CN107384017A - A kind of woodgrained paper Special digital air brushing ink and preparation method thereof - Google Patents
A kind of woodgrained paper Special digital air brushing ink and preparation method thereof Download PDFInfo
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- CN107384017A CN107384017A CN201710810609.9A CN201710810609A CN107384017A CN 107384017 A CN107384017 A CN 107384017A CN 201710810609 A CN201710810609 A CN 201710810609A CN 107384017 A CN107384017 A CN 107384017A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
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Abstract
A kind of woodgrained paper Special digital air brushing ink, is made up of the raw material of following parts by weight：4~10 parts of pigment, 1~2 part of wetting dispersing agent, 10~15 parts of absolute ethyl alcohol, 5~10 parts of diethylene glycol (DEG), 1~2 part of defoamer, 20~40 parts of water-based acrylic resin emulsion, 25~45 parts of deionized water；The ink system average grain diameter is small and narrow distribution, and storage stability is good, and air brushing color ink color after wood grain paper is clear, full, and pattern stereoscopic impression is strong, and the pigment ink sunlight fastness, heat-resistant stability are preferable.
Description
(1) technical field
The present invention relates to a kind of water-based ink and preparation method thereof, and in particular to a kind of woodgrained paper Special digital air brushing ink
And preparation method thereof.
(2) background technology
Compared to the gravure printing technique largely used now, numerial code spray drawing technology have can small lot production, can individual character
The features such as changing customization, and equipment volume needed for numerial code spray drawing printing is small, in the case of limited in space, still can efficiently produce,
Therefore increasingly favored at present by market.
During digit inkjet printer continuous inkjet, it is desirable to ink nonchoking nozzle, and soaked all the time at nozzle, this will
Good wetability need to be had to nozzle by asking while the average grain diameter of color type air brushing ink system is small, particle diameter distribution is narrow.Also need
Point out, because stock is wood grain paper, ink rate of drying is greater than to paper penetration speed, otherwise easily occurred between ink droplet
Colour contamination, causes color that aberration occurs, and pattern stereoscopic impression is deteriorated.
And the wood grain paper Special digital air brushing ink of commercial type only possesses single or several features mostly at present, nothing
Method is taken into account, therefore needs to research and develop new product and substituted.
(3) content of the invention
In view of the shortcomings of the prior art, the invention provides a kind of woodgrained paper Special digital air brushing ink and its preparation side
Method.The coding ink system average grain diameter is small, particle diameter distribution is narrow, has that not stifled nozzle, easy cleaning, stability is good, rate of drying
It hurry up, be moderate to paper penetration power, the advantages that paper does not crease easily.
Technical scheme is as follows：
A kind of woodgrained paper Special digital air brushing ink, is made up of the raw material of following parts by weight：
4~10 parts of pigment, 1~2 part of wetting dispersing agent, 10~15 parts of absolute ethyl alcohol, 5~10 parts of diethylene glycol (DEG), defoamer 1~
2 parts, 20~40 parts of water-based acrylic resin emulsion, 25~45 parts of deionized water.
Particularly preferred, the woodgrained paper Special digital air brushing ink is made up of the raw material of following parts by weight：
8 parts of pigment, 1 part of wetting dispersing agent, 10 parts of absolute ethyl alcohol, 5 parts of diethylene glycol (DEG), 1 part of defoamer, water-based acrylic resin
30 parts of emulsion, 45 parts of deionized water.
The pigment is selected from one of following：It is the blue BG of Clariant Corporation production, blue A4R, blue A2R, red D3G, red B, red
HGR, red 3B, red BNP, red HB, red HF4B, red E3B, red E5B, red HG, red HFT, yellow HR02, yellow HR, yellow HG, yellow H9G, H2G,
Yellow H2GR, yellow HGR, yellow H3R or yellow HGGVP2388；Black the 0066 of BASF AG's production.
The wetting dispersing agent is selected from the mixture of one of the following or two or more arbitrary proportions：BYK companies produce
DISPERBYK-102, DISPERBYK-103, DISPERBYK-106, DISPERBYK-109, DISPERBYK-115,
DISPERBYK-130、DISPERBYK-142、DISPERBYK-145、DISPERBYK-194N、DISPERBYK-2050、
DISPERBYK-2118、DISPERBYK-2164、BYKJET-9131、BYKJET-9133、BYKJET-9142、BYKJET-
9150th, BYKJET-9151, BYKJET-9152 and BYKJET-9170.
