CN107382244A - A kind of water proof type brushing gypsum and preparation method thereof - Google Patents
A kind of water proof type brushing gypsum and preparation method thereof Download PDFInfo
- Publication number
- CN107382244A CN107382244A CN201710635264.8A CN201710635264A CN107382244A CN 107382244 A CN107382244 A CN 107382244A CN 201710635264 A CN201710635264 A CN 201710635264A CN 107382244 A CN107382244 A CN 107382244A
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- Prior art keywords
- parts
- water
- proof type
- water proof
- brushing gypsum
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
- C04B28/142—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing synthetic or waste calcium sulfate cements
- C04B28/144—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements containing synthetic or waste calcium sulfate cements the synthetic calcium sulfate being a flue gas desulfurization product
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The present invention relates to a kind of water proof type brushing gypsum and preparation method thereof, it includes following components and content:50 60 parts of desulfurated plasters, 5 20 parts of quartz sands, 13 parts of natural stone-powders, 0.3 0.4 parts of retarder, 0.2 0.5 parts of cellulose ethers, 0.1 0.2 parts of dispersibility latex powders, 0.05 0.3 parts of water-proof adhesives, in parts by weight.The beneficial effects of the present invention are:The cost of the water proof type brushing gypsum of preparation is low, good water-proof effect, and waterproof rate is up to more than 90%, and higher more than the 15Mpa of its more than shear bond strength 0.3Mpa, rupture strength, presetting period and final setting time are short.
Description
Technical field
The present invention relates to a kind of plastering material, is related to a kind of water proof type brushing gypsum and preparation method thereof, belongs to chemical industry and build
Material technical field.
Background technology
Gypsum is as one of traditional three big inorganic coagulation materials, and application field is extensive, at present, as green, environment protection architecture
Material is increasingly burning hot on walling is painted, but because brushing gypsum raw gypsum powder itself has water imbibition, and met in dry mash
A large amount of spaces can be formed during water hydratable and provide chance for moisture invasion and attack, brushing gypsum water suction can excessively cause its mouldy de-
Fall, therefore limit brushing gypsum application, it is difficult to be applied again under southern wet environment, water proof type brushing gypsum meets the tendency of
And give birth to.Patent publication No. CN105130359A reduces the water consumption of slurry using addition flyash, increase system mobility,
The compaction rate of raising system, but it influences brushing gypsum outward appearance, using organosilicon moisture repellent as waterproofing agent, reduces gypsum
Intensity and adhesion.Patent publication No. 102745969A improves brushing gypsum water resistance using liquid silane, waterproof effect compared with
It is good, but gypsum wall caking property is poor by force, gypsum intensity decreases, easily comes off.
The content of the invention
It is an object of the invention to provide a kind of water proof type brushing gypsum and preparation method thereof, solves current rendering stone
Cream poor water resistance is made moist easy mouldy the problems such as coming off.
Technical scheme is used by the present invention solves above-mentioned technical problem:A kind of water proof type brushing gypsum, it includes
Following components and content:50-60 parts desulfurated plaster, 5-20 parts quartz sand, 1-3 parts natural stone-powder, 0.3-0.4 parts retarder,
0.2-0.5 parts cellulose ether, 0.1-0.2 part dispersibilitys latex powder, 0.05-0.3 part water-proof adhesives, in parts by weight.
By such scheme, the particle diameter of described water proof type brushing gypsum is less than 0.074mm.
By such scheme, the retarder is from one kind in sodium tripolyphosphate, citric acid or sodium citrate.
By such scheme, the cellulose ether selects methylcellulose or hydroxypropyl methyl cellulose.
By such scheme, its modulus of fineness of the quartz sand is 1.6-2.2.
By such scheme, the water-proof adhesive is that natural resin glue, polyvinyl alcohol and starch ether are (5-20) in proportion:
(1-5):The mixture of (0.5-2).
The preparation method of the water proof type brushing gypsum, it is characterised in that include following steps:
(1) by 1-3 parts natural stone-powder, 0.2-0.5 parts cellulose ether, 0.1-0.2 part dispersibilitys latex powder, 0.3-0.4
The well mixed obtained gypsum flour additive agent of part retarder, 0.05-0.3 parts water-proof adhesive;
(2) by 50-60 parts desulfurated plaster at 250-300 DEG C calcining at constant temperature 2-3h;
(3) gypsum flour additive agent obtained by the desulfurated plaster, 5-20 parts quartz sand and step (1) after step (2) is calcined is pressed
Ratio, which mixes, is made water proof type brushing gypsum.
By such scheme, the water-proof adhesive is that natural resin glue, polyvinyl alcohol and starch ether are (5-20) in proportion:
(1-5):The mixture of (0.5-2).
