CN107384004A - A kind of pigment of changeable colour - Google Patents
A kind of pigment of changeable colour Download PDFInfo
- Publication number
- CN107384004A CN107384004A CN201710597262.4A CN201710597262A CN107384004A CN 107384004 A CN107384004 A CN 107384004A CN 201710597262 A CN201710597262 A CN 201710597262A CN 107384004 A CN107384004 A CN 107384004A
- Authority
- CN
- China
- Prior art keywords
- parts
- pigment
- changeable colour
- micro mist
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
Abstract
The invention belongs to technical field of fine, is related to stationery leisure goods field, and in particular to a kind of pigment of changeable colour.A kind of pigment of changeable colour, include the component of following parts by weight：35~50 parts of inorganic filler, 5~8 parts of discoloration micro mist, 1~10 part of thickener, 1.5~4 parts of dispersant, 15~30 parts of organic solvent, 1~3 part of water and 3~8 parts of moisture regulating material.The present invention proposes a kind of powder pigments of changeable colour, and after it is volatilized by oil-based solvent, surface of pigments polarity and acid-base property are with ambient water changes of contents so as to causing color change.
Description
Technical field
The invention belongs to technical field of fine, is related to stationery leisure goods field, and in particular to a kind of changeable colour
Pigment.
Background technology
The solvent that the visible color class product in market uses is generally single oiliness or aqueous solvent.
Such as Publication No. CN101137729A patent of invention discloses one kind at least containing pigment, high-molecular compound
With the oil-based pigmented ink composition of organic solvent, contain the acetic acid methoxyl group fourth for accounting for all weight % of ink composite 20~90
Above-mentioned oil-based ink color compositions of the ester as organic solvent；Particularly contain and account for all weight % of ink composite 1~50
Nitrogenous and/or Oxygenic heterocyclic compounds, and/or contain (poly-) alkylidene two for accounting for all weight % of ink composite 1~50
Above-mentioned oil-based ink color compositions of the 01 derivatives as other organic solvents；Flash-point is more than 61 DEG C, and 25 DEG C of viscosity
It is 2.0~6.5cp, 25 DEG C of surface tension is 20~40mN/m above-mentioned oil-based ink color compositions.
For another example Publication No. CN105111829A patent of invention discloses a kind of water-based pigment colour paste, by below into
It is grouped into：Colour carbon black 20.0-30.0 parts by weight；Wetting agent 1.6-4.5 parts by weight；Dispersant 3.6-9.0 parts by weight；Defoamer
0.1-0.2 parts by weight；Cosolvent 8.0-16.0 parts by weight；PH adjusting agent 1.0-2.0 parts by weight；And deionized water 39.2-
65.7 parts by weight.The water-based pigment colour paste formula constituent of the invention is simple, is easy to industrialized production, and can be in the situation of low viscosity
The high viscosity stability of lower holding and particle size stability, while by adjusting the proportioning of wetting agent in formula, can change by water-based
The thixotropy of Neutral writing ink made from dispersible pigment color paste, obtaining has different thixotropic Neutral writing inks, is easy to match different type
Nib.
Although above-mentioned single oiliness or single aqueous pigment product has been used to industrial production, in the market there is no water
The pigment of oily both sexes makes up the market vacancy.The purpose of the present invention is directed to a kind of water oil both sexes powder pigments.
The content of the invention
In order to solve the above-mentioned technical problem, the invention provides a kind of pigment of changeable colour, the group of following parts by weight is included
Point：
35~50 parts of inorganic filler；
5~8 parts of discoloration micro mist；
0.1~5 part of thickener；
0.2~10 part of dispersant；
15~30 parts of organic solvent；
1~3 part of water；
3~8 parts of moisture regulating material.
Further, described inorganic filler is inorganic non-metallic powder, including kaolin, talcum powder, white carbon, sulfuric acid
At least one of calcium and calcium carbonate.Used in powder pigments as packing material.