The defoamer is selected from the mixture of one of the following or two or more arbitrary proportions：The production of BYK companies
BYK-012、BYK-016、BYK-017、BYK-019、BYK-021、BYK-022、BYK-024、BYK-044、BYK-065、BYK-
066N, BYK-088 and BYK-094.
The water-based acrylic resin emulsion is self-control, and its composition of raw materials and preparation method are disclosed in patent document
CN103601837A.Particularly preferred, the water-based acrylic resin emulsion is prepared as follows obtaining (following preparation method
In, number refers both to parts by weight)：
(1) 0.05 part of lauryl sodium sulfate and 0.2 part of NPE are dissolved in 5 parts of deionized waters and are formed
Aqueous phase, then 25 parts of methyl methacrylates and 1 part of n-butyl acrylate are added to aqueous phase, 30 DEG C, stir under the conditions of 400rpm
30min carries out pre-emulsification, forms stratum nucleare pre-emulsion；
(2) 0.15 part of lauryl sodium sulfate and 0.6 part of NPE are dissolved in 5 parts of deionized waters and are formed
Aqueous phase, then 10 parts of methyl methacrylates, 8 parts of n-butyl acrylates and 0.15 part of N- (isobutoxy) Methacrylamide are added
Enter to aqueous phase, 30 DEG C, stir 20min under the conditions of 400rpm and carry out pre-emulsification, form cross-linked layer pre-emulsion；
(3) 0.05 part of lauryl sodium sulfate and 0.2 part of NPE are dissolved in 2 parts of deionized waters and are formed
Aqueous phase, then 6 parts of n-butyl acrylates and 1 part of methacrylic acid are added to aqueous phase, 30 DEG C, stirring 5min enters under the conditions of 400rpm
Row pre-emulsification, form shell pre-emulsion；
(4) 0.02 part of lauryl sodium sulfate of addition, 0.08 part of NPE and 20 parts in four-hole boiling flask
Deionized water forms aqueous phase, and stratum nucleare pre-emulsion prepared by 8 parts of steps (1) is added dropwise under 350rpm stirring conditions, is warming up to 80
DEG C, the ammonium persulfate aqueous solution of 2.1 parts of mass concentrations 4.8% is added, is stirred after there is macroscopic blue light to system, is continued
10min is kept, 23.25 parts of stratum nucleare emulsions are then added dropwise simultaneously and the sodium peroxydisulfate of 10.16 parts of mass concentrations 1.57% is water-soluble
Liquid, the insulated and stirred 0.5h after 2h is added dropwise；Be added dropwise simultaneously again cross-linked layer pre-emulsion prepared by 23.9 parts of steps (2) and
The sodium persulfate aqueous solution of 10.14 parts of mass concentrations 1.38%, the insulated and stirred 0.5h after 2h is added dropwise；Then in 0.5h
Drip the ammonium persulfate water that 2.01 parts of mass concentrations 0.5% are added dropwise after shell pre-emulsion prepared by 9.25 parts of steps (3) again
Solution, 85 DEG C of insulated and stirred 0.5h are warming up to, are 8 with ammoniacal liquor (mass concentration 1%) regulation system pH value, i.e., when cooling down room temperature
Obtain target water-based acrylic resin product emulsion.
Present invention also offers the preparation method of the woodgrained paper Special digital air brushing ink, the preparation method is by as follows
Step is carried out：
According to composition of raw materials, deionized water, pigment, wetting dispersing agent, diethylene glycol (DEG) are mixed and stirred for uniform (stir speed (S.S.)
For 200~300rpm, mixing time is 0.5~1h), then carry out continuously grinding (10~14h) and mill base is made；Then by gained
Mill base is mixed with absolute ethyl alcohol, defoamer, water-based acrylic resin emulsion and continues stirring to the uniform and stable (stirring of system
Speed is 150~200rpm, and mixing time is 1~2h), produce described woodgrained paper Special digital air brushing ink.
