CN107381889A - A kind of circulating water treatment method - Google Patents

A kind of circulating water treatment method Download PDF

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Publication number
CN107381889A
CN107381889A CN201710693777.4A CN201710693777A CN107381889A CN 107381889 A CN107381889 A CN 107381889A CN 201710693777 A CN201710693777 A CN 201710693777A CN 107381889 A CN107381889 A CN 107381889A
Authority
CN
China
Prior art keywords
water
treatment method
circulating water
circulating
condensed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710693777.4A
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Chinese (zh)
Inventor
李玖彬
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qinghai Qing Shun Water Treatment Technology Extension Center
Original Assignee
Qinghai Qing Shun Water Treatment Technology Extension Center
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qinghai Qing Shun Water Treatment Technology Extension Center filed Critical Qinghai Qing Shun Water Treatment Technology Extension Center
Priority to CN201710693777.4A priority Critical patent/CN107381889A/en
Publication of CN107381889A publication Critical patent/CN107381889A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/441Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/469Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
    • C02F1/4693Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis electrodialysis

Abstract

The invention provides a kind of circulating water treatment method, including:Filtration treatment is carried out to industrial raw water, obtains the clear water for removing suspended impurity;The clear water for removing suspended impurity is subjected to reverse-osmosis treated, obtains primary production water and condensed water, wherein primary production water enters in circulating water pool and recycled;The condensed water that counter-infiltration is obtained carries out electrodialysis process, obtains afterproduct water and high power condensed water, and wherein afterproduct water enters in circulating water pool and recycled or returned in industrial raw water, and the high power condensed water, which enters in water storage box, to be used.The equipment amount that the present invention uses is few and small volume, removable chlorion are simple to operate without dosing.And the rate of recovery of waste water is high, caused a small amount of sewage can be used for flushing the toilet, ore cleaning, dedusting of irrigating the fields, efficiently utilize water resource.