The natural stone-powder selected in the present invention can form C-S-H gels in semi-hydrated gypsum hydration process as swelling agent and fill out
Gypsum space is filled, prevents moisture from attacking;The cellulose ether selects methylcellulose or hydroxypropyl methyl cellulose, improves powder
The water retention property of brush gypsum and improve its denseness and anti-vertical fluidity;Using dispersibility latex powder, polyvinyl alcohol and starch ether
Compound action can increase sticky power between gypsum crystal;The natural resin of addition can effectively reduce brushing gypsum
Water absorption rate, improve its water resistance.
The beneficial effects of the present invention are:The cost of the water proof type brushing gypsum of preparation is low, and good water-proof effect, waterproof rate reaches
More than 90%, higher more than the 15Mpa of its more than shear bond strength 0.3Mpa, rupture strength, presetting period and final setting time are short.
Embodiment
For a better understanding of the present invention, with reference to the embodiment content that the present invention is furture elucidated, but the present invention
Content is not limited solely to the following examples.
Embodiment 1
A kind of water proof type brushing gypsum, wherein, the brushing gypsum includes each component of following weight percent content:It is de-
Sulphur gypsum 50kg, river sand (modulus of fineness 1.6) 20kg, natural stone-powder 1kg, retarder 0.3kg, methylcellulose 0.2kg, can
Dispersed latex powder 0.1kg, water-proof adhesive compositing formula are that natural resin glue, polyvinyl alcohol and starch ether quality proportioning are
20:1:2nd, water-proof adhesive dosage is 0.05kg.
Wherein, the retarder selects sodium tripolyphosphate, and the cellulose ether selects methylcellulose.
Take natural stone-powder, cellulose ether, dispersibility latex powder, retarder, waterproof binding agent mixing equal by above-mentioned quality
Even obtained gypsum flour additive agent;By desulfurated plaster at 250 DEG C calcining at constant temperature 3h;By the desulfurated plaster after calcining, quartz sand and
Gypsum flour additive agent obtained by step mixes obtained water proof type brushing gypsum in proportion, in use, adding the stirring of 40% water thereto
.
Gained its waterproof rate of water proof type brushing gypsum of the invention is up to 93%, shear bond strength 0.44MPa, rupture strength
14.8MPa。
Embodiment 2
A kind of water proof type brushing gypsum, wherein, the brushing gypsum includes each component of following weight percent content:It is de-
Sulphur gypsum 60kg, quartz sand (modulus of fineness 2.2) 15kg, natural stone-powder 2kg, retarder 0.4kg, hydroxypropyl methyl cellulose
0.3kg, dispersibility latex powder 0.2kg, water-proof adhesive compositing formula are natural resin glue, polyvinyl alcohol and starch ether quality
Match as 10:5:0.5th, water-proof adhesive dosage is 0.2kg.
Wherein, the retarder selects sodium citrate, and the cellulose ether selects hydroxypropyl methyl cellulose.
Take natural stone-powder, cellulose ether, dispersibility latex powder, retarder, waterproof binding agent mixing equal by above-mentioned quality
Even obtained gypsum flour additive agent;By desulfurated plaster at 250 DEG C calcining at constant temperature 3h;By the desulfurated plaster after calcining, quartz sand and
Gypsum flour additive agent obtained by step mixes obtained water proof type brushing gypsum in proportion, in use, adding the stirring of 40% water thereto
.
Gained its waterproof rate of water proof type brushing gypsum of the invention is up to 90%, shear bond strength 0.24MPa, rupture strength
12.8MPa。
Embodiment 3
A kind of water proof type brushing gypsum, wherein, the brushing gypsum includes each component of following weight percent content:It is de-
Sulphur gypsum 55kg, quartz sand 30kg, natural stone-powder 3kg, retarder 0.35kg, hydroxypropyl methyl cellulose 0.5kg, dispersibility
Latex powder 0.15kg, water-proof adhesive compositing formula are that natural resin glue, polyvinyl alcohol and starch ether quality proportioning are 5:2:
0.5th, water-proof adhesive dosage is 0.3kg.
Take natural stone-powder, cellulose ether, dispersibility latex powder, retarder, waterproof binding agent mixing equal by above-mentioned quality
Even obtained gypsum flour additive agent;By desulfurated plaster at 300 DEG C calcining at constant temperature 2h;By the desulfurated plaster after calcining, quartz sand and
Gypsum flour additive agent obtained by step mixes obtained water proof type brushing gypsum in proportion, in use, adding the stirring of 40% water thereto
.
Gained water proof type brushing gypsum waterproof rate of the invention is up to 95%, shear bond strength 0.53MPa, rupture strength
16.3MPa。
Claims (8)
1. a kind of water proof type brushing gypsum, it includes following components and content:50-60 parts desulfurated plaster, 5-20 parts quartz sand,
1-3 parts natural stone-powder, 0.3-0.4 parts retarder, 0.2-0.5 parts cellulose ether, 0.1-0.2 part dispersibilitys latex powder, 0.05-
0.3 part of water-proof adhesive, in parts by weight.