The beneficial effects of the present invention are：The ink system average grain diameter is small and narrow distribution, storage stability are good.Air brushing
Color ink color is clear, full after wood grain paper, and pattern stereoscopic impression is strong, and pigment ink sunlight fastness, the heat-resistant stability
It is preferable.
(4) illustrate
Fig. 1 is woodgrained paper Special digital air brushing ink grain size and its scatter chart in the embodiment of the present invention 1；
Fig. 2 is woodgrained paper Special digital air brushing ink grain size and its scatter chart in the embodiment of the present invention 2；
Fig. 3 is woodgrained paper Special digital air brushing ink grain size and its scatter chart in the embodiment of the present invention 3；
Fig. 4 is woodgrained paper Special digital air brushing ink grain size and its scatter chart in the embodiment of the present invention 4；
Fig. 5 is woodgrained paper Special digital air brushing ink grain size and its scatter chart in the embodiment of the present invention 5；
Fig. 6 is woodgrained paper Special digital air brushing ink grain size and its scatter chart in the embodiment of the present invention 6.
(5) embodiment
With reference to specific embodiment, the present invention is described further, but protection scope of the present invention is not limited in
This.
The special coding ink viscosity of woodgrained paper of the present invention uses the DV-II+ type rotor viscosimeters of Bookfield companies
It is measured；Ink particle diameter and particle diameter distribution are surveyed using the nanometer laser particle size analyzers of Malvern company Mastersizer 000
It is fixed；Electrical conductivity is measured using DDS-11A conductivity meters；Surface tension is entered using German KRUSS K100 type surface tension instruments
Row measure.
Sunlight fastness of the special coding ink air brushing of woodgrained paper of the present invention after paper uses ZT-UV-50S types UV
Ageing-resistant test instrument is simulated, and standard is that outturn is placed under ultraviolet source after irradiation 100h, if ink face on paper
Color is that aberration does not occur, then to be qualified；Heat resistance of the coding ink air brushing after paper is tested using compact hot press, mark
Standard is that outturn is placed in into 200 DEG C of pressing plates lower 120 seconds, if ink color is not sent out with former state compared with as former state on paper after hot pressing
Add lustre to difference, then to be qualified.
Embodiment 1
(form and aspect C) is formulated by table 1, by 45 parts by weight of deionized water, 1 parts by weight DISPERBYK-145 wetting dispersing agents
Mixed with 5 parts by weight diethylene glycol (DEG)s, then add 8 parts by weight Clariant indigo plant A4R type pigment while stirring.Stirring is moistened completely to pigment
Wet, this process takes around 0.5h~1h.Afterwards, the pigments system mixed is added into sand mill (SGM-15M sand mills),
Grinding technics needs 10h~14h to complete.Finally, ground mill base is added into 10 parts by weight absolute ethyl alcohols, 1 parts by weight
BYK-016 defoamers and 30 parts by weight water-based acrylic resin emulsions, stirring 1h~2h is homogeneous to system, and it is special to produce woodgrained paper
Numerial code spray drawing ink.Performance ginseng is shown in Table 7.
Table 1
| Raw material | Model (or specification) | Parts by weight |
| Pigment | Clariant indigo plant A4R | 8 |
| Wetting dispersing agent | DISPERBYK-145 | 1 |
| Absolute ethyl alcohol | AR | 10 |
| Diethylene glycol (DEG) | AR | 5 |
| Defoamer | BYK-016 | 1 |
| Water-based acrylic resin emulsion | Company makes by oneself | 30 |
| Deionized water | ≤0.8μs/cm | 45 |
Embodiment 2
(form and aspect M) is formulated by table 2, by 35 parts by weight of deionized water, 1 parts by weight DISPERBYK-145 and 1 parts by weight
DISPERBYK-106 wetting dispersing agents and the mixing of 8 parts by weight diethylene glycol (DEG)s, then the red HGR types of 6 parts by weight Clariants are added while stirring
Pigment.Stirring to pigment complete wetting, this process takes around 0.5h~1h.Afterwards, the pigments system mixed is added
Sand mill (SGM-15M sand mills), grinding technics needs 10h~14h to complete.Finally, ground mill base is added 12
Parts by weight absolute ethyl alcohol, 2 parts by weight BYK-094 defoamers and 35 parts by weight water-based acrylic resin emulsions, stirring 1h~2h is extremely
System is homogeneous, produces woodgrained paper Special digital air brushing ink.Performance ginseng is shown in Table 7.