Description

A kind of circulating water treatment method
Technical field
The present invention relates to water-treatment technology field, more particularly to a kind of circulating water treatment method.
Background technology
Currently known water technology has two major classes.The first kind is medicament water process, is added into recirculated water a certain amount of Chemical agent, prevent water in easy scale-forming ion be combined so as to reach improve recirculated water cycles of concentration purpose, make circulation Water utilization rate can improve, and shortcoming is that recirculated water cannot be concentrated infinitely, must have one after the cycles of concentration that water reaches certain Quantitative blowdown, so that recirculated water cycles of concentration balances;Second class is equipment water process, uses counter-infiltration, demineralizer or mixed bed Zwitterion in removing water is carried out Deng water treatment facilities, so as to reach the purpose of the removing circulation water hardness, but these equipment have One common disadvantage is that blowdown flow rate is big.
The content of the invention
Therefore, the present invention proposes one kind can use recirculated water with high usage, and at the recirculated water of without sewage discharge Reason method.
The invention provides a kind of circulating water treatment method, including:Filtration treatment is carried out to industrial raw water, obtains to remove and hangs The clear water of floating impurity;The clear water for removing suspended impurity is subjected to reverse-osmosis treated, primary production water and condensed water are obtained, wherein one Secondary product water, which enters in circulating water pool, to be recycled;The condensed water that counter-infiltration is obtained carries out electrodialysis process, obtains two Secondary product water and high power condensed water, wherein afterproduct water, which enter in circulating water pool, to be recycled or returns in industrial raw water, The high power condensed water enters in water storage box.
Further, described that industrial raw water is carried out in filtration step using filter, the filter of selection is multimedium Filter.
Further, the filtrate used in the more medium filter includes quartz sand, anthracite and manganese sand.
Further, described to carry out the clear water for removing suspended impurity in reverse-osmosis treated step, selection is hollow fibre The membrane separation plant of dimension formula or rolling.
Further, the membrane separation plant uses anisotropic membrane or composite membrane.
Further, the condensed water that counter-infiltration is obtained is carried out in electrodialysis process step, from pole-reversing electroosmosis EDR equipment.
Further, a kind of described circulating water treatment method also includes the high power condensed water in the water storage box being used in Water closet, in washup pond or sprinkling truck.
The equipment amount that the present invention uses is few and small volume, removable chlorion are simple to operate without dosing.And waste water The rate of recovery it is high, caused a small amount of sewage can be used for flushing the toilet, ore cleaning, dedusting of irrigating the fields, efficiently utilize water resource.
The additional aspect and advantage of the present invention will be set forth in part in the description, and will partly become from the following description Obtain substantially, or recognized by the practice of the present invention.
Brief description of the drawings
Fig. 1 is a kind of flow chart of circulating water treatment method of the embodiment of the present invention;
Fig. 2 is a kind of FB(flow block) of circulating water treatment method of the embodiment of the present invention.
Embodiment
Embodiments of the invention are described below in detail, the example of the embodiment is shown in the drawings, wherein from beginning to end Same or similar label represents same or similar element or the element with same or like function.Below with reference to attached The embodiment of figure description is exemplary, it is intended to for explaining the present invention, and is not considered as limiting the invention.
The embodiments of the invention provide a kind of circulating water treatment method, as shown in figure 1, including:
Step S1, filtration treatment is carried out to industrial raw water, obtains the clear water for removing suspended impurity.The filter of this step can From more medium filter, the more medium filter is to utilize one or more of filter mediums, under pressure turbid The higher water of degree is conventional so as to which effectively removing suspended impurity makes clarification of water by certain thickness granular or non-grain material Filtrate has quartz sand, anthracite, manganese sand etc., is mainly used in water process turbidity removal, softened water, prime pretreatment of pure water etc., water outlet Turbidity is up to less than 3 degree.
Step S2, the clear water for removing suspended impurity is subjected to reverse-osmosis treated, obtains primary production water and condensed water, wherein Primary production water, which enters in circulating water pool, to be recycled.What is selected in this step is hollow fiber form or the UF membrane of rolling Equipment, wherein permeable membrane are anisotropic membrane or composite membrane.Counter-infiltration is also known as reverse osmosis, be one kind using pressure differential as motive force, from The UF membrane operation of solvent is isolated in solution.Pressure is applied to the feed liquid of film side, it is molten when pressure exceedes its osmotic pressure Agent can make inverse osmosis against the direction of naturally osmotic, so as in the solvent that is passed through of low-pressure side of film, i.e., in this step Primary production water;The solution that high-pressure side is concentrated, i.e. condensed water.
Step S3, the condensed water that counter-infiltration is obtained carry out electrodialysis process, obtain afterproduct water and high power condensed water, Wherein afterproduct water enters in circulating water pool and recycles or return in industrial raw water, and the high power condensed water enters water storage In case.Preferably, the condensed water that counter-infiltration is obtained is carried out in electrodialysis process step, from the EDR of pole-reversing electroosmosis Equipment.EDR technologies are a kind of electrochemical desalination processes, and electrodialytic technique and ion exchange technique are organically combined together by it, Instead of traditional ion exchange resin technique, can effectively remove micro electrolytic ion impurity in water removal, have can continuously, nothing Acid-alkali regeneration is needed to have the function that concentrating and separating sewage.EDR equipment is mainly handed over by medium between anodic-cathodic plate, ion exchange resin, ion Change the composition such as film.When the ion in water is ion exchanged resin capture, water obtains desalting and purifying;In the presence of electric field, it is caught Cation permeable anode membrane, the anion-permeable cavity block obtained, after the ion permeable amberplex in the water including chlorion Collect discharge into concentrated water room.Under certain electric current, hydrone is ionized to H ﹢, OH ﹣ ions, and exhausted resin is regenerated, So as to realize continuous production water, cyclic regeneration.
In a specific embodiment of the invention, as shown in Fig. 2 the counter-infiltration rate of recovery of the clear water after 100 tons of filterings is 75%, the EDR rate of recovery are 90%, i.e. EDR only discharges 2.5 tons of waste water, can produce 75 tons of primary production water and 22.5 tons of secondary productions Product water.And discharge waste water be collected into water storage box, lavatory is washed in water closet, in washup pond washup stone or Person is used in place dedusting in sprinkling truck, the part water is fully used, has saved water resource.
The equipment amount that the present invention uses is few and small volume, removable chlorion are simple to operate without dosing.And waste water The rate of recovery it is high, caused a small amount of sewage can be used for flushing the toilet, ore cleaning, dedusting of irrigating the fields, efficiently utilize water resource.
Although embodiments of the invention have been shown and described above, it is to be understood that above-described embodiment is example Property, it is impossible to limitation of the present invention is interpreted as, one of ordinary skill in the art within the scope of the invention can be to above-mentioned Embodiment is changed, changed, replacing and modification.

Claims (7)

  1. A kind of 1. circulating water treatment method, it is characterised in that including:
    Filtration treatment is carried out to industrial raw water, obtains the clear water for removing suspended impurity;
    The clear water for removing suspended impurity is subjected to reverse-osmosis treated, obtains primary production water and condensed water, wherein primary production water Recycled into circulating water pool;
    The condensed water that counter-infiltration is obtained carries out electrodialysis process, afterproduct water and high power condensed water is obtained, wherein secondary production Product water, which enters in circulating water pool, to be recycled or returns in industrial raw water, and the high power condensed water enters in water storage box.
  2. 2. a kind of circulating water treatment method as claimed in claim 1, it is characterised in that described to use filter to industrial raw water Carry out in filtration step, the filter of selection is more medium filter.
  3. 3. a kind of circulating water treatment method as claimed in claim 2, it is characterised in that used in the more medium filter Filtrate includes quartz sand, anthracite and manganese sand.
  4. A kind of 4. circulating water treatment method as claimed in claim 1, it is characterised in that the clear water that suspended impurity will be removed Carry out in reverse-osmosis treated step, selection is hollow fiber form or the membrane separation plant of rolling.
  5. 5. a kind of circulating water treatment method as claimed in claim 4, it is characterised in that the membrane separation plant uses asymmetric Film or composite membrane.
  6. A kind of 6. circulating water treatment method as claimed in claim 1, it is characterised in that the condensed water for obtaining counter-infiltration Carry out in electrodialysis process step, from the EDR equipment of pole-reversing electroosmosis.
  7. 7. a kind of circulating water treatment method as any one of claim 1-6, it is characterised in that also include the storage High power condensed water in water tank is used in water closet, in washup pond or sprinkling truck.
CN201710693777.4A 2017-08-14 2017-08-14 A kind of circulating water treatment method Pending CN107381889A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710693777.4A CN107381889A (en) 2017-08-14 2017-08-14 A kind of circulating water treatment method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710693777.4A CN107381889A (en) 2017-08-14 2017-08-14 A kind of circulating water treatment method

Publications (1)

Publication Number Publication Date
CN107381889A true CN107381889A (en) 2017-11-24

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109354243A (en) * 2018-10-23 2019-02-19 浙江工贸职业技术学院 A kind of direct drinking water purification processing system
CN112981711A (en) * 2021-03-10 2021-06-18 福建绿阳新材科技有限公司 Water-saving production process of spunlace non-woven fabric
CN113153676A (en) * 2021-03-29 2021-07-23 童成双 Method and system for generating power by using temperature difference energy

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103508602A (en) * 2013-07-23 2014-01-15 南京九思高科技有限公司 Membrane and evaporation crystallization integrated process with zero discharge of high-salinity industrial wastewater
CN103723799A (en) * 2013-12-23 2014-04-16 北京京润新技术发展有限责任公司 Electrodialyzer and near-zero-release industrial wastewater recycling technique
CN103922537A (en) * 2014-04-04 2014-07-16 西安西热水务环保有限公司 System for recycling wastewater from circulating cooling water by adopting membrane process
JP2015029931A (en) * 2013-07-31 2015-02-16 三菱重工業株式会社 Desalination apparatus and desalination method, method for producing fresh water, and method for co-producing fresh water, salt and valuable-material
CN105000737A (en) * 2015-07-13 2015-10-28 浙江沐源环境工程有限公司 Industrial sewage treatment system and sewage treatment method

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103508602A (en) * 2013-07-23 2014-01-15 南京九思高科技有限公司 Membrane and evaporation crystallization integrated process with zero discharge of high-salinity industrial wastewater
JP2015029931A (en) * 2013-07-31 2015-02-16 三菱重工業株式会社 Desalination apparatus and desalination method, method for producing fresh water, and method for co-producing fresh water, salt and valuable-material
CN103723799A (en) * 2013-12-23 2014-04-16 北京京润新技术发展有限责任公司 Electrodialyzer and near-zero-release industrial wastewater recycling technique
CN103922537A (en) * 2014-04-04 2014-07-16 西安西热水务环保有限公司 System for recycling wastewater from circulating cooling water by adopting membrane process
CN105000737A (en) * 2015-07-13 2015-10-28 浙江沐源环境工程有限公司 Industrial sewage treatment system and sewage treatment method

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109354243A (en) * 2018-10-23 2019-02-19 浙江工贸职业技术学院 A kind of direct drinking water purification processing system
CN112981711A (en) * 2021-03-10 2021-06-18 福建绿阳新材科技有限公司 Water-saving production process of spunlace non-woven fabric
CN113153676A (en) * 2021-03-29 2021-07-23 童成双 Method and system for generating power by using temperature difference energy

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Application publication date: 20171124