CN107586088A - A kind of warm-land cushion course gypsum based self-leveling mortar and preparation method with thermal and insulating performance - Google Patents

A kind of warm-land cushion course gypsum based self-leveling mortar and preparation method with thermal and insulating performance Download PDF

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Publication number
CN107586088A
CN107586088A CN201710916601.0A CN201710916601A CN107586088A CN 107586088 A CN107586088 A CN 107586088A CN 201710916601 A CN201710916601 A CN 201710916601A CN 107586088 A CN107586088 A CN 107586088A
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parts
based self
thermal
warm
leveling mortar
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陈勇
唐永波
孟醒
刘丽娟
杨志
许文龙
马红青
徐辉
郭泰民
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JIANGSU EFFUL SCIENCE AND TECHNOLOGY Co Ltd
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JIANGSU EFFUL SCIENCE AND TECHNOLOGY Co Ltd
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Abstract

The invention discloses a kind of warm-land cushion course gypsum based self-leveling mortar with thermal and insulating performance and preparation method thereof, include the component of following parts by weight:40 parts~50 parts of α high strength gypsums powder, 4 parts~8 parts of cement, 0 part~6 parts of flyash, 6 parts~12 parts of filler, 35 parts~45 parts of aggregate, 0.2 part~1 part of foaming agent, 0.1 part~0.2 part of foam stabilizer, 0.1 part~0.2 part of water-loss reducer, 0.1 part~0.3 part of water reducer, 0.03 part~0.07 part of retarder.Preparation method of the present invention includes preparing alpha type high-strength gypsum powder and prepares two steps of gravity flowing levelling mortar, good effect of heat insulation of the present invention, can keep larger mobile performance and preferable strength character, while the later stage does not ftracture, do not shunk, and volume stability is preferable.

Description

It is a kind of with the warm-land cushion course gypsum based self-leveling mortar of thermal and insulating performance and preparation Method
Technical field
The invention belongs to a kind of building ground floor material, relates particularly to a kind of warm-land cushion course with thermal and insulating performance Gypsum based self-leveling mortar.
Background technology
Japan has had ten in the basic research for having begun to gypsum-based self-leveling material in 1972, to Japan in 1979 The gypsum-based self-leveling material of a variety of brands, the 1980s, Anglo-American Law Russia started the research and development of gypsum based self-leveling, arrived German dry-mixed mortar has taken up an area the 16.4% of terrace material within 2001.
Common gravity flow self-leveling floor material has three kinds both at home and abroad:1. cement-based self-leveling material;2. epoxy resin flows automatically Flat material;3. gypsum based self-leveling mortar.Wherein cement-based self-leveling and epoxies self-leveling material have had at home at present Fairly large application.But because cement-based self-leveling material has larger shrinkage, it can not typically be used as thickness at present The ground of the larger standard width of a room in an old-style house of terrace or primary concreting of layer, epoxy resin self-leveling material are typically used as the surface layer of thin layer Terrace uses.
It is late 1980s that China, which starts to research and develop gypsum based self-leveling, in recent years mostly using building gypsum plaster or Anhydrite ensures to reach corresponding performance, causes gypsum based self-leveling as raw material by introducing substantial amounts of chemical addition agent Material cost it is very high, and performance is not often very stable, so market acceptance level is not high.
Patent is concentrated mainly on the following aspects in terms of domestic gypsum based self-leveling mortar at present:1. utilize plaster of Paris Powder and substantial amounts of cement are compounded, and then add certain chemical addition agent, and its patent represented has Fujian Construction Building Materials section A kind of water desulfurized gypsum base surfacing self-leveling floor mortar of β types half of skill development corporation, Ltd., application number 201610348686.2.2. profit Alpha type high-strength gypsum powder is prepared with desulfurated plaster or prepare alpha type high-strength gypsum powder using ardealite, then using preparing Alpha type high-strength gypsum powder configures gypsum based self-leveling mortar, wherein more representational have the rising sun religion of Nanjing University of Technology Lee east A kind of composite gypsum based self-leveling mortar and preparation method awarded, application number:201610882329.4 with Wuhan University of Technology horse Protect the α high strength gypsums based self-leveling material prepared using ardealite and production technology of state professor, application publication number:CN 103288410 A.3. in the anhydrite class gypsum based self-leveling mortar that certain exciting agent configures, its generation, are added using natural anhydrite Table has a kind of natural anhydrite gravity flow flat crack resistant mortars of Zhang Xuejian, application number:201610103519.1.