Table 2
| Raw material | Model (or specification) | Parts by weight |
| Pigment | The red HGR of Clariant | 6 |
| Wetting dispersing agent | DISPERBYK-106/DISPERBYK-145 | 1/1 |
| Absolute ethyl alcohol | AR | 12 |
| Diethylene glycol (DEG) | AR | 8 |
| Defoamer | BYK-094 | 2 |
| Water-based acrylic resin emulsion | Company makes by oneself | 35 |
| Deionized water | ≤0.8μs/cm | 35 |
Embodiment 3
(form and aspect Y) is formulated by table 3, by 35 parts by weight of deionized water, 1.5 parts by weight BYKJET-9151 wetting dispersing agents
And 5 parts by weight diethylene glycol (DEG) mixing, then 5 parts by weight Clariant Huang HR type pigment are added while stirring.Stir to pigment complete wetting,
This process takes around 0.5h~1h.Afterwards, the pigments system mixed is added into sand mill (SGM-15M sand mills), ground
Grinding process needs 10h~14h to complete.Finally, ground mill base is added into 12 parts by weight absolute ethyl alcohols, 1.5 parts by weight
BYK-012 defoamers and 40 parts by weight water-based acrylic resin emulsions, stirring 1h~2h is homogeneous to system, and it is special to produce woodgrained paper
Numerial code spray drawing ink.Performance ginseng is shown in Table 7.
Table 3
Embodiment 4
(form and aspect K) is formulated by table 4, by 40 parts by weight of deionized water, 0.5 parts by weight DISPERBYK-194N and 0.5 weight
Part BYKJET-9142 wetting dispersing agents and the mixing of 7 parts by weight diethylene glycol (DEG)s are measured, then to add 5 parts by weight BASFs while stirring black
0066 type pigment.Stirring to pigment complete wetting, this process takes around 0.5h~1h.Afterwards, the pigment body that will be mixed
System adds sand mill (SGM-15M sand mills), and grinding technics needs 10h~14h to complete.Finally, by ground mill base
10 parts by weight absolute ethyl alcohols, 2 parts by weight BYK-088 defoamers and 35 parts by weight water-based acrylic resin emulsions are added, stir 1h
~2h is homogeneous to system, produces woodgrained paper Special digital air brushing ink.Performance ginseng is shown in Table 7.
Table 4
| Raw material | Model (or specification) | Parts by weight |
| Pigment | BASF black 0066 | 5 |
| Wetting dispersing agent | DISPERBYK-194N/BYKJET-9142 | 0.5/0.5 |
| Absolute ethyl alcohol | AR | 10 |
| Diethylene glycol (DEG) | AR | 7 |
| Defoamer | BYK-088 | 2 |
| Water-based acrylic resin emulsion | Company makes by oneself | 35 |
| Deionized water | ≤0.8μs/cm | 40 |
Embodiment 5
(form and aspect LC) is formulated by table 5, by 30 parts by weight of deionized water, 2 parts by weight DISPERBYK-2164 wetting and dispersings
Agent and the mixing of 6 parts by weight diethylene glycol (DEG)s, then 5 parts by weight Clariant indigo plant BG type pigment are added while stirring.Stirring is moistened completely to pigment
Wet, this process takes around 0.5h~1h.Afterwards, the pigments system mixed is added into sand mill (SGM-15M sand mills),
Grinding technics needs 10h~14h to complete.Finally, ground mill base is added into 15 parts by weight absolute ethyl alcohols, 2 parts by weight
BYK-017 defoamers and 40 parts by weight water-based acrylic resin emulsions, stirring 1h~2h is homogeneous to system, and it is special to produce woodgrained paper
Numerial code spray drawing ink.Performance ginseng is shown in Table 7.
