloy water-base cutting fluid according to claim 1, it is characterised in that: the modified additive Preparation process are as follows: (N- amidino groups) dodecylacrylamide is mixed with methoxy poly (ethylene glycol) 1:1~2:1 in mass ratio, and Be added 0.1~0.2 times of polyethyleneglycol derivative quality paracide and 0.07~0.10 times of polyethyleneglycol derivative quality Ferrocene is stirred to get modified additive.
6. a kind of environment-friendly type aluminium alloy water-base cutting fluid according to claim 1, it is characterised in that: the carbomer is card wave Any one in nurse 971P, CARBOPOL 974P or carbomer940.
7. a kind of environment-friendly type aluminium alloy water-base cutting fluid according to claim 1, it is characterised in that: the chelating agent is lemon Acid or malic acid in any one.
8. a kind of environment-friendly type aluminium alloy water-base cutting fluid according to claim 1, it is characterised in that: the isocyanates is first Any one in phenylene diisocyanate, isofoer diisocyanate or dicyclohexyl methyl hydride diisocyanate.
CN201811104049.6A 2018-09-21 2018-09-21 A kind of environment-friendly type aluminium alloy water-base cutting fluid Withdrawn CN109207243A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811104049.6A CN109207243A (en) 2018-09-21 2018-09-21 A kind of environment-friendly type aluminium alloy water-base cutting fluid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811104049.6A CN109207243A (en) 2018-09-21 2018-09-21 A kind of environment-friendly type aluminium alloy water-base cutting fluid

Publications (1)

Publication Number Publication Date
CN109207243A true CN109207243A (en) 2019-01-15

Family

ID=64984747

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811104049.6A Withdrawn CN109207243A (en) 2018-09-21 2018-09-21 A kind of environment-friendly type aluminium alloy water-base cutting fluid

Country Status (1)

Country Link
CN (1) CN109207243A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108456590A (en) * 2018-03-12 2018-08-28 苏州福瑞斯德新材料科技有限公司 A kind of environment-friendly type micro-lubricating cutting liquid composition
CN109943083A (en) * 2019-02-20 2019-06-28 庄文琴 A kind of preparation method of stretch-proof compound rubber asphalt mixture

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108456590A (en) * 2018-03-12 2018-08-28 苏州福瑞斯德新材料科技有限公司 A kind of environment-friendly type micro-lubricating cutting liquid composition
CN109943083A (en) * 2019-02-20 2019-06-28 庄文琴 A kind of preparation method of stretch-proof compound rubber asphalt mixture

Similar Documents

Publication Publication Date Title
CN101870909B (en) Magnesium alloy cutting liquid
CN101717684B (en) Spray supply mode cutting oil for metal material cutting processing
CN106800963B (en) A kind of water soluble oil metalworking fluid raw material and metalworking fluid
CN109207243A (en) A kind of environment-friendly type aluminium alloy water-base cutting fluid
KR20080106468A (en) Oil composition for metal working, method for metal working and metal work
CN109439419B (en) Cutting oil with ultrahigh lubricating property and preparation method thereof
CN106590907A (en) Graphene-containing metal cutting fluid and preparation method thereof
CN105950268A (en) Metal processing multifunctional lubricating agent containing graphene additive and preparation method of metal processing multifunctional lubricating agent
CN105154180A (en) Preparation method of rolling oil for cold rolling of sheets
CN108359522A (en) A kind of Biostatic type metal working fluid and preparation method thereof
CN104357181A (en) Special magnetic cutting oil and preparation method thereof
CN107011977B (en) Cutting fluid and preparation method thereof
CN102766500A (en) High-base-number compound-sulfonic lithium/calcium composite lubricating grease and preparation method thereof
CN105713700A (en) Base oil for metal working fluid and preparation method of base oil
CN106811280A (en) A kind of cutting fluid and preparation method thereof
CN103351926A (en) Water base emulsified cutting fluid and preparation method thereof
CN111117754A (en) High-lubrication stable cutting fluid and preparation method thereof
CN103351937B (en) Water-soluble cutting fluid and preparation method thereof
CN108504432A (en) Metal cutting environmentally friendly synthetic cutting fluid and preparation method thereof
CN107828489A (en) A kind of environment-friendly type metal cutting fluid and preparation method thereof
CN102766519A (en) Cutting fluid for after-cutting processing of neodymium iron boron
WO2021128618A1 (en) Environment-friendly cutter grinding oil
JPH01301793A (en) Lubricating oil
CN104342276A (en) Special cutting fluid for aluminum profile, and preparation method thereof
CN115651744B (en) Environment-friendly microemulsion cutting fluid

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication
WW01 Invention patent application withdrawn after publication

Application publication date: 20190115