CN107381931A - Method based on Strong oxdiative and circulation biochemical treatment dyestuff intermediate production waste water - Google Patents

Method based on Strong oxdiative and circulation biochemical treatment dyestuff intermediate production waste water Download PDF

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Publication number
CN107381931A
CN107381931A CN201710439312.6A CN201710439312A CN107381931A CN 107381931 A CN107381931 A CN 107381931A CN 201710439312 A CN201710439312 A CN 201710439312A CN 107381931 A CN107381931 A CN 107381931A
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waste water
strong oxdiative
water
circulation
flow rate
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李春生
李园
王悦排
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Hebei Zhuo Environment Technology Co Ltd
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Hebei Zhuo Environment Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/467Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
    • C02F1/4672Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/20Heavy metals or heavy metal compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/34Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
    • C02F2103/36Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/06Sludge reduction, e.g. by lysis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/02Specific form of oxidant
    • C02F2305/023Reactive oxygen species, singlet oxygen, OH radical
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/06Nutrients for stimulating the growth of microorganisms
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • C02F3/1205Particular type of activated sludge processes
    • C02F3/1215Combinations of activated sludge treatment with precipitation, flocculation, coagulation and separation of phosphates
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • C02F3/1205Particular type of activated sludge processes
    • C02F3/1221Particular type of activated sludge processes comprising treatment of the recirculated sludge

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)
  • Activated Sludge Processes (AREA)

Abstract

The present invention relates to the method based on Strong oxdiative and circulation biochemical treatment dyestuff intermediate production waste water,Belong to technical field of sewage,This method by wastewater collection and squeezes into regulating reservoir progress water quality adjustment and runoff investigation first,Waste water after regulation carries out two-stage Strong oxdiative by two multidimensional being sequentially connected Strong oxdiative equipment,Eliminate the acid in waste water,Alkali,Salt environment,Heavy metal and free metal ion in absorptive collection waste water,Organic matter and the simple organic matter of directly degrading that difficulty or ease are degraded are decomposed by electrode simultaneously,The flocculation sediment carried out therewith is by heavy metal,Free metal ion,Inorganic compound and halogen carry out precipitation separation and eliminated,Then circulation that waste water is carried out to level Four is biochemical,Pass through remaining organic pollution in the metabolic consumption water of comprehensive bacterium,Eventually pass through further flocculation sediment and adsorption filtration obtains qualified processing water,The processing water is enough to be applied to green plant irrigation,Landscape is sprayed water,The occasions such as urban road sprinkling.