Further, described thickener includes montmorillonite, modified cellulose, polyacrylate, aerosil, had
At least one of machine bentonite, polyamide, cellulose, polyvinyl alcohol and polyacrylate.Thickener can in powder pigments
To maintain product viscosity, not sagging.On the one hand the fluid volume of polymer in itself is improved, reduces the sky of Particle free activity
Between, so as to improve the viscosity of whole pigments system.In addition the thickener of cellulose family not only has good water-retaining property and flowing
Property, while it is small to be diluted with water rear viscosity fall.
Further, described dispersant is anionic dispersing agent, cationic dispersing agent and non-ionic dispersing agent
At least one of.Specifically, described anionic dispersing agent is at least one in enuatrol, carboxylate and sulfuric acid
Kind；Described cationic dispersing agent is at least one of alkyl quaternary ammonium salts, amino propylamine dioleate or quaternary amine；It is described
Non-ionic dispersing agent is at least one of fatty acid ethylene oxide and polyethylene glycol.Various dispersants are scattered due to pigment
And keep the stabilization of mixed system.
Further, described organic solvent, which includes methanol, ethanol, propyl alcohol, acetone, butanone and tetrahydrofuran isopolarity, has
At least one of solvent.Above-mentioned organic solvent is the highly polar organic solvent of low boiling, and the oiliness in the present invention is molten
After agent volatilization, the polarity and acid-base property of surface of pigments can cause color change with the change of around water content.
Further, described moisture regulating material is polynary higher boiling alcohols, be specifically as follows ethylene glycol, glycerine or
The combination of both persons.For adjusting the water content in pigment.
Further, described discoloration micro mist is made by the following method：Phenolphthalein or other camouflage paints, carboxymethyl cellulose
Element is dissolved in 30% ethanol water, is then added No. 200 solvent naphthas, absolute ethyl alcohol is slowly added to, after evaporation solvent
Must be changed colour micro mist.
As a kind of more preferable scheme, the pigment of described changeable colour includes the component of following parts by weight：30 parts
Kaolin, 5 parts of white carbon, 8 parts of discoloration micro mist, 5 parts of montmorillonite, 0.1 part of enuatrol, 1 part of the oil of amino propylamine two
Acid esters, 30 parts of ethanol, 3 parts of ethylene glycol and 1 part of water.
As another more preferable scheme, the pigment of described changeable colour includes the component of following parts by weight：Including
The component of following parts by weight：40 parts of calcium sulfate, 10 parts of talcum powder, 6 parts of discoloration micro mist, 3 parts of montmorillonite, 4 parts of ammonia
Base propylamine dioleate, 15 parts of acetone, 3 parts of polyethylene glycol, 5 parts of ethylene glycol and 2 parts of water.
As another more preferable scheme, the pigment of described changeable colour includes the component of following parts by weight：Including
The component of following parts by weight：20 parts of white carbon, 20 parts of talcum powder, 5 parts of discoloration micro mist, 0.1 part of montmorillonite, 1 part
Enuatrol, 3 parts of polyethylene glycol, 10 parts of ethanol, 20 parts of tetrahydrofuran, 8 parts of glycerine and 3 parts of water.
Water oil both sexes pigment provided by the invention, compared with prior art, beneficial effect is：Pigments system is stable, category
In the pigment of water oil both sexes, after it is volatilized by oil-based solvent, surface of pigments polarity and acid-base property with ambient water changes of contents from
And cause color change, industry blank can be made up.
Embodiment
The present invention is described in further detail below by specific embodiment.
Embodiment 1：
A kind of pigment of changeable colour, include the component of following parts by weight：30 parts of kaolin, 5 parts of white carbon, 8 parts
Change colour micro mist, 5 parts of montmorillonite, 0.5 part of enuatrol, 1 part of amino propylamine dioleate, 30 parts of ethanol, 3 parts of second two
Alcohol and 1 part of water.Wherein discoloration micro mist is made by the following method：Phenolphthalein and carboxymethyl cellulose are dissolved in 30% ethanol water
In solution, No. 200 solvent naphthas are then added, are slowly added to absolute ethyl alcohol, must change colour micro mist after evaporation solvent.