Table 5
Embodiment 6
(form and aspect LM) is formulated by table 6, by 30 parts by weight of deionized water, 2 parts by weight DISPERBYK-115 wetting dispersing agents
And 7 parts by weight diethylene glycol (DEG) mixing, then the red E3B types pigment of 4 parts by weight Clariants is added while stirring.Stirring is moistened completely to pigment
Wet, this process takes around 0.5h~1h.Afterwards, the pigments system mixed is added into sand mill (SGM-15M sand mills),
Grinding technics needs 10h~14h to complete.Finally, ground mill base is added into 15 parts by weight absolute ethyl alcohols, 1 parts by weight
BYK-021 and 1 parts by weight BYK-065 defoamers and 40 parts by weight water-based acrylic resin emulsions, stirring 1h~2h are equal to system
One, produce woodgrained paper Special digital air brushing ink.Performance ginseng is shown in Table 7.
Table 6
| Raw material | Model (or specification) | Parts by weight |
| Pigment | The red E3B of Clariant | 4 |
| Wetting dispersing agent | DISPERBYK-115 | 2 |
| Absolute ethyl alcohol | AR | 15 |
| Diethylene glycol (DEG) | AR | 7 |
| Defoamer | BYK-021/BYK-065 | 1/1 |
| Water-based acrylic resin emulsion | Company makes by oneself | 40 |
| Deionized water | ≤0.8μs/cm | 30 |
Woodgrained paper Special digital air brushing ink property indices in the embodiment 1,2,3,4,5,6 of table 7
| Test event | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 |
| Ink-jet viscosity mPa.s (25 DEG C) | 6.5 | 7.0 | 7.0 | 8.5 | 7.5 | 6.5 |
| Average grain diameter nm | 120.7 | 100.0 | 105.4 | 121.1 | 79.37 | 84.1 |
| Electrical conductivity μ s/cm | 563.1 | 786.5 | 654.8 | 890.2 | 698.2 | 734.3 |
| Surface tension mn/m | 24.3 | 27.1 | 26.8 | 26.3 | 25.7 | 24.8 |
| Sun-resistant performance ＞ 100h | It is qualified | It is qualified | It is qualified | It is qualified | It is qualified | It is qualified |
| 200 DEG C of heat resistance, 120s | It is qualified | It is qualified | It is qualified | It is qualified | It is qualified | It is qualified |
Claims (6)
1. a kind of woodgrained paper Special digital air brushing ink, is made up of the raw material of following parts by weight：
4~10 parts of pigment, 1~2 part of wetting dispersing agent, 10~15 parts of absolute ethyl alcohol, 5~10 parts of diethylene glycol (DEG), 1~2 part of defoamer,
20~40 parts of water-based acrylic resin emulsion, 25~45 parts of deionized water.
2. woodgrained paper Special digital air brushing ink as claimed in claim 1, it is characterised in that the woodgrained paper Special digital spray
Ink is painted to be made up of the raw material of following parts by weight：
8 parts of pigment, 1 part of wetting dispersing agent, 10 parts of absolute ethyl alcohol, 5 parts of diethylene glycol (DEG), 1 part of defoamer, water-based acrylic resin emulsion
30 parts, 45 parts of deionized water.
3. woodgrained paper Special digital air brushing ink as claimed in claim 1 or 2, it is characterised in that the pigment is selected from following
One of：Clariant Corporation production blue BG, blue A4R, blue A2R, red D3G, red B, red HGR, red 3B, red BNP, red HB, red HF4B,
Red E3B, red E5B, red HG, red HFT, yellow HR02, yellow HR, yellow HG, yellow H9G, H2G, yellow H2GR, yellow HGR, yellow H3R or Huang
HGGVP2388；Black the 0066 of BASF AG's production.
4. woodgrained paper Special digital air brushing ink as claimed in claim 1 or 2, it is characterised in that the wetting dispersing agent choosing
From one of the following or the mixture of two or more arbitrary proportions：The DISPERBYK-102 of BYK companies production,
DISPERBYK-103、DISPERBYK-106、DISPERBYK-109、DISPERBYK-115、DISPERBYK-130、
DISPERBYK-142、DISPERBYK-145、DISPERBYK-194N、DISPERBYK-2050、DISPERBYK-2118、
DISPERBYK-2164、BYKJET-9131、BYKJET-9133、BYKJET-9142、BYKJET-9150、BYKJET-9151、
BYKJET-9152 or BYKJET-9170.