2. water proof type brushing gypsum according to claim 1, it is characterised in that the particle diameter of described water proof type brushing gypsum
For less than 0.074mm.
3. water proof type brushing gypsum according to claim 1, it is characterised in that the retarder from sodium tripolyphosphate,
One kind in citric acid or sodium citrate.
4. water proof type brushing gypsum according to claim 1, it is characterised in that the cellulose ether selects methylcellulose
Or hydroxypropyl methyl cellulose.
5. water proof type brushing gypsum according to claim 1, it is characterised in that its modulus of fineness of the quartz sand is 1.6-
2.2。
6. water proof type brushing gypsum according to claim 1, it is characterised in that the water-proof adhesive is natural resin
Glue, polyvinyl alcohol and starch ether are (5-20) in proportion:(1-5):The mixture of (0.5-2).
7. the preparation method of water proof type brushing gypsum according to claim requires 1-6 any one, it is characterised in that including
There are following steps:
(1) 1-3 parts natural stone-powder, 0.2-0.5 parts cellulose ether, 0.1-0.2 part dispersibilitys latex powder, 0.3-0.4 parts are delayed
Solidifying agent, the well mixed obtained gypsum flour additive agent of 0.05-0.3 parts water-proof adhesive;
(2) by 50-60 parts desulfurated plaster at 250-300 DEG C calcining at constant temperature 2-3h;
(3) gypsum flour additive agent obtained by the desulfurated plaster, 5-20 parts quartz sand and step (1) after step (2) is calcined is in proportion
Mix and water proof type brushing gypsum is made.
8. the preparation method of water proof type brushing gypsum according to claim 7, it is characterised in that the water-proof adhesive is
Natural resin glue, polyvinyl alcohol and starch ether are (5-20) in proportion:(1-5):The mixture of (0.5-2).
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108033753A (en) * | 2017-12-13 | 2018-05-15 | 郭盛 | The gypsum compositions of toughness reinforcing waterproof |
CN108164238A (en) * | 2017-12-07 | 2018-06-15 | 宁波森泰新材料有限公司 | A kind of water-resistant type interior wall render gypsum mortar for rendering |
CN108264318A (en) * | 2018-01-24 | 2018-07-10 | 合肥市大卓电力有限责任公司 | A kind of waterproof brushing gypsum and preparation method thereof |
CN111925180A (en) * | 2020-07-23 | 2020-11-13 | 中建材创新科技研究院有限公司 | Bonding gypsum |
CN113943141A (en) * | 2021-11-30 | 2022-01-18 | 客诺环保科技(青岛)有限公司 | Surface-modified reinforced gypsum powder and preparation method and application thereof |
CN114276102A (en) * | 2021-10-31 | 2022-04-05 | 平安电气股份有限公司 | Coal gangue modified bottom layer plastering gypsum and preparation method thereof |
Citations (1)
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CN105731960A (en) * | 2016-01-25 | 2016-07-06 | 上海傅罗实业有限公司 | Gypsum-based mortar |
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CN105731960A (en) * | 2016-01-25 | 2016-07-06 | 上海傅罗实业有限公司 | Gypsum-based mortar |
Non-Patent Citations (3)
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刘润章: "石膏防水性能研究", 《西北民族学院学报( 自然科学版)》 * |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108164238A (en) * | 2017-12-07 | 2018-06-15 | 宁波森泰新材料有限公司 | A kind of water-resistant type interior wall render gypsum mortar for rendering |
CN108033753A (en) * | 2017-12-13 | 2018-05-15 | 郭盛 | The gypsum compositions of toughness reinforcing waterproof |
CN108264318A (en) * | 2018-01-24 | 2018-07-10 | 合肥市大卓电力有限责任公司 | A kind of waterproof brushing gypsum and preparation method thereof |
CN111925180A (en) * | 2020-07-23 | 2020-11-13 | 中建材创新科技研究院有限公司 | Bonding gypsum |
CN111925180B (en) * | 2020-07-23 | 2022-01-07 | 中建材创新科技研究院有限公司 | Bonding gypsum |
CN114276102A (en) * | 2021-10-31 | 2022-04-05 | 平安电气股份有限公司 | Coal gangue modified bottom layer plastering gypsum and preparation method thereof |
CN113943141A (en) * | 2021-11-30 | 2022-01-18 | 客诺环保科技(青岛)有限公司 | Surface-modified reinforced gypsum powder and preparation method and application thereof |
CN113943141B (en) * | 2021-11-30 | 2022-12-06 | 客诺环保科技(青岛)有限公司 | Surface modification enhanced gypsum powder and preparation method and application thereof |
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Application publication date: 20171124 |