The general gypsum based self-leveling mortar using building gypsum plaster configuration tends not to meet existing industry JC/T 1023-2007 standard requirement.And the gypsum based self-leveling mortar of anhydrite configuration is used, anhydrite needs alkali-activated carbonatite just to have glue Solidifying activity, hydration rate is slower, plus limitation of the current country to the exploitation of natural gypsum ore deposit, so the gypsum base of anhydrite configuration Gravity flowing levelling mortar can not be promoted well.So it is current master to configure gypsum based self-leveling mortar using alpha type high-strength gypsum Stream.The alpha type high-strength gypsum powder common intensity better performances prepared using desulfurated plaster, but its color is yellow, is configured to sand Also it is in yellow after slurry hydration and hardening, traction is not high.And ardealite prepares alpha type high-strength gypsum, if later stage powder is handled Imperfection, faintly acid is often presented after its aquation, so has an impact to concrete base layer.
The chemical gypsum of chlorine industry by-product is compared with compared to other kinds of industry by-product gypsum, its calcium sulphate dihydrate Content be up to 99%, the alpha type high-strength gypsum powder intensity prepared using Dynamic Hydrothermal method using chlorine industry by-product gypsum Performance is good, and whiteness is up to 85, and adhesive property is also closer to the high-quality natural gypsum.
Do not possess thermal and insulating performance already in the case of the less ratio of water to material of gypsum based self-leveling mortar, it is specific by introducing Component makes the gypsum based self-leveling mortar performance with insulation again, into the hot topic studied instantly.
The content of the invention
For in place of above-mentioned the deficiencies in the prior art, the present invention solve the problems, such as be:There is provided one kind has insulation, disappears The high gypsum based self-leveling mortar of sound, intensity and preparation method.
To solve the above problems, the technical scheme that the present invention takes is as follows:
A kind of warm-land cushion course gypsum based self-leveling mortar with thermal and insulating performance, include the group of following parts by weight Point:40 parts~50 parts of α high strength gypsums powder, 4 parts~8 parts of cement, 0 part~6 parts of flyash, 6 parts~12 parts of filler, 35 parts of aggregate~ 45 parts, 0.2 part~1 part of foaming agent, 0.1 part~0.2 part of foam stabilizer, 0.1 part~0.2 part of water-loss reducer, water reducer 0.1 part~0.3 Part, 0.03 part~0.07 part of retarder.
Further, it is characterised in that described cement is P.O42.5 ordinary portland cement.
Further, described flyash is second class powered coal ash.
Further, described aggregate is the quartz sand or the continuous grains of 0.1mm~0.6mm of 0.1mm~0.6mm Continuous Particle Sizes Footpath and the yellow sand without mud.
Further, described filler is dicalcium powder, and fineness is more than 85% in the mesh of 150 mesh~300, calcium carbonate mass content.
Further, described foaming agent is a kind of or more in Tea Saponin, saponin, high-performance protide foaming agent Kind.
Further, described foam stabilizer is the one or more in triethanolamine, alkylolamides or Arabic gum.
Further, described water-loss reducer is low-viscosity hydroxypropylmethylc,llulose ether, range of viscosities 200mPas~ 600mPa·s;Water reducer be one kind either in polyethers water reducer of BASF F10, carboxylic acid type water reducing agent, polyester water reducer or Two kinds;Retarder is the one or more in protide or trisodium citrate and SG-10.