Description

Method based on Strong oxdiative and circulation biochemical treatment dyestuff intermediate production waste water
Technical field
The invention belongs to technical field of sewage, is related to based on Strong oxdiative and circulation biochemical treatment dyestuff intermediate production The method of waste water.
Background technology
Dyestuff intermediate production waste water is the technique waste water discharged in dyestuff intermediate production process, the life of dyestuff intermediate Production process mainly by the basic organics such as benzene, naphthalene, anthracene are sulfonated, nitrification, reduction, halogenation, amination, oxidation, acylation, alkyl The chemical reaction processes such as change, product structure is extremely complex, including the organic compound without dye characteristic, such as H acid, Tu Shi Acid and J acid etc., former dyestuff is made through courses of reaction such as diazotising, couplings in dyestuff intermediate.Former dyestuff post-processes through dyestuff again, system Into commercial dye.The raw material that DYE PRODUCTION process consumes is more, and material consumption per ton is up to several tons to tens tons, while in its production process In, one or many washings are generally required, thus it is very big to produce substantial amounts of accessory substance or waste material, especially waste liquid yield.
Contain acid, alkali, salt, halogen, hydrocarbon, nitro compounds, amine and dyestuff and intermediate etc. in dyestuff intermediate production waste water Material, benzidine, pyridine, ammonia, phenol and heavy metal Hg, cadmium, chromium in the waste water having in addition also containing severe toxicity etc.;In waste water COD value typically in more than 40000mg/L, for acid dyes, direct dyes and food colour, due to raw material often with Sulfonic acid group, it is soluble in water, cause these organic pollutions are more to be present in water-soluble state in waste water;Dyestuff is based on making when making It is general that there is preferably anti-light solution, the characteristic of anti-oxidant and antibiont degraded so that these waste water are conventional with stable consideration Method is difficult to handle.
The content of the invention
The present invention makes up the deficiencies of the prior art, there is provided one kind is based on Strong oxdiative and circulates among biochemical treatment dyestuff The method that body produces waste water, acid, alkali, the salt that this method can be eliminated in waste water disturb, decompose the organic matter for being difficult to degrade, eliminate Heavy metal in water body and free toxicant, the processing water finally given water quality, colourity etc. can reach compared with High discharge standard.
The present invention concrete technical scheme be:
Method based on Strong oxdiative and circulation biochemical treatment dyestuff intermediate production waste water, key point is methods described bag Include following steps:
A, progress water quality adjustment and runoff investigation in regulating reservoir are squeezed into after dyestuff intermediate being produced into wastewater collection;
Waste water after regulation is squeezed into progress two-stage multidimensional Strong oxdiative in two multidimensional Strong oxdiative equipment being sequentially connected B, Multidimensional Strong oxdiative equipment is filled with the two-dimentional electrolytic cell of granular electrode material, power frequency 20-30KHz, when continuing between electrode Between be 25-35min, into the waste water after multidimensional Strong oxdiative plus coagulant and flocculation aid, coagulant PAC, addition is the step The one thousandth of wastewater flow rate is to 3/1000ths in rapid, flocculation aid PAM, and addition is wastewater flow rate 5/10000ths to very much Two, flocculation sediment duration 2.5-3.5H;
C, the waste water after precipitation separation, which is squeezed into four biochemical systems being sequentially connected, carries out level Four circulation biochemistry, department of biochemistry System includes aeration tank, sedimentation basin and activating tank, and waste water is first squeezed into activating tank into caused sludge behind aeration tank and activated, Sludge after activation is returned again in aeration tank, aeration tank mesophytization time 8H, sludge reflux amount 60-80%, sludge concentration 8000mg/L, the waste water that end is aerated in aeration tank are squeezed into sedimentation basin, precipitate duration 3.5-4H, and the sludge of precipitation is first beaten Enter in activating tank and activated, the sludge after activation is returned in aeration tank, sludge reflux amount 60-80%, sludge concentration 8000mg/ L;
D, the waste water after circulation is biochemical carries out advanced treating, first adds coagulant and flocculation aid, coagulant PAC, addition For 5/3000ths to thousand/1000ths of wastewater flow rate in the step, flocculation aid PAM, addition is that wastewater flow rate is very much in the step 0. 2/50000ths to ten thousand, duration 2.5-3.5H, then carry out integrating adsorption filtration, duration 10-20min, Finally give qualified processing water.