Embodiment 2：
A kind of pigment of changeable colour, include the component of following parts by weight：40 parts of calcium sulfate, 10 parts of talcum powder, 6 parts
Change colour micro mist, 10 parts of montmorillonite, 1 part of amino propylamine dioleate, 15 parts of acetone, 3 parts of polyethylene glycol, 5 parts of second
Glycol and 2 parts of water.Wherein discoloration micro mist is made by the following method：Methyl orange and carboxymethyl cellulose are dissolved in 30% second
In alcohol solution, No. 200 solvent naphthas are then added, are slowly added to absolute ethyl alcohol, must change colour micro mist after evaporation solvent.
Embodiment 3：
A kind of pigment of changeable colour, include the component of following parts by weight：40 parts of calcium sulfate, 10 parts of talcum powder, 6 parts
Change colour micro mist, 10 parts of montmorillonite, 1 part of amino propylamine dioleate, 15 parts of acetone, 3 parts of polyethylene glycol, 5 parts of second
Glycol and 2 parts of water.Wherein discoloration micro mist is made by the following method：Reindeer moss and carboxymethyl cellulose are dissolved in 30% ethanol
In the aqueous solution, No. 200 solvent naphthas are then added, are slowly added to absolute ethyl alcohol, must change colour micro mist after evaporation solvent.
Embodiment 4：
A kind of pigment of changeable colour, include the component of following parts by weight：30 parts of calcium carbonate, 5 parts of talcum powder, 7 parts
Change colour micro mist, 3 parts of montmorillonite, 2 parts of fatty acid ethylene oxide, 20 parts of propyl alcohol, 10 parts of tetrahydrofuran, the third the three of 6 parts
Alcohol and 2 parts of water.Wherein discoloration micro mist is made by the following method：Phenolphthalein and carboxymethyl cellulose are dissolved in 30% ethanol water
In solution, No. 200 solvent naphthas are then added, are slowly added to absolute ethyl alcohol, must change colour micro mist after evaporation solvent.
Embodiment 5：
A kind of pigment of changeable colour, include the component of following parts by weight：20 parts of white carbon, 20 parts of talcum powder, 5 parts
Change colour micro mist, 0.1 part of montmorillonite, 1 part of enuatrol, 3 parts of polyethylene glycol, 10 parts of ethanol, 20 parts of tetrahydrofuran, 8
The glycerine and 3 parts of water of part.Wherein discoloration micro mist is made by the following method：Reindeer moss and carboxymethyl cellulose are dissolved in 30%
Ethanol water in, then add No. 200 solvent naphthas, be slowly added to absolute ethyl alcohol, must change colour micro mist after evaporation solvent.
The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, for the skill of this area
For art personnel, the present invention can have various modifications and variations.Within the spirit and principles of the invention, that is made any repaiies
Change, equivalent substitution, improvement etc., should be included in the scope of the protection.
Claims (10)
1. a kind of pigment of changeable colour, it is characterised in that include the component of following parts by weight：
35~50 parts of inorganic filler；
5~8 parts of discoloration micro mist；
0.1~5 part of thickener；
0.2~10 part of dispersant；
15~30 parts of organic solvent；
1~3 part of water；
3~8 parts of moisture regulating material.
2. the pigment of changeable colour according to claim 1, it is characterised in that described inorganic filler is inorganic non-metallic powder
End, including at least one of kaolin, talcum powder, white carbon, calcium sulfate and calcium carbonate.
3. the pigment of changeable colour according to claim 2, it is characterised in that described thickener includes montmorillonite, modification
Cellulose, polyacrylate, aerosil, organobentonite, polyamide, cellulose, polyvinyl alcohol and polyacrylate
At least one of.
4. the pigment of changeable colour according to claim 3, it is characterised in that described dispersant is anionic dispersion
At least one of agent, cationic dispersing agent and non-ionic dispersing agent；
Described anionic dispersing agent is at least one of enuatrol, carboxylate and sulfuric acid；Described cationic
Dispersant is at least one of alkyl quaternary ammonium salts, amino propylamine dioleate or quaternary amine；The non-ionic dispersing agent is
At least one of fatty acid ethylene oxide and polyethylene glycol.