5. woodgrained paper Special digital air brushing ink as claimed in claim 1 or 2, it is characterised in that the defoamer is selected from down
The mixture of one or both of row any of the above ratio：BYK companies production BYK-012, BYK-016, BYK-017,
BYK-019, BYK-021, BYK-022, BYK-024, BYK-044, BYK-065, BYK-066N, BYK-088 or BYK-094.
6. the preparation method of woodgrained paper Special digital air brushing ink as claimed in claim 1, it is characterised in that the preparation side
Method is carried out as follows：
According to composition of raw materials, deionized water, pigment, wetting dispersing agent, diethylene glycol (DEG) are mixed and stirred for uniformly, then carried out continuous
Mill base is made in grinding；Then gained mill base is mixed and continued with absolute ethyl alcohol, defoamer, water-based acrylic resin emulsion
Stirring is uniform and stable to system, produces described woodgrained paper Special digital air brushing ink.
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| CN201710810609.9A CN107384017A (en) | 2017-09-11 | 2017-09-11 | A kind of woodgrained paper Special digital air brushing ink and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108178949A (en) * | 2018-01-16 | 2018-06-19 | 深圳市墨库图文技术有限公司 | A kind of woodgrained paper digital printing paint ink and preparation method thereof |
| CN108384322A (en) * | 2018-04-03 | 2018-08-10 | 东莞市世丰油墨有限公司 | A kind of ink and preparation method thereof for furniture thin paper aqueous intaglio printing |
| CN108589402A (en) * | 2018-03-14 | 2018-09-28 | 东莞市东彩印刷包装有限公司 | A kind of wood grain wrapping paper |
| CN113583510A (en) * | 2021-06-29 | 2021-11-02 | 杭州海维特化工科技有限公司 | Pre-impregnated paper gravure printing water-based ink and preparation method thereof |
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| CN103554341A (en) * | 2013-10-30 | 2014-02-05 | 华南理工大学 | Low-temperature self-crosslinking acrylate emulsion with core-shell structure as well as preparation method and application thereof |
| CN103601837A (en) * | 2013-11-15 | 2014-02-26 | 杭州浙大海维特化工科技有限公司 | Polyacrylate emulsion and preparation method thereof |
| CN103641962A (en) * | 2013-11-25 | 2014-03-19 | 汕头市东和机械有限公司 | Polyuria-acrylate emulsion and aqueous gravure ink prepared from same |
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| CN101993633A (en) * | 2010-12-06 | 2011-03-30 | 上海英威喷墨科技有限公司 | Water-based pigment type ink for absorbent base material spray ink printing, preparation and printing methods thereof |
| CN103554341A (en) * | 2013-10-30 | 2014-02-05 | 华南理工大学 | Low-temperature self-crosslinking acrylate emulsion with core-shell structure as well as preparation method and application thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108178949A (en) * | 2018-01-16 | 2018-06-19 | 深圳市墨库图文技术有限公司 | A kind of woodgrained paper digital printing paint ink and preparation method thereof |
| CN108178949B (en) * | 2018-01-16 | 2021-10-29 | 深圳市墨库图文技术有限公司 | Pigment ink for digital printing of wood grain paper and preparation method thereof |
| CN108589402A (en) * | 2018-03-14 | 2018-09-28 | 东莞市东彩印刷包装有限公司 | A kind of wood grain wrapping paper |
| CN108589402B (en) * | 2018-03-14 | 2020-12-11 | 东莞市东彩印刷包装有限公司 | Wood grain packaging paper |
| CN108384322A (en) * | 2018-04-03 | 2018-08-10 | 东莞市世丰油墨有限公司 | A kind of ink and preparation method thereof for furniture thin paper aqueous intaglio printing |
| CN113583510A (en) * | 2021-06-29 | 2021-11-02 | 杭州海维特化工科技有限公司 | Pre-impregnated paper gravure printing water-based ink and preparation method thereof |
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