In described step A, water quality adjustment includes the regulation of pH value, SS, COD and salinity, adjust to pH value, SS values, COD value and salinity value stabilization.
In described step B, the coagulant addition is 2/1000ths of wastewater flow rate in the step, and the flocculation aid adds Dosage be the step in wastewater flow rate a ten thousandth, flocculation sediment duration 3H.
In described step D, the coagulant addition is 4/1000ths of the step wastewater flow rate, the flocculation aid addition Measure as a ten thousandth of wastewater flow rate in the step, flocculation sediment duration 3H, adsorption filtration time 15min.
The present invention remarkable result be:The present invention eliminates the acid in waste water, alkali, salt environment by multidimensional Strong oxdiative, is Biochemical bacteria provides the existence interference adapted to, while electrode can directly degrade simple organic matter and will be difficult to the organic matter degraded Easily biodegradable organicses are decomposed into, degradable organic matter is decomposed into simple compound, and electrode can also be by the metal after ionization Heavy metal in ion and waste water carries out absorptive collection, and the multidimensional Strong oxdiative of two-stage ensures that acid, alkali, salt contain in waste water to greatest extent The growth of suitable biochemical bacteria is measured, while ensures that the content for being difficult to degradation of organic substances meets discharge standard, then passes through to greatest extent Heavy metal, free toxicant, halogen and inorganic compound in flocculation sediment separation waste water etc., level Four circulates biochemical mistake Cheng Caiyong sludge activations method both ensure that the elimination of residual organic contaminants, realize the decrement operation of sludge again, then by wadding Retrogradation shallow lake and adsorption filtration obtain qualified processing water, and the processing colority of water and dissolved oxygen content are obtained for improvement, are contaminated in water Material and its intermediate, the content for the organic matter for being difficult to degrade substantially reduce, the processing water disclosure satisfy that applied to landscape water spray, The occasions such as urban road sprinkling.
Brief description of the drawings
Fig. 1 is the schematic flow sheet of method in the present invention.
Embodiment
The present invention relates to the method based on Strong oxdiative and circulation biochemical treatment dyestuff intermediate production waste water, in this method Multidimensional Strong oxdiative equipment is that granular working electrode is loaded between the electrode of conventional two-dimensional electrolytic cell, and granular working electrode is diameter 5- 10mm graphite particle, multidimension electrode structure is formed after filling, multidimensional Strong oxdiative process is electro-catalysis, electric flocculation or electric Fenton At least one of, circulate biochemistry and carry out four times, regulations of the wastewater treatment process based on above-mentioned 2 points progress including regulating reservoir, Two-stage multidimensional Strong oxdiative, flocculation sediment, level Four circulate biochemical and final flocculation sediment and adsorption filtration, finally give and reach The processing water of discharge standard, this method can also be applied to the production wastewater treatment of coloring agent, agricultural chemicals and resin etc., this method Particular content in implementation process is illustrated by specific embodiment.
Specific embodiment, as shown in figure 1, the method for processing dyestuff intermediate production waste water comprises the following steps:
A, progress water quality adjustment and runoff investigation in regulating reservoir are squeezed into after dyestuff intermediate being produced into wastewater collection, water is adjusted Time 20H is saved, the volume of regulating reservoir is designed according to the treating capacity of the residence time, the yield of waste water and waste water, The treating capacity of dyestuff intermediate production waste water is 100-300m3/ d, water quality adjustment include the tune of pH value, SS, COD and salinity Section, adjust stable to pH value, SS values, COD value and salt content;
Waste water after regulation is squeezed into progress two-stage multidimensional Strong oxdiative in two multidimensional Strong oxdiative equipment being sequentially connected B, In multidimensional Strong oxdiative equipment, Strong oxdiative particle, example are produced by the direct degradation of organic substances of anode reaction, or by anode reaction A kind of strong oxidizer such as hydroxyl, oxygen, hydrogen peroxide, hydroxyl radical free radical, ozone, these strong oxidizers are optionally with giving up Organic pollution in water quickly occurs chain reaction and carries out oxidative degradation, is degraded to the small-molecule substance of easy biochemistry, this drop It is more thorough that solution method decomposes organic matter, and advantage is:1st, these granular working electrodes being filled between both positive and negative polarity improve Mass transfer in liquid phase efficiency and current efficiency;2nd, electronics transfer is only carried out between electrode and waste water component, and oxidation reaction relies on system Hydroxyl radical free radical is carried out caused by oneself, it is not necessary to adds decoction, non-secondary pollution;3rd, water inlet pollutant concentration high load capacity, COD Concentration may be up to tens thousand of mg/L, decolourize, detoxification significant effect, and percent of decolourization is up to more than 50-80%, organic pollutant degradation processing Course of reaction it is rapid, retention time of sewage is short, it is only necessary to which 30min, required equipment volume are small;4th, efficiently can remove simultaneously in waste water Ammonia nitrogen, total phosphorus and colourity;5th, reaction condition is gentle, is carried out under normal temperature and pressure, and operation is flexible, can be by changing voltage, electric current Reaction condition is adjusted at any time, and controllability is good;6th, floor space is small, and the completion time of project is short, and operating cost is low;7th, non-stripping property DSA sun Pole, electrodeless burn into problem of passivation, there is the characteristics of efficient, the long-life;
The power frequency 20-30KHz of multidimensional Strong oxdiative, duration 30min, electricity is utilized during first order Strong oxdiative Pole is ionized the acid in waste water, alkali, salt, and the circulation biochemistry bacterium then to carry out provides viability environment, and subsequent electrode is inhaled Metal ion and heavy metal Hg, cadmium, chromium for dissociating in attached waste water etc., while anode can be carried out water-soluble organic pollutant directly Connect degraded, degraded generates simple compound, and anode can also be by extremely toxic substance energy such as the benzidine for being difficult to degrade, pyridine, ammonia, phenol Degradable organic matter is enough broken down into, continues thereafter with and is decomposed into simple compounds, the Strong oxdiative particle of anode reaction generation is also Organic pollution can decompose to generation carbon dioxide and water, second level Strong oxdiative process by remnants be difficult to degradation of organic substances with And caused easily biodegradable organicses carry out Electrocatalytic Oxidation degraded after decomposing for the first time, reduce be difficult to degrade in waste water to greatest extent The content of organic matter, the material that acid, alkali, salt etc. can additionally be influenceed to biochemical bacterium ionize completely, improve life to greatest extent Change the living environment of bacterium, improve the biodegradability of waste water, Strong oxdiative terminates in backward waste water plus coagulant, flocculation aid, described mixed Solidifying agent is PAC, and addition is 2/1000ths of waste water weight in the step, and the flocculation aid is PAM, and addition is in the step The a ten thousandth of waste water weight, flocculation sediment duration 3H, heavy metal ion, free metal ion in waste water, halogen And inorganic compound carries out flocculation sediment, during flocculation sediment, the floccule absorption waste water of agglomerated particle is gradually formed The dyestuff and its intermediate of middle residual, the colourity of waste water significantly reduce;
C, the waste water after precipitation separation, which is squeezed into four biochemical systems being sequentially connected, carries out level Four circulation biochemistry, department of biochemistry Uniting includes aeration tank, sedimentation basin and activating tank, and caused sludge, which is first squeezed into activating tank, in aeration tank is activated, after activation Sludge is returned again in aeration tank, aeration tank mesophytization time 8H, sludge reflux amount 60-80%, sludge concentration 8000mg/L, is utilized The organic pollution of residual in aeration tank in the metabolic consumption waste water of aerobic bacteria, aeration process can also flocculate residual Precipitation particle is broken up, and discharges organic pollution therein, provides nutriment for comprehensive bacteria growing, improves the activity of comprehensive bacterium, Floccule after breaing up can carry out separation elimination by follow-up precipitation, and waste water is squeezed into precipitation by aeration tank mesophytization after terminating Chi Zhong, duration 3.5-4H is precipitated, the sludge of precipitation, which is first squeezed into activating tank, to be activated, and the sludge after activation returns to aeration Chi Zhong, sludge reflux amount 60-80%, sludge concentration 8000mg/L;
D, the waste water after circulation is biochemical carries out advanced treating, first adds coagulant and flocculation aid to carry out coagulating sedimentation, coagulant For PAC, addition is 4/1000ths of waste water weight in the step, and flocculation aid PAM, addition is waste water weight in the step A ten thousandth, duration 3H, then carry out integrating adsorption filtration, duration 15min, finally give qualified processing Water.