5. the pigment of changeable colour according to claim 4, it is characterised in that described organic solvent is that polarity is organic molten
Agent, including at least one of methanol, ethanol, propyl alcohol, acetone, butanone and tetrahydrofuran.
6. the pigment of changeable colour according to claim 5, it is characterised in that described moisture regulating material is polynary height boiling
Point alcohols, including ethylene glycol and/or glycerine.
7. the pigment of the changeable colour according to any one of claim 1~6, it is characterised in that described discoloration micro mist passes through
Following methods are made：Phenolphthalein and carboxymethyl cellulose are dissolved in 30% ethanol water, then add No. 200 solvent naphthas,
Absolute ethyl alcohol is slowly added to, must change colour micro mist after evaporation solvent.
8. the pigment of changeable colour according to claim 7, it is characterised in that include the component of following parts by weight：30 parts
Kaolin, 5 parts of white carbon, 8 parts of discoloration micro mist, 5 parts of montmorillonite, 0.1 part of enuatrol, 0.1 part of amino propylamine two
Oleate, 30 parts of ethanol, 3 parts of ethylene glycol and 1 part of water.
9. the pigment of changeable colour according to claim 7, it is characterised in that include the component of following parts by weight：40 parts
Calcium sulfate, 10 parts of talcum powder, 6 parts of discoloration micro mist, 3 parts of montmorillonite, 4 parts of amino propylamine dioleate, the third of 15 parts
Ketone, 3 parts of polyethylene glycol, 5 parts of ethylene glycol and 2 parts of water.
10. the pigment of changeable colour according to claim 7, it is characterised in that include the component of following parts by weight：20 parts
White carbon, 20 parts of talcum powder, 5 parts of discoloration micro mist, 0.1 part of montmorillonite, 1 part of enuatrol, 3 parts of polyethylene glycol, 10
The ethanol, 20 parts of tetrahydrofuran, 8 parts of glycerine and 3 parts of water of part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710597262.4A CN107384004B (en) | 2017-07-20 | 2017-07-20 | Color-changeable pigment |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710597262.4A CN107384004B (en) | 2017-07-20 | 2017-07-20 | Color-changeable pigment |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107384004A true CN107384004A (en) | 2017-11-24 |
| CN107384004B CN107384004B (en) | 2022-03-08 |
Family
ID=60337328
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710597262.4A Active CN107384004B (en) | 2017-07-20 | 2017-07-20 | Color-changeable pigment |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107384004B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108675871A (en) * | 2018-07-11 | 2018-10-19 | 佛山皖阳生物科技有限公司 | A kind of preparation method of carboxymethyl cellulose slow-release fertilizer coating materials |
| CN115231879A (en) * | 2022-08-15 | 2022-10-25 | 东莞环球经典新型材料有限公司 | Color-changeable inorganic artificial stone and preparation method thereof |
| CN116163158A (en) * | 2023-02-24 | 2023-05-26 | 云南省烟草质量监督检测站 | Preparation method of color-changeable cigarette paper |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101007916A (en) * | 2006-12-09 | 2007-08-01 | 欧德占 | Color-changing oil ink |
| CN104130627A (en) * | 2014-07-23 | 2014-11-05 | 王勇 | Stable discoloration ink |
| CN105131717A (en) * | 2015-09-10 | 2015-12-09 | 上海贝达包装材料有限公司 | Environment-friendly color-changeable printing ink with humidity display function and preparation method of printing ink |
| CN106752391A (en) * | 2016-11-23 | 2017-05-31 | 北京麦尔化工科技有限公司 | Aqueous carbon black color paste of a kind of feature of environmental protection for latex product and preparation method thereof |
| CN106905833A (en) * | 2017-04-05 | 2017-06-30 | 山西大学 | A kind of environmentally friendly allochroic paint with alarm function and preparation method thereof |