A kind of preparation method of the warm-land cushion course gypsum based self-leveling mortar with thermal and insulating performance, step are as follows:
S1, prepare alpha type high-strength gypsum powder:By CaCl2Solution, which is put into chlor-alkali industrial waste water, fully to be reacted, filtering Reacted solution, obtain solid CaSO4·2H2O, by CaSO4·2H2O is configured to suspension, will contain CaSO4·2H2O hangs Supernatant liquid adds crystal modifier and carries out hydro-thermal reaction, and alpha type high-strength gypsum powder is obtained finally by centrifugation, drying, grinding;
S2, prepare gravity flowing levelling mortar:By α high strength gypsums powder, cement, flyash, filler, aggregate, foaming agent, foam stabilizer, Water-loss reducer, water reducer, retarder carry out being thoroughly mixed to form powder, then add water to be sufficiently stirred in powder, control ratio of water to material For 0.21~0.25, gypsum based self-leveling mortar is finally given.
Further, described gypsum based self-leveling mortar mixing speed control is in 20~30r/min, mixing time 4 to 2min~3min is stood after 6min and carries out construction casting.
Beneficial effects of the present invention
The present invention adds foaming agent and foam stabilizer in the component of preparation, and both materials belong to the head of this area addition Wound, it can allow in gypsum based self-leveling mortar and contain a number of porosity, the certain guarantor of imparting gypsum based self-leveling mortar The heat-insulated performance muffler of temperature, especially when being foaming agent using Tea Saponin and saponin, hole is more uniform, and foaming effect is moderate. The α gypsum that the present invention is prepared using chlorine industry chemical gypsum substitutes alpha type high-strength gypsum prepared by traditional industry by-product gypsum Alpha type high-strength gypsum powder prepared by powder or the natural gypsum, and by adjusting the rational grading of other fillers and aggregate so that Gypsum based self-leveling mortar can keep larger mobile performance and preferable strength character, while the later stage does not ftracture, do not shunk, Volume stability is preferable;The present invention simultaneously, belong to chlorine industry discarded object recycling, chlorine industry sustainable development can be helped Exhibition.
Brief description of the drawings
Fig. 1 is the mineral constituent analysis chart of alpha semi-hydrated gypsum of the present invention.
Fig. 2 is the crystal morphology figure of the alpha type high-strength gypsum of the present invention.
Embodiment
Present invention is described in further detail below in conjunction with the accompanying drawings.
A kind of preparation method of the warm-land cushion course gypsum based self-leveling mortar with thermal and insulating performance, step are as follows:
S1, prepare alpha type high-strength gypsum powder:By CaCl2Solution, which is put into chlor-alkali industrial waste water, fully to be reacted, filtering Reacted solution, obtain solid CaSO4·2H2O, by CaSO4·2H2O is configured to suspension, will contain CaSO4·2H2O hangs Supernatant liquid adds crystal modifier and carries out hydro-thermal reaction, and alpha type high-strength gypsum powder is obtained finally by centrifugation, drying, grinding.
S2, prepare gravity flowing levelling mortar:By α high strength gypsums powder, cement, flyash, filler, aggregate, foaming agent, foam stabilizer, Water-loss reducer, water reducer, retarder carry out being thoroughly mixed to form powder, then add water to be sufficiently stirred in powder, control ratio of water to material For 0.21~0.25, gypsum based self-leveling mortar is finally given.Gypsum based self-leveling mortar mixing speed is controlled in 20~30r/ Min, 2min~3min is stood after mixing time 4 to 6min and carries out construction casting.
The specific proportioning of each component is implemented as follows:
Embodiment 1
By mass, match ratio is as follows:43 parts of α high strength gypsums powder, the P.O42.5 of chlorine industry by-product chemical gypsum preparation 8 parts of ordinary portland cement, 3 parts of second class powered coal ash, 8 parts of dicalcium powder, 40 parts of quartz sand, 0.2 part of Tea Saponin, 0.1 part of triethanolamine, low 0.2 part of 0.2 part of viscosity hydroxypropylmethyl cellulose ether, carboxylic acid type water reducing agent and polyester water reducer, 0.05 part of trisodium citrate, water Material is than being 0.233.
Embodiment 2
By mass, match ratio is as follows:46 parts of α high strength gypsums powder, the P.O42.5 of chlorine industry by-product chemical gypsum preparation 6 parts of ordinary portland cement, 8 parts of dicalcium powder, 40 parts of yellow sand, 0.6 part of Tea Saponin, 0.15 part of alkylolamides, low viscosity hydroxypropyl first 0.2 part of 0.15 part of base cellulose ether, BASF F10 and polyethers water reducer, SG-10 are 0.05 part, ratio of water to material 0.235.
Embodiment 3
By mass, match ratio is as follows:42 parts of α high strength gypsums powder, the P.O42.5 of chlorine industry by-product chemical gypsum preparation 6 parts of ordinary portland cement, 12 parts of dicalcium powder, 40 parts of quartz sand, 0.1 part of Tea Saponin, 0.1 part of saponin, 0.1 part of Arabic gum, low Viscosity hydroxypropylmethyl cellulose ether 0.15,0.2 part of polyethers water reducer, 0.05 part of trisodium citrate, ratio of water to material 0.25.
Embodiment 4
By mass, match ratio is as follows:40 parts of α high strength gypsums powder, the P.O42.5 of chlorine industry by-product chemical gypsum preparation 6 parts of ordinary portland cement, 6 parts of second class powered coal ash flyash, 8 parts of dicalcium powder, 40 parts of yellow sand, 0.4 part of Tea Saponin, saponin totally 0.2, 0.15 part of triethanolamine, alkylolamides or Arabic gum, 0.2 part of low-viscosity hydroxypropylmethylc,llulose ether, polyester diminishing 0.2 part of agent, 0.07 part of trisodium citrate, ratio of water to material 0.233.
Embodiment 5
By mass, match ratio is as follows:50 parts of α high strength gypsums powder, the P.O42.5 of chlorine industry by-product chemical gypsum preparation 4 parts of ordinary portland cement, 5 parts of second class powered coal ash flyash, 6 parts of dicalcium powder, 35 parts of quartz sand, 1 part of Tea Saponin, triethanolamine and alkane 0.2 part of base alkylolamides, 0.2 part of low-viscosity hydroxypropylmethylc,llulose ether, 0.3 part of carboxylic acid type water reducing agent, trisodium citrate 0.03 Part, ratio of water to material 0.250.
Embodiment 6
By mass, match ratio is as follows:45 parts of α high strength gypsums powder, the P.O42.5 of chlorine industry by-product chemical gypsum preparation 4 parts of ordinary portland cement, 6 parts of dicalcium powder, 45 parts of yellow sand, 0.2 part of saponin, 0.1 part of Arabic gum, low viscosity hydroxypropyl methyl it is fine It is 0.03 part to tie up plain 0.1 part of ether, 0.2 part of BASF F10, SG-10, ratio of water to material 0.246.
According to standard JC/T1023-2007《Gypsum based self-leveling mortar》The gypsum-based self-leveling material prepared to the present invention Performance detect, shown in concrete outcome table 1.
Table 1
As shown in figure 1, the alpha type high-strength gypsum powder purity of the present invention is high, almost 99% is all alpha semi-hydrated gypsum, whiteness is good, Adhesive property is good;As shown in Fig. 2 alpha type high-strength gypsum crystal morphology is almost 1:1 to 1:2 short cylinder form, it can ensure While intensity, preferable mobile performance is provided for gypsum-based self-leveling material.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention God any modification, equivalent substitution and improvements made etc., should be included in the scope of the protection with principle.

Claims (10)

1. a kind of warm-land cushion course gypsum based self-leveling mortar with thermal and insulating performance, it is characterised in that including following weight The component of number:40 parts~50 parts of α high strength gypsums powder, 4 parts~8 parts of cement, 0 part~6 parts of flyash, 6 parts~12 parts of filler, bone 35 parts~45 parts of material, 0.2 part~1 part of foaming agent, 0.1 part~0.2 part of foam stabilizer, 0.1 part~0.2 part of water-loss reducer, water reducer 0.1 Part~0.3 part, 0.03 part~0.07 part of retarder.
2. the warm-land cushion course gypsum based self-leveling mortar according to claim 1 with thermal and insulating performance, its feature exist In described cement is P.O42.5 ordinary portland cement.
3. the warm-land cushion course gypsum based self-leveling mortar according to claim 1 with thermal and insulating performance, its feature exist In described flyash is second class powered coal ash.
4. the warm-land cushion course gypsum based self-leveling mortar according to claim 1 with thermal and insulating performance, its feature exist In, described aggregate for the quartz sand or 0.1mm~0.6mm Continuous Particle Sizes of 0.1mm~0.6mm Continuous Particle Sizes and without mud Yellow sand.
5. the warm-land cushion course gypsum based self-leveling mortar according to claim 1 with thermal and insulating performance, its feature exist It is dicalcium powder in, described filler, fineness is more than 85% in the mesh of 150 mesh~300, calcium carbonate mass content.
6. the warm-land cushion course gypsum based self-leveling mortar according to claim 1 with thermal and insulating performance, its feature exist In described foaming agent is the one or more in Tea Saponin, saponin, high-performance protide foaming agent.
7. the warm-land cushion course gypsum based self-leveling mortar according to claim 1 with thermal and insulating performance, its feature exist In described foam stabilizer is the one or more in triethanolamine, alkylolamides or Arabic gum.
8. the warm-land cushion course gypsum based self-leveling mortar according to claim 1 with thermal and insulating performance, its feature exist In, described water-loss reducer be low-viscosity hydroxypropylmethylc,llulose ether, range of viscosities 200mPas~600mPas;Water reducer To be one or two kinds of in BASF F10, carboxylic acid type water reducing agent, polyester water reducer or polyethers water reducer;Retarder is egg One or more in white class or trisodium citrate and SG-10.
A kind of 9. preparation method of the warm-land cushion course gypsum based self-leveling mortar with thermal and insulating performance, it is characterised in that step It is rapid as follows:
S1, prepare alpha type high-strength gypsum powder:By CaCl2Solution, which is put into chlor-alkali industrial waste water, fully to be reacted, filtering reaction Solution afterwards, obtain solid CaSO4·2H2O, by CaSO4·2H2O is configured to suspension, will contain CaSO4·2H2O suspension Add crystal modifier and carry out hydro-thermal reaction, alpha type high-strength gypsum powder is obtained finally by centrifugation, drying, grinding;
S2, prepare gravity flowing levelling mortar:By α high strength gypsums powder, cement, flyash, filler, aggregate, foaming agent, foam stabilizer, water conservation Agent, water reducer, retarder carry out being thoroughly mixed to form powder, then in powder plus water is sufficiently stirred, control the ratio of water to material to be 0.21~0.25, finally give gypsum based self-leveling mortar.
10. the preparation side of the warm-land cushion course gypsum based self-leveling mortar according to claim 9 with thermal and insulating performance Method, it is characterised in that described gypsum based self-leveling mortar mixing speed is controlled in 20~30r/min, mixing time 4 to 6min 2min~3min is stood afterwards carries out construction casting.
CN201710916601.0A 2017-09-29 2017-09-29 A kind of warm-land cushion course gypsum based self-leveling mortar and preparation method with thermal and insulating performance Pending CN107586088A (en)

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CN108395194A (en) * 2018-04-09 2018-08-14 合肥月煌新型装饰材料有限公司 A kind of glass fiber reinforced gypsum based composites and preparation method thereof
CN108793799A (en) * 2018-06-16 2018-11-13 山东新大地环保建材有限公司 Building for substituting stone fills skeletal grain, application, preparation facilities and method
CN110436848A (en) * 2019-08-12 2019-11-12 河南城建学院 A kind of cement composition, foamed cement slurry, foam concrete pour material and preparation method thereof
CN110436871A (en) * 2019-08-20 2019-11-12 北京金隅砂浆有限公司 A kind of mobility light gypsum ground cushion material and preparation method thereof
CN110981392A (en) * 2019-12-14 2020-04-10 武汉每天建材科技有限公司 Self-leveling thermal insulation mortar and preparation method thereof
CN111995348A (en) * 2020-09-21 2020-11-27 中山蓝翠鸟新型环保材料有限公司 Ternary system foaming leveling mortar
CN112095999A (en) * 2020-07-29 2020-12-18 威海金象实业有限公司 Warm-keeping building structure and preparation method thereof
CN112694343A (en) * 2021-02-08 2021-04-23 河南强耐新材股份有限公司 High-strength heat-preservation sound-insulation gypsum-based self-leveling mortar and preparation method thereof
CN113683375A (en) * 2020-05-18 2021-11-23 博湃建筑科技(上海)有限公司 Gypsum-based 3D printing mortar and preparation method thereof
CN115368095A (en) * 2022-08-16 2022-11-22 安徽倍兆业建材科技有限公司 Light heat-preservation sound-insulation self-leveling mortar system and construction method thereof
CN115819061A (en) * 2022-11-30 2023-03-21 江苏省苏安能节能建材科技有限公司 Gypsum-based self-leveling mortar and preparation method thereof

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CN108395194A (en) * 2018-04-09 2018-08-14 合肥月煌新型装饰材料有限公司 A kind of glass fiber reinforced gypsum based composites and preparation method thereof
CN108793799A (en) * 2018-06-16 2018-11-13 山东新大地环保建材有限公司 Building for substituting stone fills skeletal grain, application, preparation facilities and method
CN110436848A (en) * 2019-08-12 2019-11-12 河南城建学院 A kind of cement composition, foamed cement slurry, foam concrete pour material and preparation method thereof
CN110436871B (en) * 2019-08-20 2021-09-03 北京金隅砂浆有限公司 Flowable light gypsum ground cushion material and preparation method thereof
CN110436871A (en) * 2019-08-20 2019-11-12 北京金隅砂浆有限公司 A kind of mobility light gypsum ground cushion material and preparation method thereof
CN110981392A (en) * 2019-12-14 2020-04-10 武汉每天建材科技有限公司 Self-leveling thermal insulation mortar and preparation method thereof
CN113683375A (en) * 2020-05-18 2021-11-23 博湃建筑科技(上海)有限公司 Gypsum-based 3D printing mortar and preparation method thereof
CN113683375B (en) * 2020-05-18 2023-11-07 博湃建筑科技(上海)有限公司 Gypsum-based 3D printing mortar and preparation method thereof
CN112095999A (en) * 2020-07-29 2020-12-18 威海金象实业有限公司 Warm-keeping building structure and preparation method thereof
CN111995348A (en) * 2020-09-21 2020-11-27 中山蓝翠鸟新型环保材料有限公司 Ternary system foaming leveling mortar
CN112694343A (en) * 2021-02-08 2021-04-23 河南强耐新材股份有限公司 High-strength heat-preservation sound-insulation gypsum-based self-leveling mortar and preparation method thereof
CN115368095A (en) * 2022-08-16 2022-11-22 安徽倍兆业建材科技有限公司 Light heat-preservation sound-insulation self-leveling mortar system and construction method thereof
CN115819061A (en) * 2022-11-30 2023-03-21 江苏省苏安能节能建材科技有限公司 Gypsum-based self-leveling mortar and preparation method thereof

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Application publication date: 20180116