Claims (4)

1. the method based on Strong oxdiative and circulation biochemical treatment dyestuff intermediate production waste water, it is characterised in that methods described bag Include following steps:
A, progress water quality adjustment and runoff investigation in regulating reservoir are squeezed into after dyestuff intermediate being produced into wastewater collection;
Waste water after regulation is squeezed into progress two-stage multidimensional Strong oxdiative, multidimensional in two multidimensional Strong oxdiative equipment being sequentially connected B, Strong oxdiative equipment is filled with the two-dimentional electrolytic cell of granular electrode material between electrode, and power frequency 20-30KHz, the duration is 25-35min, into the waste water after multidimensional Strong oxdiative plus coagulant and flocculation aid, coagulant PAC, addition are in the step The one thousandth of wastewater flow rate is to 3/1000ths, flocculation aid PAM, addition for wastewater flow rate 1/10000th five to ten thousand/ Two, flocculation sediment duration 2.5-3.5H;
C, the waste water after precipitation separation, which is squeezed into four biochemical systems being sequentially connected, carries out level Four circulation biochemistry, biochemical system bag Aeration tank, sedimentation basin and activating tank are included, waste water is first squeezed into activating tank into caused sludge behind aeration tank and activated, and is activated Sludge afterwards is returned again in aeration tank, aeration tank mesophytization time 8H, sludge reflux amount 60-80%, sludge concentration 8000mg/L, The waste water that end is aerated in aeration tank is squeezed into sedimentation basin, precipitates duration 3.5-4H, and the sludge of precipitation first squeezes into activating tank In activated, sludge after activation is returned in aeration tank, sludge reflux amount 60-80%, sludge concentration 8000mg/L;
D, the waste water after circulation is biochemical carries out advanced treating, first adds coagulant and flocculation aid, coagulant PAC, addition is should 5th/3000th to thousand/1000ths of wastewater flow rate in step, flocculation aid PAM, addition are 1/10000th of wastewater flow rate in the step Point 2/50000ths to ten thousand, duration 2.5-3.5H, then carry out integrating adsorption filtration, duration 10-20min, finally Obtain qualified processing water.
2. the method according to claim 1 based on Strong oxdiative and circulation biochemical treatment dyestuff intermediate production waste water, its Be characterised by, in described step A, water quality adjustment includes the regulation of pH value, SS, COD and salinity, adjust to pH value, SS values, COD value and salinity value stabilization.
3. the method according to claim 1 based on Strong oxdiative and circulation biochemical treatment dyestuff intermediate production waste water, its It is characterised by, in described step B, the coagulant addition is 2/1000ths of wastewater flow rate in the step, the flocculation aid Addition be the step in wastewater flow rate a ten thousandth, flocculation sediment duration 3H.
4. the method according to claim 1 based on Strong oxdiative and circulation biochemical treatment dyestuff intermediate production waste water, its It is characterised by, in described step D, the coagulant addition is 4/1000ths of the step wastewater flow rate, and the flocculation aid adds Dosage be the step in wastewater flow rate a ten thousandth, flocculation sediment duration 3H, adsorption filtration time 15min.
CN201710439312.6A 2017-06-12 2017-06-12 Method based on Strong oxdiative and circulation biochemical treatment dyestuff intermediate production waste water Pending CN107381931A (en)

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Publication number Priority date Publication date Assignee Title
CN107973489A (en) * 2017-11-30 2018-05-01 瞿永顺 A kind of organic wastewater treating system of adsorbent burning regeneration
CN108947006A (en) * 2018-07-20 2018-12-07 江苏力祺环保科技有限公司 A kind of sewage water treatment method

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CN203976586U (en) * 2014-07-02 2014-12-03 山东国瑞环保产业有限公司 Printing and dyeing wastewater treatment system
CN105417894A (en) * 2016-01-05 2016-03-23 宜兴市永创环保科技有限公司 Treatment method for high-concentration wastewater difficult to degrade
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CN203976586U (en) * 2014-07-02 2014-12-03 山东国瑞环保产业有限公司 Printing and dyeing wastewater treatment system
CN105417894A (en) * 2016-01-05 2016-03-23 宜兴市永创环保科技有限公司 Treatment method for high-concentration wastewater difficult to degrade
CN105621603A (en) * 2016-01-05 2016-06-01 长沙奥邦环保实业有限公司 Returned sludge elutriation process of biological sewage treatment system

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107973489A (en) * 2017-11-30 2018-05-01 瞿永顺 A kind of organic wastewater treating system of adsorbent burning regeneration
CN108947006A (en) * 2018-07-20 2018-12-07 江苏力祺环保科技有限公司 A kind of sewage water treatment method

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Application publication date: 20171124