-
2017
- 2017-07-20 CN CN201710597262.4A patent/CN107384004B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101007916A (en) * | 2006-12-09 | 2007-08-01 | 欧德占 | Color-changing oil ink |
| CN104130627A (en) * | 2014-07-23 | 2014-11-05 | 王勇 | Stable discoloration ink |
| CN105131717A (en) * | 2015-09-10 | 2015-12-09 | 上海贝达包装材料有限公司 | Environment-friendly color-changeable printing ink with humidity display function and preparation method of printing ink |
| CN106752391A (en) * | 2016-11-23 | 2017-05-31 | 北京麦尔化工科技有限公司 | Aqueous carbon black color paste of a kind of feature of environmental protection for latex product and preparation method thereof |
| CN106905833A (en) * | 2017-04-05 | 2017-06-30 | 山西大学 | A kind of environmentally friendly allochroic paint with alarm function and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 哈成勇: "《道路涂料与涂装技术》", 31 July 2001 * |
| 李肇强: "《现代涂料的生产及应用》", 31 March 2017 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108675871A (en) * | 2018-07-11 | 2018-10-19 | 佛山皖阳生物科技有限公司 | A kind of preparation method of carboxymethyl cellulose slow-release fertilizer coating materials |
| CN115231879A (en) * | 2022-08-15 | 2022-10-25 | 东莞环球经典新型材料有限公司 | Color-changeable inorganic artificial stone and preparation method thereof |
| CN116163158A (en) * | 2023-02-24 | 2023-05-26 | 云南省烟草质量监督检测站 | Preparation method of color-changeable cigarette paper |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107384004B (en) | 2022-03-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP2906644B1 (en) | Dispersing agent from renewable raw materials for binding agent-free pigment preparations | |
| US9371457B2 (en) | Stable color-changing ink | |
| TWI546347B (en) | Low voc colorant compositions | |
| JP2011068838A (en) | Aqueous ink composition | |
| CN107384004A (en) | A kind of pigment of changeable colour | |
| CN103403105A (en) | Ink composition for continuous deflected jet printing | |
| JP2009197166A (en) | Aqueous ink composition | |
| CN103429675A (en) | Biodegradable liquid ink composition for ink jet printing | |
| WO2016059066A1 (en) | Epoxy/amine adducts for dispersing solids | |
| CN104449042A (en) | Weak solvent ink-jet ink | |
| CN106928791A (en) | A kind of environment-friendly water-based acrylic modified alkyd protective paint for spray coating mechanical equipment and material and preparation method thereof | |
| CN104974598A (en) | Erasable neutral ink and preparation method thereof | |
| CN103351647B (en) | Preparation method of water and oil applicable, nano transparent iron oxide yellow paste | |
| US20230331911A1 (en) | Water-Based Pigment Preparations, Production And Use Of Same | |
| EP2898021B1 (en) | Derivatives of sulphosuccinic acid as a dispersing agent in aqueous binder-free pigment preparations | |
| BR112015006153B1 (en) | AQUEOUS LIQUID DYE COMPOSITION, ARCHITECTURAL COATING COMPOSITION, AND COLOR TUNING SCHEME | |
| JP2010018741A (en) | Aqueous ink composition | |
| CN105504981A (en) | Water-based ink for intaglio printing process of aluminum foil and preparation method of water-based ink | |
| CN104725935A (en) | Tipping paper anti-bacterial aqueous printing ink | |
| DE202015008045U1 (en) | Universal pigment dispersions based on N-alkylglucamines | |
| CN103131256B (en) | Manufacturing method of soy-protein-type water-based decorative paper printing ink | |
| DE102013016889B4 (en) | Aqueous, binder-free pigment preparations and their uses | |
| CN104559463A (en) | Water-based silkscreen printing ink and preparation process thereof | |
| CN106280700A (en) | Gravure water-based metal ink and production method thereof | |
| AU2004226982A1 (en) | Ink composition for continuous deflected jet printing, especially on letters and postal articles |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |